SAFETY DATA SHEET
Tetrammine Platinum (II) Nitrate Solution
180244 Version Number 1.00
1. Identification of the substance/preparation and of the
company/undertaking
Identification of the substance or preparation
Product name : Tetrammine Platinum (II) Nitrate Solution
Company/undertaking identification
Manufacturer : Johnson Matthey Plc,
Orchard Road,
Royston,
Herts SG8 5HE
Emergency telephone number : 01763 253000
2. Composition/information on ingredients
Substance/preparation : Preparation
Ingredient name CAS % EC Number Classification
number
Nitric acid 7697-37-2 5 - 10 231-714-2 O; R8
C; R35
tetraammineplatinum dinitrate 20634-12-2 5.4 - 9.3 243-929-9 E; R1
O; R9
Xn; R22
See section 16 for the full text of the R Phrases
declared above
* Occupational Exposure Limit(s), if available, are listed in Section 8
3. Hazards identification
The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification : E; R1
O; R8, 9
C; R34
Physical/chemical hazards : Explosive when dry.
Contact with combustible material may cause fire.
Explosive when mixed with combustible material.
Human health hazards : Causes burns.
See section 11 for more detailed information on health effects and symptoms.
4. First aid measures
First aid measures
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Obtain medical attention immediately.
Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person. Obtain medical attention immediately.
Skin Contact : In case of contact, immediately flush skin copiously with water for at least 15 minutes
while removing contaminated clothing and shoes. Wash clothing before reuse.
Clean shoes thoroughly before reuse. Obtain medical attention immediately.
Eye contact : In case of contact, immediately flush eyes with a copious amount of water for at least
15 minutes. Obtain medical attention immediately.
See section 11 for more detailed information on health effects and symptoms.
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Tetrammine Platinum (II) Nitrate Solution
5. Fire-fighting measures
Extinguishing media : Use an extinguishing agent suitable for surrounding fires.
Special exposure hazards : This material increases the risk of fire and may aid combustion. Explosive when
mixed with combustible material.
Hazardous thermal : These products are nitrogen oxides (NO, NO2...). Some metallic oxides.
decomposition products
Special protective : Fire fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.
Remark : The residue, ash or char left after a fire may have catalytic properties and may
promote the re-ignition of flammable materials and vapours.
6. Accidental release measures
Personal Precautions : Immediately contact emergency personnel. Eliminate all ignition sources. Keep
unnecessary personnel away. Use suitable protective equipment (Section 8). Do not
touch or walk through spilled material.
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
Methods for cleaning up : If emergency personnel are unavailable, contain spilled material. For small spills add
absorbent (soil may be used in the absence of other suitable materials) and use a
non-sparking or explosion proof means to transfer material to a sealed, appropriate
container for disposal. For large spills dike spilled material or otherwise contain
material to ensure runoff does not reach a waterway. Place spilled material in an
appropriate container for disposal.
7. Handling and storage
Handling : Do not get in eyes, on skin or on clothing. Keep container closed. Use only with
adequate ventilation. Do not breathe vapour or mist. Store in tightly-closed container.
Avoid contact with combustible materials. Wash thoroughly after handling.
Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area.
Separate from acids, alkalis, reducing agents and combustibles.
Packaging materials
Recommended : Use original container.
8. Exposure controls/personal protection
Ingredient name Occupational exposure limits
Nitric acid EH40-OES (United Kingdom (UK), 1/2003).
STEL: 10 mg/m3 15 minute(s). Form: All forms
STEL: 4 ppm 15 minute(s). Form: All forms
TWA: 5.2 mg/m3 8 hour(s). Form: All forms
TWA: 2 ppm 8 hour(s). Form: All forms
tetraammineplatinum dinitrate EH40-OES (United Kingdom (UK)). Notes: Platinum compounds,
soluble
TWA: 0.002 mg/m3 8 hour(s).
Exposure controls
Occupational exposure : Use explosion-proof electrical (ventilating, lighting and material handling) equipment.
controls Provide exhaust ventilation or other engineering controls to keep the airborne
concentrations of vapours below their respective occupational exposure limits.
Ensure that eyewash stations and safety showers are close to the workstation
location.
Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary.Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the
safe working limits of the selected respirator.
Hand protection : Chemical-resistant, impervious gloves or gauntlets complying with an approved
standard should be worn at all times when handling chemical products if a risk
assessment indicates this is necessary.
Eye protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts.
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Skin protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist before
handling this product.
9. Physical and chemical properties
General information
Appearance
Physical state : Liquid.
Colour : Colourless.
Odour : Acidic.
Important health, safety and environmental information
Boiling point : The lowest known value is 83.89掳C (183掳F) (Nitric acid).
Melting point : May start to solidify at -41.11掳C (-42掳F) based on data for: Nitric acid.
Relative density : >1
10. Stability and reactivity
: Unstable. (tetraammineplatinum dinitrate)
Stability
Conditions to Avoid : Explosive when dry. (tetraammineplatinum dinitrate)
Incompatibility : Avoid contact with organic materials.
Explosibility : Explosive when dry.
11. Toxicological information
Potential acute health effects
Inhalation : Corrosive to the respiratory system.
Ingestion : May cause burns to mouth, throat and stomach.
Skin Contact : Corrosive to the skin.
Eye contact : Corrosive to eyes.
Acute toxicity
Product/ingredient name Test Result Route Species
Nitric acid LDLo 430 mg/kg Oral human
tetraammineplatinum dinitrate LD50 >1500 mg/kg Oral Rat
similar material (tetraammineplatinum dinitrate)
Over-exposure signs/symptoms
Target organs : Contains material which causes damage to the following organs: lungs, mucous
membranes, upper respiratory tract, skin, eye, lens or cornea, teeth.
12. Ecological information
Biodegradability Not available.
Other adverse effects : No known significant effects or critical hazards.
Not available.
13. Disposal considerations
Methods of disposal : Return accumulated waste material to the refinery for metal recovery, or dispose of in
accordance with local and national regulations.
14. Transport information
International transport regulations
Regulatory UN number Proper shipping name Class Packing group Label Additional
information Information
ADR/RID Class UN3139 OXIDIZING LIQUID, N.O.S. 5.1 II Limited quantity
(tetraammineplatinum LQ10
dinitrate)
5.1
CEFIC Tremcard
51GO1-I+II+III
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Tetrammine Platinum (II) Nitrate Solution
IMDG Class UN3139 OXIDIZING LIQUID, N.O.S. 5.1 II Emergency
(tetraammineplatinum schedules (EmS)
dinitrate) F-A, S-Q
5.1
IATA Class UN3139 Oxidizing liquid, n.o.s. 5.1 II Quantity limitation -
(tetraammineplatinum Passenger Aircraft -
dinitrate) Limited quantity
5.1
0.5 L
Quantity limitation -
Passenger Aircraft
1L
Quantity limitation -
Cargo Aircraft
5L
15. Regulatory information
EU Regulations
Hazard symbol(s) :
Oxidising, Corrosive
Risk Phrases : R1- Explosive when dry.
R8- Contact with combustible material may cause fire.
R9- Explosive when mixed with combustible material.
R34- Causes burns.
Safety Phrases : S7- Keep container tightly closed.
S17- Keep away from combustible material.
S26- In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S36/37/39- Wear suitable protective clothing, gloves and eye/face protection.
S45- In case of accident or if you feel unwell, seek medical advice immediately (show
the label where possible).
Product use : Classification and labelling have been performed according to EU directives
67/548/EEC, 1999/45/EC, including amendments and the intended use.
- Industrial applications.
16. Other information
Full text of R phrases : R1- Explosive when dry.
referred to in sections 2 and R8- Contact with combustible material may cause fire.
3 - United Kingdom (UK) R9- Explosive when mixed with combustible material.
R22- Harmful if swallowed.
R34- Causes burns.
R35- Causes severe burns.
Full text of classifications : E - Explosive
referred to in sections 2 and O - Oxidising
3 - United Kingdom (UK) C - Corrosive
Xn - Harmful
History
Date of printing : 29/04/2005.
: 29/04/2005.
Date of issue
Date of previous issue : No Previous Validation.
Version : 0.02
Notice to reader
This information relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process. Such information is given in good faith, being based on the latest information available to Johnson Matthey PLC
and is to the best of Johnson Matthey PLC's knowledge and belief, accurate and reliable at the time of preparation. However, no
representation, warranty or guarantee is made as to the accuracy, liability or completness and Johnson Matthey PLC assumes no
responsibility therefore, and disclaims any liability for any loss, damage or injury howsoever arising (including in respect of any claim
brought by any third party) incurred using this information. The product is supplied on the condition that the user accepts responsibility to
satisfy himself as to the suitability and completeness of such information for his own particular use. Freedom from patent or any other
proprietary rights of any third party must not be assumed.
Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)
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Tetrammine Platinum (II) Nitrate Solution
Johnson Matthey National Sales Offices
Johnson Matthey .PLC Orchard Road, Royston Hertfordshire, SG8 5HE England Tel:+44(0)1763 253000 Fax: +44
(0)1763 253668
Johnson Matthey PLC 33 Jeffreys Road, Brimsdown, Enfield, Middlesex, EN3 7PW United Kingdom Tel: 0208 8048 8111
Fax: 020 8804 1918
Johnson Matthey& Co G.m.b.H, Steckhovengasse 12, 1132 WIEN, 脰sterreich Tel:877 98 90 Fax: 877 98 933
S.A. Johnson Matthey N.V 8 Avenue de Bale, 1140 Brussel,Belgi毛 / Belgique Tel:2 729 0711 Fax:2 216 9061
Johnson Matthey A/S Frederikssundsvej 274 D,Br垄nsh垄j 2700, Denmark Tel:38 89 62 00 Fax:38 89 62 01
Oy Johnson Matthey A.B Kielotie 7A 4KRS, 01300 Bantaa, Soumi Tel:08574 800 Fax: 08574 807
Johnson Matthey GmbH Alfa Products. Zeppelinstrasse 7, Postfach 6540,D-7500 Karlsruhe 1, Deutschland Tel:721
8400 70 Fax: 721 849674
Johnson Matthey SA 13 Rue de la Perdrix, Z1 Paris Nord 11, BP 50240, 95996 Roissy,CDG Cedix France Tel:1 48 63
22 99 Fax:1 48 63 27 02
Johnson Matthey GmbH Otto-Volger-Strasse 9B, D-65843 Sulzbach/Ts, Deutschland Tel:(0 61 96)70 38-21 Fax:(0 61
96)70 38 12
Johnson Matthey. PLC Unit 1-2, Blanchardstown Business Centre, Clonsilla Road, Blanchardstown, Dublin 15 Republic
of Ireland Tel 1 820 7722 Fax:1 820 7733
Johnson Matthey A.B. Victor Hasselblads Gata 8, S-421 31 V盲stra Fr枚lunda, Sverige Tel:031 891390 Fax: 031 477795
Johnson Matthey & Brandenberger A.G. Glattalstrasse 18, CH-8052 Zurich, Switzerland Tel:01 307 1919 Fax:01 307
1920
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