Material Name: LAWX 321 Adhesive Material Safety Data
Sheet ID: 2016
Section 1 - Chemical Product and Company Identification
Product Name LAWX 321 Adhesive
CAS# Mixture
Generic Name Adhesive (Latex)
Formula Mixture
Chemical Name: Mixture
Manufacturer Information
Johns Manville Insulation Group Telephone: 303-978-2000 8:00AM-5:00PM M-F
Building Insulation Division Internet Address: http://www.jm.com
P.O. Box 5108 Emergency: 800-424-9300 (Chemtrec, In English)
Denver, CO 80127 USA
Trade Names: 321 Adhesive
Section 2 - Composition / Information on Ingredients
CAS # Component Percent
Proprietary Butadiene/polyvinylidene polymer 40-60
21645-51-2 Aluminum trihydrate 0-20
1309-64-4 Antimony trioxide 7-12
1163-19-5 Decabromodiphenyl oxide 7-10
7732-18-5 Water 10-30
1309-42-8 Magnesium hydroxide 3-8
148-79-8 Thiabendazole [fungicide) 0-5
Not Available Surfactants & thickening agents 0-5
Additional Component Information
Note: Due to the product form, exposures to hazardous dusts or fumes are not expected to occur. Exposure limits are given
for reference only.
Section 3 - Hazards Identification
Emergency Overview
APPEARANCE AND ODOR: Off-white liquid of medium viscosity. Slight latex odor.
Under normal conditions of use and handling, this product is not expected to create any health or safety hazards.
Potential Health Effects
Summary
Due to the form of the product hazardous exposures are unlikely to occur. Exposure may cause slight temporary irritation to
skin, eyes, nose, or throat.
Inhalation
Due to the form of the product hazardous exposures are unlikely to occur. Exposure may cause slight temporary irritation to
skin, eyes, nose, or throat.
Skin
Temporary irritation of the skin may occur in some individuals.
Ingestion
This product is not intended to be ingested or eaten under normal conditions of use. If ingested, it may cause nausea and
systemic poisoning.
Eyes
Temporary irritation or redness may occur.
Primary Routes of Entry (Exposure)
Inhalation, skin, and eye contact.
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Material Name: LAWX 321 Adhesive Material Safety Data
Sheet ID: 2016
Target Organs
Skin, eyes, nose, throat.
Medical Conditions Aggravated by Exposure
None.
Section 4 - First Aid Measures
First Aid: Inhalation
Remove to fresh air. If symptoms persist contact a physician.
First Aid: Skin
Remove contaminated clothing. Wash exposed areas with soap and water. If irritation develops or persists, seek medical
attention. Launder contaminated clothing before reuse.
First Aid: Ingestion
This product is not intended to be ingested or eaten. If this product is ingested, do not induce vomiting. Drink plenty of water.
Contact a physician immediately.
First Aid: Eyes
Flush eyes with large amounts of water for 5-20 minutes. Contact a medical professional.
First Aid: Notes to Physician
Treat symptomatically. Emesis may be indicated in recent (within 30 minutes) ingestion of large quantities.
Section 5 - Fire Fighting Measures
Flash Point: Not applicable Method Used: Not applicable
Upper Flammable Limit (UFL): Not applicable Lower Flammable Limit (LFL): Not applicable
Auto Ignition: None known Flammability Classification: Not determined
Rate of Burning: Not determined
General Fire Hazards
Combustibility depends on the product form. As latex, the material is not combustible. The dried resin, however, is
combustible, similar to wood. Burning resin emits dense, black smoke.
Extinguishing Media
Dry chemical, foam, carbon dioxide, water fog.
Fire Fighting Equipment/Instructions
No special procedures are expected to be necessary for this product. Normal fire fighting procedures should be followed to
avoid inhalation of smoke and gases.
Section 6 - Accidental Release Measures
Containment Procedures
Dam, mop, absorb onto sawdust or other absorbent, and place in suitable container. Do not allow liquid to contaminate
sewers, or other water sources.
Clean-Up Procedures
Dispose of spilled material in approved landfill or incinerate in compliance with federal, state and local regulations. If you are
unsure of the regulations, contact your local Public Health Department, or the local office of the Environmental Protection
Agency (EPA).
Section 7 - Handling and Storage
Handling Procedures
Use protective equipment as described in Section 8 of this material safety data sheet when handling uncontained material.
Store at temperatures between 4掳-43掳C/40掳-110掳F.
Storage Procedures
Warehouse storage should be in accordance with package directions, if any. Material should be kept dry, and protected from
moisture.
Section 8 - Exposure Controls / Personal Protection
Exposure Guidelines
A: General Product Information
No information available for the product.
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Material Name: LAWX 321 Adhesive Material Safety Data
Sheet ID: 2016
B: Component Exposure Limits
Antimony trioxide (1309-64-4)
ACGIH: 0.5 mg/m3 TWA (related to Antimony)
OSHA: 0.5 mg/m3 TWA (related to Antimony)
PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Eyes/Face
Safety glasses with sideshields, chemical goggles, or face mask recommended.
Personal Protective Equipment: Skin
Any chemical impervious glove may be used to protect skin.
Personal Protective Equipment: Respiratory
Respiratory protection is not required if mechanical or dilution ventilation is sufficient to keep the exposure levels below the
applicable exposure limits.
Ventilation
Local exhaust or general dilution ventilation should be provided to keep exposure levels below the applicable exposure limits.
Personal Protective Equipment: General
An apron or coveralls impervious to chemicals can be used to protect clothing. Wash exposed skin after contact, before breaks
and meals, and at end of work period.
Section 9 - Physical & Chemical Properties
Appearance: Odor:
Off-white liquid of medium Slight latex
viscosity
Physical State: pH:
Liquid 9.0
Vapor Pressure: Vapor Density:
17.5 mm Hg 1 (20潞C/68潞F)
Boiling Point: Melting Point:
100潞C/212潞F Not applicable
Solubility (H2O): Specific Gravity:
<40% 1.32
Freezing Point: Evaporation Rate:
Not determined Same as water
Viscosity: Percent Volatile:
2,200 cps (#3 at 12 rpm) 39%
VOC: Not applicable
Section 10 - Chemical Stability & Reactivity Information
Chemical Stability
This is a stable material.
Incompatibility
Cationic chemicals and mineral acids.
Hazardous Decomposition
Dried films forced to burn will produce carbon monoxide, carbon dioxide, smoke, antimony halides, and hydrogen bromide.
Hazardous Polymerization
Will not occur.
Section 11 - Toxicological Information
Acute Toxicity
A: General Product Information
Skin, eye, and upper respiratory irritation may occur after contact with product.
B: Component Analysis - LD50/LC50
Aluminum trihydrate (21645-51-2)
Oral LD50 Rat: >5000 mg/kg
Antimony trioxide (1309-64-4)
Oral LD50 Rat: >34600 mg/kg
Water (7732-18-5)
Oral LD50 Rat: >90 mL/kg
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Material Name: LAWX 321 Adhesive Material Safety Data
Sheet ID: 2016
Decabromodiphenyl oxide (1163-19-5)
Inhalation LC50 Rat: >48.2 mg/L/1H; Oral LD50 Rat: >2000 mg/kg; Dermal LD50 Rabbit: >2000 mg/kg
Magnesium hydroxide (1309-42-8)
Oral LD50 Rat: 8500 mg/kg
Thiabendazole [fungicide) (148-79-8)
Oral LD50 Rat: 2080 mg/kg
Carcinogenicity
A: General Product Information
The Occupational Safety and Health Administration (OSHA), National Toxicology Program (NTP), International Agency for
Research on Cancer (IARC), and American Conference of Governmental Industrial Hygienists (ACGIH) have not classified
this product as a carcinogen.
B: Component Carcinogenicity
Antimony trioxide (1309-64-4)
ACGIH: A2 - Suspected Human Carcinogen (production)
IARC: Group 2B - Possibly Carcinogenic to Humans (IARC Monograph 47 [1989])
Decabromodiphenyl oxide (1163-19-5)
IARC: Group 3 - Not Classifiable (IARC Monograph 71 [1999] Monograph 48 [1990])
Chronic Toxicity
Inhalation of antimony trioxide dust has been shown to cause lung and liver cancer in animals, but carcinogenicity in humans
has not been established. Due to product form, exposures to hazardous dusts are not expected to occur.
Section 12 - Ecological Information
Ecotoxicity
A: General Product Information
No data available for this product.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
Antimony trioxide (1309-64-4)
96 Hr LC50 Pimephales promelas: 833.0 mg/L; 96 Hr LC50 Lepomis macrochirus: 530 mg/L; 96 Hr LC50 Brachydanio rerio:
>1000 mg/L [static]
72 Hr EC50 Selenastrum capricornutum: 67 mg/L
7 Hr EC50 Pseudomonas putida: >3.5 mg/L
48 Hr EC50 Daphnia magna: >1000 mg/L
Decabromodiphenyl oxide (1163-19-5)
72 Hr EC50 Skeletonema costatum: >1 mg/L
Section 13 - Disposal Considerations
US EPA Waste Number & Descriptions
A: General Product Information
Wastes are not hazardous as defined by the Resource Conservation and Recovery Act (RCRA; 40 CFR 261). Comply with
state and local regulations for disposal of solid wastes. If you are unsure of the regulations, contact your local Public Health
Department, or the local offices of the Environmental Protection Agency (EPA).
B: Component Waste Numbers
No EPA Waste Numbers are applicable for this product's components.
Disposal Instructions
Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations.
Section 14 - Transportation Information
Shipping Name: This product is not classified as hazardous for transportation.
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Material Name: LAWX 321 Adhesive Material Safety Data
Sheet ID: 2016
Section 15 - Regulatory Information
US Federal Regulations
A: General Product Information
SARA 311/312: This product is not classified as hazardous under SARA 311/312.
B: Component Analysis
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355
Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).
Antimony trioxide (1309-64-4)
SARA 313: 1.0 % de minimis concentration (related to Antimony)
CERCLA: 1000 lb final RQ; 454 kg final RQ
Decabromodiphenyl oxide (1163-19-5)
SARA 313: 1.0 % de minimis concentration
State Regulations
A: General Product Information
Other state regulations may apply. Check individual state requirements.
B: Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:
Component CAS # CA FL MA MN NJ PA
Antimony trioxide 1309-64-4 Yes No Yes Yes Yes Yes
Decabromodiphenyl oxide 1163-19-5 No No Yes Yes Yes Yes
The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65):
WARNING! This product contains a chemical known to the state of California to cause cancer.
Antimony trioxide CAS# 1309-64-4
A: TSCA Status
This product and its components are listed on the TSCA 8(b) inventory.
The following components listed in this product are listed on the TSCA Export Notification 12(b) list.
TSCA 12(b)
Component CAS TSCA 12 (b)
Decabromodiphenyl oxide 1163-19-5 Yes
B: Component Analysis - Inventory
Component CAS # TSCA DSL EINECS
Aluminum trihydrate 21645-51-2 Yes Yes Yes
Antimony trioxide 1309-64-4 Yes Yes Yes
Water 7732-18-5 Yes Yes Yes
Decabromodiphenyl oxide 1163-19-5 Yes Yes Yes
Magnesium hydroxide 1309-42-8 Yes Yes Yes
Thiabendazole [fungicide) 148-79-8 Yes No Yes
Component Analysis - WHMIS IDL
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:
Component CAS # Minimum Concentration
Antimony trioxide 1309-64-4 1%
Section 16 - Other Information
Other Information
Prepared for:
Johns Manville
Building Insulation Division
P.O. Box 5108
Denver, CO 80217-5108
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Page 5 of 6 Issue Date: 08/03/2006 Revision: 1.0303
Material Name: LAWX 321 Adhesive Material Safety Data
Sheet ID: 2016
Prepared by:
Johns Manville Technical Center
P.O. Box 625005
Littleton, CO USA 80162-5005
As of the date of preparation of this document, the foregoing information is believed to be accurate and is provided in good
faith to comply with applicable federal and state law(s). However, no warranty or representation with respect to such
information is intended or given.
The information herein is presented in good faith and believed to be accurate as of the effective date given. However, no
warranty, expressed or implied, is given. It is the buyer's responsibility to ensure that its activities comply with Federal, State or
provincial, and local laws.
Date MSDS # Reason
08/01/00 2016-1.0000 New MSDS authoring system.
10/14/02 2016-1.0100 Updated Sect. 15 for TSCA 12B: Decabromodiphenyl oxide has
been delisted.
10/27/03 2016-1.0101 Section 15, TSCA 12b, add Decabromodiphenyl oxide; Update
Section 15, State data, Antimony trioxide
11/26/03 2016-1.0102 Section 16 division change from RID to BID
07/14/05 2016-1.0103 Regulatory update: Section15
09/29/05 2016-1.0104 319, 320, and 322 Adhesives were removed from trade names.
Obsolete products. Section 2: 4-methylphenol was removed from
composition.
08/02/06 2016-1.0105 Edited Material Name from LAWX Adhesive to LAWX 321
Adhesive.
This is the end of MSDS # 2016
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