BASF Corporation
MATERIAL SAFETY DATA SHEET EMERGENCY TELEPHONE NUMBERS:
Agricultural Products Group
BASF Corporation: 1 (800) 832-HELP
P.O.Box 13528,
Research Triangle Park, NC 27709 CHEMTREC: 1 (800) 424-9300
(919) 547-2000
Product No.: 579717 Phantom庐 termiticide-insecticide
Date Prepared: 8/3/2000 Date Revised: 3/14/2002
SECTION I
Trade Name: Phantom庐 termiticide-insecticide
Chemical Name: 4-bromo-2-(4-chlorophenyl)-1-ethoxymethyl-5-(trifluoromethyl)-1H-pyrrole-3-carbonitrile
Synonyms: chlorfenapyr, CL 303,630 Formula: C(15) H(11) Br Cl F(3) N(2) O
Chemical Family: Pyrrole Mol Wt: 407.62
SECTION II - INGREDIENTS
COMPONENT CAS NO. % PEL/TLV - SOURCE
CL 303,630 Technical (chlorfenapyr) 122453-73-0 21.44 None established
Propylene glycol 57-55-6 7.50 None established
Inerts N/A 71.06 None established
SARA Title III Section 313: Not listed
SECTION III - PHYSICAL DATA
BOILING/MELTING POINT@760mm Hg: N/D pH: 6.87 @ 2% dispersion
VAPOR PRESSURE mmHg @ 20潞C: N/D
SPECIFIC GRAVITY OR BULK DENSITY: 1.16 g/mL @ 20潞 C
SOLUBILITY IN WATER: Disperses
APPEARANCE: Tan liquid ODOR: Sweet INTENSITY: Mild
SECTION IV - FIRE AND EXPLOSION DATA
FLASH POINT (TEST METHOD): N/D AUTOIGNITION TEMP: N/D
FLAMMABILITY LIMITS IN AIR (% BY VOL): LOWER: N/D UPPER: N/D
NFPA 704 HAZARD CODES
FLAMMABLE: N/R INSTABILITY: N/R OTHER: N/R
HEALTH: N/R
NFPA 30 STORAGE CLASSIFICATION: N/R
EXTINGUISHING Use water fog, foam, CO(2), or dry chemical extinguishing media.
MEDIUM
SPECIAL Firefighters should be equipped with self-contained breathing apparatus and turnout gear.
FIREFIGHTING Decontaminate emergency personnel with soap and water before leaving the fire area.
PROCEDURES
UNUSUAL FIRE None known.
EXPLOSION
HAZARDS
SELECT ACRONYM KEY
N/A - Not available; N/D - Not determined; N/R - Not rated; N/E - Not established
Page 1 of 4
Product No.: 579717 Phantom庐 termiticide-insecticide BASF Corporation
SECTION V - HEALTH DATA
TOXICOLOGICAL TEST DATA:
Data for the formulated product:
Rat (male), Oral LD50 = 560 mg/kg
Rat (female), Oral LD50 = 567 mg/kg
Rabbit, Dermal LD50 > 2000 mg/kg
Rat, males Inhalation LC50 (4 hr) = 0.571 mg/L
Rat, females Inhalation LC50 (4 hr) = 2.43 mg/L
Rabbit, Eye Irritation - Slightly irritating
Rabbit, Skin Irritation - Slightly irritating
Guinea pig, Dermal Sensitizer - Not a sensitizer
Note: Inhalation data for mists were not used to classify this material for transportation because it is
reasonably foreseeable that such concentrations (mists) would not be encountered by a human during transport
49 CFR 173.132 (b) (3) 0 - 0
OSHA, NTP, or IARC Carcinogen: Not listed.
EFFECTS OF OVEREXPOSURE:
See Product Label and Directions For Use for additional precautionary statements.
CAUTION
Harmful if swallowed, inhaled or absorbed through the skin. Causes moderate eye irritation. Do not get in eyes,
on skin, or on clothing. Avoid breathing vapors or spray mist. Remove contaminated clothing and wash clothing before reuse.
Existing medical conditions aggravated by this product:
None known.
FIRST AID PROCEDURES
Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able
If swallowed:
to swallow. Do not induce vomiting unless told to by a poison control center or doctor. Do not give anything to
an unconscious person.
Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison
If on skin or clothing:
control center or doctor for treatment advice.
Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration,
If inhaled:
preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice.
Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present,
If in eyes:
after first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.
Have the product container or label with you when calling a poison control center or doctor or going for
Note:
treatment.
SECTION VI - REACTIVITY DATA
STABILITY: Stable. Do not store below 32潞 F. Donot store in heat or in sunlight.
Store in original container in cool,dry, well ventilated place away from ignition
CONDITIONS TO AVOID:
sources, heat or flame.
Oxidizing agents.
CHEMICAL INCOMPATIBILITY:
Oxides of carbon and nitrogen, acid halides.
HAZARDOUS DECOMPOSITION PRODUCTS:
Does not occur.
HAZARDOUS POLYMERIZATION:
Does not polymerize.
CONDITIONS TO AVOID:
No OXIDIZER: No
CORROSIVE TO METAL:
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Product No.: 579717 Phantom庐 termiticide-insecticide BASF Corporation
SECTION VII - PERSONAL PROTECTION
Users of a pesticidal end use product should refer to the product label for personal protective equipment
requirements.
RECOMMENDATIONS FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING
WORKERS:
Respiratory Protection:
Supplied air respirators should be worn if large quantities of mist/dust are generated or prolonged exposure
possible.
Eye Protection:
Chemical goggles when respirator does not provide eye protection.
Protective Clothing:
Long-sleeved shirt, slacks, shoes and socks, chemically resistant gloves such as barrier laminate
Ventilation:
Whenever possible, engineering controls should be used to minimize the need for personal protective
equipment.
or butyl rubber, or nitrile rubber or neoprene or polyvinyl chloride (PVC) or viton (> 14 mils).
SECTION VIII - ENVIRONMENTAL DATA
ENVIRONMENTAL TOXICITY DATA
This product is toxic to aquatic organisms, birds, and wildlife.
SARA 311/312 REPORTING
FIRE:N PRESSURE: N REACTIVITY: N ACUTE: Y CHRONIC: N TPQ(lbs): N/R
SPILL AND LEAK PROCEDURES:
In case of large scale spillage of this product, avoid contact, isolate area and keep out animals and unprotected
persons. Call CHEMTREC (800 424-9300) or BASF Corporation (800 832-HELP). For a small spill, wear personal
protective equipment as specified on the label.
FOR A LIQUID SPILL: Dike and contain the spill with inert material (sand, earth , etc.) and transfer the liquid and
solid diking materials to separate containers for disposal.
FOR A SOLID SPILL: Sweep solid into a drum for re-use or disposal. Remove personal protective equipment
and decontaminate it prior to re-use.
HAZARDOUS SUBSTANCE SUPERFUND: No RQ(lbs): None
WASTE DISPOSAL METHOD:
Pesticide wastes are acutely hazardous. Wastes resulting from this product may be disposed of on site or at an
approved waste disposal facility. Improper disposal of excess pesticide, spray mix or rinsate is a violation of
federal law. If these wastes cannot be disposed of according to label instructions, contact the state agency
responsible for pesticide regulation or the Hazardous Waste representative at the nearest EPA Regional Office for
guidance.
HAZARDOUS WASTE 40CFR261: No HAZARDOUS WASTE NUMBER: None
CONTAINER DISPOSAL:
FOR PLASTIC CONTAINERS: Triple rinse (or equivalent) and add rinsate to the spray tank. Then offer for
recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or by incineration, or if allowed by state
and local authorities, by burning. If burned, stay out of smoke.
FOR BULK CONTAINERS: Reusable containers should be returned to the point of purchase for cleaning and re-
filling.
FOR MINIBULK CONTAINERS: Clean all tanks on an approved loading pad so rinsate can be collected and
mixed into the spray solution or into a dedicated tank. Using a high pressure sprayer, rinse several times with
small volumes of water to minimize rinsate.
Page 3 of 4
Product No.: 579717 Phantom庐 termiticide-insecticide BASF Corporation
SECTION IX - SHIPPING DATA - PACKAGE AND BULK
D.O.T. PROPER SHIPPING NAME (49CFR172.101-102): HAZARDOUS SUBSTANCE
(49CFR CERCLA LIST):
None
RQ(lbs): None
D.O.T. HAZARD CLASSIFICATION (CFR 172.101-102):
PRIMARY SECONDARY
None
D.O.T. LABELS REQUIRED (49CFR172.101-102): D.O.T. PLACARDS POISON CONSTITUENT
REQUIRED (CFR172.504): (49CFR172.203(K)):
None None None
BILL OF LADING DESCRIPTION
Insecticides, NOIBN
Not applicable None
CC NO.: UN/NA CODE:
SECTION X - ADDITIONAL INFORMATION
Phantom庐 termiticide-insecticide
Do not store in heat or in sun light.
EPA Reg. No. 241-392
KEEP OUT OF REACH OF CHILDREN
CAUTION
BASF Corporation
Agricultural Products Group
P.O.Box 13528,
Research Triangle Park, NC 27709
(919) 547-2000
DISCLAIMER
IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE
PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE
ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND
THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR
PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESS OR IMPLIED, INCLUDING
WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE
REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE
PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL
PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR
DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER,
YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND
INFORMATION FURNISHED BY BASF HEREUNDER ARE GIVEN GRATIS AND BASF ASSUMES NO
OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR
RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK.
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