Material Safety Data Sheet according 91/155/EEC
Product Name : 278000 Glaze Brush fix, Standard
Date: 23.06.06 Revision date: 12.06.06 page: 1/5
1. IDENTIFICATION OF THE PREPARATION AND COMPANY
Product Name and Code : Glaze Brush fix, Standard 278000
NAME AND FULL ADDRESS OF COMPANY:
Heinrich K枚nig & Co. KG
An der Rosenhelle 5
D-61138 Niederdorfelden
EMERGENCY-CALL OF COMPANY : +49 6101 53 60 50 (R&D)
Telephone number (in general) : +49 6101 53 60 0
Telefax number : +49 6101 53 60 11
2. COMPOSITION/INFORMATION ON INGREDIENTS
Substances presenting a health hazard within the meaning of the Dangerous
Substances Directive 67/548/EEC.
EINECS-No. Names
R-phrases Symb. Conc.
203-132-9 propylbenzene
103-65-1 10-37-51/53-65 Xn,N < 0.5
203-604-4 1,3,5-trimethylbenzene, mesitylene
108-67-8 10-37-51/53 Xi,N < 0.5
200-751-6 butan-1-ol, n-butanol
71-36-3 10-22-37/38-41-67 Xn 5 - 10
205-500-4 ethyl acetate
141-78-6 11-36-66-67 Xi,F 25 - 50
203-539-1 1-methoxy-2-propanol, monopropylene glycol methyl ether
107-98-2 10 12.5 - 20
204-658-1 n-butyl acetate
123-86-4 10-66-67 12.5 - 20
200-578-6 ethanol
64-17-5 11 F 5 - 10
200-661-7 isopropanol, isopropyl alcohol, propan-2-ol
67-63-0 11-36-67 Xi,F 5 - 10
202-436-9 1,2,4-trimethylbenzene
95-63-6 10-20-36/37/38-51/53 Xn,N 0.5 - 1
265-199-0 Solvent naphtha (petroleum), light arom.; Low boiling point
64742-95-6 naphtha - unspecified
65 Xn 1 - 2.5
See full text of R-phrases under chapter 16
3. HAZARDS IDENTIFICATION OF THE PREPARATION
Danger classification : Xi Irritant
F Highly flammable
36 Irritating to eyes.
66 Repeated exposure may cause skin dryness or cracking.
67 Vapours may cause drowsiness and dizziness.
4. FIRST AID MEASURES
General: In all cases of doubt, or when symptoms persist, seek medical
attention. Never give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air, keep patient warm and at rest, if breathing
is irregular or stopped, administer artificial respiration. Give nothing by
mouth. If unconscious place in recovery position and seek medical advice.
Material Safety Data Sheet according 91/155/EEC
Product Name : 278000 Glaze Brush fix, Standard
Date: 23.06.06 Revision date: 12.06.06 page: 2/5
Eye contact: Remove contact lenses, irrigate copiously with clean, fresh water
for at least 10 minutes, holding the eyelids apart and seek medical advice.
Skin contact: Remove contaminated clothing. Wash skin thoroughly with soap
and water or use recognised skin cleanser. Do NOT use solvents or thinners.
Ingestion: If accidentally swallowed obtain immediate medical attention.
Keep at rest. Do NOT induce vomiting.
5. FIRE-FIGHTING MEASURES
Extinguishing media: recommended: alcohol resistant foam, CO2, powders,
water spray
not to be used: water jet.
Recommendations: Fire will produce dense black smoke. Exposure to
decomposition products may cause a health hazard. Appropriate breathing
apparatus may be required. Cool closed containers exposed to fire with water.
Do not allow run-off from fire fighting to enter drains or watercourses.
6. ACCIDENTAL RELEASE MEASURES
Exclude sources of ignition and ventilate the area. Avoid breathing vapours.
Refer to protective measures listed in sections 7 and 8. Contain and collect
spillage with non-combustible absorbent materials, e.g. sand, earth,
vermiculite, diatomaceous earth and place in container for disposal according
to local regulations (see section 13). Do not allow to enter drains or
watercourses. Clean preferably with a detergent; avoid use of solvents.
If the product contaminates lakes, rivers or sewages, inform appropriate
authorities in accordance with local regulations.
7. HANDLING AND STORAGE
Handling
Vapours are heavier than air and may spread along floors. Vapours may form
explosive mixtures with air. Prevent the creation of flammable or explosive
concentrations of vapour in air and avoid vapour concentration higher than
the occupational exposure limits. In addition, the product should only be
used in areas from which all naked lights and other sources of ignition have
been excluded. Electrical equipment should be protected to the appropriate
standard. Preparation may charge electrostatically: always use earthing
leads when transferring from one container to another. Operators should wear
antistatic footwear and clothing and floors should be of the conducting type.
Keep container tightly closed. Isolate from sources of heat, sparks and open
flame. No sparking tools should be used. Avoid skin and eye contact. Avoid
inhalation of dust, particulates and spray mist arising from the application
of this preparation. Avoid inhalation of dust from sanding. Smoking, eating
and drinking should be prohibited in application area. For personal protection
see Section 8. Never use pressure to empty : container is not a pressure
vessel. Always keep in containers of same material as the original one.
Comply with the health and safety at work laws.
Storage
Although the storage and use of this product is not subject to specific
statutory requirements, observation of the principles of the Highly Flammable
Liquids and Liquefied Petroleum Gases Regulations as appropriate will be seen
as good industrial practice in meeting the general duties of the Health and
Safety at Work Act. Observe label precautions. Store between 15 and 30掳C in
a dry, well ventilated place away from sources of heat and direct sunlight.
Keep away from sources of ignition. Keep away from oxidizing agents,
from strongly alkaline and strongly acid materials. No smoking. Prevent
unauthorized access. Containers which are opened must be carefully resealed
and kept upright to prevent leakage.
Material Safety Data Sheet according 91/155/EEC
Product Name : 278000 Glaze Brush fix, Standard
Date: 23.06.06 Revision date: 12.06.06 page: 3/5
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Measures
Provide adequate ventilation. Where reasonably practicable this should be
achieved by the use of local exhaust ventilation and good general extraction.
If these are not sufficient to maintain concentrations of particulates and
solvent vapour below the OEL, suitable respiratory protection must be worn.
Exposure Limits
Occupational exposure limit for :
EINECS-No. Names STEL LTEL
200-751-6 butan-1-ol, n-butanol 50.000 0.000 ppm
205-500-4 ethyl acetate 400.000 ppm
203-539-1 1-methoxy-2-propanol, monopropylene glycol methyl ether
300.000 100.000 ppm
204-658-1 n-butyl acetate 200.000 150.000 ppm
200-578-6 ethanol 1000.000 ppm
200-661-7 isopropanol, isopropyl alcohol, propan-2-ol
500.000 400.000 ppm
265-199-0 Solvent naphtha (petroleum), light arom.; Low boiling point
naphtha unspecified 50.000 ppm
Personal Protection
Respiratory protection: If workers are exposed to concentrations above
the exposure limit they must use appropriate, certified respirators.
Hand protection: For prolonged or repeated handling, use suited gloves
(EN 374). Barrier creams may help to protect the exposed areas of the skin,
they should however not be applied once exposure has occurred.
Eye protection: Use safety eyewear designed to protect against splash of
liquids.
Skin protection: Personnel should wear antistatic clothing made of natural
fibre or of high temperature resistant synthetic fibre.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state : viscous. Method:
flash point : 18 c.c.
viscosity at 掳C:
specific gravity : 0.89
vapour density : 42
lower explosion limit: 1.9
solubility in water : not soluble
10. STABILITY AND REACTIVITY
Stable under recommended storage and handling conditions (See section 7).
When exposed to high temperatures may produce hazardous decomposition
products such as carbon monoxide and dioxide, smoke, oxides of nitrogen
etc. Keep away from oxidising agents, strongly alkaline and strongly acid
materials in order to avoid exothermic reactions.
NONE OF THE UPPER DESCRIBED DECOMPOSED PRODUCTS WILL OCCUR UNDER NORMAL
CONDITIONS AND PROPER USE !
11. TOXICOLOGICAL INFORMATION
There are no data available on the preparation itself. The preparation has
been assessed following the conventional methods of the Dangerous Preparations
Directive 1999/45/EC and classified for toxicological hazards accordingly.
See Chapter 2 and 15 for details. Exposure to component solvents vapours
concentration in excess of the stated occupational exposure limit may result
in adverse health effects such as mucous membrane and respiratory system
irritation and adverse effects on kidney, liver and central nervous system.
Material Safety Data Sheet according 91/155/EEC
Product Name : 278000 Glaze Brush fix, Standard
Date: 23.06.06 Revision date: 12.06.06 page: 4/5
Symptoms and signs include headache, dizziness, fatigue, muscular weakness,
drowsiness and in extreme cases, loss of consciousness. Solvents may cause
some of the above effects by absorption through the skin. Repeated or
prolonged contact with the preparation may cause removal of natural fat
from the skin resulting in non-allergic contact dermatitis and absorption
through the skin. The liquid splashed in the eyes may cause irritation and
reversible damage.
12. ECOLOGICAL INFORMATION
The product should not be allowed to enter drains or watercourses.
13. DISPOSAL CONSIDERATIONS
Do not allow into drains or watercourses. Wastes and emptied containers
should are to be deposited according to the official rules.
Code of waste Waste Designation:
080111 waste paint and varnish containing organic solvents or
other dangerous substances
14. TRANSPORT INFORMATION
Transport only in accordance with ADR for road, RID for rail, IMDG for
sea and ICAO/IATA for air transport.
ADR/RID Class: 3
Tremcard: 3
UN-No: 1263
Transport document name: PAINT
SONDERVORSCHRIFT 640D
Packaging Group: II
IMDG-Class : 3
Tremcard : 3
UN-No : 1263
EmS-Nr. : F-E, S-E
Proper shipping name: PAINT
Packaging group : II
Marine pollutant: n.a.
ICAO/IATA Class: 3
UN No: 1263
Proper shipping name: PAINT
Packaging group: II
15. REGULATORY INFORMATION
In accordance with requirements of the Classification Packaging and
Labelling of Dangerous Substances Regulations.
The product is labelled as follows :
Danger classification :
Xi Irritant
F Highly flammable
Contains: n.a.
R-phrases:
36 Irritating to eyes.
66 Repeated exposure may cause skin dryness or cracking.
67 Vapours may cause drowsiness and dizziness.
Material Safety Data Sheet according 91/155/EEC
Product Name : 278000 Glaze Brush fix, Standard
Date: 23.06.06 Revision date: 12.06.06 page: 5/5
S-phrases:
16 Keep away from sources of ignition - No smoking.
24 Avoid contact with skin.
26 In case of contact with eyes, rinse immediately with
plenty of water and seek medical advice.
51 Use only in well-ventilated areas.
other phrases: n.a.
16. OTHER INFORMATION
Full text of R-phrases with no. appearing in section 2:
10 Flammable.
37 Irritating to respiratory system.
51/53 Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
65 Harmful: may cause lung damage if swallowed.
22 Harmful if swallowed.
37/38 Irritating to respiratory system and skin.
41 Risk of serious damage to eyes.
67 Vapours may cause drowsiness and dizziness.
11 Highly flammable.
36 Irritating to eyes.
66 Repeated exposure may cause skin dryness or cracking.
20 Harmful by inhalation.
36/37/38 Irritating to eyes, respiratory system and skin.
The information of this SDS is based on the present state of our knowledge
and on current EU and national laws. The product is not to be used for other
purposes than those specified under section 1 without first obtaining
written handling instruction. It is always the responsibility of the user
to take all necessary steps in order to fulfil the demand laid down in
the local rules and legislation. The information in this SDS is meant as
a description of the safety requirements of our product: it is not to be
considered as a guarantee of the products' properties.
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