Material Safety Data Sheet
CREW SHOWER, TUB & TILE CLEANER HC
Fire Hazard
National Fire Hazardous Material Health 3
Protection Information System
0 Fire Hazard 0
30
Health Reactivity
Association (NFPA) (HMIS)
0
Reactivity
Specific Hazard
Emergency Dark Red. Liquid. See Section 9.
Protective
DANGER. CORROSIVE. CAUSES EYE AND SKIN BURNS.
Clothing Overview
HARMFUL OR FATAL IF SWALLOWED.
Section 1. Chemical Product and Company Identification
4970 & 3063453 &
Code
CREW SHOWER, TUB & TILE CLEANER HC
Product Name
3063461
PMS#
Industrial/Institutional: Washroom care. This product is intended 3131954
Product Use
to be diluted prior to use.
7/23/2003
114608002 Validation Date
MSDS#
7/23/2003
Print Date
U.S. Headquarters Canadian Headquarters
JohnsonDiversey, Inc. JohnsonDiversey - Canada, Inc. 7/23/2003.
Supersedes
8310 16th Street 2401 Bristol Circle
(800) 851-7145
In Case of
Sturtevant, Wisconsin 53177-0902 Oakville, Ontario L6H 6P1
Emergency
Phone: (800) 725-6737 Phone: 1-888-746-5971
MSDS Internet Address:
www.johnsondiversey.com
Section 2. Composition and Information on Ingredients
Ingredients CAS # % by Weight Exposure Limits LC50/LD50
Diethyl phthalate 84-66-2 0.1 - <1.0 ACGIH (United States). Not available.
TWA: 5 mg/m3
OSHA (United States).
TWA: 5 mg/m3
Fragrance 1-5 Not available. Not available.
Sodium Lauriminodipropionate 14960-06-6 1-5 Not available. Not available.
Alcohol Ethoxylates 68439-46-3 10-30 Not available. ORAL (LD50): Acute: 1378
mg/kg [Rat]. DERMAL (LD50):
Acute: >2000 mg/kg [Rabbit].
Phosphoric Acid 7664-38-2 30-60 OSHA (United States). ORAL (LD50): Acute: 1530
TWA: 1 mg/m3 mg/kg [Rat]. DERMAL (LD50):
STEL: 3 mg/m3 Acute: 2740 mg/kg [Rabbit].
ACGIH (United States).
TWA: 1 mg/m3
STEL: 3 mg/m3
Water 7732-18-5 30-60 Not available. Not available.
Section 3. Hazards Identification
Eye contact. Skin contact Inhalation.
Routes of Entry
Potential Acute Health Effects
Eyes Corrosive. May cause permanent damage including blindness.
Skin Corrosive. May cause permanent damage.
Inhalation May cause irritation and corrosive effects to nose, throat and respiratory tract.
Ingestion Corrosive. May cause burns to mouth, throat, and stomach.
Individuals with chronic respiratory disorders such as asthma, chronic bronchitis, emphysema, etc., may
Medical Conditions
Aggravated by Overexposure: be more susceptible to irritating effects.
See Toxicological Information (section 11)
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Material Safety Data Sheet
CREW SHOWER, TUB & TILE CLEANER HC
Section 4. First Aid Measures
Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Get medical
Eye Contact
attention immediately.
Flush immediately with plenty of water for at least 15 minutes. Get medical attention immediately.
Skin Contact
If breathing is difficult: Remove to fresh air. Get medical attention immediately.
Inhalation
Do not induce vomiting! Immediately drink one cupful of water or milk. Never give anything by mouth to an
Ingestion
unconscious person. Get medical attention immediately.
Section 5. Fire Fighting Measures
Flammability of the Product None known.
Closed cup: >93.333掳C (200掳F).
Flash Points
None known.
Products of Combustion
Extinguish with water spray or carbon dioxide, dry chemical powder or appropriate foam. Normal fire
Fire Fighting Media
fighting procedure may be used.
and Instructions
Put on appropriate personal protective equipment (see Section 8.).
Protective Clothing (Fire)
Special Remarks on Fire and Corrosive material (See sections 8 and 10).
Explosion Hazards
Section 6. Accidental Release Measures
Put on appropriate personal protective equipment (see Section 8.).
Personal Precautions
In the event of major spillage: Use appropriate containment to avoid environmental contamination. Sweep
Environmental Precautions
or scrape up material. Place in suitable clean, dry containers for disposal by approved methods. Use a
and Clean-up Methods
water rinse for final clean-up.
Section 7. Handling and Storage
Avoid contact with eyes, skin and clothing. Do not taste or swallow. Avoid breathing vapors or spray
Handling
mists. Wash thoroughly after handling. Remove and wash contaminated clothing and footwear before
re-use. Product residue may remain on/in empty containers. All precautions for handling the product must
be used in handling the empty container and residue. FOR COMMERCIAL AND INDUSTRIAL USE
ONLY.
Store in a dry, cool and well-ventilated area. Protect from freezing. Keep container tightly closed. KEEP
Storage
OUT OF REACH OF CHILDREN.
Section 8. Exposure Controls/Personal Protection
Good general ventilation should be sufficient to control airborne levels. Respiratory protection is not
Engineering Controls
required if good ventilation is maintained.
Personal Protection
Eyes Chemical splash goggles.
Hands Chemical resistant gloves. Includes: Neoprene gloves. Rubber gloves.
Respiratory If mists/vapors are not adequately controlled by ventilation, use appropriate respiratory protection to avoid
over exposure. A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2
requirements must be followed whenever workplace conditions warrant a respirator's use.
Feet Protective footwear.
Body If major exposure is possible, wear suitable protective clothing and footwear.
Section 9. Physical and Chemical Properties
Liquid.
Physical State and
Appearance
Powder.
Odor
Dark Red.
Color
<1[Acidic.]
pH
1.4
Specific Gravity
>93掳C (200掳F)
Boiling/Condensation Point
0掳C (32掳F)
Melting/Freezing Point
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Material Safety Data Sheet
CREW SHOWER, TUB & TILE CLEANER HC
Dispersible.
Solubility in water
Section 10. Stability and Reactivity
Stability and Reactivity The product is stable.
None known.
Conditions of Instability
Incompatibility with Various Reactive with alkalis. Slightly reactive to reactive with metals. Avoid mixing with: Chlorine products. Can
react to give chlorine gas. If this occurs leave area immediately. Do not return for half hour.
Substances
When exposed to fire: Produces normal products of combustion. Toxic decomposition products include:
Hazardous Decomposition
Oxides of phosphorous.
Products
Will not occur.
Hazardous Polymerization
Section 11. Toxicological Information
Corrosive.
Acute toxicity
Effects of Chronic Exposure None known.
None known.
Other Toxic Effects
Section 12. Ecological Information
Not available.
Section 13. Disposal Considerations
Undiluted product is regulated under environmental and transportation laws as a corrosive waste. Dispose
Waste Information
of according to all federal, state and local regulations.
Section 14. Transport Information
DOT Classification
Please refer to the Bill of Lading/receiving documents for up to date shipping information.
DOT Proper
Shipping Name
TDG Classification
Please refer to the Bill of Lading/receiving documents for up to date shipping information.
TDG Proper
Shipping Name
TDG Class
Section 15. Regulatory Information
Reporting in this section is based on ingredients disclosed in Section 2
US Regulations
Federal SARA 313 toxic chemical notification and release reporting: Phosphoric Acid
Clean Water Act (CWA) 307: Diethyl phthalate
Clean Water Act (CWA) 311: Phosphoric Acid
CERCLA: Hazardous substances.: Phosphoric Acid, Diethyl phthalate
State New Jersey spill list: Phosphoric Acid, Diethyl phthalate
New Jersey: Phosphoric Acid, Diethyl phthalate
Massachusetts spill list: Phosphoric Acid, Diethyl phthalate
Massachusetts RTK: Phosphoric Acid, Diethyl phthalate
Pennsylvania RTK: Phosphoric Acid, Diethyl phthalate
This product is not subject to the reporting requirements under California's Proposition 65.
Registered Product Not applicable.
Information
Canadian Regulations
Canadian NPRI Canadian NPRI: Phosphoric Acid, Diethyl phthalate.
WHMIS Classification Class E: Corrosive liquid.
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Material Safety Data Sheet
CREW SHOWER, TUB & TILE CLEANER HC
WHMIS Icon
Registered Product Not applicable.
Information
All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control
Chemical Inventory Status
Act (TSCA) Chemical Substance Inventory
Section 16. Other Information
Not available.
Other Special
Considerations
2.01
Version
Notice to Reader
This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied,
as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to
evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws
and regulations.
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