Material Safety Data Sheet
Conforming to EC Guide 91/155/EWG
Date of Preparation: 9/22/98 Revision: August 2003
Page 1 of 4
Section 1 - Chemical Product and Company Identification
Product/Chemical Name: LAMCHEM PAP-75
Chemical Formula: NA
CAS Number: see Section 2
Other Designations: Phenyl Acid Phosphate, 75%
General Use:
Manufacturer: Lambent Technologies
7247 N. Central Park Avenue
Skokie, IL 60076-4093
USA
Phone: 847-675-3950
Fax: 847-675-3013
Section 2 鈥? Preparation Composition / Information on Ingredients
Ingredient Name EINECS Number CAS Number % wt or
% vol
Phosphoric acid monophenyl ester 701-64-4 30-60
221-917-4
Phosphoric acid diphenyl ester 838-85-7 30-60
212-657-2
Butanol 71-36-3 24-26
200-751-6
Phenol 108-95-2 0-10
203-632-7
The ingredients of this product are all on the TSCA Inventor list.
OSHA PEL ACGIH TLV NIOSH PEL NIOSH
Ingredient TWA STEL TWA STEL TWA STEL IDLH
Butanol 100 ppm 150 ppm C 50 ppm 100 ppm 150 ppm 8000 ppm
Phenol 5 ppm 15.6 ppm 5 ppm none estab. 5 ppm 15.6 ppm 250 ppm
Section 3 - Hazards Identification
R23 Toxic by inhalation.
R24/25 Toxic in contact with skin and if swallowed.
R34 Causes burns
Section 4 鈥? Safety Phrases and First Aid Measures
S24 Avoid contact with skin
S25 Avoid contact with eyes
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S27 Take off immediately all contaminated clothing
S28 After contact with skin, wash immediately with plenty of water
S36/37/39* Wear suitable protective clothing, gloves and eye/face
Protection
S45 In case of accident or you feel unwell seek medical advise immediately
Section 5 - Fire-Fighting Measures
Suitable Extinguishers: Dry chemical, foam, Halon, CO2, water spray or fog. Water stream may splash NFPA
burning liquid and spread flame.
2
Unusual Fire or Explosion Hazards: Forms irritating oxides of phosphorous upon burning.
0
2
Hazardous Combustion Products: Oxides of phosphorous, carbon monoxide and carbon dioxide.
Acid
Fire-Fighting Instructions: Do not release runoff from fire control methods to sewers or waterways.
Fire-Fighting Equipment: Because fire may produce toxic thermal decomposition products, wear a self-contained breathing
apparatus (SCBA) with a full facepiece operated in pressure-demand or positive-pressure mode.
MSDS No. 6 Trade Name: LAMCHEM PAP-75 Revision: 4, August 2003
Page 2 of 4
Section 6 - Accidental Release Measures
Spill /Leak Procedures: Remove sources of ignition, contain spill to smallest area possible. Stop leak if possible
Small Spills: Pick up small spills with acid neutralizing absorbent material such as sodium bicarbonate or soda ash.
Large Spills: Recover large spills for salvage or disposal.
Containment: For large spills, dike far ahead of liquid spill for later disposal. Do not release into sewers or waterways.
Cleanup: Wash hard surface with safety solvent or detergent to remove remaining oil film. Greasy nature will result in a
slippery surface.
Section 7 - Handling and Storage
Handling Precautions: Do not use near heat, spark, or open flame. Do not puncture, drag, or slide this container. Drum is not a
pressure vessel; never use pressure to empty drum. Empty container may contain flammable vapors.
Storage Requirements:
S7 Store in closed containers between 50 掳F and 120 掳F.
S9 Store and use in well-ventilated areas.
S13 Keep away from food, drink and animal feedingstuff
S14 Keep away from oxidizing agents, excessive heat, and ignition sources.
Do not store in direct sunlight.
Section 8 - Exposure Controls and Protection of the Body
Ventilation:
S9 Keep container in well ventilated place
S51 Use only in well ventilated areas
Respiratory Protection:
S23 Do not breath vapors or mist
S38 Incase of insufficient ventilation, wear suitable respiratory equipment
Protective Clothing/Equipment:
S36 Wear suitable protective clothing
S37 Wear suitable gloves
S39 Wear eye/face protection
Contaminated Equipment:
S27 Take off immediately any contaminated clothing
Comments:
S20 When using, do not eat or drink
Section 9 - Physical and Chemical Properties
Flash Point: >140 掳F (60 掳C)
9.1 Appearance
Condition: liquid Flash Point Method: COC
Color: pale yellow LEL: 1.4 % v/v
Smell: butanol odor UEL: 11.2% v/v
Water Solubility: 2% by volume, readily dispersible at
9.2 Safety Data
Vapor Pressure: 2 mm Hg at 68 掳F (20 掳C) higher concentrations.
Boiling Point: >243 掳F (>117 掳C)
Vapor Density (Air=1): 1.5
Density: 9.84 Freezing/Melting Point: NA
Specific Gravity (H2O=1, at 4 掳C): 1.18 Evaporation Rate Butyl acetate=1: <1
pH: 10% aqueous 0.9
Section 10 - Stability and Reactivity
Conditions to Avoid: Keep away from oxidizing agents, heat, sparks or flame. Do not store in sunlight.
Revision: 4 Trade Name: LAMCHEM PAP-75 MSDS No. 6
Page 3 of 4
Section 11- Toxicological Information
Toxicity Data:*
Eye Effects: Causes burns Acute Inhalation Effects:
Human, inhalation, Butanol TCLo: 50ppm
Skin Effects: Causes burns Human, inhalation, Phenol TCLo: 5ppm
Acute Oral Effects:
Rat, oral, LD50: Phenol 530 mg/kg
Rat, oral, LD50: Butanol 4360 mg/kg
Section 12 - Ecological Information
Ecotoxicity: NA
Environmental Fate: NA
Environmental Degradation: NA
Soil Absorption/Mobility: NA
Section 13 - Disposal
Disposal:
S35 This material and its container must be disposed of in a safe way.
S56 Dispose of this material and its container to hazardous or special waste collection point
Section 14 - Transport Information
Transport by rail, Road tankers, or bulk ships in containers of high-quality steel or in barrels of plastic lined steel or
polyethylene.
This product is one of the group of Dangerous Goods as defined by international transport regulations
U.S. D.O.T. and IATA Data (U.S. 49 CFR 172.101):
Shipping Name: Toxic Liquid, Packaging Authorizations Quantity Limitations
Corrosive, Organic, n.o.s. a) Exceptions: none a) Passenger, Aircraft, or Railcar: 1 L
b) Non-bulk Packaging: 173.202 b) Cargo Aircraft Only: 30 L
Shipping Symbols:
UN Hazard Class: UN 2927 c) Bulk Packaging: 173.243
DOT Hazard Class: 6.1, II Vessel Stowage Requirements
(Subsidiary risk: 8,II Corrosive) a) Vessel Stowage: B
ID No.: UN2927 b) Other: 40
Packing Group: II
Label: 6.1 8
Special Provisions (172.102):
T42
MSDS No. 6 Trade Name: LAMCHEM PAP-75 Revision: 4, August 2003
Page 4 of 4
Section 15 - Regulatory Information
Labeling to conform to EC Guides:
LAMCHEM PAP-75 UN:2927
Contains: BUTANOL-norm, PHENOL
TOXIC CORROSIVE
Too many Risk/Safety phrases 鈥? see below for full list.
Lambent Technologies Corp., 7247 North Central Park Avenue
Skokie, IL 60076, U.S.A.
Risk and safety phrase details
Toxic in contact with skin and if swallowed. Causes burns, irritating to respiratory system. Vapors may cause drowsiness
and dizziness.
Avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice. Take off immediately all contaminated clothing. Wear suitable protective clothing, gloves and eye/face
protection. In case of insufficient ventilation, wear suitable respiratory equipment. In case of accident or if you feel
unwell, seek medical advice immediately (show the label where possible). This material and its container must be
disposed of a hazardous waste.
National Regulations:
Substances Hazardous to Water Classification: WGK 2 T: R24/25 C: R34 XI: R37 R67
US EPA Regulations:
RCRA Hazardous Waste Number: (40 CFR 261.33) Phenol U188; Butanol U031
RCRA Hazardous Waste by Characteristic: corrosive
CERCLA Hazardous Substance (40 CFR 302.4) Phenol listed specific per RCRA, Sec. 3001; CWA, Sec. 311 (b)(4); CWA,
Sec. 307(a), CAA, Sec. 112; Butanol listed specific per RCRA, sec. 3001
CERCLA Reportable Quantity (RQ), Phenol 1,000 lb. (454 kg) Butanol 5,000 lb. (2,270)
SARA 311/312 Codes: An immediate health hazard. A delayed health hazard. A fire hazard.
SARA Toxic Chemical (40 CFR 372.65): Phenol, CAS Number: 108-95-2, Concentration: 10% max.
SARA EHS (Extremely Hazardous Substance) (40 CFR 355): Phenol listed, Threshold Planning Quantity (TPQ) 500 lbs.
U.S. OSHA Regulations:
Air Contaminant (29 CFR 1910.1000, Table Z-1, Z-1-A): Not listed
OSHA Specifically Regulated Substance (29CFR 1910.1200) Phenol is considered a hazardous ingredient.
Section 16 - Other Information
Prepared By: Joseph E. Lohr, Jr.
Revision Notes: Transferred from 14-Section MSDS
Revision Notes: #2, #3 and #4 add label to section 15; correct NFPA ratings; add Risk/Safety phrases to reflect changes.
Additional Hazard Rating Systems: The General Administrative rules governing the identification of hazardous-to-water
substances and their classification according to their hazardous nature-VwV of Hazardous-to-Water Substances (VwVwS) of 9
March 1990.
Disclaimer: This information relates only to the specific material designated and may not be valid for such material used in
combination with any other materials or in any other process. Such information is to the best of the company鈥檚 knowledge and
believed accurate and reliable as of the date indicated. However, no representation, warranty or guarantee of any kind, express
or implied, is made as to its accuracy, reliability or completeness, and we assume no responsibility for any loss, damage or
expense, direct or consequential, arising out of use. It is the user鈥檚 responsibility to satisfy himself as to the suitableness and
completeness of such information for his own particular use.
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