Page 1/7
Material Safety Data Sheet
According to 91/155 EEC
Printing date 10.05.2006 Reviewed on 17.03.2006
Hazardous according to criteria of Worksafe Australia
1 Identification of the substance/preparation and of the company/undertaking
路 Product details
路 Trade name: Easy Paper Box 110 CD-R
路 Article number: 5KPGL, 5LC4P
路 Application of the substance / the preparation Photographic colour developer concentrate
路 Manufacturer/Supplier:
a&o imaging solutions GmbH
Chemische Fabrik Vaihingen/Enz (former AGFA / AgfaPhoto)
Steinbeisstrasse 49
D-71665 Vaihingen/Enz
Germany
distributed by :
Photo Direct P/L
Suite 2, 358 Whitehorse Rd
Nunawading Vic 3131
Australia
Phone: + 61 3 9894 1644
Fax: + 61 3 9894 1677
路 Further information obtainable from:
Productmanagement, Tel.: + 49 7042 913-41, Fax: + 49 7042 913-18
路 Information in case of emergency:
Australia / New Zealand :
The Australian Centre for Occupational Health & Safety (ACOHS Pty Ltd)
6 Burleigh Court, Nunawading, VIC 3131
Phone : 1800 638 556 (24 hours, 7 days a week)
2 Composition/information on ingredients
路 Chemical characterization
路 Description: Mixture of substances listed below with nonhazardous additions.
路 Dangerous components:
CAS: 584-08-7 potassium carbonate 11.0%
EINECS: 209-529-3
p-Phenylendiamin-Derivat (ACD 3) 6.2%
CAS: 111-46-6 2,2'-oxybisethanol 4.9%
EINECS: 203-872-2
CAS: 3710-84-7 N,N-diethylhydroxylamine 3.0%
EINECS: 223-055-4
CAS: 26099-09-2 Belclene 200 2.5%
CAS: 1310-58-3 potassium hydroxide 2.0%
EINECS: 215-181-3
路 Additional information: For the wording of the listed risk phrases refer to section 16.
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(Contd. on page 2)
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Material Safety Data Sheet
According to 91/155 EEC
Printing date 10.05.2006 Reviewed on 17.03.2006
Trade name: Easy Paper Box 110 CD-R
(Contd. of page 1)
3 Hazards identification
路 Hazard description:
Irritant
Dangerous for the environment
路 Information concerning particular hazards for human and environment:
Th e prod uct h as to b e lab elled due t o the calcu lat ion procedure o f the " Gen eral C lassifi cati on
guideline for preparations of the EU" in the latest valid version.
Irritating to eyes and skin.
May cause sensitisation by skin contact.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
路 Classification system:
The classification is according to th e latest edit ions of the EU-lists, and extended by company and
literature data.
4 First aid measures
路 After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
路 After skin contact: Immediately wash with water and soap and rinse thoroughly.
路 After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
路 After swallowing: If symptoms persist consult doctor.
5 Fire-fighting measures
路 Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
路 Protective equipment: No special measures required.
6 Accidental release measures
路 Person-related safety precautions: Not required.
路 Measures for environmental protection:
Inform respective authorities in case of seepage into water course or sewage system.
Dilute with plenty of water.
Do not allow to enter sewers/ surface or ground water.
路 Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
7 Handling and storage
路 Handling:
路 Information for safe handling: No special measures required.
路 Information about fire - and explosion protection: No special measures required.
(Contd. on page 3)
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Material Safety Data Sheet
According to 91/155 EEC
Printing date 10.05.2006 Reviewed on 17.03.2006
Trade name: Easy Paper Box 110 CD-R
(Contd. of page 2)
路 Storage:
路 Requirements to be met by storerooms and receptacles: No special requirements.
路 Information about storage in one common storage facility: Not required.
路 Further information about storage conditions: Keep container tightly sealed.
8 Exposure controls/personal protection
路 Additional information about design of technical facilities: No further data; see item 7.
路 Ingredients with limit values that require monitoring at the workplace:
1310-58-3 potassium hydroxide
NES (Australia) 2 mg/m鲁
路 Additional information: The lists valid during the making were used as basis.
路 Personal protective equipment:
路 General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
路 Respiratory protection: Not required.
路 Protection of hands:
Protective gloves
The g lo ve mat eria l ha s t o be i mp ermeab le a nd resi st an t to t he p ro d uct/ t he sub st an ce/ th e
preparation.
Du e to missing t ests n o reco mmen dat ion to t he glo ve mat eria l can b e given for th e prod uct/ t he
preparation/ the chemical mixture.
Selection of the glo ve material on considera tion of the penetration times, rates of diffu sion and the
degradation
路 Material of gloves
The sel ection of th e suitable gl oves does not only depend on the mat erial, but al so on further marks
of qu ality and varies from manufact urer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has t herefore
to be checked prior to the application.
路 Penetration time of glove material
The exact break trough time ha s to be found out by the manu facturer of the pro tective gl oves and
has to be observed.
路 Eye protection:
Tightly sealed goggles
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(Contd. on page 4)
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Material Safety Data Sheet
According to 91/155 EEC
Printing date 10.05.2006 Reviewed on 17.03.2006
Trade name: Easy Paper Box 110 CD-R
(Contd. of page 3)
9 Physical and chemical properties
路 General Information
Form: Fluid
Colour: According to product specification
Odour: Characteristic
路 Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 100掳C (212掳F)
路 Flash point: Not applicable.
路 Self-igniting: Product is not selfigniting.
路 Danger of explosion: Product does not present an explosion hazard.
路 Vapour pressure at 20掳C (68掳F): 23 hPa (17 mm Hg)
路 Density at 20掳C (68掳F): 1.178 g/cm鲁
路 Solubility in / Miscibility with
water: Fully miscible.
路 pH-value at 20掳C (68掳F): 13
路 Viscosity:
Kinematic at 20掳C (68掳F): 13 s (DIN 53211/4)
路 Solvent content:
Organic solvents: 4.9 %
Water: 57.6 %
路 Solids content: 22.8 %
10 Stability and reactivity
路 Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
路 Dangerous reactions No dangerous reactions known.
路 Dangerous decomposition products: No dangerous decomposition products known.
11 Toxicological information
路 Acute toxicity:
路 LD/LC50 values relevant for classification:
1310-58-3 potassium hydroxide
Oral LD50 273 mg/kg (rat)
路 Primary irritant effect:
路 on the skin: Irritant to skin and mucous membranes.
路 on the eye: Irritating effect.
路 Sensitization: Sensitization possible through skin contact.
(Contd. on page 5)
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Material Safety Data Sheet
According to 91/155 EEC
Printing date 10.05.2006 Reviewed on 17.03.2006
Trade name: Easy Paper Box 110 CD-R
(Contd. of page 4)
路 Additional toxicological information:
The pro duct shows the fol lowing dang ers accord ing to t he calcul ation meth od o f th e General EU
Classification Guidelines for Preparations as issued in the latest version:
Irritant
12 Ecological information
路 Ecotoxical effects:
路 Remark: Toxic for fish
路 General notes:
Water hazard class 3 (German Regulation) (Self-assessment): extremely hazardous for water
Do n ot a ll ow prod uct to reach grou nd wa ter, w at er co urse o r sew ag e syst em, even in sma ll
quantities.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
Rinse off of bigger amou nts into drains or the aquatic environment may l ead to increased pH-values.
A h ig h p H-va lu e h arms aq ua ti c o rg an isms. In t he d il u ti on o f t he u se-level t he p H-val ue i s
considerab ly reduced, so that after th e use of the product the aqueous waste, emptied into drains, is
only low water-dangerous.
13 Disposal considerations
路 Product:
路 Recommendation
Mu st not be disposed tog eth er wit h hou seho ld ga rba ge. Do not al low p rodu ct to reach sewa ge
system.
路 Uncleaned packaging:
路 Recommendation: Disposal must be made according to official regulations.
路 Recommended cleansing agents: Water, if necessary together with cleansing agents.
14 Transport information
路 Land transport ADR/RID (cross-border)
路 ADR/RID class: 8 (C5) Corrosive substances.
路 Danger code (Kemler): 80
路 UN-Number: 1719
路 Packaging group: III
路 Hazard label: 8
(Contd. on page 6)
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Material Safety Data Sheet
According to 91/155 EEC
Printing date 10.05.2006 Reviewed on 17.03.2006
Trade name: Easy Paper Box 110 CD-R
(Contd. of page 5)
路 Description of goods: 1719 CAUSTIC ALKALI LIQUID, N.O.S. (potassium carbonate solution)
路 Maritime transport IMDG:
路 IMDG Class: 8
路 UN Number: 1719
路 Label 8
路 Packaging group: II
路 EMS Number: F-A,S-B
路 Marine pollutant: No
路 Proper shipping name: CAUSTIC ALKALI LIQUID, N.O.S. (POTASSIUM HYDROXIDE)
路 Air transport ICAO-TI and IATA-DGR:
路 ICAO/IATA Class: 8
路 UN/ID Number: 1719
路 Label 8
路 Packaging group: II
路 Proper shipping name: CAUSTIC ALKALI LIQUID, N.O.S. (POTASSIUM HYDROXIDE)
15 Regulatory information
路 Australian Inventory of Chemical Substances
7732-18-5 water, distilled, conductivity or of similar purity
25322-68-3 Polyethylene glycol
584-08-7 potassium carbonate
p-Phenylendiamin-Derivat (ACD 3)
111-46-6 2,2'-oxybisethanol
3710-84-7 N,N-diethylhydroxylamine
26099-09-2 Belclene 200
1310-58-3 potassium hydroxide
路 Labelling according to EU guidelines:
Th e pro duct ha s been cl assi fied an d marked in accordan ce wi th EU Direct ives / Ordin ance on
Hazardous Materials.
路 Code letter and hazard designation of product:
Irritant
Dangerous for the environment
路 Hazard-determining components of labelling:
p-Phenylendiamin-Derivat (ACD 3)
(Contd. on page 7)
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Material Safety Data Sheet
According to 91/155 EEC
Printing date 10.05.2006 Reviewed on 17.03.2006
Trade name: Easy Paper Box 110 CD-R
(Contd. of page 6)
potassium hydroxide
路 Risk phrases:
Irritating to eyes and skin.
May cause sensitisation by skin contact.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
路 Safety phrases:
Avoid contact with skin.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Wear suitable gloves.
This material and its container must be disposed of as hazardous waste.
路 National regulations:
Class Share in %
Wasser 57.6
NK 4.9
16 Other information
This in formation is b ased on our present knowledg e. However, th is shall not constitute a guarantee
for any specific product features and shall not establish a legally valid contractual relationship.
路 Department issuing MSDS: Productmanagement department
路 Contact: Mr. Vollhofer, a&o imaging solutions, Tel.: + 49 7042 913-43
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