BondPak 4144 Adhesive Material Safety Data Sheet 1 of 12
MANUFACTURER:
BondPro Corporation Transportation Emergency
650 Brakke Drive Chemtrec: 800-424-9300
Hudson, WI 54016
Phone: 715-386-6206
Fax: 715-386-1462
ISSUSED: March 10, 2003
TRADE NAME:
BondPak 4144 Adhesive
This product is a kit which contains both the Part A and Part B
independently packaged in a duel cartridge syringe. An MSDS for each
of these components is included. Please do not separate the component
MSDSs from this cover page.
The information in this Material Safety Data Sheet (MSDS) is believed
to be correct as of the date issued. BONDPRO CORPORATION MAKES
WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY
IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE
OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for
determining whether the BondPro Corporation product is fit for a
particular purpose and suitable for user鈥檚 methods of use or
application. Given the variety of factors that can affect the use and
application of a BondPro Corporation product, some of which are
uniquely within the user鈥檚 knowledge and control, it is essential that
the user evaluate the BondPro Corporation product to determine whether
it is fit for a particular purpose and suitable for user鈥檚 method of
use or application.
BondPro Corporation provides information in electronic form as a
service to its customers. Due to the remote possibility that
electronic transfer may have resulted in errors, omissions or
alterations in this information, BondPro Corporation makes no
representations as to its completeness or accuracy. In addition,
information obtained from a database may not be as current as the
information in the MSDS available directly from BondPro Corporation.
BondPak 4144 Adhesive Material Safety Data Sheet 2 of 12
SECTION 1. CHEMICAL PRODUCT AND COMPANY INFORMATION
Page 1 of 6
MANUFACTURER:
BondPro Corporation Transportation Emergency
650 Brakke Drive Chemtrec: 800-424-9300
Hudson, WI 54016
Phone: 715-386-6206
Fax: 715-386-1462
ISSUED: May 24, 2001
TRADE NAME:
BondPak 4144 Part A Urethane
SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS
SUBSTANCE DESCRIPTION PERCENT CAS#
Urethane Propolymer 鈥? N.J. Trade Secret
Registry No. 04499600-5770P 15.0 鈥? 40.0 Trade Secret
Talc 10.0 鈥? 30.0 14807-96-6
Higher Oligomers of MDI 10.0 鈥? 30.0 9016-87-9
Diphenylmethane Diisocyanate (MDI) 1.0 鈥? 5.0 26447-40-5
Zeolite 1.0 鈥? 5.0 68989-22-0
This product contains the following toxic chemical or chemicals subject
to the reporting requirements of Section 313 of Title III of the
Emergency Planning and Community Right-To-Know Act of 1986 and 40 CFR
Part 372:
HIGHER OLIGOMERS OF MDI
SECTION 3. PHYSICAL DATA
BOILING POINT: 406 F @ 5mm Hg
VAPOR DENSITY: N/A
VAPOR PRESSURE: 0.0000 mm Hg @ 25 C
EVAPORATION RATE: N/A
SOLUBILITY IN WATER: Insoluble
SPECIFIC GRAVITY: 1.350 Water=1
PERCENT VOLATILE: 0.00% by wt ASTM
pH: N/A
VISCOSITY: 15000 鈥? 40000 centipoise
MELTING POINT N/D
APPEARANCE & ODOR:
Viscous liquid, brown.
BondPak 4144 Adhesive Material Safety Data Sheet 3 of 12
BondPak 4144 Part A Page 2 of 6
SECTION 4. FIRE AND EXPLOSION HAZARD DATA
Flash Point N/A
Flammable Limits 鈥? LEL N/A
Flammable Limits 鈥? UEL N/A
Autoignition Temperature: N/D
EXTINGUISHING MEDIA:
Water spray, Carbon dioxide, Dry chemical, Foam
SPECIAL FIRE FIGHTING PROCEDURES:
Wear full protective clothing, including helmet, self-contained,
positive pressure or pressure demand breathing apparatus, bunker coat
and pants, bands around arms, waist and legs, face mask, and protective
covering for exposed areas of the head.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
None known
NFPA HAZARD CLASSIFICATION
HEALTH: 2 FIRE: 0 REACTIVITY: 1
UNUSUAL REACTION HAZARD: NONE
SECTION 5. REACTIVITY DATA
STABILITY: Stable
INCOMPATIBILITY 鈥? MATERIALS/CONDITIONS TO AVOID:
Amines, Alcohols, Water. Heat is generated during cure. Do not cure a
mass larger than 50 grams in a confined space to prevent a premature
reaction (exotherm) with production of intense heat and smoke.
Reaction with water, alcohols and amines is not hazardous if container
can vent to the atmosphere to prevent pressure buildup.
HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur.
HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon Monoxide and Carbon Dioxide, Oxides of Nitrogen, Hydrogen
Cyanide, Isocyanates, Toxic Vapors, Gases or Particulates.
SECTION 6. ENVIRONMENTAL INFORMATION
SPILL RESPONSE:
Refer to other sections of this MSDS for information regarding physical
and health hazards, respiratory protection, ventilation, and personal
protective equipment. Contain spill. Evacuate unprotected personnel
from hazard area. Pour isocyanate decontaminant solution (90% water 8%
concentrated ammonia, 2% detergent) on spill and allow to react for 10
minutes. Alternatively, pour water on spill and allow to react from
more than 30 minutes. Cover with absorbent. Place in an approved
BondPak 4144 Adhesive Material Safety Data Sheet 4 of 12
BondPak 4144 Part A Page 3 of 6
drum, but do not seal the drum for 48 hours to avoid possible pressure
buildup. Neutralize spill residue with decontaminant solution.
RECOMMENDED DISPOSAL:
Cure product according to product instructions. Incinerate in an
industrial or commercial facility in the presence of a combustible
material. Dispose of completely cured (or polymerized) material in a
sanitary landfill. Dispose of waste product in a facility permitted to
accept chemical waste.
ENVIRONMENTAL DATA:
Not determined.
REGULATORY INFORMATION:
Volatile Organic Compounds: 3.6 gms/liter
VOC Less H2O & Exempt Solvents: 3.6 gms/liter
Since regulations vary, consult applicable regulations or authorities
before disposal. In the event of an uncontrolled release of this
material, the user should determine if the release qualifiers as a
reportable quantity. U.S. EPA Hazardous Waste Number = None (Not U.S.
EPA Hazardous).
VOC less water and exempt solvent = 1.7 g/l for adhesive when
components are mixed as recommended.
EPCRA HAZARD CLASS:
FIRE HAZARD: No PRESSURE: No REACTIVITY: No ACUTE: Yes
CHRONIC: Yes
SECTION 7. SUGGESTED FIRST AID
EYE CONTACT:
Immediately flush eyes with large amounts of water. Get immediate
medical attention.
SKIN CONTACT:
Immediately wash skin with soap and large amounts of water. Remove
contaminated clothing. If signs/symptoms occur, call a physician.
Wash contaminated clothing before reuse and dispose of contaminated
shoes.
INHALATION:
Remove person to fresh air. If not breathing, give artificial
respiration. If breathing is difficult get immediate medical
attention.
IF SWALLOWED:
Do not induce vomiting. Drink two glasses of water. Call a physician.
BondPak 4144 Adhesive Material Safety Data Sheet 5 of 12
BondPak 4144 Part A Page 4 of 6
SECTION 8. PRECAUTIONARY INFORMATION
EYE PROTECTION:
Avoid eye contact. Wear ventilated goggles. Where safety Glasses with
side shields.
SKIN PROTECTION:
Avoid skin contact. Wear appropriate gloves when handling this
material. A pair of gloves made from the following material (s) are
recommended: polyethylene/ethylene vinyl alcohol, polyvinyl alcohol,
polyetrafluoroethylene (Teflon), fluoroelastomer (Viton). Use one or
more of the following personal protection items as necessary to prevent
skin contact: apron, coveralls.
RECOMMENDED VENTILATION:
Use in a well-ventilated area. Provide sufficient ventilation to
maintain emissions below recommended exposure limits. If exhaust
ventilation is not adequate, use appropriate respiratory protection.
RESPIRATORY PROTECTION:
Avoid breathing of vapors. Select one of the following NIOSH approved
respirators based on airborne concentration of contaminants and in
accordance with OSHA regulations: half mask supplied air respirator.
PREVENTION OF ACCIDENTAL INGESTION:
Do not ingest.
RECOMMENDED STORAGE:
Store at temperatures below 120 degrees F (49 degrees C). Keep
container closed when not in use. Keep out of the reach of children.
FIRE AND EXPLOSION AVOIDANCE:
Keep container tightly closed.
OTHER PRECAUTIONARY INFORMATION:
When grinding or sanding the cured material follow precautions for
dusts given in the PART B (No. 4144) Material Safety Data Sheet.
EXPOSURE LIMITS
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
Urethane prepolymer 鈥? N.J. Trade
Secret Registry No. 04499600-5770P 10 MG/M3 TWA AIHA
AS A PARTICULATE
Talc 2 MG/M3 TWA OSHA
RESPIRABLE
Talc 2 MG/M3 TWA ACGIH
RESPIRABLE
Talc 0.5 MG/M3 TWA CMRG
AS RESPIRABLE DUST
Diphenylmethane Diisocyanate (MDI) 0.005 PPM TWA ACGIH
Diphenylmethane Diisocyanate (MDI) 0.02 PPM CEIL OSHA
Higher Oligomers of MDI NONE NONE NONE NONE
ZEOLITE NONE NONE NONE NONE
BondPak 4144 Adhesive Material Safety Data Sheet 6 of 12
BondPak 4144 Part A Page 5 of 6
*SKIN NOTATION:
Listed substances indicated with 鈥榊鈥? under SKIN refer to the potential
contribution to the overall exposure by the cutaneous route including
mucous membrane and eye, either by airborne or, more particularly, by
direct contact with the substance. Vehicles can alter skin absorption.
SOURCE OF EXPOSURE LIMIT DATA:
-ACGIH: American Conference of Governmental Industrial Hygienists
-AIHA: American Industrial Hygiene Assoc. Workplace Environmental
Exposure Level Guideline
-CMRG: Chemical Manufacturer Recommended Exposure Guidelines
-OSHA: Occupational Safety and Health Administration
-NONE: None Established
SECTION 9. HEALTH HAZARD DATA
EYE CONTACT:
Moderate Eye Irritation: signs/symptoms may include redness, swelling,
pain, tearing, and hazy vision.
SKIN CONTACT:
Allergic Skin Reaction: signs/symptoms can include redness, swelling,
blistering, and itching.
Mild Skin Irritation: signs/symptoms can include redness, swelling, and
itching.
INHALATION:
Allergic Respiratory Reaction: signs/symptoms can include difficulty
breathing, wheezing, tightness of chest, and respiratory failure.
Irritation (upper respiratory): signs/symptoms can include soreness of
the nose and throat, coughing and sneezing.
Vapors of the uncured product may cause irritation of the respiratory
system.
IF SWALLOWED:
Ingestion may cause:
Irritation of Gastrointestinal Tissues: signs/symptoms can include
pain, vomiting, abdominal tenderness, nausea, blood in vomitus, and
blood in feces.
Abbreviations: N/D 鈥? Not Determined N/A 鈥? Not Applicable C/A 鈥?
Approximately
The information in this Material Safety Data Sheet (MSDS) is believed
to be correct as of the date issued. BONDPRO CORPORATION MAKES
WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY
IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE
BondPak 4144 Adhesive Material Safety Data Sheet 7 of 12
BondPak 4144 Part A Page 6 of 6
OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for
determining whether the BondPro Corporation product is fit for a
particular purpose and suitable for user鈥檚 methods of use or
application. Given the variety of factors that can affect the use and
application of a BondPro Corporation product, some of which are
uniquely within the user鈥檚 knowledge and control, it is essential that
the user evaluate the BondPro Corporation product to determine whether
it is fit for a particular purpose and suitable for user鈥檚 method of
use or application.
BondPro Corporation provides information in electronic form as a
service to its customers. Due to the remote possibility that
electronic transfer may have resulted in errors, omissions or
alterations in this information, BondPro Corporation makes no
representations as to its completeness or accuracy. In addition,
information obtained from a database may not be as current as the
information in the MSDS available directly from BondPro Corporation.
SECTION 1. CHEMICAL PRODUCT AND COMPANY INFORMATION
BondPak 4144 Adhesive Material Safety Data Sheet 8 of 12
Page 1 of 6
MANUFACTURER:
BondPro Corporation Transportation Emergency
650 Brakke Drive Chemtrec: 800-424-9300
Hudson, WI 54016
Phone: 715-386-6206
Fax: 715-386-1462
ISSUED: May 24, 2001
TRADE NAME:
BondPak 4144 Part B Urethane
SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS
SUBSTANCE DESCRIPTION PERCENT CAS#
Polyester Resin 鈥? N.J. Trade Secret
Registry No. 3176530002-5392P 40.0 鈥? 60.0 Trade Secret
Polypropylene Glycol 10.0 鈥? 30.0 25322-69-4
Talc 10.0 鈥? 30.0 14807-96-6
Polyoxypropylene Triol 3.0 鈥? 7.0 25723-16-4
O-Diethylbisaniline 1.0 鈥? 5.0 13680-35-8
Zeolite 1.0 鈥? 5.0 68989-22-0
Beta-(3,4-Epoxycyclohexyl)
Ethyltrimethoxysilane 0.1 - 0.1 3388-04-3
The components of this priduct are in compliance with the chemical
notification requirements of TSCA
SECTION 3. PHYSICAL DATA
BOILING POINT: N/A
VAPOR DENSITY: N/A
VAPOR PRESSURE: N/A
EVAPORATION RATE: N/A
SOLUBILITY IN WATER: Very slight
SPECIFIC GRAVITY: 1.310 Water=1
PERCENT VOLATILE: 0.00% by wt
pH: N/A
VISCOSITY: 10000 鈥? 40000 centipoise
MELTING POINT N/D
APPEARANCE & ODOR:
Viscous liquid, off-white.
SECTION 4. FIRE AND EXPLOSION HAZARD DATA
Flash Point N/A
Flammable Limits 鈥? LEL N/A
Flammable Limits 鈥? UEL N/A
Autoignition Temperature: N/D
BondPak 4144 Adhesive Material Safety Data Sheet 9 of 12
BondPak 4144 Part B Page 2 of 6
EXTINGUISHING MEDIA:
Water spray, Carbon dioxide, Dry chemical, Foam
SPECIAL FIRE FIGHTING PROCEDURES:
Wear full protective clothing, including helmet, self-contained,
positive pressure or pressure demand breathing apparatus, bunker coat
and pants, bands around arms, waist and legs, face mask, and protective
covering for exposed areas of the head.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
None known
NFPA HAZARD CLASSIFICATION
HEALTH: 1 FIRE: 0 REACTIVITY: 1
UNUSUAL REACTION HAZARD: NONE
SECTION 5. REACTIVITY DATA
STABILITY: Stable
INCOMPATIBILITY 鈥? MATERIALS/CONDITIONS TO AVOID:
Heat is generated during cure. Do not cure a mass larger than 50 grams
in a confined space to prevent a premature reaction (exotherm) with
production of intense heat and smoke.
HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur.
HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon Monoxide and Carbon Dioxide, Oxides of Nitrogen, Toxic Vapors,
Gases or Particulates.
SECTION 6. ENVIRONMENTAL INFORMATION
SPILL RESPONSE:
Refer to other sections of this MSDS for information regarding physical
and health hazards, respiratory protection, ventilation, and personal
protective equipment. Cover with absorbent material. Collect spilled
material. Place in a U.S. DOT-approved container.
RECOMMENDED DISPOSAL:
Cure product according to product instructions. Incinerate in an
industrial or commercial facility in the presence of a combustible
material. Dispose of completely cured (or polymerized) material in a
sanitary landfill. Dispose of waste product in a facility permitted to
accept chemical waste.
ENVIRONMENTAL DATA:
Not determined.
REGULATORY INFORMATION:
Volatile Organic Compounds: 17.2gms/liter
VOC Less H2O & Exempt Solvents: 17.2 gms/liter
BondPak 4144 Adhesive Material Safety Data Sheet 10 of 12
BondPak 4144 Part B Page 3 of 6
Since regulations vary, consult applicable regulations or authorities
before disposal. U.S. EPA Hazardous Waste Number = None (Not U.S.
EPA Hazardous).
VOC less water and solvent 鈥? 1/7 gms/liter for this adhesive when
components are mixed as recommended.
EPCRA HAZARD CLASS:
FIRE HAZARD: No PRESSURE: No REACTIVITY: No ACUTE: Yes
CHRONIC: Yes
SECTION 7. SUGGESTED FIRST AID
EYE CONTACT:
Immediately flush eyes with large amounts of water. Get immediate
medical attention.
SKIN CONTACT:
Flush skin with large amounts of water. If irritation persists, get
medical attention.
INHALATION:
If signs/symptoms occur, remove person to fresh air. If signs/symptoms
continue, call a physician.
IF SWALLOWED:
Do not induce vomiting. Drink two glasses of water. Call a physician.
SECTION 8. PRECAUTIONARY INFORMATION
EYE PROTECTION:
Avoid eye contact. Wear vented goggles. Where safety Glasses with
side shields.
SKIN PROTECTION:
Avoid skin contact. Wear appropriate gloves when handling this
material. A pair of gloves made from the following material (s) are
recommended: polyethylene/ethylene vinyl alcohol, polyvinyl alcohol,
polyetrafluoroethylene (Teflon), fluoroelastomer (Viton).
RECOMMENDED VENTILATION:
Use in a well-ventilated area. Provide sufficient ventilation to
maintain emissions below recommended exposure limits. If exhaust
ventilation is not adequate, use appropriate respiratory protection.
RESPIRATORY PROTECTION:
Avoid breathing of vapors created during the cure cycle. Avoid
breathing of dust created by cutting, sanding, or grinding. Select one
of the following NIOSH approved respirators based on airborne
concentration of contaminants and in accordance with OSHA regulations:
half mask dust respirator.
PREVENTION OF ACCIDENTAL INGESTION:
Do not ingest.
BondPak 4144 Adhesive Material Safety Data Sheet 11 of 12
BondPak 4144 Part B Page 4 of 6
RECOMMENDED STORAGE:
Store at temperatures below 120 degrees F (49 degrees C). Keep
container closed when not in use. Keep out of the reach of children.
FIRE AND EXPLOSION AVOIDANCE:
Keep container tightly closed.
OTHER PRECAUTIONARY INFORMATION:
When this Part B is used in combination with Part A (No. 4144) follow
the precautions outlined in the Part A (No. 4144) Material Safety Data
Sheet. When grinding or sanding the cured material follow precautions
for ventilation and respiratory protection for dusts given below.
EXPOSURE LIMITS
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
Polyester Resin 鈥? N.J. Trade
Secret Registry
No. 3176530002-5392P NONE NONE NONE NONE
Polypropylene Glycol 10 MG/M3 TWA AIHA
AS PARTICULATE
Talc 2 MG/M3 TWA OSHA
RESPIRABLE
Talc 2 MG/M3 TWA ACGIH
RESPIRABLE
Talc 0.5 MG/M3 TWA CMRG
AS RESPIRABLE DUST
Polyoxypropylene Triol NONE NONE NONE NONE
O-Diethylbisaniline NONE NONE NONE NONE
Zeolite NONE NONE NONE NONE
Beta-(3,4-Epoxycyclohexyl)
Ethyltrimethoxysilane NONE NONE NONE NONE
*SKIN NOTATION:
Listed substances indicated with 鈥榊鈥? under SKIN refer to the potential
contribution to the overall exposure by the cutaneous route including
mucous membrane and eye, either by airborne or, more particularly, by
direct contact with the substance. Vehicles can alter skin absorption.
SOURCE OF EXPOSURE LIMIT DATA:
-ACGIH: American Conference of Governmental Industrial Hygienists
-AIHA: American Industrial Hygiene Assoc. Workplace Environmental
Exposure Level Guideline
-CMRG: Chemical Manufacturer Recommended Exposure Guidelines
-OSHA: Occupational Safety and Health Administration
-NONE: None Established
BondPak 4144 Adhesive Material Safety Data Sheet 12 of 12
BondPak 4144 Part B Page 5 of 6
SECTION 9. HEALTH HAZARD DATA
EYE CONTACT:
Moderate Eye Irritation: signs/symptoms may include redness, swelling,
pain, tearing, and hazy vision.
SKIN CONTACT:
Mild Skin Irritation: (after prolonged or repeated contact):
signs/symptoms can include redness, swelling, and itching.
INHALATION:
Irritation (upper respiratory): signs/symptoms can include soreness of
the nose and throat, coughing and sneezing.
Vapors of the heated material may cause respiratory system irritation.
Dust from cutting, grinding, sanding or machining may cause irritation
of the respiratory system.
IF SWALLOWED:
Ingestion may cause:
Irritation of Gastrointestinal Tissues: signs/symptoms can include
pain, vomiting, abdominal tenderness, nausea, blood in vomitus, and
blood in feces.
OTHER HEALTH HAZARD INFORMATION:
Beta-(3,4-epoxycyclohexyl) ethyltrimethoxysilane, (present at a level
below 0.5%) has been shown to be weakly tumorigenic in mice by chronic
recurrent application to the skin. The relevance of these findings to
man is unknown.
Abbreviations: N/D 鈥? Not Determined N/A 鈥? Not Applicable C/A 鈥?
Approximately
The information in this Material Safety Data Sheet (MSDS) is believed
to be correct as of the date issued. BONDPRO CORPORATION MAKES
WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY
IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE
OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for
determining whether the BondPro Corporation product is fit for a
particular purpose and suitable for user鈥檚 methods of use or
application. Given the variety of factors that can affect the use and
application of a BondPro Corporation product, some of which are
uniquely within the user鈥檚 knowledge and control, it is essential that
the user evaluate the BondPro Corporation product to determine whether
it is fit for a particular purpose and suitable for user鈥檚 method of
use or application.
BondPro Corporation provides information in electronic form as a
service to its customers. Due to the remote possibility that
electronic transfer may have resulted in errors, omissions or
alterations in this information, BondPro Corporation makes no
representations as to its completeness or accuracy. In addition,
information obtained from a database may not be as current as the
information in the MSDS available directly from BondPro Corporation.
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