Material Safety Data Sheet U.S. Department of Labor
May be used to comply with Occupational Safety and Health Administration
OSHA's Hazard Communication Standard, (Non-Mandatory Form)
29 CFR 1910.1200. Standard must be consulted Form Approved
for specific requirements. OMB No. 1218-0072
IDENTITY (As Used on Label and List)
Bonide Wasp & Hornet Killer (Aerosol) ID # 4392
Date: May 27, 2008
Section I
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Bonide Products, Inc. (800) 424-9300
6301 Sutliff Rd. (315) 736-8231
Oriskany, NY 13424
Section II - Hazardous Ingredients/Identity
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Hazardous Components (Specific Chemical Identity: Common Name(s) OSHA PEL ACGIH TLV Other Limits % (Optional)
Tetramethrin (CAS# 7696-12-0) N/E N/E 0.1
Permethrin (CAS# 52645-53-1) N/E N/E 0.25
Piperonyl butoxide (CAS# 51-03-6) N/E N/E 0.5
Section III - Physical/Chemical Ingredients
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APPEARANCE: Liquid
pH: NA
DENSITY: 6.55 lbs/gal
PHYSICAL STATE: Liquid
VISCOSITY: 20.3 cp @ 22掳C
STABILITY: Stable
SOLUBILITY (H2O): NA
ODOR: Odorless to faint deodorized kerosene odor.
HAZARDOUS POLYMERIZATION: Will not occur.
Section IV - Fire and Explosion Data
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FLAMMABLE PROPERTIES: FLASH POINT: 192掳F 89掳F TCC
FIRE AND EXPLOSION HAZARDS: Flammable. Contents under pressure. Keep away from heat, sparks and
open flame. Do not puncture or incinerate container. Exposure to temperatures above 130掳F may cause bursting.
EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Foam, or Water.
FIRE FIGHTING INSTRUCTIONS: As in any fire, wear self-contained breathing apparatus pressure-demand,
MSHA/NIOSH approved (or equivalent) and full protective gear.
Section V - Health Hazard Information
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EMERGENCY OVERVIEW: Causes moderate eye irritation. Avoid contact with eyes or clothing. Prolonged or
frequently repeated skin contact may cause allergic reactions in some individuals. This product is toxic to fish and
aquatic invertebrates. Flammable. Contents under pressure.
PRIMARY ROUTE (S) OF ENTRY: Skin contact.
EYES: Causes moderate eye irritation.
SKIN: Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals.
CHRONIC (CANCER INFORMATION): See Section 11 for carcinogenic/oncogenic effects of piperonyl butoxide
and permethrin.
Section VI - First Aid Measures
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EYES: Flush with plenty of water. Call a physician if irritation persists.
SKIN: Wash thoroughly with soap and water.
Bonide Wasp & Hornet Killer (Aerosol) ID # 4392 page 2 of 3
Section VII - Accidental Release Measures
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Soak up with an absorbent material and dispose of in trash.
Section VIII - Handling and Storage
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HANDLING PRECAUTIONS:
Avoid contact with eyes or clothing. Do not use in commercial food/feed handling establishments, restaurants, or
other sites where food/feed in commercially prepared or processed. Not for use in USDA meat and poultry plants.
STORAGE PRECAUTIONS:
Do not store near heat or open flame. Store in a cool, dry area away from children.
WORK/HYGIENIC PRACTICES:
Wash thoroughly with soap and water after handling.
Dielectric breakdown (non-conductive up to 47,300 volts.
Section IX - Exposure Controls/Personal Protection
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ENGINEERING CONTROLS: Use in a well-ventilated area.
EYE/FACE PROTECTION: Safety glasses
SKIN PROTECTION: Chemical-resistant gloves.
Section X - Toxicological Information
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ACUTE STUDIES: Acute toxicity data is bridged from a similar product; Tetraperm Wasp & Hornet Killer FEQ 24,
EPA Reg. 432-776, which contains 0.15% Tetramethrin, 0.375% Permethrin, and 0.75% Piperonyl Butoxide.
EYE EFFECTS: Moderately irritating.
SKIN EFFECTS: IRRITATION: Slightly irritation.
ABSORPTION: LD50 > 18.92 /mgL (for DOT classification)
SENSITIZATION: Positive
ACUTE ORAL EFFECTS: LD50 > 5,000 mg/kg
ACUTE INHALATION EFFECTS: 4-hour LD50 > 4.73 mg/L
CHRONIC (CANCER INFORMATION): A statistically significant increase in the incidence of lung and liver
tumors was observed in female mice receiving diets containing 375 and 750 mg/kg/day of permethrin technical over
85 weeks.
A statistically significant increase in the number of benign liver tumors appeared in mice fed piperonyl butoxide
technical at doses which far exceed any anticipated daily human intake. Independent and industry toxicological
experts who have reviewed the data agree that the findings of the study do not indicate a health risk to human
beings.
CARCINOGENICITY:
NTP: No IARC: No OSHA: No
Section XI - Ecological Information
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OTHER ENVIRONMENTAL INFORMATION:
This product is toxic to fish and aquatic invertebrates. No not apply directly to water.
Section XII - Disposal Consideration
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Replace cap. Wrap container in several layers of newspaper and discard in trash. Do not incinerate or puncture. Can
be disposed of with other recyclables where local law permits.
Section XIII - Transport Information
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PROPER SHIPPING NAME: Aerosols, Nonflammable
HAZARD CLASS: 2.2
DOT IDENTIFICATION NUMBER UN1950
DOT SHIPPING LABEL: Nonflammable gas
Bonide Wasp & Hornet Killer (Aerosol) ID # 4392 page 3 of 3
Section XIV - Regulatory Information
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SARA TITLE III NOTIFICATIONS AND INFORMATION
SARA TITLE III - SECTION 313 SUPPLIER NOTIFICATION
This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the
Emergency Planning and Community Right-To-Know Act (EPCRA) of 1986 and of 40 CFR 372:
CAS NUMBER INGREDIENT NAME PERCENT BY WEIGHT
7696-12-0 Tetramethrin =0.1
52645-53-1 Permethrin =0.25
51-03-6 Piperonyl butoxide =0.5
This information must be included on all MSDS鈥檚 that are copied and distributed for this material.
REGULATED INGREDIENTS:
INGREDIENT: Tetramethrin
CAS NUMBER: 7696-12-0
PERCENT BY WEIGHT: = 0.1
REGULATIONS: SARA Section 313 Toxic Chemical
INGREDIENT: Permethrin
CAS NUMBER: 52645-53-1
PERCENT BY WEIGHT: = 0.25
REGULATIONS: Massachusetts Hazardous Substance
New Jersey Workplace Hazardous Substance
SARA Section 313 Toxic Chemical
INGREDIENT: Piperonyl butoxide
CAS NUMBER: 51-03-6
PERCENT BY WEIGHT: = 0.5
REGULATIONS: SARA Section 313 Toxic Chemical
INGREDIENT: Carbon dioxide
CAS NUMBER: 124-38-9
PERCENT BY WEIGHT: > 2
REGULATIONS: Illinois Toxic Substance
Massachusetts Hazardous Substance
New Jersey Workplace Hazardous
Pennsylvania Workplace Hazardous Substance
Section XV - Other Information
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HMIS HAZARD RATING: NFPA HAZARD RATING:
HEALTH: 1 Slight HEALTH: 1 Slight
FIRE: 2 Moderate FIRE: 2 Moderate
PROTECTION: B PROTECTION: B
MSDS IDENTIFICATION CODE/NUMBER: 4392
KEEP OUT OF REACH OF CHILDREN
ABBREVIATION KEY
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N/A: NOT AVAILABLE OR APPLICABLE N/E: NOT ESTABLISHED ND: Not Determined
TLV: THRESHOLD LIMIT VALUE TWA: TIME WEIGHTED AVG./ 8 HOUR WORKDAY
STEL: SHORT TERM EXPOSURE LIMIT D.O.T.: DEPARTMENT OF TRANSPORTATION
DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES
Buyer assumes all risks of use, storage and handling of this material not in strict accordance with directions given herewith.
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