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Material Safety Data Sheet U.S. Department of Labor
May be used to comply with Occupational Safety and Health Administration
OSHA's Hazard Communication Standard, (Non-Mandatory Form)
29 CFR 1910.1200. Standard must be consulted Form Approved
for specific requirements. OMB No. 1218-0072
IDENTITY (As Used on Label and List)
Bonide Ant, Roach & Spider Killer (Aerosol) ID # 4461(2)
Date: February 4, 2008
Section I
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Bonide Products, Inc. (800) 424-9300
6301 Sutliff Road (315) 736-8231
Oriskany, NY 13424
Section II - Hazardous Ingredients/Identity
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Hazardous Components (Specific Chemical Identity: Common Name(s) OSHA PEL ACGIH TLV Other Limits % (Optional)
S-Bioallethrin (CAS# 28434-00-6) N/E N/E 0.05
Deltamethrin (CAS# 52918-63-5) N/E N/E 0.02
Balance Inert Ingredients
Section III - Physical/Chemical Ingredients
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APPEARANCE: Off White Liquid Aerosol
ODOR: Soapy detergent, faint oily like . PH: 5.6 (premix)
DENSITY: 8.10 lbs/gal PHYSICAL STATE: Liquid
STABILITY: Stable
INCOMPATABILITY : Strong oxidizing agents and acids SOLUBILITY (H2O): Emulsifiable
HAZARDOUS POLYMERIZATION: Will not occur.
Section IV - Fire and Explosion Data
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FLAMMABLE PROPERTIES:
FLASH POINT: 168掳F METHOD: TTC
FIRE AND EXPLOSION HAZARDS: Flammable. Contents under pressure. Keep away from heat, sparks and
open flame. Do not puncture or incinerate container. Exposure to temperatures above 130掳F may cause bursting.
Do not use this product in or on electrical equipment due to the possibility of shock hazard.
EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Foam, or Water.
FIRE FIGHTING INSTRUCTIONS: As in any fire, wear self-contained breathing apparatus pressure-demand,
MSHA/NIOSH approved (or equivalent) and full protective gear. Keep upwind. Isolate hazard area. Avoid
Inhalation of smoke and fumes. Use water or foam to reduce fumes. Do not touch spilled material. If possible,
move containers from area. Extinguish only if flow can be stopped. Dike runoff. Cool containers with flooding
amount of water from as far a distance as possible. Avoid breathing vapors.
Hazardous Combustion Products: May form toxic materials: Carbon dioxide and carbon monoxide, various
hydrocarbons, etc.
Section V - Health Hazard Information
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EMERGENCY OVERVIEW: Causes minimal eye irritation. Avoid contact with eyes or clothing. Prolonged or
frequently repeated skin contact may cause allergic reactions in some individuals. This product is toxic to fish and
aquatic invertebrates and bees. Flammable, Contents under pressure.
Signs & Symptoms of Systemic Effects: May cause gastrointestinal effects such as nausea, vomiting and diarrhea.
Inhalation of high vapor or mist concentration can cause respiratory tract and eye irritation as well as central nervous
system effects including death.
PRIMARY ROUTE(S) OF ENTRY: Skin contact.
EYES: Causes minimal eye irritation.
SKIN: Minimally irritating. Skin contact may result in transient tingling and reddening of the skin. Prolonged or
repeated contact may result in contact dermatitis which is characterized by dryness, chapping and reddening.
Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals.
INGESTION: May cause irritation if ingested. Not an expected route of exposure for an aerosol product.
INHALATION: Slightly irritating. Harmful or fatal if inhaled in excess.
Bonide Ant, Roach & Spider Killer ID # 4461(2)
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Section VI - First Aid Measures
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EYES: Flush with plenty of water for 15 minutes. Call a physician if irritation persists.
SKIN: Wash thoroughly with soap and water for 15 to 20 minutes. Remove contaminate clothing and launder
separately before reuse. Contact physician if irritation persists.
INGESTION: Call poison control center or doctor immediately for treatment advice. Have person sip a glass of
water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or a doctor. Do not
give anything by mouth to an unconscious person.
INHALATION: Move person to fresh air. If person is not breathing, call 911 or an ambulance, and then give
artificial respiration. Preferably mouth to mouth; if possible. Call a poison control center or doctor for further
treatment advice.
HINTS FOR PHYSICIAN: this product is a synthetic Pryethroid pesticide. If ingested and vomiting has not
occurred, emesis should be induced with supervision. Keep patient鈥檚 head below hips to prevent aspiration. If
symptoms such as loss of gag reflex, convulsions or unconsciousness occur before emesis, gastic lavage using a
cuffed endotracheal tube should be considered.
Do not administer milk, cream or other substances containing vegetable or animal fats. These only enhance
absorption of lipophilic substances.
If localized paresthesia develops, the site should be thoroughly washed soap and water. Cold cream can be applied
to help diminish the effect.
Section VII - Accidental Release Measures
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GENERAL: Remove all sources of ignition. Ventilate area. Stop the source of the spill if safe to do so. Contain
the spill to prevent further contamination of the soil, surface water or ground water.
CLEAN UP: Rinse area with small amount of soapy water. Soak up with an absorbent material such as sand,
sawdust, clay, fuller鈥檚 earth etc. and dispose of in trash. Do not allow water to contaminate water supplies or
sewers.
Section VIII - Handling and Storage
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HANDLING PRECAUTIONS:
Avoid breathing vapors or spray mist. Avoid contamination of feed and foodstuff. Avoid contact with eyes or
clothing. Keep away from heat, sparks and open flame. Do not puncture or incinerate container. Do not use this
product in or on electrical equipment due to possibility of shock hazard.
STORAGE PRECAUTIONS:
Do not store near heat or open flame. Store in a cool, dry area away from children. Do not store near feed or
foodstuff. Do not transport or store below 32掳F. Do not store near heat or open flame. Exposure to temperatures
above 130掳F may cause bursting.
WORK/HYGIENIC PRACTICES:
Wash thoroughly with soap and water after handling.
Section IX - Exposure Controls/Personal Protection
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ENGINEERING CONTROLS: Use in a well-ventilated area. Avoid being upwind of the mist or spray. Avoid
breathing mist or spray.
EYE/FACE PROTECTION: Safety glasses
SKIN PROTECTION: Chemical-resistant gloves.
Section X - Toxicological Information
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CHRONIC/ CARCINOGENICITY:
S-bioallethrin: No known chronic effects based on available data.
Deltamethrin: General neurological symptoms were exhibited in studies with rats, mice and dogs. These symptoms
included unsteadiness, abnormal gait, tremors and liquid feces. No histopathologic findings were observed except
some signs of slight hepatotoxicity in mice. No Observed Effects Levels (NOEL鈥檚) were 1 mg/kg/day in the 2-year
rat and dog studies. The NOEL for the 2-year mouse study was approximately 12mg/kg/day/ Deltametherin were
not carcinogenic in rats or mice.
Bonide Ant, Roach & Spider Killer ID # 4461(2)
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NTP: No IARC: No OSHA: No
Section XI - Ecological Information
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OTHER ENVIRONMENTAL INFORMATION:
This product is toxic to fish and aquatic invertebrates. No not apply directly to water.
Section XII - Disposal Consideration
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Replace cap, wrap container in several layers of newspaper and discard in trash. Do not incinerate or puncture. Can
be disposed of with other recyclables where local law permits.
RCRA HAZARDOUS WASTE INGREDIENTS: None
Section XIII - Transport Information
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D.O.T. PROPER SHIPPING NAME: Consumer Commodity RQ: NA
D.O.T. HAZARD CLASS: ORM-D
DOT IDENTIFICATION NUMBER: NA EXEMPTION REQUIREMENT: 49 CFR 173.306
DOT SHIPPING LABEL: Nonflammable gas
Section XIV - Regulatory Information
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REGULATIONS UNDER FIFRA: All pesticides are governed under FIFRA. Therefore the regulations presented
below are pertinent only when handled outside of the normal use and applications of pesticides. This includes waste
streams resulting from manufacturing/formulation facilities, spills or misuse of product, and storage of large
quantities of products containing hazardous or extremely hazardous substances.
EPA REGISTRATION#: 73049-177
TSCA Inventory: Registered Pesticide, exempt fro TSCA
SARA TITLE III - SECTION 313 SUPPLIER NOTIFICATIONS
This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the
Emergency Planning and Community Right-To-Know Act (EPCRA) of 1986 and of 40 CFR 372:
CAS NUMBER INGREDIANT NAME PERCENT BY WEIGHT
------------NONE---------------
SARA Title III: Acute Health Hazard- Yes
Chronic Health Hazard- No
Fire Hazard- No
Sudden Release of Pressure 鈥? No
Reactivity Hazard- No
This information must be included on all MSDS鈥檚 that are copied and distributed for this material.
REGULATED INGREDIENTS:
INGREDIENT: Deltamethrin
CAS NUMBER: 52918-63-5
PERCENT BY WEIGHT: = 0.1
REGULATIONS: European Inventory of existing Commercial Substances
INGREDIENT: Isobutane
CAS NUMBER: 52645-53-1
PERCENT BY WEIGHT: = 0.02
REGULATIONS: Massachusetts Hazardous Substance
New Jersey Workplace Hazardous Substance
Pennsylvania Workplace Hazardous Substance
INGREDIENT: Propane
CAS NUMBER: 74-98-6
PERCENT BY WEIGHT: = <20
REGULATIONS: Illinois Toxic Substance
State right to know: NJ, MA, PA
Bonide Ant, Roach & Spider Killer ID # 4461(2)
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INGREDIENT: Aliphatic Petroleum Distillates/Aliphatic hydrocarbon
CAS NUMBER: 64742-47-8
PERCENT BY WEIGHT: 0<10
REGULATIONS: Canadian DSL; EINECS
INGREDIENT: Hydrotreated Middle Distillate
CAS NUMBER: 64742-46-7
PERCENT BY WEIGHT: 0<10
REGULATIONS: Canadian DSL; EINECS
State Right to know: NJ, PA
INGREDIENT: Paraffinic Hydrocarbos
CAS NUMBER: 629-59-4,90622-46-1,64771-72-8 or 64742-47-8
PERCENT BY WEIGHT: 0<10
REGULATIONS: US TSCA Inventory Status
Canadian DSL; EINECS
Australian (AICS), Japan (MITI)
INGREDIENT: Acetyltributyl Citrate
CAS NUMBER: 77-90-7
PERCENT BY WEIGHT: 0<10
REGULATIONS: US TSCA Inventory Status
Canadian DSL; EINECS (201-067-0)
Australian (AICS), Japan (2-1327X)
Korean (KE-00158); Philippine (PICCS); Switzerland
INGREDIENT: Epoxidized Linseed Oil
CAS NUMBER: 8016-11-3
PERCENT BY WEIGHT: 0<10
REGULATIONS: US TSCA Inventory Status
Canadian DSL; EINECS; Australian (AICS)
INGREDIENT: Nonionic Surfactants
CAS NUMBER: mixture
PERCENT BY WEIGHT: 0<10
REGULATIONS: US TSCA Inventory Status
Canadian DSL; EINECS; Australian (AICS)
INGREDIENT: Polyoxyethylene (20) Sorbitian Monopalmitate
CAS NUMBER: 9005-66-7
PERCENT BY WEIGHT: 0<10
REGULATIONS: US TSCA Inventory Status
Canadian DSL; California Proposition 65- this product contains a chemical know to State
of California to cause cancer and birth defects or other reproductive harm.
Section XV - Other Information
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HMIS HAZARD RATING: NFPA HAZARD RATING:
HEALTH: 1 Slight HEALTH: 1 Slight
FIRE: 2 Moderate FIRE: 2 Moderate
PROTECTION: B PROTECTION: B
KEEP OUT OF REACH OF CHILDREN
ABBREVIATION KEY
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N/A: NOT AVAILABLE OR APPLICABLE N/E: NOT ESTABLISHED ND: Not Determined
TLV: THRESHOLD LIMIT VALUE TWA: TIME WEIGHTED AVG./8 HOUR WORKDAY
STEL: SHORT TERM EXPOSURE LIMIT D.O.T.: DEPARTMENT OF TRANSPORTATION
DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES
Buyer assumes all risks of use, storage and handling of this material not in strict accordance with directions given herewith.
Bonide Ant, Roach & Spider Killer ID # 4461(2)
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