MATERIAL SAFETY DATA SHEET
Prescription Treatment庐 brand Camelot庐 Fungicide / Bactericide
EMERGENCY PHONE NUMBERS:
MEDICAL: 800-225-3320 (PROSAR) TRANSPORTATION: 800-424-9300 (CHEMTREC)
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION UNUSUAL FIRE, EXPLOSION AND REACTIVITY HAZARDS
No unusual fire or explosion hazards known other than product is combustible. Heat may
Product Name: Prescription Treatment brand Camelot Fungicide / Bactericide
庐 庐
cause drums to rupture.
EPA Reg. No.: 1812-381-499
IN CASE OF FIRE
Product Code: 09-2371 (4 x 1 Gallon)
Extinguisher Media: CO2, sand, dry chemical, or other media used for petroleum fires.
EPA Signal Word: CAUTION
Water emulsifies product making clean-up difficult.
Distributed by: Whitmire Micro-Gen Research Laboratories, Inc.
Special Fire Fighting Procedures: Product easily emulsifies in water resulting in slick
3568 Tree Court Industrial Blvd.
floors and making clean-up difficult. Product is slick and sticky.
St. Louis MO 63122-6682
Special Fire Fighting Equipment: Wear protective clothing and self-contained breathing
apparatus.
SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS
SECTION 6. ACCIDENTAL RELEASE MEASURES
COMPOSITION INFORMATION
ACTIVE INGREDIENTS (58.0%) % CAS NO. IN CASE OF SPILL OR LEAK
If container begins to leak (through puncture, etc.) remove ignition sources. Cover spill with
Copper salts of fatty and rosin acids 58.0% 61789-22-8
absorbent material such as sweeping compound or lime. Sweep up and place in an appropriate
OTHER INGREDIENTS (42.0%) chemical waste container for disposal. This product contains the Comprehensive Environmental
Xylene range aromatic petroleum solvent 28.4% 1330-20-7 Response, Compensation, and Liability Act (CERCLA) listed chemicals Metallic Copper and
Xylene which have reportable quantities (RQ) of 1 lb. Any release of this product is reportable to
EXPOSURE INFORMATION the National Response Center (800-424-8802).
OSHA PEL ACGIH TLV Emergency Telephone Number of Chemtrec: (800) 424-9300 (for transportation spills)
Material STEL TWA STEL TWA
PROTECTIVE EQUIPMENT FOR CLEANUP PERSONNEL
Copper salts of fatty and rosin acids NE 1 mg/M3* NE 1 mg/M3 Eyes: Use proper protection - safety glasses as a minimum.
Xylene range aromatic petroleum solvent NE 435 mg/M3 655 mg/M3 435 mg/M3 Skin: Chemical-resistant gloves such as nitrile rubber, neoprene rubber or polyvinyl chloride.
* As copper dusts or mists (CAS #7440-50-8) (Good practice requires that gross amounts of any chemical be removed from the skin as soon as
practical, especially before eating or smoking.)
SECTION 3. HAZARDS IDENTIFICATION Inhalation: Use of a respirator may be appropriate when working with spills in enclosed or
confined spaces. If using a respirator, wear a NIOSH approved respirator with an organic
NOTE TO PHYSICIAN vapor (OV) cartridge or any R, P, or HE prefilter.
Product contains aromatic petroleum distillates; treat accordingly. Other Protective Equipment: Wear coveralls over short-sleeved shirt and short pants,
chemical-resistant headgear for overhead exposure, chemical-resistant apron and shoes
SIGNS/SYMPTOMS OF EXPOSURE
plus socks.
May cause irritation of the mucous membranes. Exposure to copper fumes may result in a
metallic taste, nausea, vomiting, and metal fume fever with chills, fever, aching muscles, dry WASTE DISPOSAL METHOD
throat, and headache. May be irritating to the eyes, but is reversible. Slight skin irritant. Do not contaminate water, food or feed by storage or disposal of wastes. Take full or leaking
Excessive exposure, especially if prolonged, may produce skin irritation. Repeated exposure may containers to a local disposal company for biological treatment or incineration. Review all
cause allergic contact dermatitis. Ingestion of copper salts may result in irritation of the gas- local, State, and Federal regulations concerning health and pollution be reviewed to deter-
trointestinal tract, nausea, vomiting, salivation, gastric pain, hemorrhagic gastritis, diarrhea, mine approved disposal procedures. NEVER PLACE WASTES DOWN ANY INDOOR OR OUT-
capillary damage, liver and kidney damage and central nervous system stimulation followed DOOR DRAIN OR SEWER.
by depression. Jaundice, pain in the liver, and hemolytic anemia have been reported follow-
ing acute human poisonings.
SECTION 7. HANDLING AND STORAGE
ROUTES OF ENTRY
Primary: Skin Secondary: Ingestion Tertiary: Inhalation HAZARDS TO HUMANS AND DOMESTIC ANIMALS
Keep out of reach of children. CAUTION - Contains petroleum distillates. Causes skin irritation and
HAZARDOUS DECOMPOSITION PRODUCTS
moderate eye irritation. Harmful if swallowed, absorbed through the skin or inhaled. Avoid contact with skin, eyes
None at normal process temperatures and pressures. On combustion, copper, CO2 and water
or clothing. Avoid breathing spray mist. Prolonged or frequently repeated skin contact may cause allergic reac-
would form.
tions in some individuals.
UNUSUAL FIRE, EXPLOSION AND REACTIVITY HAZARDS
USER SAFETY RECOMMENDATIONS
No unusual fire or explosion hazards known other than product is combustible. Heat may
Users Should: Wash hands before eating, drinking, chewing gum, using tobacco or using
cause drums to rupture.
the toilet. Remove clothing immediately if pesticide gets inside. Then wash thoroughly and
put on clean clothing.
SECTION 4. FIRST AID MEASURES
PHYSICAL OR CHEMICAL HAZARDS
Have the product container or label with you when calling a poison control center or doctor or Combustible. Do not use or store near heat or open flame.
going for treatment. Describe any symptoms and follow the advice given. STORAGE
Inhalation: Remove victim to fresh air. If not breathing, call 911 or an ambulance, then give artifi- Store in a cool, secure place away from fire or open flame. Open dumping is prohibited.
cial respiration, preferably mouth-to-mouth. Call a poison control center or doctor for further Keep container closed and reseal after use. Product is not damaged by freezing, but should
treatment advice. be stored at temperatures above 32掳 F. If spilled, use absorbent materials and dispose of in
approved landfill.
Eye Contact: Hold eye open and rinse slowly and gently for 15-20 minutes. Remove contact lens-
es, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or
doctor for treatment advice. SECTION 8. EXPOSURE CONTROL / PERSONAL PROTECTION
Skin Contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for
PESTICIDE APPLICATORS & WORKERS
15-20 minutes. Call a poison control center or doctor for treatment advice.
These workers must refer to the Product Label and Directions for Use attached to the product
Ingestion: Immediately call a poison control center or doctor. Do not induce vomiting unless told
for Agricultural Use Requirements in accordance with the EPA Worker Protection Standard
to do so by the poison control center or doctor. Do not give ANY liquid to the person. Do not
40 CFR part 170.
give anything by mouth to an unconscious person.
PERSONAL PROTECTIVE EQUIPMENT (PPE)
Note to Physician: Contains petroleum distillate - vomiting may cause aspiration pneumonia.
Respiratory Protection: None required. Use of a respirator may be appropriate when
using this product in enclosed or confined spaces. If using a respirator, wear a NIOSH
SECTION 5. FIRE FIGHTING MEASURES
approved respirator with an organic vapor (OV) cartridge or any R, P, or HE prefilter.
Protective Gloves: Wear chemical resistant gloves such as Nitrile rubber, Neoprene rub-
FIRE AND EXPLOSION
ber, or Polyvinyl chloride. (Good practice requires that gross amounts of any chemical be
Flash Point (TAG Closed Cup): 108掳 F
removed from the skin as soon as practical, especially before eating or smoking.)
Flammable Limits in Air (% by volume): NE
Autoignition Temperature: NE Eye Protection: Use proper protection - safety glasses as a minimum.
Page 1 of 2
MATERIAL SAFETY DATA SHEET
Prescription Treatment庐 brand Camelot庐 Fungicide / Bactericide
SECTION 13. DISPOSAL CONSIDERATION
Other Protective Equipment: Wear coveralls over short-sleeved shirt and short pants,
chemical-resistant headgear for overhead exposure, chemical-resistant apron and shoes
Do not contaminate water, food or feed by disposal.
plus socks.
Container Disposal: Triple rinse (or equivalent). Then offer for recycling or reconditioning, or
VENTILATION
puncture and dispose of in a sanitary landfill, or by other procedures approved by state and local
Local Exhaust: None required.
authorities, or plastic containers by incineration, or, if allowed by state and local authorities, by
Mechanical: None required.
burning. If burned, stay out of smoke.
Special: None required.
Other: None required. Waste Disposal: Pesticide wastes are toxic. Improper disposal of excess pesticide, spray mix-
ture, or rinsate is a violation of Federal law. If these wastes cannot be dispose of by use accord-
ing to label instructions, contact your State Pesticide or Environmental Control Agency, or the
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Hazardous Waste representative at the nearest EPA Regional Office for guidance.
Appearance: Dark green liquid. Odor: Petroleum solvent odor.
Solubility in Water: Emulsifiable in Vapor Pressure: 1.5 @ 20掳 C, SECTION 14. TRANSPORT INFORMATION
water - wide range % 8.8 @ 25掳 C
SHIPMENT BY GROUND WITHIN U.S. (DOT CLASSIFICATION)
Viscosity: NE Vapor Density: NE
Proper Shipping Description: Flammable liquids, n.o.s. (1,2,4-trimethylbenzene,
Boiling Point: 200-212掳 F @ 760 mm Hg Freezing/Melting Point: NE
xylene), 3, UN 1993, PG III
pH: Neutral (1% in H2O) Density: 1.006 g/ml @ 70掳 F
Package Marking: 鈥淔lammable liquids, n.o.s. (1,2,4-trimethylbenzene, xylene), 3, UN
1993, PG III鈥?
SECTION 10. STABILITY AND REACTIVITY Package Labeling: Label as 鈥淔lammable Liquid鈥? (class 9).
Certified Packaging: Required.
REACTIVITY
Stability: This material is stable under normal conditions. SHIPMENT BY AIR (IATA CLASSIFICATION)
Conditions to Avoid: Excessive heat. Proper Shipping Description: Flammable liquids, n.o.s. (1,2,4-trimethylbenzene,
xylene), 3, UN 1993, PG III
Incompatibility (Material to Avoid): None known.
Package Marking: 鈥淔lammable liquids, n.o.s. (1,2,4-trimethylbenzene, xylene), 3, UN
Hazardous Polymerization: Material is not known to polymerize.
1993, PG III鈥?
HAZARDOUS DECOMPOSITION PRODUCTS Package Labeling: Label as 鈥淔lammable Liquid鈥? (class 9).
None at normal process temperature and pressures. On combustion, copper, CO2 and water Certified Packaging: Required.
would form.
SHIPMENT BY WATER (IMDG CLASSIFICATION)
Proper Shipping Description: Flammable liquids, n.o.s. (1,2,4-trimethylbenzene,
SECTION 11. TOXICOLOGICAL INFORMATION xylene), 3, UN 1993, PG III
Package Marking: 鈥淔lammable liquids, n.o.s. (1,2,4-trimethylbenzene, xylene), 3, UN
ROUTES OF ENTRY
1993, PG III鈥?
Primary: Skin Secondary: Ingestion Tertiary: Inhalation
Package Labeling: Label as 鈥淔lammable Liquid鈥? (class 9).
ACUTE Certified Packaging: Required.
Inhalation: Acute inhalation (4-hour mist) LC50 > 1.45 mg/L. May cause irritation of the
mucous membranes. SECTION 15. REGULATORY INFORMATION
Skin Irritation: Moderate primary skin irritant. Primary dermal irritation index = 3.15.
Skin Absorption: Acute dermal LD50 > 2000 mg/kg. CERCLA
Ingestion: Oral LD50 = 4000 mg/kg (rats). This product contains the CERCLA listed chemicals Metallic Copper and Xylene which have
reportable quantities (RQ) of 1 lb.
CHRONIC HEALTH HAZARDS
This product contains ethylbenzene. The International Agency for Research on Cancer (IARC) SARA TITLE III SECTION 311/312 HAZARD CLASS
This product has been reviewed according to the EPA 鈥淗azard Categories鈥? promulgated under
has evaluated ethylbenzene and classified it as a possible human carcinogen (group 2B)
Section 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III)
based on sufficient evidence for carcinogenicity in experimental animals, but inadequate evi-
and is considered, under applicable definitions, to meet the following categories:
dence for cancer in exposed humans.
Acute Health Hazard
Repeated or prolonged inhalation of dust, mist or fumes of copper and copper salts may
Fire Hazard
cause irritation of the upper respiratory tract and occasionally ulceration and perforation of
SARA TITLE III SECTION 313 CHEMICALS
the nasal septum. Depending on the concentration and duration of contact, repeated or pro-
This product contains the following substances subject to the reporting requirements of
longed exposure to the eyes may result in symptoms as in acute exposure. Repeated or pro-
Section 313 of the Title III of the Superfund Amendments and Reauthorization Act of 1986
longed exposure may cause dermattitis. Rarely, sensitization to copper may occur. Repeated
and 40 CFR Part 372:
ingestion of copper salts may result in anemia, liver and kidney damage.
Metallic Copper (CAS #61789-22-8)
SPECIAL HEALTH EFFECTS Xylene (CAS #1330-20-7)
Acute overexposure may cause irritation in certain individuals. None are known or reported
TSCA
in use or production.
All components of this product are listed or excluded from listing on the US Toxic Substance
Control Act (TSCA) Chemical Substance Inventory.
SECTION 12. ECOLOGICAL INFORMATION
SECTION 16. OTHER INFORMATION
ECOTOXICITY
Test Type Species Value
KEY: 4 = Severe
NFPA HEALTH RATING INFORMATION
Aquatic EC50 Pinfish 4.9 ppm @ 24 hrs; 1.8 ppm @ 48 hrs.
3 = Serious
HEALTH - 2 FLAMMABILITY - 2 REACTIVITY - 0
This pesticide is toxic to fish and aquatic organisms. Do not apply directly to water, or areas 2 = Moderate
where surface water is present, or to inter-tidal areas below the mean high water mark. Do not NFPA HEALTH RATING INFORMATION 1 = Slight
contaminate water when disposing of equipment wash-waters. HEALTH - 2 FLAMMABILITY - 2 REACTIVITY - 0 0 = Minimal
The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the
information contained herein.
Questions concerning the safe handling of the product should be referred to the Whitmire Micro-Gen Customer Service Department at 800-777-8570.
NA - Not Applicable Effective Date: 06/02/04
WHITMIRE MICRO-GEN
NE - Not Established Review Date: NA
PEL - Permissible Exposure Limit Supersedes: 5/1/04
RESEARCH LABORATORIES, INC.
TLV - Threshhold Limit Value Code #: NA
STEL - Short Term Exposure Limit (15 min.) Text ID: 040224-3
TWA - Time Weighted Average (8 hrs.) Part No: 19-0100-03
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