Bayer CropScience
Material Safety Data Sheet MSDS Number: 102000012448
MSDS Version 1.1
AE F106464 00 SC43 A4 INSECTICIDE
Revision Date: 03/03/2005
SECTION 1. CHEMICAL PRODUCT AND COMPANY INFORMATION
AE F106464 00 SC43 A4 INSECTICIDE
Product Name
102000012448
MSDS Number
264-827
EPA Registration No.
Insecticide for use in pest management, suppression of insect vectored diseases
Product Use
and maintenance of plant health.
Bayer CropScience
2 T.W. Alexander Drive
Research Triangle PK, NC 27709
USA
For MEDICAL, TRANSPORTATION or other EMERGENCY call 1-800-334-7577 (24 hours/day)
For Product Information call 1-866-99BAYER (1-866-992-2937)
SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Component Name CAS-No. Average % by Weight
Imidacloprid 138261-41-3 42.80
SECTION 3. HAZARDS IDENTIFICATION
NOTE: Please refer to Section 11 for detailed toxicological information.
Caution! Harmful if swallowed or absorbed through skin. Avoid contact with skin,
Emergency Overview
eyes and clothing.
liquid
Physical State
slightly perceptible
Odor
blue
Appearance
Ingestion, Eye contact, Skin Absorption, Skin contact
Routes of Exposure
Immediate Effects
May cause mild irritation to eyes. Avoid contact with eyes.
Eye
May cause slight irritation. Avoid contact with skin and clothing.
Skin
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Bayer CropScience
Material Safety Data Sheet MSDS Number: 102000012448
MSDS Version 1.1
AE F106464 00 SC43 A4 INSECTICIDE
Do not take internally. Harmful if swallowed.
Ingestion
Do not breathe vapours or spray mist.
Inhalation
SECTION 4. FIRST AID MEASURES
Have the product container or label with you when calling a poison control center
General
or doctor or going for treatment.
Hold eye open and rinse slowly and gently with water for 15-20 minutes.
Eye
Remove contact lenses, if present, after the first 5 minutes, then continue rinsing
eye. Call a poison control center or doctor for treatment advice.
Take off all contaminated clothing immediately. Rinse immediately with plenty of
Skin
water for at least 15 minutes. Call a poison control center or doctor for treatment
advice.
Call a poison control center or doctor immediately for treatment advice. Have
Ingestion
person sip a glass of water if able to swallow. DO NOT induce vomiting unless
directed to do so by a physician or poison control center. Never give anything by
mouth to an unconscious person.
Move to fresh air. If person is not breathing, call 911 or an ambulance, then give
Inhalation
artificial respiration, preferably mouth-to-mouth if possible. Call a poison control
center or doctor for further treatment advice.
Notes to Physician
There is no specific antidote. Appropriate supportive and symptomatic treatment
Treatment
as indicated by the patient's condition is recommended.
SECTION 5. FIRE FIGHTING MEASURES
> 100 掳C / > 212 掳F
Flash Point
foam, dry chemical, water spray
Suitable Extinguishing
Media
Keep out of smoke. Fight fire from upwind position. Cool closed containers
Fire Fighting
exposed to fire with water spray. Do not allow run-off from fire fighting to enter
Instructions
drains or water courses. Equipment or materials involved in pesticide fires may
become contaminated.
Wear self-contained breathing apparatus and protective suit.
SECTION 6. ACCIDENTAL RELEASE MEASURES
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Bayer CropScience
Material Safety Data Sheet MSDS Number: 102000012448
MSDS Version 1.1
AE F106464 00 SC43 A4 INSECTICIDE
Keep unauthorized people away. Isolate hazard area. Avoid contact with spilled
Personal Precautions
product or contaminated surfaces.
Use personal protective equipment. Dike contaminated area with absorbent
Additional Advice
granules, soil, sand, etc. Carefully sweep up absorbed spilled material. Place in
an approved chemical waste container for disposal. Do not allow material to
enter streams, sewers, or other waterways or contact vegetation.
SECTION 7. HANDLING AND STORAGE
Handle and open container in a manner as to prevent spillage.
Handling Procedures
Do not contaminate water, food, or feed by storage or disposal.
Storing Procedures
Store in a cool, dry place and in such a manner as to prevent cross
contamination with other pesticides, fertilizers, food, and feed. Store in original
container and out of the reach of children, preferably in a locked storage area.
Wash hands before eating, drinking, chewing gum, using tobacco or using the
Work/Hygienic
toilet.
Procedures
Remove clothing immediately if pesticide gets inside. Then wash thoroughly and
put on clean clothing.
Remove Personal Protective Equipment (PPE) immediately after handling this
product. Before removing gloves clean them with soap and water. As soon as
practical, wash thoroughly and change into clean clothing.
SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Maintain exposure levels below the exposure limit through the use of general
Engineering Controls
and local exhaust ventilation.
protective eyewear.
Eye/Face Protection
Chemical-resistant gloves (barrier laminate, butyl rubber, nitrile rubber or Viton)
Hand Protection
Wear long-sleeved shirt and long pants and shoes plus socks.
Body Protection
Follow manufacturer's instructions for cleaning/maintaining PPE. If no such
General Protection
instructions for washables, use detergent and hot water. Keep and wash PPE
separately from other laundry.
Follow all label instructions. Educate and train employees in safe use of the
product.
Exposure Limits
This product contains material which are Trade Secret and may have
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Bayer CropScience
Material Safety Data Sheet MSDS Number: 102000012448
MSDS Version 1.1
AE F106464 00 SC43 A4 INSECTICIDE
Occupational Exposure Limits. If more information is required, call the product
information number listed in Section 1.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
blue
Appearance
liquid
Physical State
slightly perceptible
Odor
6.5 - 8.5 (undiluted)
pH
1.29 g/cm鲁 at 20 掳C
Density
SECTION 10. STABILITY AND REACTIVITY
Stable under normal conditions.
Chemical Stability
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity studies have not been performed on this product as formulated. The acute toxicity data
provided has been bridged from a similar formulation containing a higher percentage of the active ingredient,
imidacloprid. The non-acute information pertains to the technical-grade active ingredient.
male/female rat: LD50: 609 mg/kg
Acute Oral Toxicity
male/female rat: LD50: > 2,000 mg/kg
Acute Dermal Toxicity
male/female rat: LC50: > 3.18 mg/l
Acute Inhalation Toxicity
Exposure time: 4 h
Determined in the form of liquid aerosol.
(actual)
male/female rat: LC50: > 12.72 mg/l
Exposure time: 1 h
Determined in the form of liquid aerosol.
Extrapolated from the 4 hr LC50.
(actual)
rabbit: slight irritation
Skin Irritation
rabbit: Minimally irritating.
Eye Irritation
guinea pig: Non-sensitizing
Sensitization
In a 3-week dermal toxicity study, rabbits treated with imidacloprid showed no
Subchronic Toxicity
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Bayer CropScience
Material Safety Data Sheet MSDS Number: 102000012448
MSDS Version 1.1
AE F106464 00 SC43 A4 INSECTICIDE
local or systemic effects at levels up to and including 1000 mg/kg, the limit dose.
In a 4 week inhalation study, rats exposed to high concentrations of imidacloprid
exhibited decreased body weight gains and changes in clinical chemistries and
organ weights.
In chronic dietary studies in rats and dogs exposed to imidacloprid, the target
Chronic Toxicity
organs were the thyroids and/or liver.
Assessment Carcinogenicity
In oncogenicity studies in rats and mice, imidacloprid was not considered carcinogenic in either species.
ACGIH
None.
NTP
None.
IARC
None.
OSHA
None.
REPRODUCTION: In a two-generation reproduction study in rats, imidacloprid
Reproductive &
was not a primary reproductive toxicant. Offspring exhibited reduced body
Developmental Toxicity
weights at the high dose and in conjunction with maternal toxicity.
DEVELOPMENTAL TOXICITY: In developmental toxicity studies in rats and
rabbits, there was no evidence of an embryotoxic or teratogenic potential for
imidacloprid. In both species, developmental effects were observed only at high
doses and in conjunction with maternal toxicity.
In acute and subchronic neurotoxicity screening studies in rats, imidacloprid
Neurotoxicity
produced slight neurobehavioral effects in each study at the highest dose tested.
There were no correlating morphological changes observed in the neural tissues.
In a one-generation developmental neurotoxicity screening study in rats,
offspring exposed to imidacloprid showed decreased motor activities. These
effects occurred at the highest dose tested and in conjunction with maternal
toxicity. There were no correlating morphological changes observed in the
neural tissues.
The imidacloprid mutagenicity studies, taken collectively, demonstrate that the
Mutagenicity
active ingredient is not genotoxic or mutagenic.
SECTION 12. ECOLOGICAL INFORMATION
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Bayer CropScience
Material Safety Data Sheet MSDS Number: 102000012448
MSDS Version 1.1
AE F106464 00 SC43 A4 INSECTICIDE
Do not apply directly to water, to areas where surface water is present or to
Environmental
intertidal areas below the mean high water mark. Do not contaminate surface or
Precautions
ground water by cleaning equipment or disposal of wastes, including equipment
wash water.
This product is highly toxic to bees exposed to direct treatment or residues on
blooming crops or weeds. Do not apply this product or allow it to drift to blooming
crops or weeds if bees are visiting the treatment area. This product is toxic to
wildlife. Highly toxic to aquatic invertebrates.
This chemical demonstrates the properties and characteristics associated with
Ecological Information
chemicals detected in ground water. The use of this chemical in areas where
soils are permeable, particularly where the water table is shallow, may result in
ground water contamination.
SECTION 13. DISPOSAL CONSIDERATIONS
Pesticide Disposal: Wastes resulting from the use of this product may be
General Disposal
disposed of on site or at an approved waste disposal facility.
Guidance
Triple rinse containers. Then offer for recycling or reconditioning or puncture and
Container Disposal
dispose of in a sanitary landfill or incineration, or if allowed by State and Local
authorities, by burning. If burned, stay out of smoke.
SECTION 14. TRANSPORT INFORMATION
DOT CLASSIFICATION:
Not Regulated For Domestic Surface Transportation
FREIGHT CLASSIFICATION:
Insecticides or Fungicides, N.O.I., other than poison
SECTION 15. REGULATORY INFORMATION
This product contains material(s) which are Trade Secret and are on various Regulatory Lists. These
material(s) are not listed below. If more information is required, call the product information number listed in
Section 1.
264-827
EPA Registration No.
US Federal Regulations
TSCA list
None.
US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D)
None.
SARA Title III - Section 302 - Notification and Information
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Bayer CropScience
Material Safety Data Sheet MSDS Number: 102000012448
MSDS Version 1.1
AE F106464 00 SC43 A4 INSECTICIDE
None.
SARA Title III - Section 313 - Toxic Chemical Release Reporting
None.
US States Regulatory Reporting
CA Prop65
This product does not contain any substances known to the State of California to cause cancer.
This product does not contain any substances known to the State of California to cause reproductive
harm.
US State Right-To-Know Ingredients
None.
Canadian Regulations
Canadian Domestic Substance List
None.
Environmental
CERCLA
None.
Clean Water Section 307 Priority Pollutants
None.
Safe Drinking Water Act Maximum Contaminant Levels
None.
SECTION 16. OTHER INFORMATION
NFPA
Health - 1 Flammability - 1 Reactivity - 0 Others - none
0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard
Reason to Revise: New Material Safety Data Sheet.
Revision Date: 03/03/2005
This information is provided in good faith but without express or implied warranty. Buyer assumes all
responsibility for safety and use not in accordance with label instructions. The product names are registered
trademarks of Bayer.
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