Material Safety Data Sheet
MSDS Number: 000000000108
庐 MSDS Version: 1
MOCAP BRAND EC NEMATICIDE/INSECTICIDE
SECTION 1. CHEMICAL PRODUCT AND COMPANY INFORMATION
庐
Product Name MOCAP BRAND EC NEMATICIDE/INSECTICIDE
Chemical Name ETHOPROP, ENT27318, V-C 9-104, MOBIL 10000, PROPHOS,
ETHOPROPHOS
Synonym ETHOPROP, ENT27318, V-C 9-104, MOBIL 10000, PROPHOS,
ETHOPROPHOS
MSDS Identification 000000000108
Number
Chemical Family
Chemical Formulation C8H19O2PS2
EPA Registration 264-458
Number
Canadian Registration
Number
Aventis CropScience USA LP
2 T.W. Alexander Drive
Research Triangle PK, NC 27709
US
For Product Use Information: (888)-AVENTIS (283-6847) Monday through Friday
8:00AM-4:30PM
For Medical Emergency contact DART: (800) 334-7577 24 Hours/Day
For Transportation Emergency CHEMTREC: (800) 424-9300 24 Hours/Day
Product Use Description FIFRA regulated use only.
SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS
Component Name CAS No. Concentration % by
Weight
Minimum Maximum
ETHOPROP 13194-48-4 69.600
NAPHTHALENE 91-20-3 <2.800
Other ingredients (Trade secret)
SECTION 3. HAZARDS IDENTIFICATION
NOTE: Please refer to Section 11 for detailed toxicological information.
Emergency Overview Warning Statements:
DANGER! POISONOUS IF SWALLOWED, INHALED OR
ABSORBED THROUGH SKIN. RAPIDLY ABSORBED THROUGH
THE SKIN. COMBUSTIBLE LIQUID.
Odor mercaptan odor
Appearance amber oily liquid.
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Material Safety Data Sheet
MSDS Number: 000000000108
庐 MSDS Version
MOCAP BRAND EC NEMATICIDE/INSECTICIDE
Immediate Effects
Eye May be absorbed through the eye and produce symptoms similar to
those from ingestion. May cause redness, tearing.
Skin Highly toxic if absorbed through skin. May produce symptoms similar
to those from ingestion. May cause redness, swelling.
Ingestion May be fatal if swallowed. This product causes reversible
cholinesterase inhibition. Repeated overexposure may cause more
severe cholinesterase inhibition with more pronounced signs and
symptoms. Aspiration of the swallowed or vomited product can cause
severe pulmonary complications. May lead to rapid onset of nausea,
vomiting, diarrhea, abdominal pain, pinpoint pupils, blurred vision,
profuse sweating, involuntary shaking, excess salivation, temporary
paralysis, respiratory depression, convulsions.
Inhalation Highly toxic if inhaled. May produce symptoms similar to those from
ingestion. May cause headache, nausea, vomiting.
Chronic or Delayed
Long-Term This product does not contain any ingredient designated by IARC,
NTP, ACGIH or OSHA as probable or suspected human carcinogens.
Medical Conditions
Aggravated by Exposure Inhalation of product may aggravate existing chronic respiratory
problems such as asthma, emphysema or bronchitis. Skin contact may
aggravate existing skin disease.
SECTION 4. FIRST AID MEASURES
Eye Hold eyelids open and flush with a steady, gentle stream of water for
at least 15 minutes. Seek immediate medical attention.
Skin In case of contact, immediately wash with plenty of soap and water for
at least 15 minutes. Seek medical attention. Remove contaminated
clothing and shoes while washing. Clean contaminated clothing and
shoes before re-use or discard if they cannot be thoroughly cleaned.
Ingestion If victim is conscious and alert, give 2-3 glasses of water to drink and
induce vomiting by touching back of throat with a finger. Do not induce
vomiting or give anything by mouth to an unconscious person. Seek
immediate medical attention. Do not leave victim unattended. Vomiting
may occur spontaneously. To prevent aspiration of swallowed product,
lay victim on side with head lower than waist. If vomiting occurs and
the victim is conscious, give water to further dilute the chemical.
Inhalation Remove victim from immediate source of exposure and assure that
the victim is breathing. If breathing is difficult, administer oxygen, if
available. If victim is not breathing, administer CPR (cardio-pulmonary
resuscitation). Seek medical attention.
Note to Physician All treatments should be based on observed signs and symptoms of
distress in the patient. Consideration should be given to the possibility
that overexposure to materials other than this product may have
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Material Safety Data Sheet
MSDS Number: 000000000108
庐 MSDS Version
MOCAP BRAND EC NEMATICIDE/INSECTICIDE
occurred.
If emesis has not occurred, the stomach should be emptied by gastric
lavage. This product is a cholinesterase inhibitor. Severe symptoms
and signs include diarrhea, pinpoint and non-reactive pupils,
respiratory difficulty, pulmonary edema, cyanosis, loss of sphincter
control, convulsions, and coma. Support respiration as needed.
Measures should include removal of secretions, maintenance of patent
airway, and, if necessary, artificial ventilation. If cyanosis is absent,
give Atropine 2-4 mg intravenously (0.5 mg/kg for children). Repeat
Atropine at 5 to 10 minute intervals until atropinization occurs (dry,
flushed skin, tachycardia, pupillary dilation), and maintain for 48 hours.
If cyanotic, give initial atropine intramuscularly and start measures to
improve ventilation. Start 2-PAM at the same time. Give 1 to 2 gm 2-
PAM (20 to 40 mg/kg for children) in 100 cc saline over 15 to 30
minutes. If pulmonary edema is present, give intravenously slowly as a
5% solution in water over 5 minutes. A second dose may be given
after 1 hour if muscle weakness persists. Additional doses may be
given cautiously for persistent muscle weakness. May be given by
intramuscular or subcutaneous routes if intravenous administration is
not feasible. In case of skin contact, wash patient with soap and water
followed by wash with 95% ethyl alcohol. Keep patient under constant
observation for 24 to 36 hours. Symptoms may persist for 1 month.
SECTION 5. FIRE FIGHTING MEASURES
Flash Point 84 掳C / 183 掳F
Flammability Class: COMBUSTIBLE.
Method Used: Tagliabue Closed Cup
Lower Flammable Limit 0.6 %(V)
Upper Flammable Limit 7 %(V)
Fire and Explosion
Hazards Product will burn under fire conditions.
Suitable Extinguishing
Media Recommended: dry chemical, foam, water, carbon dioxide.
Fire Fighting
Instructions Firefighters should wear NIOSH/MSHA approved self-contained
breathing apparatus and full protective clothing. Keep unnecessary
people away, isolate hazard area and deny entry. Stay upwind; keep
out of low areas. Evacuate residents who are downwind of fire. Dike
area to prevent runoff and contamination of water sources. Dispose of
fire control water later.
SECTION 6. ACCIDENTAL RELEASE MEASURES
General and Disposal Evacuation Procedures and Safety:
Wear appropriate protective gear for the situation. See Personal
Protection information in Section 8. Evacuate and isolate spill area.
Stay upwind if possible. Exclude all except properly equipped
emergency personnel.
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Material Safety Data Sheet
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MOCAP BRAND EC NEMATICIDE/INSECTICIDE
Cleanup and Disposal of Spill:
Pump any free liquid into an appropriate closed container (see Section
7: Handling and Storage). Absorb with vermiculite or other inert
absorbent. Shovel up into an appropriate closed container (see
Section 7: Handling and Storage). Decontaminate tools and equipment
following cleanup.
Land Spill or Leaks Containment of Spill:
Stop leak if it can be done without risk. Dike spill using absorbent or
impervious materials such as earth, sand or clay. Follow procedure
described below under Cleanup and Disposal of Spill. Collect and
contain contaminated absorbent and dike material for disposal.
Environmental and Regulatory Reporting:
Do not flush to drain. If spilled on the ground, the affected area should
be removed to a depth of one or two inches and placed in an
appropriate container for disposal. Runoff from fire control or dilution
water may cause pollution. Prevent material from entering public
sewer system or any waterways. Spills may be reportable to the
National Response Center (800-424-8802) and to state and/or local
agencies.
SECTION 7. HANDLING AND STORAGE
Handling Procedures Do not breathe vapors and mists. Do not get on skin or in eyes. Do not
ingest.
Storing Procedures Store in an area that is away from ignition sources, away from food,
feedstuffs, fertilizers and seed.
Work/Hygienic
Procedures Personal hygiene is an important work practice exposure control
measure and the following general measures should be taken when
working with or handling this material:
(1) Do not store, use, and/or consume foods, beverages, tobacco
products, or cosmetics in areas where this material is stored.
(2) Wash hands and face carefully before eating, drinking, using
tobacco, applying cosmetics, or using the toilet.
(3) Wash exposed skin promptly to remove accidental splashes of
contact with this material.
In addition, based upon the specific hazards of this product:
(4) Do not take clothing/objects contaminated by this material off the
work site.
(5) Shower and change into street clothes before leaving the work site.
Min/Max Storage
Temperatures Not Available
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Material Safety Data Sheet
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MOCAP BRAND EC NEMATICIDE/INSECTICIDE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls Where engineering controls are indicated by use conditions or a
potential for excessive exposure exists, the following traditional
exposure control techniques may be used to effectively minimize
employee exposures: local exhaust ventilation at the point of
generation.
Eye/Face Protection Eye and face protection requirements will vary dependent upon work
environment conditions and material handling practices. Appropriate
ANSI Z87 approved equipment should be selected for the particular
use intended for this material. Eye contact should be prevented
through use of chemical safety glasses with side shields or splash
proof goggles. An emergency eye wash must be readily accessible to
the work area. Face contact should be prevented through use of a
face shield.
Body Protection Skin contact should be prevented through use of suitable protective
clothing, gloves and footwear, selected with regard for use conditions
and exposure potential. Consideration must be given both to durability
as well as permeation resistance.
Respiratory Protection When respirators are required, select NIOSH/MSHA approved
equipment based on actual or potential airborne concentrations and in
accordance with the appropriate regulatory standards and/or industrial
recommendations. Under normal conditions, in the absence of other
airborne contaminants, the following devices should provide protection
from this material up to the conditions specified by the appropriate
OSHA, WHMIS or ANSI standard(s): Air-purifying (half-mask/full-face)
respirator with cartridges/canister approved for use against pesticides.
Under conditions immediately dangerous to life or health, or
emergency conditions with unknown concentrations, use a full-face
positive pressure air-supplied respirator equipped with an emergency
escape air supply unit or use a self-contained breathing apparatus
unit.
General Protection Introductory Remarks:
These recommendations provide general guidance for handling this
product. Because specific work environments and material handling
practices vary, safety procedures should be developed for each
intended application. While developing safe handling procedures, do
not overlook the need to clean equipment and piping systems for
maintenance and repairs. Waste resulting from these procedures
should be handled in accordance with Section 13: Disposal
Considerations. Assistance with selection, use and maintenance of
worker protection equipment is generally available from equipment
manufacturers.
Exposure Exposure limits represent regulated or recommended worker breathing
Limits/Guidelines zone concentrations measured by validated sampling and analytical
methods, meeting the regulatory requirements. The following limits
apply to this material, where, if indicated, S=skin and C=ceiling limit:
ETHOPROP
Notes TWA STEL
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Material Safety Data Sheet
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MOCAP BRAND EC NEMATICIDE/INSECTICIDE
Mfg. Exp Limits 0.1 mg/cu m
Mfg. Exp Limits 0.01 ppm
NAPHTHALENE
Notes TWA STEL
ACGIH 52 mg/cu m 79 mg/cu m
ACGIH 10 ppm 15 ppm
OSHA 10 ppm 75 mg/cu m
OSHA 50 mg/cu m 15 ppm
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance amber oily liquid.
Odor mercaptan odor
pH Not Applicable
Vapor Pressure Not Available
Vapor Density (air = 1) Not Available
Specific Gravity 1.03 20 掳C
Boiling Point Not Available
Melting/Freezing Point Melting Point Range: Not Available
Freezing Point Range: < 0掳C (32掳F)
Solubility (in water) Insoluble
Molecular Weight 242.3
Other Information Physical and Chemical properties here represent typical properties of
this product. Contact the business area using the Product Information
phone number in Section 1 for its exact specifications.
SECTION 10. STABILITY AND REACTIVITY
Chemical Stability This material is stable under normal handling and storage conditions
described in Section 7.
Conditions to Avoid extreme heat
Incompatibility with strong oxidizing agents, bases
Decomposition Temperature Range: 203掳C (397掳F)
Hazardous Products of
Decomposition Decomposition Type: thermal
oxides of sulfur
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Material Safety Data Sheet
MSDS Number: 000000000108
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MOCAP BRAND EC NEMATICIDE/INSECTICIDE
oxides of phosphorus
oxides of carbon
Hazardous
Polymerization not applicable
(Conditions to avoid)
SECTION 11. TOXICOLOGICAL INFORMATION
Acute Oral Toxicity Toxicological Information and Interpretation
Rat (female) LD50 - lethal dose 50% of test species, 15.9 mg/kg.
Rat (male) LD50 - lethal dose 50% of test species, 46.7 mg/kg.
Acute Dermal Toxicity Toxicological Information and Interpretation
Rabbit (female) LD50 - lethal dose 50% of test species, 166 mg/kg.
Rat (male) LD50 - lethal dose 50% of test species, 369 mg/kg).
Rabbit (female) LD50 - lethal dose 50% of test species, 18.6 mg/kg.
Rabbit (male) LD50 - lethal dose 50% of test species, 21.2 mg/kg.
Acute Inhalation Toxicity Acute Respiratory Irritation:
No test data found for product.
Acute Inhalation Toxicity:
Toxicological Information and Interpretation
Rat (male) LC50 - lethal concentration 50% of test species,
0.86 mg/l/4 hr
Rat (female) LC50 - lethal concentration 50% of test species,
0.32 mg/l/4 hr
Skin Irritation No test data found for product.
Eye Irritation No test data found for product.
Chronic Toxicity This product does not contain any substances that are considered by
OSHA, NTP, IARC or ACGIH to be probable or suspected human
carcinogens.
No additional test data found for product.
SECTION 12. ECOLOGICAL INFORMATION
Ecological Information For ecotoxicological data call the product information phone number
listed in Section 1.
Environmental Fate For chemical fate data call the product information phone number
listed in Section 1.
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Material Safety Data Sheet
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MOCAP BRAND EC NEMATICIDE/INSECTICIDE
SECTION 13. DISPOSAL CONSIDERATIONS
General Disposal
Guidance Chemical additions, processing or otherwise altering this material may
make the waste management information presented in this MSDS
incomplete, inaccurate or otherwise inappropriate. Please be advised
that state and local requirements for waste disposal may be more
restrictive or otherwise different from federal laws and regulations.
Consult state and local regulations regarding the proper disposal of
this material.
Container Disposal Any containers or equipment used should be decontaminated
immediately after use.
EPA Hazardous Waste - NO
SECTION 14. TRANSPORT INFORMATION
For Transportation Regulatory Information call the Product Information phone number in Section 1.
SECTION 15. REGULATORY INFORMATION
Inventory Status
Inventory Status
UNITED STATES (TSCA) E
CANADA (DSL) E
EUROPEAN UNION (EINECS) P
AUSTRALIA (AICS) Y
JAPAN (MITI) N
SOUTH KOREA (KECL) E
Y = All ingredients are on the inventory.
E = All ingredients are on the inventory or exempt from listing.
P = One or more ingredients fall under the polymer exemption or are onthe no longer polymer list. All
other ingredients are on the inventory or exempt from listing.
N = Not determined or one or more ingredients are not on the inventoryand are not exempt from
listing.
FEDERAL REGULATIONS
TSCA Inventory Status:
This product is excluded from TSCA because it is solely for FIFRA regulated use.
SARA Title III Hazard Classes:
Fire Hazard - YES
Reactive Hazard - NO
Release of Pressure - NO
Acute Health Hazard - YES
Chronic Health Hazard - NO
SARA 313 Chemicals
ETHOPROP (69.6%)
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Material Safety Data Sheet
MSDS Number: 000000000108
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MOCAP BRAND EC NEMATICIDE/INSECTICIDE
NAPHTHALENE ( <2.8%)
SARA Extremely Hazardous Substances (EHS)/CERCLA Hazardous Substances
Ingredient CERCLA/SARA RQ SARA EHS TPQ
ETHOPROP 1000 lbs
NAPHTHALENE 100 lbs
STATE REGULATIONS:
This product contains the following components that are regulated under California Proposition 65.
Ingredient Name Cancer Reprod. No Sign. Risk Lvl (ug/day)
List List California *AEL
Ethoprop Y N **ND **ND
(CAS No.: 13194-48-4)
*Aventis CropScience Established Exposure Limits
**ND - Not Determined
SECTION 16. OTHER INFORMATION
National Fire Protection Association Hazard Ratings--NFPA(R):
3 Health Hazard Rating--Serious
2 Flammability Rating--Moderate
1 Instability Rating--Slight
National Paint & Coating Hazardous Materials Identification
3 Health Hazard Rating--Serious
2 Flammability Rating--Moderate
1 Reactivity Rating--Slight
Reason for Revisions:
Change Company Name & Address. Changes to Section 15, Regulatory Information.
Disclaimer:
The information herein is given in good faith but no warranty,expressed or implied, is made.
Print Date: 05/09/2001
Supersedes MSDS, which is older than: 05/09/2001
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