Material Safety Data Sheet
MSDS Number: 104
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MOCAP 15% GRANULAR (15G) NEMATICIDE INSECTICIDE MSDS Version 4.0
SECTION 1. CHEMICAL PRODUCT AND COMPANY INFORMATION
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Product Name MOCAP 15% GRANULAR (15G) NEMATICIDE INSECTICIDE
Chemical Name ETHOPROP, ENT27318, V-C 9-104, MOBIL10000, PROPHOS,
ETHOPROPHOS
Synonym
MSDS Number 104
Chemical Family ORGANOPOSPHATE
Chemical Formulation C8H19O2PS2
EPA Registration No. 264-457
Canadian Registrat. No.
Aventis CropScience USA LP
2 T.W. Alexander Drive
Research Triangle PK, NC 27709
USA
For Product Use Information: (888)-AVENTIS (283-6847) Monday through Friday
8:00AM-4:30PM
For Medical Emergency contact DART: (800) 334-7577 24 Hours/Day
For Transportation Emergency CHEMTREC: (800) 424-9300 24 Hours/Day
SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS
Component Name CAS No. Concentration % by Weight
Minimum Maximum
ETHOPROP 13194-48-4 15.0000
Other ingredients (Trade secret) 85.0000
SECTION 3. HAZARDS IDENTIFICATION
NOTE: Please refer to Section 11 for detailed toxicological information.
Emergency Overview DANGER! POISON. FATAL IF SWALLOWED. FATAL IF INHALED. HARMFUL
IF ABSORBED THROUGH SKIN.
Physical State solid
Odor mercaptan odor
Appearance grey granules
Immediate Effects
Eye May be absorbed through the eye and produce symptoms similar to those from
ingestion. Causes irritation, tearing, redness.
Skin Harmful if absorbed through skin. May produce symptoms similar to those from
ingestion. May cause irritation, redness, swelling.
Ingestion Maybe fatal if swallowed. May lead to rapid onset of nausea, vomiting,
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Material Safety Data Sheet
MSDS Number: 104
MOCAP庐 15% GRANULAR (15G) NEMATICIDE INSECTICIDE MSDS Version 4.0
abdominal pain, diarrhea, pinpoint pupils, blurred vision, profuse sweating,
temporary paralysis, involuntary shaking, respiratory depression, convulsions.
Inhalation Highly toxic if inhaled. May produce symptoms similar to those from ingestion.
May cause dizziness, headache, nausea, vomiting, death.
Chronic or Delayed This productdoes not contain any ingredient designated by IARC, NTP, ACGIH
Long-Term or OSHA as probable or suspected human carcinogens.
Medical Conditions Inhalation of product may aggravate existing chronic respiratory problems such
Aggravated by Exposure as asthma, emphysema or bronchitis. Skin contact may aggravate existing skin
disease.
SECTION 4. FIRST AID MEASURES
Eye Hold eyelids open and flush with a steady, gentle stream of water for at least 15
minutes. Seek immediate medical attention.
Skin In case of contact, immediately wash with plenty of soap and water for at least
15 minutes. Seek medical attention. Remove contaminated clothing and shoes
while washing. Clean contaminated clothing and shoes before re-use or discard
if they cannot be thoroughly cleaned.
Ingestion If victim isconscious and alert, give 2-3 glasses of water to drink and induce
vomiting by touching back of throat with a finger. Do not induce vomiting or give
anything by mouth to an unconscious person. Seek immediate medical attention.
Do not leave victim unattended. Vomiting may occur spontaneously. To prevent
aspiration of swallowed product, lay victim on side with head lower than waist. If
vomiting occurs and the victim is conscious, give water to further dilute the
chemical. Persons attending the victim should avoid direct contact with heavily
contaminated clothing and vomitus. Wear impervious gloves while
decontaminating skin and hair.Also see Note To Physician.
Inhalation Remove victim from immediate sourceof exposure and assure that the victim is
breathing. If breathing is difficult,administer oxygen, if available. If victim is not
breathing, administer CPR (cardio-pulmonary resuscitation). Seek immediate
medical attention.
Note to Physician All treatments should be based on observed signs and symptoms of distress in
the patient. Consideration should be given to the possibility that overexposure to
materials other than this product may have occurred.
This product is a cholinesterase inhibitor. Severe symptoms and signs include
diarrhea, pinpoint and non-reactive pupils, respiratory difficulty, pulmonary
edema, cyanosis, loss of sphincter control, convulsions, and coma.
Support respiration as needed. Measures should include removal ofsecretions,
maintenance of patent airway, and, if necessary, artificial ventilation.
If cyanosis is absent, give Atropine 2-4 mg intravenously (0.05 mg/kg for
children). Repeat Atropine at 5 to 10 minute intervals until atropinization occurs
(dry, flushed skin, tachycardia, pupillary dilation), and maintain for 48 hours. If
cyanotic, give initial atropine intramuscularly and start measures to improve
ventilation.
Start 2-PAM at the same time. Give 1 to 2 gm 2-PAM (20 to 40 mg/kg
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Material Safety Data Sheet
MSDS Number: 104
MOCAP庐 15% GRANULAR (15G) NEMATICIDE INSECTICIDE MSDS Version 4.0
forchildren) in 100 cc saline over 15 to 30 minutes. If pulmonary edema is
present, give intravenously slowly as a 5% solution in water over 5 minutes.
A second dose maybe given after 1 hour if muscle weakness persists. Additional
doses may be given cautiously for persistent muscle weakness. May be given by
intramuscular or subcutaneous routes if intravenous administration is not
feasible.
In case of skin contact, wash patient with soap and water followed by wash with
95% ethyl alcohol. Keep patient under constant observation for 24 to 36 hours.
Symptoms may persist for 1 month.
SECTION 5. FIRE FIGHTING MEASURES
Flash Point Not Applicable
Fire and Explosion Not combustible.
Hazards
Suitable Extinguishing Not combustible. Use extinguishing method suitable for surrounding fire.
Media
Fire Fighting Firefighters should wear NIOSH/MSHA approved self-contained breathing
Instructions apparatus and full protective clothing. Keep unnecessary people away, isolate
hazard area and deny entry. Evacuate residents who are downwind of fire. Dike
area to prevent runoff and contamination of water sources. Dispose of fire
control water later. Persons who may have been exposed to contaminated
smoke should be immediately examined by a physician and checked for
symptoms of poisoning. The symptoms should not be mistaken for heat
exhaustion or smoke inhalation.
SECTION 6. ACCIDENTAL RELEASE MEASURES
General and Disposal Evacuation Procedures and Safety:
Wear appropriate protective gear for the situation. See Personal Protection
information in Section 8. Exclude all except properly equipped emergency
personnel.
Cleanup and Disposal of Spill:
Shovel up into an appropriate closed container(see Section 7: Handling and
Storage). Avoid creation of dusty conditions. Decontaminate tools and
equipment following cleanup. Flush area with 5% sodium hydroxide or trisodium
phosphate. Absorb washings and add to container.
Land Spill or Leaks Containment of Spill:
Dike or retain dilution water or water from firefighting for later disposal. Follow
procedure described under Cleanup and Disposal of Spill.
Environmental and Regulatory Reporting:
Prevent material from entering public sewer system or any waterways. Do not
flush to drain. Spills may be reportable to the National Response Center (800-
424-8802) and to state and/or local agencies. If spilled on the ground, the
affected area should be scraped clean and placed in a appropriate container for
disposal.
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Material Safety Data Sheet
MSDS Number: 104
MOCAP庐 15% GRANULAR (15G) NEMATICIDE INSECTICIDE MSDS Version 4.0
SECTION 7. HANDLING AND STORAGE
Handling Procedures Do not get on skin or in eyes. Do not ingest. Do not breathe dusts. Avoid getting
material on clothing.
Storing Procedures Store in an area that is away from food, feedstuffs, fertilizers, seed and water
sources.
Work/Hygienic Personal hygiene is an important work practice exposure control measure and
Procedures the following general measures should be taken when working with or handling
this material:
(1) Do not store, use, and/or consume foods, beverages, tobacco products, or
cosmetics in areas where this material is stored.
(2) Wash hands and face carefully before eating, drinking, using tobacco,
applying cosmetics, or using the toilet.
(3) Wash exposed skin promptly to remove accidental splashes of contact with
this material.
In addition, based upon the specific hazards of this product:
(4) Do not take clothing/objects contaminated by this material off the work site.
(5) Shower and change into street clothes before leaving the work site.
Min/Max Storage Not Available
Temperatures
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls Where engineering controlsare indicated by use conditions or a potential for
excessive exposure exists, the following traditional exposure control techniques
may be used to effectively minimize employee exposures: local exhaust
ventilation at the point of generation.
Eye/Face Protection Eye and face protection requirements will vary dependent upon work
environment conditions and material handling practices. appropriate ANSI Z87
approved equipment should be selected for the particular use intended for this
material.
Eye contact should be prevented through use of chemical safety glasses with
side shields or splash proof goggles. An emergency eye wash must be readily
accessible to the work area.
Body Protection Skin contact must be prevented through the use of permeation resistant clothing,
gloves and footwear, selected with regard for use conditions and exposure
potential. An emergency shower must be readily accessible to the work area.
Consideration must be given both to durability as well as permeation resistance.
Respiratory Protection When respirators are required, select NIOSH/MSHA approved equipment based
on actual or potential airborne concentrations and in accordance with the
appropriate regulatory standards and/or industrial recommendations.
Under normal conditions, in the absence of other airborne contaminants, the
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Material Safety Data Sheet
MSDS Number: 104
MOCAP庐 15% GRANULAR (15G) NEMATICIDE INSECTICIDE MSDS Version 4.0
following devices should provide protection from this material up to the
conditions specified by the appropriate OSHA, WHMIS or ANSI standard(s): Air-
purifying (half-mask/full-face)respirator with cartridges/canister approved for use
against pesticides.
Under conditions immediately dangerous to life or health, or emergency
conditions with unknown concentrations, use a full-face positive pressure air-
supplied respirator equipped with an emergency escape airsupply unit or use a
self-contained breathing apparatus unit.
General Protection These recommendations provide general guidance for handling this product.
Because specific work environments and material handling practices vary, safety
procedures should be developed for each intended application. While developing
safe handling procedures, do not overlook the need to clean equipment and
piping systems for maintenance and repairs. Waste resulting from these
procedures should be handled inaccordance with Section 13: Disposal
Considerations.
Assistance with selection, use and maintenance of worker protection equipment
is generally available from equipment manufacturers.
Exposure Limits None Established
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance grey granules
Physical State solid
Odor mercaptan odor
pH Not applicable
Vapor Pressure Not Available
Vapor Density (air = 1) Not Available
Specific Gravity Not Available
Boiling Point Not Available
Melting/Freezing Point Not Available
Solubility (in water) insoluble
Molecular Weight 242.3
Decomposition 203 掳C
Temperature
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Material Safety Data Sheet
MSDS Number: 104
MOCAP庐 15% GRANULAR (15G) NEMATICIDE INSECTICIDE MSDS Version 4.0
Other Information Physical and Chemical properties here represent typical properties of this
product. Contact the business area using the Product Information phone number
in Section 1 for its exact specifications.
SECTION 10. STABILITY AND REACTIVITY
Chemical Stability This material is stable under normal handling and storage conditions described
in Section 7.
Conditions to Avoid extreme heat
Incompatibility strong oxidizing agents
bases
Hazardous Products of Decomposition Type: thermal
Decomposition oxides of sulfur
oxides of phosphorus
oxides of carbon
Hazardous not applicable
Polymerization
(Conditions to avoid)
SECTION 11. TOXICOLOGICAL INFORMATION
Acute Oral Toxicity (Rat) LD50 - 250 mg/kg
Acute Dermal Toxicity (Rabbit) LD50 > 2000 mg/kg
Acute Inhalation Toxicity Acute Respiratory Irritation:
No test data found for product.
Acute InhalationToxicity:
(Rat) LC50 - 0.07 mg/l/4 hr
Data for ethoprop formulated on a clay base having a significant level of
respirable fine particles. There is no LC50 value for the commercial granular
formulation which is not respirable and poses no inhalation hazard. However,
dust generated in the commercial product from grinding of the granules is in the
respirable range in significant quantities to present a respirable hazard.
Breathing dust from this formulation should be avoided.
Skin Irritation (Rabbit) Non-irritating.
Eye Irritation (Rabbit) Moderately irritating.
Assessment Carcinogenicity
ACGIH
None
NTP
None
IARC
None
OSHA
None
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Material Safety Data Sheet
MSDS Number: 104
MOCAP庐 15% GRANULAR (15G) NEMATICIDE INSECTICIDE MSDS Version 4.0
SECTION 12. ECOLOGICAL INFORMATION
Ecological Information The following data is based on the technical grade active ingredient(s) (TGAI).
Daphnia magna.
EC50 - 0.093 mg/l/48 hr. Mean concentration. Static.
Rainbowtrout (Oncorhynchus mykiss)
LC50 - 2.1 mg/l/96 hr. Nominal concentration. Static.
Bluegill sunfish (Lepomis macrochirus)
LC50 - 0.3 mg/l/96 hr. Nominal concentration. Static.
Environmental Fate For chemical fate data call the product information phone number listed in
Section 1.
SECTION 13. DISPOSAL CONSIDERATIONS
General Disposal Chemical additions, processing or otherwise altering this material may make the
Guidance waste management information presented in this MSDS incomplete, inaccurate
or otherwise inappropriate. Please be advised that state and local requirements
for waste disposal may be more restrictive or otherwise different from federal
laws and regulations. Consult state and local regulations regarding the proper
disposal of this material.
Container Disposal Any containers or equipment used should be decontaminated immediately after
use.
EPA Hazardous Waste - NO
RCRA Classification
SECTION 14. TRANSPORT INFORMATION
For Transportation Regulatory Information call the Product Information phone number in Section 1.
SECTION 15. REGULATORY INFORMATION
US Federal Regulations
EPA Registration No. 264-457
TSCA list
None
TSCA 12b export notification
None
SARA Title III - section 302 - notification and information
ETHOPROP 13194-48-4
SARA Title III - section 313 - toxic chemical release reporting
ETHOPROP 13194-48-4 1.0%
US States Regulatory Reporting
CA Prop65
This product contains a chemical known to the state of California to cause cancer.
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Material Safety Data Sheet
MSDS Number: 104
MOCAP庐 15% GRANULAR (15G) NEMATICIDE INSECTICIDE MSDS Version 4.0
ETHOPROP 13194-48-4
This product contains a chemical known to the state of California to cause birth defects or other
reproductive harm.
None
US State right-to-know ingredients
ETHOPROP 13194-48-4 CA, IL, LA, MA, NJ, PA
Canadian Regulations
Canadian Registrat. No.
Canadian Domestic Substance List
None
Environmental
CERCLA
None
Clean Water Section 307 Priority Pollutants
None
Safe Drinking Water Act Maximum Contaminant Levels
None
International Regulations
EU Classification
None
European Inventory of Existing Commercial Substances (EINECS)
ETHOPROP 13194-48-4
SECTION 16. OTHER INFORMATION
Health Flammability Reactivity Others
HMIS 3 0 1
NFPA 3 0 1
Reason for Revisions: Addition in Section 1, Chemical Family and Revision to Section 4, Note to Physician
Print Date: 12/13/2001
Supersedes MSDS, which is older than: 12/12/2001
This information is provided in good faith but without express or implied warranty. Buyer assumes all
responsibility for safety and use not in accordance with label instructions. The product names are registered
trademarks of Aventis.
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