SECTION V HEALTH HAZARD DATA
MATERIAL SAFETY DATA SHEET CC 555
(Air) As copper metal: 1.0 mg/m 3 for 8 hr. working day.
Threshold Limited Value
ALDON Copper (fume) TLV 0.2 mg/m3 .
1533 W.Henrietta Rd.
CC 555
Avon, New York 14414 MSDS No.
庐
CORPORATION February 1, 1996
Effective Date
(716) 226-6177 Harmful if swallowed. May cause irritation to gastrointestinal tract,
Effects of Overexposure
abdominal pain, nausea, vomiting, diarrhea and gastritis. Contact with skin
and eyes may cause irritation, redness, pain. Inhalation of copper salts
SECTION I NAME 24 HOUR EMERGENCY ASSISTANCE
causes irritation of the respiratory tract with occasional ulceration and
Product CUPRIC SULFIDE perforation of the nasal septum.
CHEMTREC Health 2
800-424-9300
Chemical
Emergency and
Indigo Copper, Copper (II) Sulfide
INGESTION: If swallowed, if conscious, give one or two glasses of water,
Synonyms 0
Fire
Day 716-226-6177
First Aid Procedures induce vomiting and call a physician. Never give anything by mouth to an
CuS
Formula 0
Reactivity unconscious person. EYES: Flush thoroughly with water for at least 15
NFPA
minutes, lifting upper and lower eyelids occasionally. Get immediate
HAZARD RATING HMIS *
up to 2.5 Kg.
Unit Size
medical attention. SKIN: Flush thoroughly with water, then wash with mild
LEAST SLIGHT MODERATE HIGH EXTREME
0 1 2 3 4 soap and water. INHALATION: Remove to fresh air. If discomfort or
1317-40-4
C.A.S. No.
illness develops, call a physician.
SECTION II INGREDIENTS OF MIXTURES
SECTION VI REACTIVITY DATA
Principal Component(s) % TLV Units
Conditions to Avoid
Stability Unstable Oxidized to Cupric Sulfate (CuSO4 ) in moist air.
Cupric Sulfide 100% See Section V.
Stable X
WARNING! MAY BE HARMFUL IF SWALLOWED OR INHALED. Incompatibility
Strong acids.
(Materials to Avoid)
CAUSES IRRITATION TO SKIN AND EYES. CONTACT WITH
Hazardous Contact with strong acids liberates hydrogen sulfide (H S) a toxic gas.
ACIDS LIBERATES HYDROGEN SULFIDE - A TOXIC GAS. 2
Thermal decomposition, emits toxic fumes of oxides of sulfur (SO2).
Decomposition Products
SECTION III PHYSICAL DATA
Conditions to Avoid
Hazardous Polymerization
Specific Gravity (H2O = 1)
Melting Point (掳F) Transition @ 103掳C (217掳F) 4.70
Not applicable.
May Occur Will Not Occur
Percent Volatile
Boiling Point (掳F) Decomposes at 220掳C (428掳F) Not applicable. X
by Volume (%)
Evaporation Rate
SECTION VII SPILL OR LEAK PROCEDURES
Vapor Pressure (mm Hg) Negligible as solid. Not applicable.
=1)
(
Steps to be taken in case
Vapor Density (Air=1) Unknown.
material is released or spilled Recover for use if not contaminated. Avoid generating dust.
Solubility in Water Insoluble. Sweep up and place in a suitable container for proper disposal.
Appearance & Odor Blue-black powder; no odor.
Discharge, treatment, or disposal may be subject to Federal, State or Local laws.
Waste Disposal Method
SECTION IV FIRE AND EXPLOSION HAZARD DATA These disposal guidelines are intended for the disposal of catalog-size quantities only.
Lower
Flammable Limits in Air Upper
Flash Point
Dispose of in an approved chemical landfill or contact a licensed chemical waste
% by Volume
Non-flammable. NA -------- --------
(Method Used)
disposal agency.
Extinguisher Use any media suitable for extinguishing supporting fire.
SECTION VIII SPECIAL PROTECTION INFORMATION
Media
None should be required in normal laboratory use. If dusty conditions prevail, work in a
Respiration Protection
ventilation hood or wear a NIOSH/MSHA-approved dust mask or respirator.
(Specify Type)
SPECIAL FIREFIGHTING
Recommended. No.
Local Exhaust Special
PROCEDURES Ventilation
In fire conditions, wear a NIOSH/MSHA-approved self-contained Recommended. No.
Mechanical (General) Other
breathing apparatus. When heated to decomposition, emits toxic
Protective Gloves Eye Protection
Rubber. Chemical safety glasses.
fumes of oxides of sulfur (SO2 ). Use flooding amounts of water in
Other Protective
early stages of fire. Goggles, smock, apron, proper gloves, ventilation hood, and eye wash station.
Equipment
SECTION IX SPECIAL PRECAUTIONS
Precautions to be Taken
UNUSUAL FIRE AND Store in a cool, dry place away from acids.
in Handling & Storing
Wash thoroughly after handling.
EXPLOSION HAZARDS Keep container tightly closed when not in use.
Read label on container before using. Do not wear contact lenses when working with chemicals.
Other Precautions
Contact with strong acids liberates flammable, explosive and very
Hydrogen Sulfide gas (H S) deadens the sense of smell. Do not depend
2
toxic hydrogen sulfide (H2 S) gas.
on odor to detect presence of gas. Avoid contact with skin and eyes.
Use with adequate ventilation. Remove and wash contaminated clothing.
For laboratory use only. Not for drug, food or household use. Keep out of reach of children.
Chemical Safety
Approved
Revision Date
No. 3 2/1/96 Michael Raszeja MR
Coordinator
D.O.T. Non Regulated. The information contained herein is furnished without warranty of any kind. Employers should use this information only as a supplement to other information
gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use of these
Approved by U.S. Department of Labor "essentially similar" to form OSHA-20 materials and the safety and health of employees. * Hazardous Materials Industrial Standards. Printed on recycled paper.
|