SECTION V HEALTH HAZARD DATA
MATERIAL SAFETY DATA SHEET DD 30
3 3
Threshold Limited Value TWA: 75 ppm; 451 mg/m . STEL: 110 ppm; 661 mg/m . (ACGIH 1992-93) Orl-rat LD50:
ALDON 1533 W.Henrietta Rd. 3,826 mg/kg. Drml-rbt LD50: > 5,010 mg/kg. Vpr-Inh-rat LC50: > 5.0 mg/1 (4 hr.)
DD 30
Avon, New York 14414 MSDS No.
庐
CORPORATION Effective Date June 18, 1996
(716) 226-6177
Effects of Overexposure Inhalation can cause effects such as loss of appetite, headache, dizziness,
nausea, irritation of the eyes, nose and throat. Contact with eyes can cause
severe irritation and pain. Skin contact with solid causes slight irritation.
SECTION I NAME 24 HOUR EMERGENCY ASSISTANCE Ingestion may cause abdominal pain, vomiting, diarrhea, coughing,
Product PARA-DICHLOROBENZENE restlessness and effects similar to those listed for inhalation.
CHEMTREC
2 3
Health
800-424-9300
Chemical
Emergency and
2 0
1,4-Dichlorobenzene INHALATION: Remove to fresh air. If not breathing, give artificial
Synonyms 2
Fire
Day 716-226-6177 respiration. If breathing is difficult, give oxygen. Get medical attention.
First Aid Procedures
Formula C6H 4CI2 INGESTION: If swallowed, if conscious, give several glasses of water to
0
Reactivity
NFPA drink. Induce vomiting. Call a physician immediately. Never give
HAZARD RATING HMIS *
Unit Size up to 2.5 Kg. anything by mouth to an unconscious person. EYES: Flush thoroughly
LEAST SLIGHT MODERATE HIGH EXTREME
with water for at least 15 minutes, lifting lower and upper eyelids
0 1 2 3 4
C.A.S. No. 106-46-7
occasionally. Get medical attention. SKIN: Flush with water, then wash
SECTION II INGREDIENTS OF MIXTURES with mild soap and water.
SECTION VI REACTIVITY DATA
Principal Component(s) % TLV Units
Conditions to Avoid
Stability Unstable Direct flame contact.
para-Dichlorobenzene 100% See Section V.
Excessive temperature and heat.
Stable X
Incompatibility Strong oxidizers and oxidizing agents.
(Materials to Avoid)
WARNING! HARMFUL IF INHALED OR SWALLOWED. CAUSES
Hazardous Thermal decomposition or burning may produce carbon dioxide and/or
SKIN, EYE AND RESPIRATORY TRACT IRRITATION. COMBUSTIBLE.
carbon monoxide, chlorides and chlorines.
Decomposition Products
SECTION III PHYSICAL DATA
Conditions to Avoid
Hazardous Polymerization
Specific Gravity (H2O = 1)
Melting Point (掳F) 53掳C (127.4掳F) 1.458 @ 20/4掳C
May Occur Will Not Occur Not applicable.
Percent Volatile
Boiling Point (掳F) 174掳C (345.2掳F) 100%
by Volume (%)
X
Evaporation Rate
SECTION VII SPILL OR LEAK PROCEDURES
Vapor Pressure (mm Hg) 0.6 @ 20掳C (68掳F) water Less than 1.
=1)
(
Steps to be taken in case
Vapor Density (Air=1) 5.1 Recover for use if not contaminated. Provide adequate
material is released or spilled ventilation. Sweep up and place in a metal container. Wash
Solubility in Water Insoluble (0.008 grams per 100 mL. water at 25掳C).
spill area with soap and water.
Appearance & Odor White crystalline solid having penetrating "mothball" odor.
Discharge, treatment, or disposal may be subject to Federal, State or Local laws.
Waste Disposal Method
SECTION IV FIRE AND EXPLOSION HAZARD DATA These disposal guidelines are intended for the disposal of catalog-size quantities only.
Lower
Flammable Limits in Air Upper
Flash Point
66掳C (150掳F) COC N/A Dispose of in an approved incinerator equipped with an afterburner and
% by Volume
(Method Used)
scrubber or contract with a licensed waste disposal service.
Extinguisher Water spray, dry chemical, foam CO2, or any class B extinguishing agent.
SECTION VIII SPECIAL PROTECTION INFORMATION
Media
None should be needed in normal laboratory handling. If fumes or vapors exists,
Respiration Protection
(Specify Type) work in ventilation hood or wear a NIOSH/MSHA approved respirator.
SPECIAL FIREFIGHTING
Local Exhaust Special
Recommended. No.
PROCEDURES Ventilation Recommended. Adequate to maintain below exposure limit.
Mechanical (General) Other
Moderate fire hazard when exposed to heat or flame. Firefighters must
wear a NIOSH/MSHA-approved, self-contained pressure-demand Protective Gloves Eye Protection
Rubber. Chemical safety glasses.
breathing apparatus for possible exposure to vapors or gases.
Other Protective
Goggles, smock, apron, eye wash station, ventilation hood, proper gloves, fire extinguisher.
Equipment
SECTION IX SPECIAL PRECAUTIONS
Precautions to be Taken
UNUSUAL FIRE AND Store in a cool, dry, well-ventilated place away from oxidizing materials, heat
in Handling & Storing
EXPLOSION HAZARDS and open flame. Wash thoroughly with soap and water after handling.
Keep container tightly closed when not in use.
Fire or excessive heat may produce hazardous decomposition Read label on container before using. Do not wear contact lenses when working with chemicals.
Other Precautions
products. Can react vigorously with oxidizing substances.
Avoid contact with skin, eyes and clothing. Avoid breathing dust, vapors or spray
mist. Use with adequate ventilation. Remove and wash contaminated clothing.
For laboratory use only. Not for drug, food or household use. Keep out of reach of children.
Chemical Safety
Approved
Revision Date
No. 5 6/18/96 Michael Raszeja MR
Coordinator
D.O.T. NON-REGULATED. The information contained herein is furnished without warranty of any kind. Employers should use this information only as a supplement to other information
gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use of these
Approved by U.S. Department of Labor "essentially similar" to form OSHA-20 materials and the safety and health of employees. * Hazardous Materials Industrial Standards. Printed on recycled paper.
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