SECTION V HEALTH HAZARD DATA
MATERIAL SAFETY DATA SHEET EE 50
Threshold Limited Value 3
ALDON Ethyl alcohol: TWA: 1,000 ppm; 1,900 mg/m . TLV (skin) Methanol
1533 W.Henrietta Rd. 3 3
200 ppm; 260 mg/m . Ethyl Acetate TWA: 400 ppm; 1400 mg/m (air).
EE 50
Avon, New York 14414 MSDS No.
庐
CORPORATION October 4, 1995
Effective Date
(716) 226-6177
Effects of Overexposure INGESTION: Causes dizziness, drowsiness, decreased reaction, euphoria,
nausea, vomiting, staggering gait, and coma. INHALATION: May cause
SECTION I NAME 24 HOUR EMERGENCY ASSISTANCE dizziness, drowsiness, nausea and vomiting, inability to concentrate and
irritation of the throat. SKIN CONTACT: Irritation and defatting of skin on
Product EOSIN Y, ALCOHOL SOLUTION
CHEMTREC prolonged contact. EYE CONTACT: May cause blindness.
3 Health 1
800-424-9300
Chemical
Emergency and
0
0
Tetrabromofluorescein, Eosin Yellow, C.I. No. 45380 INGESTION: Do NOT give anything by mouth to an unconscious or very
Synonyms 3
Fire
Day 716-226-6177 drowsy person. If conscious, have victim drink several glasses of water.
First Aid Procedures Call physician or Poison Control Center immediately. Induce vomiting if
Mixture. See Section II.
Formula 0
Reactivity
NFPA advised by physician or Poison Control Center. SKIN: Flush thoroughly
with water, then wash with mild soap and water. INHALATION: Remove to
HAZARD RATING HMIS *
up to 4 Lt.
Unit Size
fresh air. Give artificial respiration if not breathing. Oxygen may be given
LEAST SLIGHT MODERATE HIGH EXTREME
by qualified personnel if breathing is difficult. Obtain medical attention.
0 1 2 3 4
C.A.S. No. Mixture. See Section II. EYES: Flush thoroughly with water for at least 15 minutes, lifting upper and
lower eyelids occasionally. Get immediate medical attention.
SECTION II INGREDIENTS OF MIXTURES
SECTION VI REACTIVITY DATA
Principal Component(s) % TLV Units
Conditions to Avoid
Stability Unstable Protect from light, excessive temperature,
Eosin Y: (CAS No. 17372-87-1) 0.2% None established.
heat, sparks and flame.
Stable X
Ethyl Alcohol, Denatured *: (CAS No. 64-17-5) 99.8% See Section V. Incompatibility Contact with Acetyl chloride and strong oxidizing agents may react violently.
(Materials to Avoid) Concentrated nitric or sulfuric acid.
WARNING! FLAMMABLE! MAY BE HARMFUL IF SWALLOWED. AVOID PROLONGED OR
Hazardous Thermal decomposition or burning can produce carbon monoxide and/or
REPEATED BREATHING OF VAPOR. OVEREXPOSURE TO VAPOR MAY BE HARMFUL.
Decomposition Products carbon dioxide.
SECTION III PHYSICAL DATA
Conditions to Avoid
Hazardous Polymerization
Specific Gravity (H2O = 1)
Melting Point (掳F) -113掳C (-173掳F) Approx. 0.794 @ 60掳C
May Occur Will Not Occur Not applicable.
Percent Volatile
Boiling Point (掳F) 75掳-80掳C (163掳-174掳F) 99.8%
by Volume (%) X
Evaporation Rate
SECTION VII SPILL OR LEAK PROCEDURES
Vapor Pressure (mm Hg) Ca 44.6 at 68掳F ( Butyl Acetate 4.1
=1)
Steps to be taken in case Remove all sources of ignition, provide adequate ventilation. For small
Vapor Density (Air=1) 1.6
material is released or spilled spills, dilute with water and flush to sewer with copious amounts of
Solubility in Water water or absorb on vermiculite, paper, earth or other absorbent. Burn
Complete.
in an approved incinerator or open pit away from buildings and people.
Appearance & Odor Yellow, fluorescent liquid; hydrocarbon odor.
Discharge, treatment, or disposal may be subject to Federal, State or Local laws.
Waste Disposal Method
SECTION IV FIRE AND EXPLOSION HAZARD DATA These disposal guidelines are intended for the disposal of catalog-size quantities only.
Lower
Flammable Limits in Air Upper
Flash Point
Dispose of in an approved incinerator or contract with a licensed chemical waste
% by Volume
(Method Used) 8.89掳C (48掳F) TCC (Ethyl Alc.) Alcohol 3.3% (Et. Alc.) 19% (Et. Alc.)
disposal agency.
Carbon dioxide (CO2); dry chemical (ABC); water spray or fog.
Extinguisher
SECTION VIII SPECIAL PROTECTION INFORMATION
Media
Alcohol type or universal-type foams.
For normal laboratory use at room temperatures none should be needed with adequate
Respiration Protection
room ventilation. If required work in fume hood. Do not use in confined area.
(Specify Type)
SPECIAL FIREFIGHTING
Recommended. No.
Local Exhaust Special
PROCEDURES Ventilation Recommended. No.
In fire conditions, wear a NIOSH/MSHA-approved self-contained Mechanical (General) Other
* Denaturents:
breathing apparatus and full protective clothing.
Protective Gloves Eye Protection
Rubber. Chemical safety glasses.
Methanol: (CAS No. 67-56-1)
Ignition temperature: 685掳F (363掳C).
Ethyl Acetate: (CAS No. 141-78-6)
Other Protective
Methyl Isobutyl Ketone: (CAS No. 108-10-1)
Proper gloves, smock, apron, eye wash station, fire extinguisher and a ventilation hood.
Rubber Hydrocarbon Solvent: (CAS No. 64742-89-8) Equipment
Benzene: (CAS No. 71-43-2)
SECTION IX SPECIAL PRECAUTIONS
Water: (CAS No. 7732-18-5)
Precautions to be Taken
UNUSUAL FIRE AND Vapors formed from this product may travel or be moved by air Store in a cool, dry, well-ventilated area, away from fire hazards. Wash
in Handling & Storing
EXPLOSION HAZARDS currents and ignited by pilot lights, other flames, smoking, sparks, thoroughly after handling. Do not take internally.
Keep container tightly closed when not in use.
heaters, electrical equipment, static discharge, or other ignition
Read label on container before using. Do not wear contact lenses when working with chemicals.
sources at location distant from handling point. CAUTION: Other Precautions
Flame may not be visible in daylight. Fire or excessive heat may
Avoid prolonged or repeated breathing of vapor. Use with adequate
produce hazardous decomposition products; can react vigorously
ventilation. Remove and wash contaminated clothing.
with oxidizing materials.
For laboratory use only. Not for drug, food or household use. Keep out of reach of children.
Chemical Safety
Approved
(1993 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.6, GUIDE PAGE NO. 26) Revision Date MR
No. 4 10/4/95 Michael Raszeja Coordinator
D.O.T. DENATURED ALCOHOL, SOLUTION, 3, NA 1987 The information contained herein is furnished without warranty of any kind. Employers should use this information only as a supplement to other information
gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use of these
Approved by U.S. Department of Labor "essentially similar" to form OSHA-20 materials and the safety and health of employees. * Hazardous Materials Industrial Standards. Printed on recycled paper.
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