SECTION V HEALTH HAZARD DATA
MATERIAL SAFETY DATA SHEET EE 80
Ethyl Alcohol TWA: 1000 ppm; 1880 mg/m 3 (Air). Methanol TWA: 200
Threshold Limited Value
ALDON ppm; 262 mg/m3 (Skin); Ethyl Acetate TWA: 400 ppm; 1440 mg/m3
1533 W.Henrietta Rd.
EE 80 (Air),(ACGIH 1992-93).
Avon, New York 14414 MSDS No.
庐
CORPORATION November 25, 1996
Effective Date
(716) 226-6177
Effects of Overexposure INGESTION: Causes dizziness, drowsiness, decreased reaction, euphoria,
nausea, vomiting, staggering gait, and coma. INHALATION: May cause
dizziness, drowsiness, nausea and vomiting, inability to concentrate and
SECTION I NAME 24 HOUR EMERGENCY ASSISTANCE
irritation of the throat. SKIN CONTACT: Irritation and defatting of skin on
Product ETHYL ALCOHOL, DENATURED prolonged contact. EYE CONTACT: May cause blindness.
CHEMTREC
3 3
Health
800-424-9300
Chemical
Emergency and
0
0
Ethanol, Proprietary Solvent, 190 Proof INGESTION: Do NOT give anything by mouth to an unconscious or very
Synonyms 4
Fire
Day 716-226-6177 drowsy person. If conscious, have victim drink several glasses of water.
First Aid Procedures Call physician or Poison Control Center immediately. Induce vomiting if
Formula CH CH OH (Mixture - See Section II & IV) 2
Reactivity
3 2 NFPA advised by physician or Poison Control Center. SKIN: Flush thoroughly
with water, then wash with mild soap and water. INHALATION: Remove to
HAZARD RATING HMIS *
Unit Size 8 oz. ; 500 mL. ; 1, 4, 20 Lt.
fresh air. Give artificial respiration if not breathing. Oxygen may be given by
LEAST SLIGHT MODERATE HIGH EXTREME
qualified personnel if breathing is difficult. Obtain medical attention. EYES:
0 1 2 3 4
C.A.S. No. None assigned. Mixture. Flush thoroughly with water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Get immediate medical attention.
SECTION II INGREDIENTS OF MIXTURES
SECTION VI REACTIVITY DATA
Principal Component(s) % TLV Units
Conditions to Avoid
Stability Unstable
Ethyl Alcohol: (CAS No. 64-17-5) 85.7% PEL/TLV 1000 ppm Heat, fire, ignition source.
Stable X
Water: (CAS No. 7732-18-5) 7.0% None established. Incompatibility Concentrated nitric or sulfuric acid; contact with Acetyl chloride and strong oxidizing
agents may react violently.
(Materials to Avoid)
Methyl Alcohol: (CAS No. 67-56-1) 3.6% TWA: 200 ppm; STEL: 250 ppm (Skin)
Hazardous Thermal decomposition or burning can produce carbon monoxide and/or
Methyl Isobutyl Ketone: (CAS No. 108-10-1) 1.9% TWA: 50 ppm; STEL: 75 ppm
carbon dioxide.
Decomposition Products
SECTION III PHYSICAL DATA
Conditions to Avoid
Hazardous Polymerization
Specific Gravity (H2O = 1)
Melting Point (掳F) -113掳C (-173掳F) * 0.814 @ 60掳F
May Occur Will Not Occur Not applicable.
Percent Volatile
Boiling Point (掳F) 75-80掳C (163-174掳F) * 100% X
by Volume (%)
Evaporation Rate
SECTION VII SPILL OR LEAK PROCEDURES
Vapor Pressure (mm Hg) Ca 44.6 @ 68掳F * ( Butyl Acetate 4.1
=1)
Steps to be taken in case
Vapor Density (Air=1) Ca 1.59 * Remove all sources of ignition, provide adequate ventilation. For small
material is released or spilled spills, dilute with water and flush to sewer with copious amounts of water
Solubility in Water or absorb on vermiculite, paper, earth or other absorbent. Burn in an
Complete.
approved incinerator or open pit away from buildings and people.
Appearance & Odor Clear, colorless, mobile liquid; mild characteristic odor.
Discharge, treatment, or disposal may be subject to Federal, State or Local laws.
Waste Disposal Method
SECTION IV FIRE AND EXPLOSION HAZARD DATA These disposal guidelines are intended for the disposal of catalog-size quantities only.
Lower
Flammable Limits in Air Upper
Flash Point
Dispose of in an approved incinerator or contract with a licensed waste
% by Volume Pure Ethyl Alc.
(Method Used) 50掳F (10掳C) TCC. 3.3 (Et. Alc.) 19.0 (Et. Alc.) disposal service.
Extinguisher
Water spray, carbon dioxide (CO2); dry chemical (ABC); alcohol-type, or universal-type foams. SECTION VIII SPECIAL PROTECTION INFORMATION
Media
For normal laboratory use at room temperatures none should be needed with adequate
Respiration Protection
room ventilation. If required work in fume hood. Do not use in confined area.
(Specify Type)
SPECIAL FIREFIGHTING Wear a NIOSH-approved self-contained breathing apparatus and
Recommended. No.
Local Exhaust Special
PROCEDURES Ventilation
protective clothing. Use flooding amounts of water in early stages of fire.
Recommended. No.
Mechanical (General) Other
Autoignition Temperature: 363掳C (685掳F)
Protective Gloves Eye Protection
Rubber. Chemical safety glasses.
Contains Continued:
Other Protective
Ethyl Acetate: (CAS No. 141-78-6)...0.9%...TWA: 400 ppm. Smock, apron, eye wash station, goggles, fire extinguisher, proper gloves.
Equipment
Rubber Hydrocarbon Solvent: (CAS No. 64742-89-8)...0.8%...TLV/TWA: 400 ppm.
SECTION IX SPECIAL PRECAUTIONS
* For Pure Ethyl Alcohol
Precautions to be Taken
UNUSUAL FIRE AND Store in a cool, dry, well-ventilated area, away from any fire hazard.
in Handling & Storing
Vapors formed from this product may travel or be moved by air currents and
EXPLOSION HAZARDS Use with adequate ventilation. Do not take internally.
Keep container tightly closed when not in use.
ignited by pilot lights, other flames, smoking, sparks, heaters, electrical
equipment, static discharge, or other ignition sources at location distant from Read label on container before using. Do not wear contact lenses when working with chemicals.
Other Precautions
handling point. CAUTION: Flame may not be visible in daylight. Fire or
excessive heat may produce hazardous decomposition products; can react Wash thoroughly after handling.
vigorously with oxidizing materials. Remove and wash contaminated clothing.
For laboratory use only. Not for drug, food or household use. Keep out of reach of children.
Chemical Safety
(1993 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.6, GUIDE PAGE NO. 26) Approved
Revision Date
No. 8 Michael Raszeja MR
11/25/96 Coordinator
D.O.T. DENATURED ALCOHOL, 3, NA 1987, PG II The information contained herein is furnished without warranty of any kind. Employers should use this information only as a supplement to other information
gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use of these
Approved by U.S. Department of Labor "essentially similar" to form OSHA-20 materials and the safety and health of employees. * Hazardous Materials Industrial Standards. Printed on recycled paper.
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