SECTION V HEALTH HAZARD DATA
MATERIAL SAFETY DATA SHEET EE 110
Threshold Limited Value
ALDON TWA: Vapor-CEIL: 50 ppm ; CEIL: 127 mg/m3 . (ACGIH, 1992-93).
1533 W.Henrietta Rd.
EE 110
Avon, New York 14414 MSDS No.
庐
CORPORATION November 20, 1996
Effective Date
(716) 226-6177
Effects of Overexposure INHALATION: Prolonged exposure to high concentrations of the heated
vapor or mist can cause narcosis and may result in systemic toxic effect.
SECTION I NAME 24 HOUR EMERGENCY ASSISTANCE INGESTION: Can be harmful or fatal if swallowed. Repeated ingestion can
cause liver and kidney damage. EYES: May cause irritation. SKIN:
Product ETHYLENE GLYCOL Prolonged contact may result in toxic amounts penetrating the intact skin.
CHEMTREC
1 2
Health
800-424-9300
Chemical
Emergency and
1 0
1,2-Ethanediol, Glycol
Synonyms 1
Fire INHALATION AS MIST: Remove to fresh air. If breathing has stopped, give
Day 716-226-6177
First Aid Procedures artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Formula HOCH 2CH2 OH 1
Reactivity
NFPA INGESTION: If swallowed, if conscious, give one or two glasses of water to
HAZARD RATING drink. Induce vomiting and call physician immediately. Never give anything by
HMIS *
Unit Size up to 4 Lt.
mouth to an unconscious person. SKIN: Flush thoroughly with water, then
LEAST SLIGHT MODERATE HIGH EXTREME
0 1 2 3 4 wash with mild soap and water. EYES: Flush thoroughly with water for 15
C.A.S. No. 107-21-1
minutes, lifting lower and upper eyelids occasionally. Get medical attention.
SECTION II INGREDIENTS OF MIXTURES
SECTION VI REACTIVITY DATA
Principal Component(s) % TLV Units
Conditions to Avoid
Stability Unstable Excessive temperature and heat,
Ethylene Glycol 100% See Section V.
Stable open flame or sparks.
X
Incompatibility May react strongly with oxidizing materials (chlorates, nitric acid, nitrates,
permanganates, etc.).
(Materials to Avoid)
WARNING! HARMFUL OR FATAL IF SWALLOWED.
Hazardous
HARMFUL IF ABSORBED THROUGH SKIN. Thermal decomposition products; carbon monoxide and/or carbon dioxide.
Decomposition Products
SECTION III PHYSICAL DATA
Conditions to Avoid
Hazardous Polymerization
Specific Gravity (H2O = 1)
Melting Point (掳F) -13掳C (9掳F) 1.1154 (20/4掳C)
May Occur Will Not Occur Not applicable.
Percent Volatile
Boiling Point (掳F) 197.5掳C (388掳F) 100%
by Volume (%) X
Evaporation Rate
SECTION VII SPILL OR LEAK PROCEDURES
Vapor Pressure (mm Hg) 0.08 mm @ 20掳C ( Butyl Acetate 0.01
=1)
Steps to be taken in case
Vapor Density (Air=1) 2.14
Wearing suitable protective clothing, absorb spilled material in
material is released or spilled
an inert dry material. Place in a suitable container for disposal.
Solubility in Water Completely.
Wash spill area well with soap and water.
Appearance & Odor Clear, colorless, slightly viscous, hygroscopic liquid; mild odor.
Discharge, treatment, or disposal may be subject to Federal, State or Local laws.
Waste Disposal Method
SECTION IV FIRE AND EXPLOSION HAZARD DATA These disposal guidelines are intended for the disposal of catalog-size quantities only.
Lower
Flammable Limits in Air Upper
Flash Point
% by Volume
(Method Used) 232掳F (111.1掳C) TCC 275掳F 3.2% 15.3% Dispose of in accordance with federal, state and local regulations.
Extinguisher
Water spray; carbon dioxide; dry chemical. SECTION VIII SPECIAL PROTECTION INFORMATION
Media
None should be needed in normal laboratory handling at room temperature. In misty conditions, wear
Respiration Protection
a NIOSH/MSHA-approved, self-contained breathing apparatus or work in adequate ventilation hood.
(Specify Type)
SPECIAL FIREFIGHTING
No.
Local Exhaust Not needed at room temp. Special
PROCEDURES Wear a NIOSH/MSHA-approved, self-contained breathing apparatus and
Ventilation No.
Not needed at room temp.
Mechanical (General) Other
full protective clothing. Use water spray to keep fire-exposed containers
cool. Water spray may be used to flush spills away from exposures and Protective Gloves Eye Protection
Rubber. Chemical safety glasses.
to dilute spills to non-combustible mixtures.
Other Protective
Smock, apron, eye wash station, goggles, proper gloves.
Equipment
Ignition Temperature: 748掳F (398掳C).
SECTION IX SPECIAL PRECAUTIONS
Precautions to be Taken
UNUSUAL FIRE AND Store in a cool, dry, well-ventiolated area away from oxidizing materials
in Handling & Storing
EXPLOSION HAZARDS and fire hazards. Wash thoroughly after handling.
Keep container tightly closed when not in use.
Although ethylene glycol has a high flash point, vapor concentrations that Read label on container before using. Do not wear contact lenses when working with chemicals.
Other Precautions
exceed 3.2% by volume can form flammable mixtures in air. When
Do not take internally. Do not breathe vapors or fumes. Avoid contact
misted in air, glycol becomes a moderate fire and explosion hazard.
with eyes. Remove and wash contaminated clothing.
Class III B combustible liquid.
For laboratory use only. Not for drug, food or household use. Keep out of reach of children.
Chemical Safety
Approved
Revision Date
No. 3 11/20/96 Michael Raszeja MR
Coordinator
D.O.T. NON-REGULATED. The information contained herein is furnished without warranty of any kind. Employers should use this information only as a supplement to other information
gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use of these
Approved by U.S. Department of Labor "essentially similar" to form OSHA-20 materials and the safety and health of employees. * Hazardous Materials Industrial Standards. Printed on recycled paper.
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