SECTION V HEALTH HAZARD DATA
MATERIAL SAFETY DATA SHEET EKB05566
None established by ACGIH. RTECS No. EK0440000 Toxicity data:
Threshold Limited Value
ALDON orl-rat LD50: 23 gm/kg; scu-rat LD50: 20 gm/kg; orl-mus LD50:
1533 W.Henrietta Rd.
EKB05566 12980 mg/kg; orl-gpg LD50: 11 gm/kg.
Avon, New York 14414 MSDS No.
庐
CORPORATION November 26, 1996
(716) 226-6177 Effective Date
Effects of Overexposure Practically non-toxic to animals (oral LD50 rats: 23gm/kg.). Essentially
non-irritating to skin and eyes. Significant exposure to this chemical may
SECTION I NAME 24 HOUR EMERGENCY ASSISTANCE adversely affect people with chronic disease of the Central Nervous
System, blood, skin and/or cardiovascular system.
Product BUTYLENE GLYCOL CHEMTREC
1 1
Health
800-424-9300
Chemical
Emergency and
1 0
1,3-Butanediol
Synonyms 1
Fire
Day 716-226-6177 INGESTION: No harmful effects expected. INHALATION: Remove to
First Aid Procedures
Formula HOCH2CH2CHOHCH3 fresh air. If not breathing, give artificial respiration. If breathing is difficult,
0
Reactivity
NFPA give oxygen. Get medical attention. SKIN: Flush with water, then wash
HAZARD RATING HMIS *
Unit Size up to 180 Kg. with mild soap and water. EYES: Flush with water for 15 minutes, lifting
LEAST SLIGHT MODERATE HIGH EXTREME
upper and lower eyelids occasionally. If irritation develops, get medical
0 1 2 3 4
C.A.S. No. 107-88-0 attention.
SECTION II INGREDIENTS OF MIXTURES
SECTION VI REACTIVITY DATA
Principal Component(s) % TLV Units
Conditions to Avoid
Unstable
Stability
1,3-Butylene Glycol 100% None established. Heat, sparks or flame.
Stable X
See Section V. Incompatibility Sulfuric acid, phosphoric acid and other dehydrating agents; Nitric acid, oxygen
(Materials to Avoid) hydrogen peroxide, perchloric acid and other strong oxidizing agents.
CAUTION! KEEP AWAY FROM HEAT, SPARKS AND FLAME. ALWAYS
Hazardous
OPEN CONTAINER SLOWLY TO ALLOW EXCESS PRESSURE TO VENT. Carbon monoxide, butadiene.
Decomposition Products
SECTION III PHYSICAL DATA
Conditions to Avoid
Hazardous Polymerization
Specific Gravity (H2O = 1)
Melting Point (掳F) Freezing point -50掳C (-58掳F) 1.005 @ 20/20掳C
May Occur Will Not Occur Flame.
Percent Volatile
Boiling Point (掳F) 207.5掳C (406掳F) 100%
by Volume (%) X
Evaporation Rate
SECTION VII SPILL OR LEAK PROCEDURES
Vapor Pressure (mm Hg) 0.06 @ 20掳C ( Butyl Acetate Nil
=1)
Steps to be taken in case
Vapor Density (Air=1) 3.1 @ 20掳C Eliminate ignition sources. Absorb spill in absorbent material,
material is released or spilled shovel into suitable container for proper disposal. Avoid runoff into
Solubility in Water Complete. storm sewers and ditches which lead to natural waterways.
Appearance & Odor Clear, colorless, mobile syrupy liquid; essentially odorless.
Discharge, treatment, or disposal may be subject to Federal, State or Local laws.
Waste Disposal Method
SECTION IV FIRE AND EXPLOSION HAZARD DATA These disposal guidelines are intended for the disposal of catalog-size quantities only.
Lower
Flammable Limits in Air Upper
Flash Point
121掳C (250掳F) TOC ASTM D1310 N/A
% by Volume Dispose of in accordance with federal, state and local regulations.
(Method Used)
Use carbon dioxide (CO2) or dry chemical for small fires. Alcohol-type aqueous film-forming
Extinguisher
SECTION VIII SPECIAL PROTECTION INFORMATION
Media foam or water spray for large fires.
Respiration Protection
Use a NIOSH/MSHA approved respirator with organic vapor cartridge.
(Specify Type)
SPECIAL FIREFIGHTING
Recommended. No.
Local Exhaust Special
If potential for exposure to vapors or products of combustion exists,
PROCEDURES Ventilation Recommended. No.
Mechanical (General) Other
wear complete personal protective equipment, including self-contained
breathing apparatus with full facepiece operated in pressure-demand
Eye Protection
Protective Gloves Neoprene or rubber. Chemical safety goggles.
or other positive-pressure mode. Water spray can be used to reduce
Other Protective
intensity of flames and to dilute spills to non-flammable mixture. Use Lab coat, apron, eye wash station, proper gloves, safety shower.
Equipment
water spray to cool fire exposed structures and vessels.
SECTION IX SPECIAL PRECAUTIONS
Precautions to be Taken Always open containers slowly to allow any excess pressure to vent. Store in
UNUSUAL FIRE AND in Handling & Storing 15-27掳C (60-80掳F) range to minimize taste and odor buildup. Keep away
EXPLOSION HAZARDS from heat, sparks and flame. Wash thoroughly after handling.
Keep container tightly closed when not in use.
Read label on container before using. Do not wear contact lenses when working with chemicals.
Other Precautions
Foam or water can cause frothing.
Avoid contact with skin, eyes and clothing. Avoid breathing vapor or mist.
Use with adequate ventilation. Remove and wash contaminated clothing.
For laboratory use only. Not for drug, food or household use. Keep out of reach of children.
Chemical Safety
Approved
Revision Date Michael Raszeja MR
11/26/96
No. 2 Coordinator
D.O.T. NON-REGULATED. The information contained herein is furnished without warranty of any kind. Employers should use this information only as a supplement to other information
gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use of these
Approved by U.S. Department of Labor "essentially similar" to form OSHA-20 materials and the safety and health of employees. * Hazardous Materials Industrial Standards. Printed on recycled paper.
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