SECTION V HEALTH HAZARD DATA
MATERIAL SAFETY DATA SHEET DD 47
Threshold Limited Value
ALDON None established for this mixture.
1533 W.Henrietta Rd.
DD 47
Avon, New York 14414 MSDS No.
庐
CORPORATION January 4, 1996
Effective Date
(716) 226-6177
Effects of Overexposure INHALATION: Fumes can cause damage to nasal and respiratory
passages. EYES: Causes severe damage and even blindness very rapidly.
SKIN: Causes severe, deep wounds to tissue; very corrosive effect,
SECTION I NAME 24 HOUR EMERGENCY ASSISTANCE
possible deep ulcerations. INGESTION: Results in severe damage to
Product DIPHENYLAMINE OXIDATION-REDUCTION IND. SOL'N. mucous membranes and deep tissue.
CHEMTREC
0 3
Health
800-424-9300
Chemical
Emergency and
Diphenylamine Sulfuric Acid Solution 3 2 SKIN: Immediately flush exposed area with water for at least 15 minutes. If
Synonyms 0
Fire
Day 716-226-6177 irritation develops or persists, get medical attention. EYES: Immediately
First Aid Procedures
W
flush with large amounts of water for at least 15 minutes, lifting lower and
Mixture. See Section II.
Formula 4
Reactivity
NFPA upper eyelids occasionally. Get immediate medical attention. INHALA-
HAZARD RATING TION: Remove to fresh air. If not breathing, give artificial respiration. If
HMIS *
up to 4 Lt.
Unit Size
breathing is difficult, give oxygen. Call physician immediately. INGESTION:
LEAST SLIGHT MODERATE HIGH EXTREME
DO NOT INDUCE VOMITING. Drink large amounts of water. Follow with
0 1 2 3 4
Mixture. See Section II.
C.A.S. No.
milk of magnesia, vegetable oil, or beaten eggs. Call physician immediately.
SECTION II INGREDIENTS OF MIXTURES Never give anything by mouth to an unconscious person.
SECTION VI REACTIVITY DATA
Principal Component(s) % TLV Units
Conditions to Avoid
Stability Unstable Do not add water or other liquids to the acid
3
Diphenylamine: (CAS No. 122-39-4) 0.73% 10 mg/m (ACGIH).
solution.
Stable X
1 mg/m3 (ACGIH). Extremely hazardous in contact with many materials, particularly carbides,
Sulfuric Acid: (CAS No. 7664-93-9) 71% Incompatibility chlorates, fulminates, nitrates, picrates, powered metals and other combustible
(Materials to Avoid) materials. Attacks many metals, releasing hydrogen.
Water: (CAS No. 7732-18-5) 28.27%
Hazardous
DANGER! CORROSIVE! CAUSES SEVERE BURNS When heated to decomposition, may release sulfur dioxide, oxides of
TO SKIN, EYES AND MUCOUS MEMBRANES.
Decomposition Products nitrogen and carbon.
SECTION III PHYSICAL DATA
Conditions to Avoid
Hazardous Polymerization
Specific Gravity (H2O = 1)
Melting Point (掳F) Data not listed. 1.698 at 20掳C
May Occur Will Not Occur Not applicable.
Percent Volatile
Boiling Point (掳F) 28.27%
>100掳C (212掳F) but <290掳C (554掳F) X
by Volume (%)
Evaporation Rate
SECTION VII SPILL OR LEAK PROCEDURES
Vapor Pressure (mm Hg) Data not listed. Data not listed.
=1)
(
Steps to be taken in case Prevent contact with this acid solution. Minor leaks or spills can be
Vapor Density (Air=1) Data not listed.
material is released or spilled diluted with plenty of water and neutralized with soda ash or lime. If
Solubility in Water Complete. water is not available, cover contaminated area with sand, ashes, or
gravel and neutralize with soda ash or lime.
Appearance & Odor Dark blue, clear liquid; no odor.
Discharge, treatment, or disposal may be subject to Federal, State or Local laws.
Waste Disposal Method
SECTION IV FIRE AND EXPLOSION HAZARD DATA These disposal guidelines are intended for the disposal of catalog-size quantities only.
Lower
Flammable Limits in Air Upper
Flash Point Using extreme care and wearing full safety equipment neutralize the acid
% by Volume
(Method Used) Not flammable. NA -------- -------- solution using sodium bicarbonate, soda ash or lime and flush to sewer with
copious amounts of water.
Extinguisher
SECTION VIII SPECIAL PROTECTION INFORMATION
Water spray * ; foam; carbon dioxide (CO2 ); dry chemical (ABC).
Media
None needed in normal laboratory handling. If misty conditions prevail, work in ventilation
Respiration Protection
hood or wear a NIOSH/MSHA-approved full head covering respirator fixed with goggles.
(Specify Type)
SPECIAL FIREFIGHTING
Fires involving small amounts of combustibles may be smothered with If misty conditions. No.
Local Exhaust Special
PROCEDURES Ventilation
suitable dry chemical. * Use water on combustibles burning in vicinity If misty conditions. No.
Mechanical (General) Other
of this material but use care as water applied directly to this acid
Protective Gloves Eye Protection
Vinyl, Neoprene. Chemical safety glasses.
results in evolution of heat and causes spattering. In fire conditions,
wear a NIOSH/MSHA-approved self-contained breathing apparatus
Other Protective
and full protective clothing to prevent contact with skin and eyes. Goggles; lab coat and apron; proper gloves; ventilation hood; safety shower; eye wash station.
Equipment
SECTION IX SPECIAL PRECAUTIONS
(1993 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.6, GUIDE PAGE NO. 39)
Precautions to be Taken
UNUSUAL FIRE AND Keep container tightly closed when not in use. Absorbs moisture from the air. Store
in Handling & Storing
EXPLOSION HAZARDS in a cool, dry, well-ventilated area away from the incompatible materials listed above.
Not flammable but highly reactive and capable of igniting finely divided Keep container tightly closed when not in use.
combustible materials on contact. Reacts violently with water and
Read label on container before using. Do not wear contact lenses when working with chemicals.
Other Precautions
organic materials with evolution of heat. Extremely hazardous in
contact with many materials, particularly carbides, chlorates, Never add water to this acid solution. Always add this acid solution to water. Addition
fulminates, nitrates, picrates, powered metals and other combustible of water may release heat which could result in splattering. Always add slowly and in
materials. Attacks many metals, releasing hydrogen. small amounts. Never use hot water. Remove and wash contaminated clothing.
For laboratory use only. Not for drug, food or household use. Keep out of reach of children.
Chemical Safety
Approved
Revision Date
No. 3 1/04/96 Michael Raszeja MR
Coordinator
D.O.T. Sulfuric acid, (Solution), 8, UN 1830, PG II The information contained herein is furnished without warranty of any kind. Employers should use this information only as a supplement to other information
gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use of these
Approved by U.S. Department of Labor "essentially similar" to form OSHA-20 materials and the safety and health of employees. * Hazardous Materials Industrial Standards. Printed on recycled paper.
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