SECTION V HEALTH HAZARD DATA
MATERIAL SAFETY DATA SHEET FF 190
Threshold Limited Value 8 hour TWA: 1 mg/m3 (as Iron) (ACGIH 1983-84). TLV for soluble salts.
ALDON 1533 W.Henrietta Rd.
Toxicity studies: Rat, Oral LD50 1480 mg/Kg.
FF 190
Avon, New York 14414 MSDS No.
庐
CORPORATION September 13, 1995
Effective Date
(716) 226-6177
Effects of Overexposure INGESTION: Low in toxicity, but excessive ingestion can produce GI tract
disturbances, severe shock, vomiting, liver damage and even death. EYES:
SECTION I NAME 24 HOUR EMERGENCY ASSISTANCE Contact is irritating and can be damaging. SKIN: Contact with the skin,
especially if repeated or prolonged, is irritating.
Product FERROUS SULFATE
CHEMTREC Health 1
800-424-9300
Chemical
Emergency and
Iron (II) Sulfate
Synonyms EYES: Flush thoroughly with water for at least 15 minutes, lifting upper
0
Fire
Day 716-226-6177
First Aid Procedures and lower eyelids occasionally. Get medical attention. SKIN: Flush
FeSO4鈥?7H2O
Formula 0
Reactivity thoroughly with water, then wash with mild soap and water. INHALATION:
NFPA
Remove to fresh air. If illness or discomfort develops, get medical
HAZARD RATING HMIS *
up to 2.5 Kg.
Unit Size
attention. INGESTION: If swallowed, if conscious, give one or two glasses
LEAST SLIGHT MODERATE HIGH EXTREME
0 1 2 3 4 of water to drink. Induce vomiting and call physician. Never give anything
7782-63-0
C.A.S. No.
by mouth to an unconscious person.
SECTION II INGREDIENTS OF MIXTURES
SECTION VI REACTIVITY DATA
Principal Component(s) % TLV Units
Conditions to Avoid
Stability Unstable
Efflorescent in dry air; oxidizes in moist air
3
Ferrous Sulfate Heptahydrate Ca 100% 1 mg Fe/m forming a brown coating of basic ferric sulfate.
Stable X
1 mg/m 3 Aqueous solutions are oxidized slowly by air when cold, rapidly when hot; rate of oxidation
Contains small amounts of free Sulfuric Acid: 1% Incompatibility
increased by addition of alkali or exposure of light. Alkalies, sol carbonates, gold and silver salts,
(Materials to Avoid) lead acetate, limewater, potassium iodide, potassium and sodium tartrate, sodium borate.
(CAS No. 7664-93-9)
Hazardous
WARNING! HARMFUL IF SWALLOWED. IRRITANT. Thermal decomposition or burning may produce oxides of sulfur (SOx).
Decomposition Products
SECTION III PHYSICAL DATA
Conditions to Avoid
Hazardous Polymerization
Specific Gravity (H2O = 1)
Melting Point (掳F) 72掳C (147掳F) 1.897
May Occur Will Not Occur Not applicable.
Percent Volatile
Boiling Point (掳F) Decomposes. Non-volatile (NA). X
by Volume (%)
Evaporation Rate
SECTION VII SPILL OR LEAK PROCEDURES
Vapor Pressure (mm Hg) 14.6 mm Non-volatile (NA).
=1)
(
Steps to be taken in case
Vapor Density (Air=1) 9.6
material is released or spilled Sweep up and place in a suitable container.
Solubility in Water About 16 grams per 100 mL. water at 20掳C; 48.6 g. at 50掳C.
Appearance & Odor Greenish or yellow-brown crystals; no odor. Hygroscopic.
Discharge, treatment, or disposal may be subject to Federal, State or Local laws.
Waste Disposal Method
SECTION IV FIRE AND EXPLOSION HAZARD DATA These disposal guidelines are intended for the disposal of catalog-size quantities only.
Lower
Flammable Limits in Air Upper
Flash Point
Dissolve in water and flush to sewer using copious amounts of water or if uncontaminated
% by Volume
(Method Used) Non-flammable (NA). NA -------- --------
material may be disposed of in a sanitary landfill. Check local codes.
Extinguisher Use any media suitable for extinguishing supporting fire. SECTION VIII SPECIAL PROTECTION INFORMATION
Media
None should be needed in normal laboratory handling. If dusty conditions prevail, wear a
Respiration Protection
NIOSH/MSHA-approved dust mask or respirator.
(Specify Type)
SPECIAL FIREFIGHTING
Local Exhaust Special
Not needed. No.
PROCEDURES Ventilation Not needed. No.
Mechanical (General) Other
In fire conditions, wear a NIOSH/MSHA-approved self-contained
Protective Gloves Eye Protection
Rubber. Chemical safety glasses.
breathing apparatus and full protective clothing.
Other Protective
Lab coat, eye wash station, proper gloves, goggles.
Equipment
SECTION IX SPECIAL PRECAUTIONS
Precautions to be Taken
UNUSUAL FIRE AND Store in a cool, dry place away from alkaline materials and oxidizing
in Handling & Storing
agents. Store at temperature below 24掳C (75掳F) to prevent caking.
EXPLOSION HAZARDS Keep container tightly closed when not in use.
Read label on container before using. Do not wear contact lenses when working with chemicals.
Hot aqueous solutions rapidly oxidized by air. This material is Other Precautions
decomposed at high temperatures to produce toxic and
Wash thoroughly after handling.
corrosive materials.
Remove and wash contaminated clothing.
For laboratory use only. Not for drug, food or household use. Keep out of reach of children.
Chemical Safety
Approved
Revision Date 9/13/95 Michael Raszeja MR
No. 4 Coordinator
D.O.T. NON-REGULATED. The information contained herein is furnished without warranty of any kind. Employers should use this information only as a supplement to other information
gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use of these
Approved by U.S. Department of Labor "essentially similar" to form OSHA-20 materials and the safety and health of employees. * Hazardous Materials Industrial Standards. Printed on recycled paper.
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