Copper Care
MATERIAL SAFETY DATA SHEET
Wood Preservatives, Inc.
Emergency Telephone: 800-800-7620
COPPER CARE PRODUCT NAME:
SUPER-FUME
ATTENTION: SAFETY MANAGER Date of Last Revision: 04/17/08
USA EPA Registration Number: 1448-104-54471
USA EPA Est. Number: 54471-NB-001
I. OSHA HAZARD CLASSIFICATIONS
Irritating to eyes and skin, and respiratory tract. Avoid inhalation of dust.
II. HAZARDOUS COMPONENTS
Chemical Name CAS Number % by Weight TLV
Tetrahydro-3,5-dimethyl-2H-1,3,5-thiadiazine-2-thione 533-74-4 98 Not Available
The remainder of the components comprise proprietary information.
III. FIRST AID INFORMATION
Eye Exposure: Flush immediately with copious amounts of tap water or normal saline (minimum of 15 minutes). Take
exposed individual to a health care professional, preferably an ophthalmologist, for further evaluation.
Skin Exposure: Wash exposed area with plenty of soap and water. Repeat washing. Remove contaminated clothing and wash
thoroughly before reuse. If irritation persists consult a health care professional.
Inhalation: If exposure by inhalation is suspected, immediately move exposed individual to fresh air. If individual
experiences nausea, headache, dizziness, has difficulty in breathing or is cyanotic, seek a health care
professional immediately.
Ingestion: DO NOT INDUCE VOMITING. Rinse with copious amounts of water or milk, first. Irrigate the esophagus
and dilute stomach contents by slowly giving one (1) or two (2) glasses of water or milk. Avoid giving
alcohol or alcohol related products. In cases where the individual is semi-comatose, comatose or convulsing,
DO NOT GIVE FLUIDS BY MOUTH. In case of intentional ingestion of the product seek medical
assistance immediately; take individual to nearest medical facility.
IV. PRIMARY ROUTES OF EXPOSURE
1. Effects from Acute Exposure:
Eye Exposure: Hazardous in case of eye contact (irritant)
Skin Exposure: Hazardous in case of skin contact (irritant, sensitizer). Skin inflammation is characterized by itching, scaling,
reddening, or, occasionally, blistering
Inhalation: May be harmful if inhaled. Do not breathe spray mists of the undiluted product. Effects will depend upon
solution strength and length of time of exposure.
Ingestion: Ingestion is not expected to be a primary route of exposure.
2. Effects from Chronic Exposure:
The effects from chronic exposure to this product have not been fully evaluated.
Page 1 of 6 for Product SUPER-FUME
---------------------------------P.O. Box 707 鈥? Columbus, NE 68602 鈥? (800) 800-7620---------------------------------
Copper Care MATERIAL SAFETY DATA SHEET
Wood Preservatives, Inc.
Emergency Telephone: 800-800-7620
V. TOXICOLOGICAL INFORMATION
Acute Effects:
Acute Oral (LD50) = 363 mg/kg Rat
Acute Dermal (LD50) = >2000 mg/kg Rabbit
Acute Inhalation(LC50) = >1.7 mg/l (4 hours) Rat
Irritant/Sensitization Effects:
Hazardous in case of eye contact (irritant).
Hazardous in case of skin contact (irritant, sensitizer). Skin inflammation is characterized by
itching, scaling, reddening, or, occasionally, blistering.
May be harmful if inhaled. Do not breathe spray mists of the undiluted product. Effects will
depend upon solution strength and length of time of exposure.
Carcinogenic Potential:
Not tested by Copper Care Wood Preservatives, Inc. Not shown as a carcinogen by OSHA, IARC, or NTP.
Target Organs Effects:
May cause damage to the following organs: upper respiratory tract, skin, eyes.
Other Health Effects:
None known.
VI. ENVIRONMENTAL TOXICOLOGICAL INFORMATION
LC50 = 11.2 mg/l 48 hours Daphnia magna
LC50 = 16.2 mg/l 96 hours Rainbow trout
VII. PHYSICAL AND CHEMICAL PROPERTIES
Appearance...鈥︹?︹?︹?︹?︹??.鈥︹?? White, crystalline solid
Odor鈥︹?︹?︹??.鈥︹?︹?︹?︹?︹?︹??.. Slight.
Density鈥︹?︹??..鈥?.鈥︹?︹?︹??.鈥︹?? 0.53 gc,3 at 25潞C (77潞F)
Flash Point鈥︹?︹??..鈥︹?︹?︹??.鈥?. Not Available.
Melting/Freezing Point鈥?.鈥︹??.. Not Available.
Boiling Point鈥︹?︹??.鈥︹??.鈥?.鈥?.. Not Available.
Solubility鈥︹?︹?︹?︹?︹?︹??..鈥︹?︹?? Partially soluble in cold water. Partially soluble in hot water.
pH (Neat)鈥︹?︹?︹?︹??............鈥︹?? Not Available.
pH (100 ppm in water)鈥︹?︹?︹?? 6-7
Vapor Pressure鈥︹?︹?︹?︹?︹?︹?︹?? Not applicable for solids.
o/w Partition Coefficient鈥︹?︹?︹?? Not Available.
Oxidizing/Reducing Properties鈥? Not Available.
Viscosity鈥︹?︹?︹?︹?︹?︹?︹??.鈥︹?︹?? Not Available.
Additional pH Information鈥?.鈥?... Not Available.
Voc Content鈥︹?︹?︹?︹?︹?︹?︹??. .70 lbs/gal
Page 2 of 6 for Product SUPER-FUME
---------------------------------P.O. Box 707 鈥? Columbus, NE 68602 鈥? (800) 800-7620---------------------------------
Copper Care MATERIAL SAFETY DATA SHEET
Wood Preservatives, Inc.
Emergency Telephone: 800-800-7620
VIII. FIRE AND EXPLOSION INFORMATION
Flammable Limits鈥︹?︹?︹?ot available.
Extinguishing Media鈥︹??.. Water fog, carbon dioxide, foam, dry chemical.
Special Firefighting Fire-fighters should wear positive pressure self-contained breathing apparatus
Procedures鈥︹?︹?︹?︹?︹??. (SCBA) and full turnout gear.
IX. REACTIVITY INFORMATION
STABILITY鈥︹?︹?︹?︹?︹?︹?︹?︹?? Stable under normal conditions of use and storage. Keep dry.
INCOMPATIBILITY鈥︹?︹?︹??.. Moisture.
HAZARDOUS DECOMPOSITION
PRODUCTS鈥︹?︹?︹?︹?︹?︹?︹?︹?? Carbon oxides (CO, CO2, sulfer oxides (SO2, SO3)
X. HANDLING PRECAUTIONS
Rubber gloves, safety glasses or goggles, body protective clothing and shoes are required. Eye-wash fountains in the
work place are recommended. Provide ventilation to control dust. If dusting can occur a NIOSH approved respirator
is recommended. The handling precautions for this product are based on the characteristics of the neat product unless
otherwise specified.
XI. SATISFACTORY MATERIALS OF CONSTRUCTION
Not Available.
XII. SPILL, LEAK, AND DISPOSAL PROCEDURES
SPILL AND LEAK RESPONSE GUIDELINES
Important: Before responding to a spill or leak of this product, review each section of this MSDS. Follow the recommendations
given in the Handling Precautions sections. Check the Fire and Explosion Data section to determine if the use of non-sparking
tools is merited. Insure that spilled or leaked product does not come into contact with materials listed as incompatible. If irritating
fumes are present, consider evacuation of enclosed areas.
Emergency Response Assistance: Emergency technical assistance is available at any time from Copper Care by calling
(800) 800-7620.
Initially minimize area affected by the spill or leak. Block any potential routes to water systems (e.g., sewers, streams, lakes, etc).
Based on the product鈥檚 toxicological and chemical properties, and on the size and location of the spill or leak, assess the impact
on contaminated environments (e.g. water systems, ground, air equipment, etc.). There are no methods available to completely
eliminate any toxicity this product may have on aquatic environments. Minimize adverse effects on these environments.
Page 3 of 6 for Product SUPER-FUME
---------------------------------P.O. Box 707 鈥? Columbus, NE 68602 鈥? (800) 800-7620---------------------------------
Copper Care
MATERIAL SAFETY DATA SHEET
Wood Preservatives, Inc.
Emergency Telephone: 800-800-7620
XII. SPILL, LEAK, AND DISPOSAL PROCEDURES (Cont鈥?)
Copper Care Wood Preservatives, Inc. can be contacted for technical assistance. Determine if federal, state, and/or local release
notification is required (see Regulatory Classifications section of this MSDS). Recover as much of the pure product as possible
into appropriate containers. Later, determine if this recovered product can be used for its intended purpose. Address clean-up of
contaminated environments. Spill or leak residuals may have to be collected and disposed of. Flushing residual material to an
industrial sewer, if present at the site of a spill or leak incident, may be acceptable if authorized approval is obtained. If product
and/or spill/leak residuals are flushed to an industrial sewer, insure that they do not come into contact with incompatible
materials. Contact the person(s) responsible for the operation of your facility鈥檚 industrial sewer system prior to intentionally
flushing or pumping spills or leaks of this product to the industrial sewer.
DISPOSAL GUIDELINES
Note: Follow federal, state, and local regulations governing the disposal of waste materials.
Neat Product: Contact Copper Care Wood Preservatives, Inc. at (800) 800-7620
Contaminated Materials: Determine if waste containing this product can be handled by available industrial effluent system or
other on-site waste management unit. If off-site management is required, contact a company experienced in industrial waste
management. This product is not specifically listed in 40 CFR 261 as a Resource Conservation and Recovery Act (RCRA)
hazardous waste. However, spill or leak residuals may meet the criteria of a characteristic hazardous waste under this Act. Check
the characteristics of the material to be disposed of and/or the physical and reactivity data given in this MSDS for the neat
product.
Container Disposal: Empty containers, as defined by appropriate sections of the RCRA, are not RCRA hazardous wastes.
However, insure proper management of any residuals remaining in container.
XIII. TRANSPORTATION AND SHIPPING INFORMATION
DOT Shipping Information:
Not Regulated.
IMO/IMDG Shipping Information:
Not Regulated.
IATA Shipping Information:
Not Regulated.
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
Unless otherwise stated, the shipping information provided above applies only to non-bulk containers of this product. Proper
shipping name and general shipping information may vary depending on packaging and mode of shipment. All products shipped
from Copper Care locations have been properly packaged and labeled according to appropriate hazardous materials shipping
regulations. If any alteration of packaging, product, or mode of transportation is further intended, different shipping information,
including but not limited to proper shipping name, RQ designation, and labeling may apply. For further information pertaining to
the shipping requirements for this product, contact Copper Care Wood Preservatives, Inc.
Page 4 of 6 for Product SUPER-FUME
---------------------------------P.O. Box 707 鈥? Columbus, NE 68602 鈥? (800) 800-7620---------------------------------
Copper Care
MATERIAL SAFETY DATA SHEET
Wood Preservatives, Inc.
Emergency Telephone: 800-800-7620
XIV. REGULATORY INFORMATION
The following Regulations are known to apply to the use and disposal of this product. Additional Federal, State and Local
regulations may also be applicable.
SARA (Superfund Amendments and Reauthorization Act)
SARA 302 Extremely Hazardous Substances List鈥?
No components of this product are listed.
SARA 312 Hazard Category鈥?
Immediate (Acute) Health Hazard
SARA 313 Toxic Chemicals List鈥?
Tetrahydro-3,5-dimethyl-2H-1,3,5-thiadiazine-2-thione
CERCLA (Comprehensive Environmental Response, Compensation and Liability Act)
No components of this product are present above the de minimus levels.
RCRA (Resource Conversation and Recovery Act) Listed Hazardous Waste
No components of this product are listed.
CWA (Clean Water Act) Listed Substances
No components of this product are listed.
FDA (Food and Drug Administration)
This product is approved under the following FDA (21 CFR) sections : 1) 175.105 鈥? Limitations: For use as a
preservative only. 2) 178.3120 鈥? Limitations: For use as a preservative only. 3) 176.230 鈥? Limitations: For use
as a preservative for substances added to the pulp suspension prior to the sheet forming operation, provided
the preservative is volatilized by heat in the drying and finishing of the paper and paperboard. As a preservative
for coatings, provided the preservative is volatilized by heat in the drying and finishing of the coated paper and
paperboard. 4) 176.300 鈥? No known limitations.
TSCA (Toxic Substances Control Act) Applicability
All components may not be listed on the TSCA Inventory. Registered pesticides are exempt from the
requirements of TSCA.
FIFRA (Federal Insecticide, Fungicide, and Rodenticide Act)
This product is a registered pesticide. EPA Reg. No. 1448-104
HMIS/NPCA Rating Health 2 Flammability 1 Reactivity 1
NFPA Ratings Health 2 Flammability 1 Reactivity 1
State Regulations
Various State Right To Know Acts鈥?
Non-proprietary hazardous chemicals are listed in Section 2 of this MSDS. Should you require
further information on specific proprietary or inert ingredients please contact Copper Care
Wood Preservatives, Inc.
Page 5 of 6 for Product SUPER-FUME
---------------------------------P.O. Box 707 鈥? Columbus, NE 68602 鈥? (800) 800-7620---------------------------------
Copper Care
MATERIAL SAFETY DATA SHEET
Wood Preservatives, Inc.
Emergency Telephone: 800-800-7620
The information on this Material Safety Data Sheet reflects the latest information and data that we have on hazards, properties,
and handling of this product under the recommended conditions of use. Any use of this product or method of application which
is not described in the Data Sheet is the responsibility of the user. This Material Data Safety Sheet was prepared to comply with
the OSHA Hazard Communication regulations.
Copper Care Wood Preservatives, Inc. warrants that this product conforms to its chemical description and is reasonably fit for the
purpose referred to in the directions for use when used in accordance with the directions under normal conditions. Buyer assumes
the risk of any use contrary to such directions.
Seller makes no other warranty or representation of any kind, express or implied, concerning the product, including NO
IMPLIED WARRANTY OR MERCHANTABILITY OR FITNESS OF THE GOODS FOR ANY OTHER PARTICULAR
PURPOSE. No such warranties shall be implied by law and no agent of seller is authorized to alter this warranty in any way
except in writing with a specific reference to this warranty.
The exclusive remedy against seller shall be in a claim for damages not to exceed the purchase price of the product, without
regard to whether such a claim is based upon breach of warranty or tort.
Any controversy or claim arising out or relating to this contract, or breach thereof, shall be settled by arbitration in accordance
with the commercial arbitration rules of the American Arbitration Association, and judgment upon the rendered by the
Arbitrator(s) may be entered in any court having jurisdiction thereof.
Page 6 of 6 for Product SUPER-FUME
---------------------------------P.O. Box 707 鈥? Columbus, NE 68602 鈥? (800) 800-7620---------------------------------
|