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| MATERIAL SAFETY DATA SHEET |
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| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |
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PRODUCT NAME : CAULK 139 Comp.A
IDENTIFICATION NUMBER: CLK139A PREPARE / REVISED: 08/07/06
PRODUCT USE/CLASS : EPOXY HARDENER
SUPPLIER: MANUFACTURER:
Dudick, Inc. Dudick, Inc.
1818 Miller Parkway 1818 Miller Parkway
Streetsboro, Ohio 44241 Streetsboro, Ohio 44241
CHEM-TEL: 800-255-3924 CHEM-TEL: 800-255-3924
24 HOURS A DAY 24 HOURS A DAY
PREPARER: DUDICK, INC. PHONE: 800-322-1970
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| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS |
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WT/WT %
ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER LESS THAN
---------------------------------------------------------------------------
01 BENZYL ALCOHOL 100-51-6 15.0 %
02 CYCLOALIPHATIC POLYAMINE 25265-17-2 15.0 %
03 2,4,6-TRI(DIMETHYLAMINOMETHYL)PHENOL MIXTURE 5.0 %
04 RHEOLOGICAL ADDITIVE UNKNOWN 5.0 %
---------------------- EXPOSURE LIMITS --------------------
ACGIH OSHA COMPANY
ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN
---------------------------------------------------------------------------
01 NO INFO NO INFO NO INFO NO INFO NE NO
02 NE NE NE NE NE YES
03 5PPM 10PPM YES
04 10mg/m3 DUST NE 10mg/M3 DUST NE NE NO
(See Section 16 for abbreviation legend)
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| SECTION 3 - HAZARDS IDENTIFICATION |
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*** EMERGENCY OVERVIEW ***: CAUTION!...MAY CAUSE EYE AND SKIN IRRITATION.
HARMFUL IF SWALLOWED. RESPIRATORY TRACT IRRITANT. WARNING!---SEVERE EYE
IRRITANT. MODERATE SKIN IRRITANT.
EFFECTS OF OVEREXPOSURE - EYE CONTACT: EYE CONTACT MAY CAUSE SEVERE
IRRITATION WITH CORNEAL INJURY.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: PROLONGED EXPOSURE MAY CAUSE SKIN
(Continued on Page 2)
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Product: CLK139AA0000A PREPARE / REVISED: 08/07/06 Page 2
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| SECTION 3 - HAZARDS IDENTIFICATION |
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IRRITATION AND BURNS. MODERATE SKIN IRRITANT. REPEATED EXPOSURE MAY CAUSE
DRYING AND FLAKING OF THE SKIN.
EFFECTS OF OVEREXPOSURE - INHALATION: MAY CAUSE IRRITATION OF THE NOSE,
THROAT, AND LUNGS.
EFFECTS OF OVEREXPOSURE - INGESTION: INGESTION MAY CAUSE
NAUSEA,CRAMPS,VOMITING, AND DIARRHEA.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: ALLERGIC REACTIONS MAY OCCUR IN
SOME INDIVIDUALS. PREEXISTING SKIN AND EYE DISORDERS MAY BE AGGRAVATED BY
THIS PRODUCT. PREEXISTING SKIN OR LUNG INJURIES MAY INCREASE THE CHANCE OF
DEVELOPING ALLERGY SYMPTOMS FROM EXPOSURE TO THIS PRODUCT. MAY CAUSE SKIN
SENSITIZATION.
PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT SKIN ABSORPTION INHALATION
INGESTION EYE CONTACT
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| SECTION 4 - FIRST AID MEASURES |
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FIRST AID - EYE CONTACT: HOLD OPEN EYE LIDS AND FLUSH WITH COPIOUS AMOUNTS
OF FLOWING WATER FOR AT LEAST 15 MINUTES. SEEK MEDICAL ATTENTION. DO NOT
LET VICTIM RUB EYES.
FIRST AID - SKIN CONTACT: WASH AFFECTED AREAS THOROUGHLY WITH SOAP AND
WATER. IF SYMPTOMS PERSIST,SEEK MEDICAL ATTENTION. REMOVE CONTAMINATED
CLOTHING AND WASH THOROUGHLY BEFORE REUSE.
FIRST AID - INHALATION: REMOVE VICTIM TO FRESH AIR. IF VICTIM IS NOT
BREATHING, ARTIFICIAL RESPIRATION SHOULD BE ADMINISTERED BY QUALIFIED
PERSONNEL.
FIRST AID - INGESTION: DO NOT INDUCE VOMITING.SEEK MEDICAL ATTENTION.
GIVE VICTIM PLENTY OF WATER TO DRINK IF CONSCIOUS.
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| SECTION 5 - FIRE FIGHTING MEASURES |
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FLASH POINT: 231 F LOWER EXPLOSIVE LIMIT: N.A.
(SETAFLASH CLOSED CUP) UPPER EXPLOSIVE LIMIT: N.A.
AUTOIGNITION TEMPERATURE: NE
EXTINGUISHING MEDIA: ALCOHOL FOAM CO2 DRY CHEMICAL FOAM WATER FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS: HAZARDOUS CONDITIONS WILL RESULT
THROUGH CONTAMINATION WITH INCOMPATIBLES OR EXPOSURE TO EXCESSIVE HEAT.
MAY PRODUCE TOXIC CARBON MONOXIDE AND NITROGEN OXIDES UPON COMBUSTION.
TOXIC FUMES MAY BE PRODUCED IF THIS PRODUCT IS INVOLVED IN A FIRE.
SPECIAL FIREFIGHTING PROCEDURES: WATER MAY BE INEFFECTIVE BUT MAY BE USED
(Continued on Page 3)
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Product: CLK139A0000A PREPARE / REVISED: 08/07/06 Page 3
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| SECTION 5 - FIRE FIGHTING MEASURES |
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TO COOL FIRE EXPOSED CONTAINERS. FIGHT FIRE FROM A SAFE DISTANCE. WEAR
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. CONTAIN
RUNOFF IN DIKES. AVOID CONTAMINATING STREAMS.
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| SECTION 6 - ACCIDENTAL RELEASE MEASURES |
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STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: DIKE AREA TO
CONTAIN SPILLAGE. ABSORB EXCESS WITH SAND, EARTH, OR VERMICULITE. SCRAPE
UP AND PLACE IN SUITABLE CONTAINER FOR DISPOSAL. WEAR ALL APPROPRIATE
SAFETY EQUIPMENT WHILE HANDLING SPILLS.
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| SECTION 7 - HANDLING AND STORAGE |
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HANDLING: IF BODILY CONTACT OCCURS, REMOVE CONTAMINATED CLOTHING AT ONCE.
AVOID CONTACT WITH EYES AND SKIN. AVOID BREATHING VAPORS. FOR INDUSTRIAL
USE ONLY.
STORAGE: DO NOT STORE NEAR INCOMPATIBLES. DO NOT STORE NEAR EXCESSIVE
HEAT OR NEAR SOURCES OF IGNITION. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT
IN USE. BUNGS MUST BE KEPT TIGHTLY CLOSED WHEN CONTAINERS ARE NOT IN USE
OR ARE PLACED IN STORAGE AREAS.
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| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
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ENGINEERING CONTROLS: GENERAL MECHANICAL VENTILATION MAY BE SUFFICIENT TO
MINIMIZE VAPOR CONCENTRATIONS. LOCAL EXHAUST MAY BE REQUIRED.
RESPIRATORY PROTECTION: WEAR A PROPERLY FITTED NIOSH/MSHA APPROVED
RESPIRATOR WHEN EXPOSURE TO MISTS OR VAPORS IS LIKELY.
SKIN PROTECTION: IMPERVIOUS RUBBER OR NEOPRENE TYPE. CONSULT GLOVE
MANUFACTURER FOR RECOMMENDATIONS.
EYE PROTECTION: SAFETY GLASSES WITH SIDE SHIELDS RECOMMENDED AS MINIMUM
PROTECTION. GOGGLES RECOMMENDED FOR INDIVIDUALS MIXING THE RESIN AND
CATALYST.
OTHER PROTECTIVE EQUIPMENT: CLEAN, FULL BODY COVERING TO MINIMIZE SKIN
CONTACT WITH MATERIAL. AN EYEWASH STATION AND SAFETY SHOWER IS RECOMMENDED
NEAR WORK AREA.
HYGIENIC PRACTICES: SMOKING OR EATING IN THE WORK AREA SHOULD NOT BE
PERMITTED. WASH THOROUGHLY AFTER HANDLING MATERIAL. CONTAMINATED CLOTHING
MUST BE THOROUGHLY WASHED BEFORE REUSE.
(Continued on Page 4)
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Product: CLK139A0000A PREPARE / REVISED: 08/07/06 Page 4
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| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES |
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BOILING RANGE : 400 - 401 F VAPOR DENSITY : Is heavier than air
ODOR : AMMONIACAL ODOR THRESHOLD : NE
APPEARANCE : AMBER LIQUID EVAPORATION RATE: Is slower than Ether
SOLUBILITY IN H2O : SLIGHT
FREEZE POINT : NE SPECIFIC GRAVITY: 1.06
VAPOR PRESSURE : NE pH @ 0.0 % : NE
PHYSICAL STATE : LIQUID VISCOSITY : NE
COEFFICIENT OF WATER/OIL DISTRIBUTION: NE
(See Section 16 for abbreviation legend)
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| SECTION 10 - STABILITY AND REACTIVITY |
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CONDITIONS TO AVOID: HEAT, FLAME, CONTAMINANTS.
INCOMPATIBILITY: STRONG OXIDANTS. STRONG ACIDS. CORROSIVE TO COPPER AND
COPPER ALLOYS. PROMOTERS. ORGANIC ACIDS.
HAZARDOUS DECOMPOSITION PRODUCTS: BURNING WILL PRODUCE TOXIC FUMES.
OXIDES OF NITROGEN. OXIDES OF CARBON. OTHER TOXIC ORGANIC SUBSTANCES MAY
BE FORMED.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
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| SECTION 11 - TOXICOLOGICAL PROPERTIES |
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No product or component toxicological information is available.
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| SECTION 12 - ECOLOGICAL INFORMATION |
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ECOLOGICAL INFORMATION: DO NOT CONTAMINATE PONDS, STREAMS, OR UNDERGROUND
WATER SUPPLY. PREVENT FROM ENTERING SEWERS.
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| SECTION 13 - DISPOSAL CONSIDERATIONS |
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DISPOSAL METHOD: FOLLOW ALL RELEVANT LOCAL, STATE, AND FEDERAL
REGULATIONS. AS MANUFACTURED, IF THIS PRODUCT IS DISCARDED, IT WOULD NOT
BE A HAZARDOUS WASTE AS DEFINED BY RCRA. EMPTY DRUMS MAY CONTAIN RESIDUE
OR FUMES WHICH ARE HARMFUL. DO NOT WELD,GRIND,OR USE CUTTING TORCHES ON
EMPTY DRUMS. ALTHOUGH THIS PRODUCT WOULD NOT BE A RCRA HAZARDOUS WASTE IF
DISPOSED, LANDFILL DISPOSAL MAY PRESENT LONG TERM ENVIRONMENTAL HAZARDS.
(Continued on Page 5)
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Product: CLK139A0000A PREPARE / REVISED: 08/07/06 Page 5
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| SECTION 14 - TRANSPORTATION INFORMATION |
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DOT PROPER SHIPPING NAME: PLASTIC LIQUID MATERIAL N.O.I.
DOT TECHNICAL NAME: NA
DOT HAZARD CLASS: NA HAZARD SUBCLASS: NA
DOT UN/NA NUMBER: NA PACKING GROUP: NA RESP. GUIDE PAGE:
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| SECTION 15 - REGULATORY INFORMATION |
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THE FOLLOWING COMPONENTS ARE NOT SUBJECT TO REPORTING IN SECTION 2:
----------- CHEMICAL NAME ----------- CAS NUMBER WT/WT % IS LESS THAN
SODIUM ALUMINUM SILICATE UNKNOWN 55.0 %
POLYSULFIDE RESIN UNKNOWN 25.0 %
IRON OXIDE 1309-37-1 5.0 %
SILICON DIOXIDE (AMORPHOUS) 7631-86-9 0.1 %
U.S. FEDERAL REGULATIONS: AS FOLLOWS -
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)
CERCLA - SARA HAZARD CATEGORY:
This product has been reviewed according to the EPA 'Hazard Categories'
promulgated under Sections 311 and 312 of the Superfund Amendment and
Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD CHRONIC HEALTH HAZARD
SARA SECTION 313:
This product contains the following substances subject to the reporting
requirements of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR Part 372:
----------- CHEMICAL NAME ----------- CAS NUMBER WT/WT % IS LESS THAN
No SARA Section 313 components exist in this product.
TOXIC SUBSTANCES CONTROL ACT:
The chemical substances in this product are on the TSCA Section 8
Inventory.
This product contains the following chemical substances subject to the
reporting requirements of TSCA 12(B) if exported from the United States:
----------- CHEMICAL NAME ----------- CAS NUMBER
No information is available.
U.S. STATE REGULATIONS: AS FOLLOWS -
(Continued on Page 6)
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Product: CLK139A0000A PREPARE / REVISED: 08/07/06 Page 6
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| SECTION 15 - REGULATORY INFORMATION |
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NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top five
components in this product:
----------- CHEMICAL NAME ----------- CAS NUMBER
SODIUM ALUMINUM SILICATE UNKNOWN
POLYSULFIDE RESIN UNKNOWN
PENNSYLVANIA RIGHT-TO-KNOW:
The following non-hazardous ingredients are present in the product at
greater than 3%:
----------- CHEMICAL NAME ----------- CAS NUMBER
SODIUM ALUMINUM SILICATE UNKNOWN
POLYSULFIDE RESIN UNKNOWN
CALIFORNIA PROPOSITION 65:
WARNING: The chemical(s) noted below and contained in this product, are
known to the state of California to cause cancer, birth defects or other
reproductive harm:
----------- CHEMICAL NAME ----------- CAS NUMBER
No Proposition 65 chemicals exist in this product.
INTERNATIONAL REGULATIONS: AS FOLLOWS -
CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: CLASS D DIVISION 2B
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| SECTION 16 - OTHER INFORMATION |
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HMIS RATINGS - HEALTH: 2 FLAMMABILITY: 1 REACTIVITY: 0
VOLATILE ORGANIC COMPOUNDS (VOCS): 0.03 lbs/gal, 4 grams/ltr
LEGEND: N.A. - Not Applicable, N.E. - Not Established,
N.D. - Not Determined
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The information contained on this MSDS has been compiled from information
obtained from raw material suppliers and is believed to be accurate. It is
the responsibility of the user to comply with all Federal, State and Local
Regulations.
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