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| MATERIAL SAFETY DATA SHEET |
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| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |
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PRODUCT NAME : CAULK PSC COMP. A
IDENTIFICATION NUMBER: CLKPSCGRYA0A PREPARE/REVISED: 08/07/06
PRODUCT USE/CLASS : POLYSULFIDE CAULK
SUPPLIER: MANUFACTURER:
Dudick, Inc. Dudick, Inc.
1818 Miller Parkway 1818 Miller Parkway
Streetsboro, Ohio 44241 Streetsboro, Ohio 44241
CHEM-TEL: 800-255-3924 CHEM-TEL: 800-255-3924
24 HOURS A DAY 24 HOURS A DAY
PREPARER: DUDICK, INC., PHONE: 800-322-1970
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| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS |
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WT/WT %
ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER LESS THAN
---------------------------------------------------------------------------
01 2,4,6-TRI(DIMETHYLAMINOMETHYL)PHENOL MIXTURE 5.0 %
02 SILICON DIOXIDE (AMORPHOUS) 7631-86-9 5.0 %
---------------------- EXPOSURE LIMITS --------------------
ACGIH OSHA COMPANY
ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN
---------------------------------------------------------------------------
01 5PPM 10PPM YES
02 10mg/m3 NO INFO 6mg/m3 NO INFO NE NO
(See Section 16 for abbreviation legend)
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| SECTION 3 - HAZARDS IDENTIFICATION |
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*** EMERGENCY OVERVIEW ***: CAUTION!...MAY CAUSE EYE AND SKIN IRRITATION.
EFFECTS OF OVEREXPOSURE - EYE CONTACT: MILD EYE IRRITANT.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: MODERATE SKIN IRRITANT.
EFFECTS OF OVEREXPOSURE - INHALATION: PRODUCT IS NOT EXPECTED TO BE A
MAJOR INHALATION HAZARD. THIS PRODUCT HAS A DISAGREEABLE ODOR AND MAY
PRODUCE SYMPTOMS AT LOW CONCENTRATIONS.
EFFECTS OF OVEREXPOSURE - INGESTION: THIS PRODUCT HAS A LOW ORDER ORAL
TOXICITY.
(Continued on Page 2)
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Product: CLKPSCGRYA0A PREPARE / REVISED: 08/07/06 Page 2
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| SECTION 3 - HAZARDS IDENTIFICATION |
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EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: PREEXISTING SKIN AND EYE
DISORDERS MAY BE AGGRAVATED BY THIS PRODUCT.
PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT EYE CONTACT
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| SECTION 4 - FIRST AID MEASURES |
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FIRST AID - EYE CONTACT: FLUSH EYES WITH FLOWING WATER UNTIL IRRITATION
CEASES.IF IRRITATION PERSISTS,SEEK MEDICAL ATTENTION.
FIRST AID - SKIN CONTACT: WASH AFFECTED AREAS THOROUGHLY WITH SOAP AND
WATER. IF SYMPTOMS PERSIST,SEEK MEDICAL ATTENTION. REMOVE CONTAMINATED
CLOTHING AND WASH THOROUGHLY BEFORE REUSE.
FIRST AID - INHALATION: REMOVE VICTIM TO FRESH AIR. IF VICTIM IS NOT
BREATHING, ARTIFICIAL RESPIRATION SHOULD BE ADMINISTERED BY QUALIFIED
PERSONNEL.
FIRST AID - INGESTION: IF SWALLOWED,CALL A PHYSICIAN IMMEDIATELY. REMOVE
CONTENTS OF STOMACH ONLY AS DIRECTED BY MEDICAL PERSONNEL. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
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| SECTION 5 - FIRE FIGHTING MEASURES |
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FLASH POINT: 201 F LOWER EXPLOSIVE LIMIT: N.A.
(SETAFLASH CLOSED CUP) UPPER EXPLOSIVE LIMIT: N.A.
AUTOIGNITION TEMPERATURE: NE
EXTINGUISHING MEDIA: ALCOHOL FOAM CO2 DRY CHEMICAL FOAM WATER FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS: TOXIC FUMES MAY BE PRODUCED IF THIS
PRODUCT IS INVOLVED IN A FIRE.
SPECIAL FIREFIGHTING PROCEDURES: WATER MAY BE INEFFECTIVE BUT MAY BE USED
TO COOL FIRE EXPOSED CONTAINERS. FIGHT FIRE FROM A SAFE DISTANCE. WEAR
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
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| SECTION 6 - ACCIDENTAL RELEASE MEASURES |
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STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: SCRAPE UP AND
PLACE IN SUITABLE CONTAINER FOR DISPOSAL. WEAR ALL APPROPRIATE SAFETY
EQUIPMENT WHILE HANDLING SPILLS.
(Continued on Page 3)
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Product: CLKPSCGRYA0A PREPARE / REVISED: 08/07/06 Page 3
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| SECTION 7 - HANDLING AND STORAGE |
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HANDLING: AVOID CONTACT WITH EYES AND SKIN. FOR INDUSTRIAL USE ONLY.
STORAGE: DO NOT STORE NEAR EXCESSIVE HEAT OR NEAR SOURCES OF IGNITION.
KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE.
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| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
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ENGINEERING CONTROLS: GENERAL MECHANICAL VENTILATION MAY BE SUFFICIENT TO
MINIMIZE VAPOR CONCENTRATIONS. LOCAL EXHAUST MAY BE REQUIRED.
RESPIRATORY PROTECTION: NOT REQUIRED UNDER NORMAL CONDITIONS.
SKIN PROTECTION: CONSULT GLOVE MANUFACTURER FOR RECOMMENDATIONS.
IMPERVIOUS GLOVES IF NEEDED TO PREVENT PROLONGED OR REPEATED CONTACT.
EYE PROTECTION: SAFETY GLASSES RECOMMENDED.
OTHER PROTECTIVE EQUIPMENT: CLEAN, FULL BODY COVERING TO MINIMIZE SKIN
CONTACT WITH MATERIAL. AN EYEWASH STATION AND SAFETY SHOWER IS RECOMMENDED
NEAR WORK AREA.
HYGIENIC PRACTICES: SMOKING OR EATING IN THE WORK AREA SHOULD NOT BE
PERMITTED. WASH THOROUGHLY AFTER HANDLING MATERIAL.
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| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES |
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BOILING RANGE : N.A. VAPOR DENSITY : Is heavier than air
ODOR : MERCAPTAN ODOR THRESHOLD : NE
APPEARANCE : PASTE EVAPORATION RATE: Is slower than Ether
SOLUBILITY IN H2O : INSOLUBLE
FREEZE POINT : NE SPECIFIC GRAVITY: 1.7
VAPOR PRESSURE : NE pH @ 0.0 % : NE
PHYSICAL STATE : PASTE VISCOSITY : NE
COEFFICIENT OF WATER/OIL DISTRIBUTION: NE
(See Section 16 for abbreviation legend)
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| SECTION 10 - STABILITY AND REACTIVITY |
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CONDITIONS TO AVOID: NONE.
INCOMPATIBILITY: NONE KNOWN.
HAZARDOUS DECOMPOSITION PRODUCTS: BURNING WILL PRODUCE TOXIC FUMES.
OXIDES OF CARBON. ALDEHYDES. OXIDES OF SULFUR.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
(Continued on Page 4)
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Product: CLKPSCGRYA0A PREPARE / REVISED: 08/07/06 Page 4
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| SECTION 11 - TOXICOLOGICAL PROPERTIES |
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No product or component toxicological information is available.
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| SECTION 12 - ECOLOGICAL INFORMATION |
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ECOLOGICAL INFORMATION: DO NOT CONTAMINATE PONDS, STREAMS, OR UNDERGROUND
WATER SUPPLY. PREVENT FROM ENTERING SEWERS.
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| SECTION 13 - DISPOSAL CONSIDERATIONS |
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DISPOSAL METHOD: FOLLOW ALL RELEVANT LOCAL, STATE, AND FEDERAL
REGULATIONS. DO NOT WELD,GRIND,OR USE CUTTING TORCHES ON EMPTY DRUMS.
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| SECTION 14 - TRANSPORTATION INFORMATION |
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DOT PROPER SHIPPING NAME: PUTTY COMPOUND NOI
DOT TECHNICAL NAME: NA
DOT HAZARD CLASS: NON-REGULATED HAZARD SUBCLASS: NA
DOT UN/NA NUMBER: NA PACKING GROUP: NA RESP. GUIDE PAGE:
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| SECTION 15 - REGULATORY INFORMATION |
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THE FOLLOWING COMPONENTS ARE NOT SUBJECT TO REPORTING IN SECTION 2:
----------- CHEMICAL NAME ----------- CAS NUMBER WT/WT % IS LESS THAN
POLYSULFIDE RESIN UNKNOWN 60.0 %
SODIUM ALUMINUM SILICATE UNKNOWN 35.0 %
IRON OXIDE 1309-37-1 1.0 %
GLYCERINE 56-81-5 1.0 %
U.S. FEDERAL REGULATIONS: AS FOLLOWS -
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)
CERCLA - SARA HAZARD CATEGORY:
This product has been reviewed according to the EPA 'Hazard Categories'
promulgated under Sections 311 and 312 of the Superfund Amendment and
Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD
(Continued on Page 5)
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Product: CLKPSCGRYA0A PREPARE / REVISED: 08/07/06 Page 5
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| SECTION 15 - REGULATORY INFORMATION |
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SARA SECTION 313:
This product contains the following substances subject to the reporting
requirements of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR Part 372:
----------- CHEMICAL NAME ----------- CAS NUMBER WT/WT % IS LESS THAN
No SARA Section 313 components exist in this product.
TOXIC SUBSTANCES CONTROL ACT:
The chemical substances in this product are on the TSCA Section 8
Inventory.
This product contains the following chemical substances subject to the
reporting requirements of TSCA 12(B) if exported from the United States:
----------- CHEMICAL NAME ----------- CAS NUMBER
No information is available.
U.S. STATE REGULATIONS: AS FOLLOWS -
NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top five
components in this product:
----------- CHEMICAL NAME ----------- CAS NUMBER
POLYSULFIDE RESIN UNKNOWN
SODIUM ALUMINUM SILICATE UNKNOWN
IRON OXIDE 1309-37-1
PENNSYLVANIA RIGHT-TO-KNOW:
The following non-hazardous ingredients are present in the product at
greater than 3%:
----------- CHEMICAL NAME ----------- CAS NUMBER
POLYSULFIDE RESIN UNKNOWN
SODIUM ALUMINUM SILICATE UNKNOWN
CALIFORNIA PROPOSITION 65:
WARNING: The chemical(s) noted below and contained in this product, are
known to the state of California to cause cancer, birth defects or other
reproductive harm:
----------- CHEMICAL NAME ----------- CAS NUMBER
No Proposition 65 chemicals exist in this product.
INTERNATIONAL REGULATIONS: AS FOLLOWS -
CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: D2
(Continued on Page 6)
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Product: CLKPSCGRYA0A PREPARE / REVISED: 08/07/06 Page 6
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| SECTION 16 - OTHER INFORMATION |
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HMIS RATINGS - HEALTH: 2 FLAMMABILITY: 1 REACTIVITY: 0
VOLATILE ORGANIC COMPOUNDS (VOCS): 0.07 lbs/gal, 8 grams/ltr
LEGEND: N.A. - Not Applicable, N.E. - Not Established,
N.D. - Not Determined
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The information contained on this MSDS has been compiled from information
obtained from raw material suppliers and is believed to be accurate. It is
the responsibility of the user to comply with all Federal, State and Local
Regulations.
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