MATERIAL SAFETY DATA SHEET
Copper Care COPPER CARE PRODUCT NAME:
Wood Preservatives, Inc.
Tenino Copper Naphthenate
Copper Care Wood Preservatives Inc. In Case of Emergency, Call
P.O. Box 707 Copper Care Wood Preservatives Inc:
Columbus, NE 68602-0707 888-817-1031
800-473-0179
A. PRODUCT INFORMATION
Product Code: Copper Naphthenate / Tenino Copper Naphthenate
Common Name/Synonyms: Naphthenic Acid, Copper Salt
Chemical Name(s): See Section G
DOT Shipping Name/ID No.: Combustible Liquid, NOS/NA 1993
HMIS Rating: Health-1 Flammability-2 Reactivity-0
Least=0; Slight=1; Moderate=2; High=3; Extreme=4;
Product Appearance/Description: Blue-green liquid
B. FIRST AID INFORMATION
Eye Contact: May cause eye irritation. Immediately flush the eyes with plenty of running
water, including under the eyelids, for at least 15 minutes. If irritation persists,
get medical attention.
Skin Contact: May cause skin irritation. Immediately wash from the skin by removing
contaminated clothing and flushing the exposed area with water and soap. If
irritation persists, get medical attention.
Inhalation: May be harmful if inhaled. Remove to fresh air. Have qualified person restore
and/or support breathing with oxygen, if needed. Keep warm. If irritation
persists, get medical attention.
Ingestion: Call a poison control center or doctor immediately for treatment advice. Do not
give any liquid to the person. Do not give anything by mouth to an unconscious
person. Do not induce vomiting unless told to do so by a poison control center or
doctor.
NOTE TO PHYSICIAN
No specific antidote is known. Based on the individual reactions of the patient, the physician's
judgment should be used to control symptoms and clinical conditions.
C. HEALTH HAZARD DATA
This material is not listed as a carcinogen by IARC, NTP or OSHA.
Page 1 of 5 for Product Tenino Copper Naphthenate
Date of Last Revision: 01/03/2007
MATERIAL SAFETY DATA SHEET
Copper Care COPPER CARE PRODUCT NAME:
Wood Preservatives, Inc.
Tenino Copper Naphthenate
Copper Care Wood Preservatives Inc. In Case of Emergency, Call
P.O. Box 707 Copper Care Wood Preservatives Inc:
Columbus, NE 68602-0707 888-817-1031
800-473-0179
This material meets the following health hazard definition(s) according to the OSHA Hazard
Communication Standard (29 CFR 1910.1200):
Highly Toxic Corrosive
Toxic x Irritant
Non-Hazardous Sensitizer
Information Not Available
D. HANDLING AND STORAGE PRECAUTIONS
Avoid contact with eyes, skin or clothing.
Avoid breathing vapors, mists or spray.
Do not take internally.
Use with adequate ventilation.
Use respiratory protection when overexposure to vapors, mists or spray is possible.
When handling, wear safety glasses, chemical splash goggles or face shield. Also wear chemically
resistant gloves such as PVC or butyl/viton and protective clothing.
Keep containers closed.
Store containers in cool, well ventilated areas away from ignition sources.
E. PERSONAL PROTECTION INFORMATION
Ventilation: Use adequate ventilation to control exposure.
Respiratory Protection: Use NIOSH/MSHA approved air purifying respirator equipped
with organic vapor cartridge(s) to minimize respiration exposure.
In case of a spill or leak resulting in unknown concentration, use
NIOSH/MSHA approved air supplied respirator.
Eye Protection: Wear chemical safety glasses or goggles. A full face shield to
protect against splashing may also be used.
Skin Protection: Wear chemical resistant gloves when handling this material.
Heavy PVC or butyl-viton is recommended. Gloves may be
decontaminated by washing with soap and water.
Other Protective Clothing
and Equipment: Impervious protective clothing and chemically resistant footwear
should be worn to minimize contact if needed.
Page 2 of 5 for Product Tenino Copper Naphthenate
Date of Last Revision: 01/03/2007
MATERIAL SAFETY DATA SHEET
Copper Care COPPER CARE PRODUCT NAME:
Wood Preservatives, Inc.
Tenino Copper Naphthenate
Copper Care Wood Preservatives Inc. In Case of Emergency, Call
P.O. Box 707 Copper Care Wood Preservatives Inc:
Columbus, NE 68602-0707 888-817-1031
800-473-0179
F. SPILL, LEAK AND DISPOSAL PROCEDURES
Evacuate area.
Shut off ignition sources.
Only properly trained personnel should respond to spills or leaks.
Wear protective equipment and/or garments as specified in Section E.
When entry must be made into an area where the concentration is unknown, use NIOSH/MSHA
approved self-contained breathing apparatus (SCBA) and protective equipment as described in
Section E.
Absorb spilled liquid onto inert material and transfer into disposal drums.
Large spills should be removed using a vacuum truck.
Wash spill area with water and foam (AFFF) and absorb onto inert material and transfer into disposal
drums.
Spills on areas other than pavement, e.g., dirt, sand, etc., may be handled by removing the affected soils
and placing in approved containers.
WASTE DISPOSAL
The materials resulting from clean-up operations of a spill may be hazardous and, therefore, subject to
specific regulations. Package, store, transport and dispose of all clean-up materials and any
contaminated equipment in accordance with all applicable federal, state and local regulations.
Shipments of waste materials may be subject to manifesting requirements per applicable regulations.
Appropriate disposal will depend on the nature of the waste and should be performed by competent and
properly permitted contractors. Ensure that all responsible federal, state and local agencies receive
proper notification of spill and disposal methods.
Spills or releases should be reported, if required, to the appropriate local, state and federal regulatory
agencies.
This material does not contain substances with Reportable Quantities (RQs).
MATERIAL REPORTABLE UNDER TITLE III, SECTION 313
The following substance(s) are subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendments and Reauthorization Act of 1986 and 40 CFR 372. The substances(s) may not
be reflected in Section C or G of this MSDS.
Substance CAS No. Approx. Wt.%
Copper Compounds Not Applicable 2% (as Cu)
Page 3 of 5 for Product Tenino Copper Naphthenate
Date of Last Revision: 01/03/2007
MATERIAL SAFETY DATA SHEET
Copper Care COPPER CARE PRODUCT NAME:
Wood Preservatives, Inc.
Tenino Copper Naphthenate
Copper Care Wood Preservatives Inc. In Case of Emergency, Call
P.O. Box 707 Copper Care Wood Preservatives Inc:
Columbus, NE 68602-0707 888-817-1031
800-473-0179
Product and/or components entered on EPA's TSCA inventory: YES
G. CHEMICAL OR HAZARDOUS COMPONENTS
Exposure Guidelines
Approx. OSHA ACGIH
TLV
Component CAS No. Wt. % PEL (ppm) mg/m鲁
1 mg/m3*
Copper Naphthenate 1338-02-9 15-20
Hydrocarbon Solvent 8052-41-3 80-85 500 525
*for copper dusts/mists (as Cu)
H. FIRE AND EXPLOSION DATA
Flash Point: >100 F (>38 C) (Cleveland Open Cup)
Explosive Range in Air; % by Vol.
- Lower: Not Established
- Upper: Not Established
Fire Extinguish. Media: Water Fog, AFFF (Foam), Dry Chemical, CO2
Special Fire Fighting Procedures: Use water spray to cool fire exposed surfaces and to
protect personnel. Isolate fuel supply from fire if possible.
Use NIOSH/MSHA approved self-contained breathing
apparatus.
Fire and Explosion Hazards: Moderate hazard. Liquid may burn upon heating to
temperatures at or above flash point. If heated to
decomposition, flammable and toxic gases may be
released. Container explosion may occur under fire
conditions.
I. REACTIVITY DATA
Stability: Stable
Conditions to Avoid: Not Established
Incompatibility
(Materials to Avoid): Strong oxidizing agents, acids, bases
Page 4 of 5 for Product Tenino Copper Naphthenate
Date of Last Revision: 01/03/2007
MATERIAL SAFETY DATA SHEET
Copper Care COPPER CARE PRODUCT NAME:
Wood Preservatives, Inc.
Tenino Copper Naphthenate
Copper Care Wood Preservatives Inc. In Case of Emergency, Call
P.O. Box 707 Copper Care Wood Preservatives Inc:
Columbus, NE 68602-0707 888-817-1031
800-473-0179
Hazardous Polymerization: Not known to occur
Hazardous Decomposition Products: Carbon Dioxide, Carbon Monoxide, Acids and aldehydes
may be formed when material burns
J. PHYSICAL DATA
Appearance: Blue-green Liquid
Odor: Petroleum
Odor Threshold: <1 ppm
pH: Not Established
Boiling Point: 310-415 F (154-213 C)
Freezing Point: Not Established
Reid Vapor Pressure: Not Established
Specific Gravity: 0.80-0.85 @ 68 F/63 F
Vapor Density (Air=1): >1
Solubility in Water: Insoluble
Coefficient of Octanol/
Water Separation: Not Available
K. ADDITIONAL COMMENTS
This material is FOR INDUSTRIAL USE ONLY.
The information on this form is furnished solely for the purpose of enabling those who transport,
handle or use our products to ensure the safety and health of their employees and to comply with
various laws and regulations (federal, state and local). This information is offered in good faith and is
believed to be accurate. Copper Care Wood Preservatives Inc., however, makes no guarantee or
warranty, expressed or implied, regarding the accuracy of these data or the results to be obtained from
the use hereof.
Page 5 of 5 for Product Tenino Copper Naphthenate
Date of Last Revision: 01/03/2007
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