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| MATERIAL SAFETY DATA SHEET |
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| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |
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PRODUCT NAME : PH-1 HARDENER
IDENTIFICATION NUMBER: PH-1HARD000B PREPARE / REVISED: 08/07/06
PRODUCT USE/CLASS : POLYESTER/VINYL ESTER HARDENER
SUPPLIER: MANUFACTURER:
Dudick, Inc. Dudick, Inc.
1818 Miller Parkway 1818 Miller Parkway
Streetsboro, Ohio 44241 Streetsboro, Ohio 44241
CHEM-TEL: 800-255-3924 CHEM-TEL: 800-255-3924
24 HOURS A DAY 24 HOURS A DAY
PREPARER: DUDICK,INC PHONE: 800-322-1970
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| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS |
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WT/WT %
ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER LESS THAN
---------------------------------------------------------------------------
01 CUMENE HYDROPEROXIDE 80-15-9 85.0 %
02 CUMENE 98-82-8 15.0 %
---------------------- EXPOSURE LIMITS --------------------
ACGIH OSHA COMPANY
ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN
---------------------------------------------------------------------------
01 50PPM 50PPM NO INFO NO INFO NE YES
02 246 mg/M3 NO INFO 245 mg/M3 NO INFO NE YES
(See Section 16 for abbreviation legend)
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| SECTION 3 - HAZARDS IDENTIFICATION |
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*** EMERGENCY OVERVIEW ***: DANGER!---ORGANIC PEROXIDE. HEAT OR
CONTAMINATION MAY CAUSE HAZARDOUS DECOMPOSITION. RESPIRATORY TRACT
IRRITANT. WARNING!...SEVERE EYE AND SKIN IRRITANT. KEEP AWAY FROM ALL
SOURCES OF IGNITION. STORE OUT OF DIRECT SUNLIGHT IN A COOL, WELL
VENTILATED AREA. MAY BE FATAL IF SWALLOWED.
EFFECTS OF OVEREXPOSURE - EYE CONTACT: EYE CONTACT MAY CAUSE SEVERE
IRRITATION WITH CORNEAL INJURY. MAY CAUSE BLINDNESS.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: PROLONGED EXPOSURE MAY CAUSE SKIN
IRRITATION AND BURNS. SEVERE SKIN IRRITANT.
(Continued on Page 2)
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Product: PH-1HARD000B PREPARE / REVISED: 08/07/06 Page 2
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| SECTION 3 - HAZARDS IDENTIFICATION |
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EFFECTS OF OVEREXPOSURE - INHALATION: MAY CAUSE IRRITATION OF THE NOSE,
THROAT, AND LUNGS.
EFFECTS OF OVEREXPOSURE - INGESTION: INGESTION MAY CAUSE BURNS TO THE
MOUTH, THROAT, AND ESOPHAGUS. INGESTION MAY CAUSE NAUSEA,CRAMPS,VOMITING,
AND DIARRHEA. ASPIRATION HAZARD.PRODUCT MAY ENTER THE LUNGS DURING
SWALLOWING AND CAUSE LUNG DAMAGE. MAY CAUSE GASTROINTESTINAL BLEEDING AND
VOMITING OF BLOOD. INGESTION MAY BE FATAL UNLESS TREATED PROMPTLY.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: CUMENE HYDROPEROXIDE HAS BEEN
REPORTED TO BE MUTAGENIC UNDER CONDITIONS OF METABOLIC ACTIVATION IN THE
AMES TEST (100mg/PLATE). CUMENE HAS BEEN REPORTED TO CAUSE EMBRYOTOXICITY
IN THREE DAY OLD CHICK EMBRYOS. PREEXISTING SKIN AND EYE DISORDERS MAY BE
AGGRAVATED BY THIS PRODUCT.
PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT SKIN ABSORPTION INHALATION
INGESTION EYE CONTACT
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| SECTION 4 - FIRST AID MEASURES |
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FIRST AID - EYE CONTACT: HOLD OPEN EYE LIDS AND FLUSH WITH COPIOUS AMOUNTS
OF FLOWING WATER FOR AT LEAST 15 MINUTES. SEEK MEDICAL ATTENTION.
FIRST AID - SKIN CONTACT: WASH AFFECTED AREAS THOROUGHLY WITH SOAP AND
WATER. IF SYMPTOMS PERSIST,SEEK MEDICAL ATTENTION. REMOVE CONTAMINATED
CLOTHING AND WASH THOROUGHLY BEFORE REUSE.
FIRST AID - INHALATION: REMOVE VICTIM TO FRESH AIR. IF VICTIM IS NOT
BREATHING, ARTIFICIAL RESPIRATION SHOULD BE ADMINISTERED BY QUALIFIED
PERSONNEL. SUPPLEMENTAL OXYGEN MAY BE INDICATED. CALL A PHYSICIAN.
FIRST AID - INGESTION: IF SWALLOWED,CALL A PHYSICIAN IMMEDIATELY. REMOVE
CONTENTS OF STOMACH ONLY AS DIRECTED BY MEDICAL PERSONNEL. GIVE VICTIM
PLENTY OF WATER TO DRINK IF CONSCIOUS.
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| SECTION 5 - FIRE FIGHTING MEASURES |
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FLASH POINT: 177 F LOWER EXPLOSIVE LIMIT: 0.9 %
(SETAFLASH CLOSED CUP) UPPER EXPLOSIVE LIMIT: 7.0 %
AUTOIGNITION TEMPERATURE: NE
EXTINGUISHING MEDIA: CO2 DRY CHEMICAL FOAM WATER FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS: HAZARDOUS CONDITIONS WILL RESULT
THROUGH CONTAMINATION WITH INCOMPATIBLES OR EXPOSURE TO EXCESSIVE HEAT.
VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL A LONG DISTANCE AND FLASH BACK.
TOXIC FUMES MAY BE PRODUCED IF THIS PRODUCT IS INVOLVED IN A FIRE.
SPECIAL FIREFIGHTING PROCEDURES: EVACUATE AREA. WATER MAY BE INEFFECTIVE
(Continued on Page 3)
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Product: PH-1HARD000B PREPARE / REVISED: 08/07/06 Page 3
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| SECTION 5 - FIRE FIGHTING MEASURES |
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BUT MAY BE USED TO COOL FIRE EXPOSED CONTAINERS. FIGHT FIRE FROM A SAFE
DISTANCE. WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE
CLOTHING.
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| SECTION 6 - ACCIDENTAL RELEASE MEASURES |
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STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: DIKE AREA TO
CONTAIN SPILLAGE. ABSORB EXCESS WITH SAND, EARTH, OR VERMICULITE. SCRAPE
UP AND PLACE IN SUITABLE CONTAINER FOR DISPOSAL. WEAR ALL APPROPRIATE
SAFETY EQUIPMENT WHILE HANDLING SPILLS. USE NON-SPARKING TOOLS. IF A
SPILL OR LEAK OCCURS IN EXCESS OF THE RQ, NOTIFY THE NATIONAL RESPONSE
CENTER (1-800-424-8802).
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| SECTION 7 - HANDLING AND STORAGE |
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HANDLING: IF BODILY CONTACT OCCURS, REMOVE CONTAMINATED CLOTHING AT ONCE.
AVOID CONTACT WITH EYES AND SKIN. AVOID BREATHING VAPORS. FOR INDUSTRIAL
USE ONLY. WEAR APPROPRIATE SAFETY EQUIPMENT WHEN HANDLING.
STORAGE: DO NOT STORE NEAR INCOMPATIBLES. DO NOT STORE NEAR EXCESSIVE
HEAT OR NEAR SOURCES OF IGNITION. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT
IN USE. BUNGS MUST BE KEPT TIGHTLY CLOSED WHEN CONTAINERS ARE NOT IN USE
OR ARE PLACED IN STORAGE AREAS.
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| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
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ENGINEERING CONTROLS: GENERAL MECHANICAL VENTILATION MAY BE SUFFICIENT TO
MINIMIZE VAPOR CONCENTRATIONS. LOCAL EXHAUST MAY BE REQUIRED.
RESPIRATORY PROTECTION: WEAR A PROPERLY FITTED NIOSH/MSHA APPROVED
RESPIRATOR WHEN EXPOSURE TO MISTS OR VAPORS IS LIKELY.
SKIN PROTECTION: IMPERVIOUS RUBBER OR NEOPRENE TYPE. CONSULT GLOVE
MANUFACTURER FOR RECOMMENDATIONS.
EYE PROTECTION: SAFETY GLASSES WITH SIDE SHIELDS RECOMMENDED AS MINIMUM
PROTECTION. GOGGLES RECOMMENDED FOR INDIVIDUALS MIXING THE RESIN AND
CATALYST.
OTHER PROTECTIVE EQUIPMENT: CLEAN, FULL BODY COVERING TO MINIMIZE SKIN
CONTACT WITH MATERIAL. AN EYEWASH STATION AND SAFETY SHOWER IS RECOMMENDED
NEAR WORK AREA.
HYGIENIC PRACTICES: SMOKING OR EATING IN THE WORK AREA SHOULD NOT BE
PERMITTED. WASH THOROUGHLY AFTER HANDLING MATERIAL.
(Continued on Page 4)
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Product: PH-1HARD000B PREPARE / REVISED: 08/07/06 Page 4
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| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES |
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BOILING RANGE : N.A. VAPOR DENSITY : Is heavier than air
ODOR : SHARP,AROMATIC ODOR THRESHOLD : NE
APPEARANCE : LIQUID-CLEAR-YEL.EVAPORATION RATE: Is slower than Ether
SOLUBILITY IN H2O : SLIGHT
FREEZE POINT : NE SPECIFIC GRAVITY: 1.05
VAPOR PRESSURE : 13.9mmHG @68 F pH @ 0.0 % : NE
PHYSICAL STATE : LIQUID VISCOSITY : NE
COEFFICIENT OF WATER/OIL DISTRIBUTION: NE
(See Section 16 for abbreviation legend)
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| SECTION 10 - STABILITY AND REACTIVITY |
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CONDITIONS TO AVOID: HEAT, FLAME, CONTAMINANTS. UNDER NO CIRCUMSTANCES
SHOULD THIS MATERIAL BE HEATED. A VIOLENT EXOTHERMIC REACTION CAN OCCUR.
NEVER USE DRUM WARMERS ON THIS MATERIAL.
INCOMPATIBILITY: STRONG OXIDANTS. STRONG ACIDS. AMINES. SULFURIC ACID.
STRONG ALKALIS. REDUCING AGENTS. TRANSITION METALS.
HAZARDOUS DECOMPOSITION PRODUCTS: BURNING WILL PRODUCE TOXIC FUMES.
OXIDES OF CARBON.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
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| SECTION 11 - TOXICOLOGICAL PROPERTIES |
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No product or component toxicological information is available.
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| SECTION 12 - ECOLOGICAL INFORMATION |
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ECOLOGICAL INFORMATION: THE ECOLOGICAL TOXICITY OF THIS PRODUCT IS NOT
KNOWN.
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| SECTION 13 - DISPOSAL CONSIDERATIONS |
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DISPOSAL METHOD: FOLLOW ALL RELEVANT LOCAL, STATE, AND FEDERAL
REGULATIONS. THIS PRODUCT AND ANY ABSORBENTS USED IN SPILL CLEANUP ARE
HAZARDOUS WASTES AND MUST BE DISPOSED OF ACCORDINGLY. DO NOT
WELD,GRIND,OR USE CUTTING TORCHES ON EMPTY DRUMS. THIS PRODUCT EXHIBITS
THE CHARACTERISTIC OF REACTIVITY PER RCRA AND MUST BE DISPOSED OF
ACCORDINGLY. EMPTY CONTAINERS CONTAIN PRODUCT RESIDUE WHICH IS
HAZARDOUS.DO NOT WELD,BRAZE, OR GRIND.KEEP AWAY FROM HEAT,FLAME, AND
SOURCES OF IGNITION.DO NOT REUSE EMPTY CONTAINERS.
(Continued on Page 5)
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Product: PH-1HARD000B PREPARE / REVISED: 08/07/06 Page 5
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| SECTION 14 - TRANSPORTATION INFORMATION |
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DOT PROPER SHIPPING NAME: ORGANIC PEROXIDE TYPE F, LIQUID
DOT TECHNICAL NAME: CUMYL HYDROPEROXIDE <90%
DOT HAZARD CLASS: 5.2 HAZARD SUBCLASS: NA
DOT UN/NA NUMBER: UN 3109 PACKING GROUP: II RESP. GUIDE PAGE: 145
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| SECTION 15 - REGULATORY INFORMATION |
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THE FOLLOWING COMPONENTS ARE NOT SUBJECT TO REPORTING IN SECTION 2:
----------- CHEMICAL NAME ----------- CAS NUMBER WT/WT % IS LESS THAN
PHTHALATE PLASTICIZER UNKNOWN 10.0 %
U.S. FEDERAL REGULATIONS: AS FOLLOWS -
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)
CERCLA - SARA HAZARD CATEGORY:
This product has been reviewed according to the EPA 'Hazard Categories'
promulgated under Sections 311 and 312 of the Superfund Amendment and
Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD CHRONIC HEALTH HAZARD FIRE HAZARD REACTION
HAZARD
SARA SECTION 313:
This product contains the following substances subject to the reporting
requirements of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR Part 372:
----------- CHEMICAL NAME ----------- CAS NUMBER WT/WT % IS LESS THAN
CUMENE HYDROPEROXIDE 80-15-9 85.0 %
CUMENE 98-82-8 15.0 %
TOXIC SUBSTANCES CONTROL ACT:
The chemical substances in this product are not on the TSCA Section 8
Inventory.
This product contains the following chemical substances subject to the
reporting requirements of TSCA 12(B) if exported from the United States:
----------- CHEMICAL NAME ----------- CAS NUMBER
No information is available.
U.S. STATE REGULATIONS: AS FOLLOWS -
(Continued on Page 6)
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Product: PH-1HARD000B PREPARE / REVISED: 08/07/06 Page 6
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| SECTION 15 - REGULATORY INFORMATION |
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NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top five
components in this product:
----------- CHEMICAL NAME ----------- CAS NUMBER
PHTHALATE PLASTICIZER UNKNOWN
PENNSYLVANIA RIGHT-TO-KNOW:
The following non-hazardous ingredients are present in the product at
greater than 3%:
----------- CHEMICAL NAME ----------- CAS NUMBER
PHTHALATE PLASTICIZER UNKNOWN
CALIFORNIA PROPOSITION 65:
WARNING: The chemical(s) noted below and contained in this product, are
known to the state of California to cause cancer, birth defects or other
reproductive harm:
----------- CHEMICAL NAME ----------- CAS NUMBER
No Proposition 65 chemicals exist in this product.
INTERNATIONAL REGULATIONS: AS FOLLOWS -
CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: F
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| SECTION 16 - OTHER INFORMATION |
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HMIS RATINGS - HEALTH: 3 FLAMMABILITY: 2 REACTIVITY: 4
VOLATILE ORGANIC COMPOUNDS (VOCS): 0.00 lbs/gal, 0 grams/ltr
LEGEND: N.A. - Not Applicable, N.E. - Not Established,
N.D. - Not Determined
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The information contained on this MSDS has been compiled from information
obtained from raw material suppliers and is believed to be accurate. It is
the responsibility of the user to comply with all Federal, State and Local
Regulations.
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