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| MATERIAL SAFETY DATA SHEET |
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| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |
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PRODUCT NAME : PRIMER 27
IDENTIFICATION NUMBER: PR27922A000A PREPARE / REVISED: 08/07/06
PRODUCT USE/CLASS : VINYL ESTER PRIMER
SUPPLIER: MANUFACTURER:
Dudick, Inc. Dudick, Inc.
1818 Miller Parkway 1818 Miller Parkway
Streetsboro, Ohio 44241 Streetsboro, Ohio 44241
CHEM-TEL: 800-255-3924 CHEM-TEL: 800-255-3924
24 HOURS A DAY 24 HOURS A DAY
PREPARER: DUDICK, INC PHONE: 800-322-1970
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| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS |
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WT/WT %
ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER LESS THAN
---------------------------------------------------------------------------
01 STYRENE MONOMER,INHIBITED 100-42-5 50.0 %
---------------------- EXPOSURE LIMITS --------------------
ACGIH OSHA COMPANY
ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN
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01 20PPM 40PPM 50PPM 100PPM NE YES
(See Section 16 for abbreviation legend)
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| SECTION 3 - HAZARDS IDENTIFICATION |
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*** EMERGENCY OVERVIEW ***: WARNING!...FLAMMABLE. EYE AND SKIN IRRITANT.
HARMFUL IF SWALLOWED. RESPIRATORY TRACT IRRITANT.
EFFECTS OF OVEREXPOSURE - EYE CONTACT: EYE CONTACT MAY CAUSE SEVERE
IRRITATION WITH CORNEAL INJURY.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: PROLONGED EXPOSURE MAY CAUSE SKIN
IRRITATION AND BURNS.
EFFECTS OF OVEREXPOSURE - INHALATION: MAY CAUSE IRRITATION OF THE NOSE,
THROAT, AND LUNGS. MAY CAUSE DIZZINESS,LOSS OF COORDINATION, AND FATIGUE.
EFFECTS OF OVEREXPOSURE - INGESTION: INGESTION MAY CAUSE BURNS TO THE
MOUTH, THROAT, AND ESOPHAGUS. INGESTION MAY CAUSE NAUSEA,CRAMPS,VOMITING,
(Continued on Page 2)
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Product: PR27922A000A PREPARE / REVISED: 08/07/06 Page 2
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| SECTION 3 - HAZARDS IDENTIFICATION |
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AND DIARRHEA. ASPIRATION HAZARD.PRODUCT MAY ENTER THE LUNGS DURING
SWALLOWING AND CAUSE LUNG DAMAGE.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: THE IARC HAS CLASSIFIED STYRENE
AS A POSSIBLE HUMAN CARCINOGEN (CLASS 2B). OVEREXPOSURE TO STYRENE HAS
BEEN FOUND TO CAUSE THE FOLLOWING EFFECTS IN LABORATORY ANIMALS: LIVER
DAMAGE,TESTIS DAMAGE,EFFECTS ON HEARING,MILD REVERSIBLE KIDNEY EFFECTS.
RESPIRATORY TRACT DAMAGE. SOME STUDIES IN HUMANS ALLEGE THAT REPEATED
EXPOSURE TO STYRENE MAY RESULT IN MINOR, SUBCLINICAL DECREASES IN THE
ABILITY TO DISCRIMINATE BETWEEN COLORS.
PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT SKIN ABSORPTION INHALATION
INGESTION EYE CONTACT
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| SECTION 4 - FIRST AID MEASURES |
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FIRST AID - EYE CONTACT: HOLD OPEN EYE LIDS AND FLUSH WITH COPIOUS AMOUNTS
OF FLOWING WATER FOR AT LEAST 15 MINUTES. SEEK MEDICAL ATTENTION.
FIRST AID - SKIN CONTACT: WASH AFFECTED AREAS THOROUGHLY WITH SOAP AND
WATER. IF SYMPTOMS PERSIST,SEEK MEDICAL ATTENTION.
FIRST AID - INHALATION: REMOVE VICTIM TO FRESH AIR. IF VICTIM IS NOT
BREATHING, ARTIFICIAL RESPIRATION SHOULD BE ADMINISTERED BY QUALIFIED
PERSONNEL. SUPPLEMENTAL OXYGEN MAY BE INDICATED. CALL A PHYSICIAN.
FIRST AID - INGESTION: DO NOT INDUCE VOMITING.SEEK MEDICAL ATTENTION.
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| SECTION 5 - FIRE FIGHTING MEASURES |
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FLASH POINT: 90 F LOWER EXPLOSIVE LIMIT: 1.1 %
(SETAFLASH CLOSED CUP) UPPER EXPLOSIVE LIMIT: 6.1 %
AUTOIGNITION TEMPERATURE: NE
EXTINGUISHING MEDIA: CO2 DRY CHEMICAL FOAM
UNUSUAL FIRE AND EXPLOSION HAZARDS: HAZARDOUS CONDITIONS WILL RESULT
THROUGH CONTAMINATION WITH INCOMPATIBLES OR EXPOSURE TO EXCESSIVE HEAT.
VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL A LONG DISTANCE AND FLASH BACK.
SPECIAL FIREFIGHTING PROCEDURES: EVACUATE AREA. WATER MAY BE INEFFECTIVE
BUT MAY BE USED TO COOL FIRE EXPOSED CONTAINERS. FIGHT FIRE FROM A SAFE
DISTANCE. WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE
CLOTHING. POLYMERIZATION MAY TAKE PLACE UNDER FIRE CONDITIONS WHICH COULD
LEAD TO VIOLENT RUPTURE OF THE CONTAINERS.
(Continued on Page 3)
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Product: PR27922A000A PREPARE / REVISED: 08/07/06 Page 3
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| SECTION 6 - ACCIDENTAL RELEASE MEASURES |
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STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: DIKE AREA TO
CONTAIN SPILLAGE. ABSORB EXCESS WITH SAND, EARTH, OR VERMICULITE. SCRAPE
UP AND PLACE IN SUITABLE CONTAINER FOR DISPOSAL. WEAR ALL APPROPRIATE
SAFETY EQUIPMENT WHILE HANDLING SPILLS. USE NON-SPARKING TOOLS.
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| SECTION 7 - HANDLING AND STORAGE |
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HANDLING: IF BODILY CONTACT OCCURS, REMOVE CONTAMINATED CLOTHING AT ONCE.
AVOID CONTACT WITH EYES AND SKIN. AVOID BREATHING VAPORS.
STORAGE: DO NOT STORE NEAR INCOMPATIBLES. DO NOT STORE NEAR EXCESSIVE
HEAT OR NEAR SOURCES OF IGNITION. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT
IN USE. BUNGS MUST BE KEPT TIGHTLY CLOSED WHEN CONTAINERS ARE NOT IN USE
OR ARE PLACED IN STORAGE AREAS.
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| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
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ENGINEERING CONTROLS: GENERAL MECHANICAL VENTILATION MAY BE SUFFICIENT TO
MINIMIZE VAPOR CONCENTRATIONS. LOCAL EXHAUST MAY BE REQUIRED.
RESPIRATORY PROTECTION: WEAR A PROPERLY FITTED NIOSH APPROVED RESPIRATOR
WITH ORGANIC VAPOR CARTRIDGE. IN AREAS OF HIGH VAPOR CONCENTRATIONS,A
POSITIVE PRESSURE BREATHING APPARATUS MAY BE NECESSARY.
SKIN PROTECTION: IMPERVIOUS RUBBER OR NEOPRENE TYPE. CONSULT GLOVE
MANUFACTURER FOR RECOMMENDATIONS.
EYE PROTECTION: USE SPLASH-PROOF GOGGLES OR FACE SHIELD WHEN EYE CONTACT
MAY OCCUR. SAFETY GLASSES WITH SIDE SHIELDS RECOMMENDED AS MINIMUM
PROTECTION. GOGGLES RECOMMENDED FOR INDIVIDUALS MIXING THE RESIN AND
CATALYST.
OTHER PROTECTIVE EQUIPMENT: CLEAN, FULL BODY COVERING TO MINIMIZE SKIN
CONTACT WITH MATERIAL. AN EYEWASH STATION AND SAFETY SHOWER IS RECOMMENDED
NEAR WORK AREA.
HYGIENIC PRACTICES: SMOKING OR EATING IN THE WORK AREA SHOULD NOT BE
PERMITTED. WASH THOROUGHLY AFTER HANDLING MATERIAL. DISCARD CONTAMINATED
LEATHER GOODS.
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| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES |
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BOILING RANGE : 293 - 293 F VAPOR DENSITY : Is heavier than air
ODOR : STYRENE ODOR THRESHOLD : NE
APPEARANCE : VISCOUS LIQUID EVAPORATION RATE: Is slower than Ether
SOLUBILITY IN H2O : NEGLIGIBLE
FREEZE POINT : NE SPECIFIC GRAVITY: 1.068
VAPOR PRESSURE : NE pH @ 0.0 % : NE
(Continued on Page 4)
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Product: PR27922A000A PREPARE / REVISED: 08/07/06 Page 4
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| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES |
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PHYSICAL STATE : LIQUID VISCOSITY : 200-400cps
COEFFICIENT OF WATER/OIL DISTRIBUTION: NE
(See Section 16 for abbreviation legend)
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| SECTION 10 - STABILITY AND REACTIVITY |
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CONDITIONS TO AVOID: HEAT, FLAME, CONTAMINANTS.
INCOMPATIBILITY: CHLOROSULFONIC ACID. SULFURIC ACID. PURE OXYGEN (O2).
STRONG ALKALIS. CORROSIVE TO COPPER AND COPPER ALLOYS.
HAZARDOUS DECOMPOSITION PRODUCTS: BURNING WILL PRODUCE TOXIC FUMES.
OXIDES OF CARBON.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
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| SECTION 11 - TOXICOLOGICAL PROPERTIES |
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No product or component toxicological information is available.
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| SECTION 12 - ECOLOGICAL INFORMATION |
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ECOLOGICAL INFORMATION: DO NOT CONTAMINATE PONDS, STREAMS, OR UNDERGROUND
WATER SUPPLY. PREVENT FROM ENTERING SEWERS.
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| SECTION 13 - DISPOSAL CONSIDERATIONS |
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DISPOSAL METHOD: FOLLOW ALL RELEVANT LOCAL, STATE, AND FEDERAL
REGULATIONS. THIS PRODUCT AND ANY ABSORBENTS USED IN SPILL CLEANUP ARE
HAZARDOUS WASTES AND MUST BE DISPOSED OF ACCORDINGLY. EMPTY DRUMS MAY
CONTAIN RESIDUE OR FUMES WHICH ARE HARMFUL. DO NOT WELD,GRIND,OR USE
CUTTING TORCHES ON EMPTY DRUMS. FOR INDUSTRIAL USE ONLY. EMPTY CONTAINERS
CONTAIN PRODUCT RESIDUE WHICH IS HAZARDOUS.DO NOT WELD,BRAZE, OR GRIND.KEEP
AWAY FROM HEAT,FLAME, AND SOURCES OF IGNITION.DO NOT REUSE EMPTY
CONTAINERS. THIS PRODUCT EXHIBITS THE CHARACTERISTIC OF IGNITABILITY IF IT
BECOMES A HAZARDOUS WASTE, D001.
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| SECTION 14 - TRANSPORTATION INFORMATION |
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DOT PROPER SHIPPING NAME: RESIN SOLUTION
DOT TECHNICAL NAME: NA
(Continued on Page 5)
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Product: PR27922A000A PREPARE / REVISED: 08/07/06 Page 5
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| SECTION 14 - TRANSPORTATION INFORMATION |
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DOT HAZARD CLASS: 3 HAZARD SUBCLASS: NA
DOT UN/NA NUMBER: UN1866 PACKING GROUP: III RESP. GUIDE PAGE: 127
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| SECTION 15 - REGULATORY INFORMATION |
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THE FOLLOWING COMPONENTS ARE NOT SUBJECT TO REPORTING IN SECTION 2:
----------- CHEMICAL NAME ----------- CAS NUMBER WT/WT % IS LESS THAN
VINYL ESTER RESIN SOLIDS 068492-68-2 55.0 %
COBALT OCTOATE 12% 7440-48-4 1.0 %
N,N-DIMETHYLANILINE 121-69-7 1.0 %
U.S. FEDERAL REGULATIONS: AS FOLLOWS -
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)
CERCLA - SARA HAZARD CATEGORY:
This product has been reviewed according to the EPA 'Hazard Categories'
promulgated under Sections 311 and 312 of the Superfund Amendment and
Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD CHRONIC HEALTH HAZARD FIRE HAZARD
SARA SECTION 313:
This product contains the following substances subject to the reporting
requirements of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR Part 372:
----------- CHEMICAL NAME ----------- CAS NUMBER WT/WT % IS LESS THAN
STYRENE MONOMER,INHIBITED 100-42-5 50.0 %
COBALT OCTOATE 12% 7440-48-4 1.0 %
N,N-DIMETHYLANILINE 121-69-7 1.0 %
TOXIC SUBSTANCES CONTROL ACT:
The chemical substances in this product are not on the TSCA Section 8
Inventory.
This product contains the following chemical substances subject to the
reporting requirements of TSCA 12(B) if exported from the United States:
----------- CHEMICAL NAME ----------- CAS NUMBER
No information is available.
U.S. STATE REGULATIONS: AS FOLLOWS -
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Product: PR27922A000A PREPARE / REVISED: 08/07/06 Page 6
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| SECTION 15 - REGULATORY INFORMATION |
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NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top five
components in this product:
----------- CHEMICAL NAME ----------- CAS NUMBER
VINYL ESTER RESIN SOLIDS 068492-68-2
PENNSYLVANIA RIGHT-TO-KNOW:
The following non-hazardous ingredients are present in the product at
greater than 3%:
----------- CHEMICAL NAME ----------- CAS NUMBER
VINYL ESTER RESIN SOLIDS 068492-68-2
CALIFORNIA PROPOSITION 65:
WARNING: The chemical(s) noted below and contained in this product, are
known to the state of California to cause cancer, birth defects or other
reproductive harm:
----------- CHEMICAL NAME ----------- CAS NUMBER
No Proposition 65 chemicals exist in this product.
INTERNATIONAL REGULATIONS: AS FOLLOWS -
CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: B, D2
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| SECTION 16 - OTHER INFORMATION |
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HMIS RATINGS - HEALTH: 2* FLAMMABILITY: 3 REACTIVITY: 1
VOLATILE ORGANIC COMPOUNDS (VOCS): 0.26 lbs/gal, 32 grams/ltr
LEGEND: N.A. - Not Applicable, N.E. - Not Established,
N.D. - Not Determined
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The information contained on this MSDS has been compiled from information
obtained from raw material suppliers and is believed to be accurate. It is
the responsibility of the user to comply with all Federal, State and Local
Regulations.
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