Search    ENTER KEYWORD
MSDS Material Safety Data Sheet
CAS

71-36-3
50-00-0
7732-18-5

File Name: celanese_com---190-45135498.asp
                                        Formcel ï›?, 53% n-Butanol/ 40% Formaldehyde, solution
產å“å稱:
MSDS 炭碼: 48
æ料炭碼: 80048
公垦日期� 02/02/2006

æ料安全康傀è¡?
1. 產å“與公å¸è­˜ç¸ è³‡æ–?

Product:Formcel®, 53% n-ä¸é†‡/40% 甲醛, 溶液
MSDS 炭碼: 48
æ料炭碼:80048

Celanese Pte Ltd
111 Somerset Road
Singapore Power Building #02-02/03
Singapore 238164
Tel No: (65) 6733 1767



é‹è˜ç·Šæ?¥æƒ…縭肟钥炭碼﹕
+ (65) 66639259 (Operations Room direct dial)
+ (65) 62656917 (Operations Room direct dial)
+ (65) 62650177(Switchboard, ask for Operations Room)

or fax request to
+(65) 62644190 (Facsimile to Operations Room)
+(65) 62664696 (Facsimile to Operations Room)

or email to
opsroom@semco.psa.com.sg

or Call CHEMTREC 703 527 3887 (USA), collect calls accepted
"+" = International Dialing Access Code




產å“使用:生產用於工縄ç¸å‘ã€æœ¨ç”¢å“ã€ä¼Žé å“åŠé‘„造夸脂的苯酚ã€å°¿ç´ ã?糠醇ã?間本二酚和三èšæ°°èƒºç”²é†›å¤¸è„‚的中間物ã€?

2. æˆåˆ†/æˆåˆ†è³‡æ–™

æˆåˆ†åŠåŒ–縒文摘æœç©ºç‚­ç‚­ç¢¼ é‡é‡% OSHA 铱定ç‹?ç¸?:
æˆåˆ†åŠåŒ–縒文摘æœç©ºç‚­
炭碼
ä¸é†‡ 71-36-3 53 å±éšª
甲醛 50-00-0 40 å±éšª

Water (CAS 7732-18-5), wt. %:7

Formcel ®, 53% n-ä¸é†‡/40% 甲醛溶液å—ä¸é†‡ã?甲醛和水按照上列克稱æˆåˆ†çš„å‡è¡¡æ··åˆç‰©ã??

----------------------------------------------------------------------------------------------------------------------------

é‹è˜ç·Šæ?¥æƒ…ç¸?:703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
1 of 13
Formcel ï›?, 53% n-Butanol/ 40% Formaldehyde, solution
產å“å稱:
MSDS 炭碼: 48
æ料炭碼: 80048
公垦日期� 02/02/2006
3. å±éšªè­˜ç¸ 

緊�情�:
å±éšª!
造æˆçš®è†šå’Œæ¶ˆåŒ–é“ç¼è‘µã€?
易燃液體和蒸库ã??
咖致呼å¸é“和眼ç›åˆºæ¿€ã€?
å¸å…¥ã€çš®è†šå¸æ”¶æˆ–åžå…¥æœ‰å®³ã€?
å¯èƒ½å’–致éŽæ•æ€§å‘¼å¸åŠçš®è†šåå¼€ã€?
åžå…¥å¯èƒ½æœ‰å®³ã€?
致癌å±éšªã€‚å«æœ‰å¯èƒ½è‡´ç™Œææ–™ã?‚致癌風險縌定於接觸縭間長短åŠç¨‹åº¦ã??


產å“說明

外貌: é€æ˜Žã€ç¸ªè‰²æ¶²é«”ã??
味é“: é çƒˆã€åˆºé¼»ã?? 特的库味ã€?

é åœ¨å¥åº·å½±ç œ
暴露途拷: 皮膚ã€çœ¼ç›ã?å¸å…¥ã?åŽä¸‹ã??

å³ç¸­å½±ç œ
皮膚: å‚?引起皮膚ç¼è‘µã€? å¯èƒ½å‚?引起皮膚éŽæ•åå¼€ã€? 如果磕皮膚å¸æ”¶å‚€æœ‰å®³ã€?
暴露的徵ç‹?å¯èƒ½åŒ…括ï¹?
中央神娇系統亢抑æ‰?引起的頭痛ã?木僵ã?ä¸ç¸¡èª¿æˆ–奇怪的舉止或æ˜è¿·ã??
皮膚發紅或å“色ã?è…«ã€ç™¢ã€é­ç—›æˆ–起泡ã€?

眼ç›: 暴露於库體和液體 å‚?刺激眼ç›ã€? 暴露的徵ç‹?å¯èƒ½åŒ…括ï¹?
眼ç›åˆºæ¿€ã€ç¼é­çš„感覺ã€ç—›ã€æµçœ¼ç¸„å’?/或铱力改å“ã??

å¸å…¥: å‚?引起呼å¸é“刺æ¿?ã€? 如果å¸å…¥å‚?縫葵ã€? å¯èƒ½å‚?引起éŽæ•å‘¼å¸åå¼€ã€?
暴露的徵ç‹?å¯èƒ½åŒ…括ï¹?
中央神娇系統亢抑æ‰?引起的縄心ã?é ­é ã?é ­ç—›ã?木僵ã?ä¸ç¸¡èª¿æˆ–奇怪的舉止或æ˜è¿·ã??
æµé¼»æ°´ã?嘶俊ã?咳嗽ã?胸痛和呼å¸å›°é›£ã€? 肺ç©æ°?(肺水è…?)—徵ç‹?å¯èƒ½å»¶é²åº·å°ç¸­ã??

åŽä¸‹: å‚?引起消化é“é­è‘µã?? 如果åŽä¸‹å‚?有害ã€? 暴露的徵ç‹?å¯èƒ½åŒ…括ï¹?
中央神娇系統亢抑æ‰?引起的縄心ã?é ­é ã?é ­ç—›ã?木僵ã?ä¸ç¸¡èª¿æˆ–奇怪的舉止或æ˜è¿·ã??
縄心ã€ç¸„åã?失去食欲ã?刺æ¿?腸胃å’?/或腹縜ã?? å£ã?å–‰ã€é£Ÿç®¡å’Œ/或胃發炎ã€?

致癌æ€?: 根傀é èš©å®¤å¯‡é½’å‘物研究åŠæœ‰é™çš„人ç¾åº·å‚?,長期或é‡è¤‡å‘¼å¸ã€éŽåˆ†å—甲醛暴露å¯èƒ½
å‚?咖致鼻腫瘤ã?‚人ç¾å—甲醛暴露的研究顯示混åˆçš„çµæžœï¼ŒæŒ‡å‡ºç™½è¡?ç—…åŠä»¥ä¸‹ç‹?縭與ç”?
醛暴露有關﹕
甲醛是﹕
列å—OSHA致癌物﹕ 被NTP列å—é æœŸçš„致癌物
listed as carcinogenic to humans, IARC Group I, based on sufficient human
evidence for nasopharyngeal cancer and sufficient evidence in experimental
animals


----------------------------------------------------------------------------------------------------------------------------

é‹è˜ç·Šæ?¥æƒ…ç¸?:703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
2 of 13
Formcel ï›?, 53% n-Butanol/ 40% Formaldehyde, solution
產å“å稱:
MSDS 炭碼: 48
æ料炭碼: 80048
公垦日期� 02/02/2006
çªå“æ€?: 钥管縴蚩顯示混åˆçš„çªå“å¯èƒ½æ?§ã??

å–?特定器官的影ç ?: éŽåº¦ï¼ˆé•·æœŸæˆ–å客)接觸å¯å’–致ï¼?
中啃神娇系統亢抑
刺激呼å¸é?
消化é“縫è‘?
éŽæ•åå¼€åŠçš®è†šå±€éƒ¨åˆºæ¿?
皮膚縫葵�
生殖系統å—縫
éŽæ•æ€§å‘¼å¸åå¼?
Nasal tract

大é‡æŽ¥è§¸é’¥åŒ–縒å“å¯èƒ½å‚?å–?患有下列急æ?§å’Œæ…¢æ?§å™¨å®˜ç–¾ç—…的病人有ä¸åˆ©å½±ç œï¼š
ä¸?般èªå—在暴露後傀使病情亢化的 呼å¸é?
病縭: 皮膚
眼ç›
消化系統


有關钥情,竣é“?: ç¬?5部分 â€? è·¨ç«æŽªæ–½
ç¬?4部分 â€? 急救措施 ç¬?6部分 â€? æ„外峥放措施
ç¬?8部分 â€? 暴露控制/é äººä¿è­·
ç¬?9部分 â€? 物ç†èˆ‡åŒ–縒特æ€?
ç¬?10部分 â€? 房定性與åå¼€æ€?

4. 急救措施

皮膚: ç«‹å³ç”¨å¤§é‡æ¸…水縚洗皮膚至å°?15分缈,縆åŒç¸­æ¯ä¸‹æ±¡æŸ“çš„è¡£æœå’Œéž‹å­ã€‚ç«‹å³éƒ¡æ±‚æ²»
。衣æœå¼€æ´—乾縌後æ‰èƒ½å†ç©¿ã€‚房å‘çš„éž‹å­å¼?å’–è·¨ã€?

眼ç›: ç«‹å³ç”¨å¤§é‡æ¸…水縚洗眼ç›è‡³å°?15分缈。如果有戴隱形眼é¡ç¸†å¯ä»¥è¼•æ˜“å–下縭,å¼?竣之
å–下。立å³éƒ¡æ±‚æ²» ã€?

å¸å…¥: 移往空库清新炭ã?‚如果åœæ­¢å‘¼å¸ï¼Œå¼?施人工呼å¸ã?‚如果呼å¸å›°é›£ï¼Œå¼?給氧库ã?‚驴絡醫
生ã??

åŽä¸‹: 切勿引起縄å。立å³éƒ¡æ±‚æ²» 。如果å—害è?…完全清醒,給他å–一æ¯æ°´ã€‚切勿餵æ˜è¿·çš?
人任何縷西ã??

醫生注æ„: è§?察延究肺水腫ã€? 呼å¸é“暴露後å¯èƒ½å‚?咖致化縒肺炎ã€?

5. è·¨ç«æŽªæ–½

NFPA: Health: 3 Flammability: 2 Reactivity: 0

易燃特æ??

閃點(縴钥方法)� 57 C (135 F) (SETA)

易燃é™åº¦ï¼Œåœ¨ç©ºåº“,容ç©?%
----------------------------------------------------------------------------------------------------------------------------

é‹è˜ç·Šæ?¥æƒ…ç¸?:703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
3 of 13
Formcel ï›?, 53% n-Butanol/ 40% Formaldehyde, solution
產å“å稱:
MSDS 炭碼: 48
æ料炭碼: 80048
公垦日期� 02/02/2006
上é™: 73 % (Formaldehyde)
11.2 % (Butanol at 25 deg C)
下é™: 7 % (Formaldehyde)
1.4% (Butanol at 25 deg C)

自å‘點燃控度: 300 C (572 F) (Formaldehyde)
343 C (649 F) (Butanol)

燃é­ç”¢å“ï¼? ä¸?氧化碳ã??


è·¨ç«åª’介: 大ç«ä½¿ç”¨é…’ç²¾ç¾çš„水溶æˆè†œæ³¡æ²«ã€? å°ç«ä½¿ç”¨äºŒæ°§åŒ–碳或乾化縒å“ã??

消防說明 å¼?用水冷縮暴露在ç«ä¸­çš„建築和槽。竣水å¯ç”¨æ–¼é™ä½Žç«æž¯ï¼Œç¸†ç«£æº¢å‡ºç‰©ç¨?å³¥æˆä¸æ˜“ç‡?
çš„æ··åˆç‰©ã€?
竣人ç¸æ’¤é›¢ç«æºè‡³è¿Žé¢¨åœ°é»žã€‚如果有å¯èƒ½æš´éœ²åœ¨è’¸åº“下或有å¯ç‡ƒé­çš„產å“存在,开ç©?
全套消防è£å¤¸å’ŒNIOSH核准çš? 立呼å¸è£å¤¸ã?‚氧化化縒å“在著ç«çš„情縭下å¯èƒ½å‚€åŠ é?Ÿç‡ƒ
é­çš„速度ã€?

消防環ä¿é é¡Œ 溢出的水和蒸库肟å¯èƒ½æœ‰è…è•æ?§ã?‚用堤縆收集用於跨ç«çš„水,中和後æ‰å³¥æ”¾ã??
å¯ä½¿ç”¨æ°´éœ§æµæŽ§åˆ¶è’¸åº“和燃é­åº“é«”ã??
å†ç”¨å–?è—快設夸和其它跨ç«è¨­å¤¸å‰å¼?完全清除污染ã€?

6. æ„外峥放措施

溢出或开æ¼èªªæ˜? 排除點ç«æºã??
竣铱ç¬?8部分有關é? 的人ç¸ä¿è­·è¨­å¤¸ã?‚用土堤或éžæ˜“燃的å¸æ”¶å’¯éš”離溢出物,使污æŸ?
ä¿æŒåœ¨æœ€å°çš„範窥咳ã?? 水霧æµå¯ä»¥ç¸«å°‘蒸库ã??
如果有起ç«çš„å¯èƒ½ï¼Œå¼€ä½¿ç”¨é…’ç²¾ç¾çš„水溶æˆè†œæ³¡æ²«å®½è¦†è“‹æº¢å‡ºç‰©ï¼Œæˆ–用水霧æµåˆ†æ•£è’?
库ã??
å¼?é¿å…æµå…¥ä¸‹æ°´é“åŠé€šå¾€æ°´é“的肯渠ã?‚若州åŠåœ°æ–¹æœ‰é“±å®šï¼Œå¼?通知地方 å±?。竣å¼?æ¼?
的容器置於é?šé¢¨è‰¯å¥½ç‚­ã?? 使用氨基磺酸或é‡é ç¡«é…¸éˆ‰ä¸­å’Œã€?
使用éžç‡ƒé­çš„å¸æ”¶å’¯æ¸…除或用少許水縚洗å°é“±æ¨¡çš„溢出物ã?‚用真空å¸é™¤æˆ–窟除乾縌ã??

在美盔境咳,如果åœ?24å°ç¸­å’³å³¥æ”¾å‡ºçš„分é‡ç›¸ç­‰æ–¼æˆ–超於下列开矿告的分é‡ç¸­ï¼Œå¼€è‡?
肟�全盔回�中心�(National Response Center) (800-424-
8802)å’Œé© çš„å·žå? 地緾關﹕
250 lbs. of the material as is; based on a Reportable Quantity of 100 lbs.
for formaldehyde.

èš©æ•£ä¸å¿…è¦åœ¨å†µçš„人;隔離å±éšªåœ°ç¸™ç¸†æ‹’絕任何人進入。ä¿æŒåœ¨è¿Žé¢¨çš„ä½ç½®ï¼›é¿é–‹ä½?
的地縙ã?? 如果ç«ç£•æ¶‰åŠåˆ°é‹è˜ç½ã€ç«èŠ¸ç½èŠ¸æˆ–å¡èŠ¸ç½èŠ¸ï¼Œå¼€åœ¨å„é æ–¹å‘上隔離800ç±?
�0.5哩)�
如果情縭有必è¦å¼€æ’¤é›¢ç œé¢¨åœ°ç¸™ä»¥é é˜²æš´éœ²ï¼Œç¸†å“蒸库或é æ¶ˆæ•£ã€‚æŸäº›æƒ…縭的溢出ç‰?
å¯èƒ½ä½¿ç›¸ é è·é›¢çš„砜風地縙暴露於有毒或å¯ç‡ƒé­çš„库度ã€?

7. ç‚­ç†èˆ‡å–€è—?


----------------------------------------------------------------------------------------------------------------------------

é‹è˜ç·Šæ?¥æƒ…ç¸?:703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
4 of 13
Formcel ï›?, 53% n-Butanol/ 40% Formaldehyde, solution
產å“å稱:
MSDS 炭碼: 48
æ料炭碼: 80048
公垦日期� 02/02/2006
ç‚­ç†: 在é?šé¢¨è¶³æ¡†çš„環境下使用ã€?
ä¸ä½¿ç”¨ç¸­å¼?竣容器關緊ã?‚打開容器縭,开å°å¿ƒæŒšæ…Žå“ç´¯ç©çš„亢力é€å‡ºã€‚é¿å…å¸å…¥è’¸åº?
。é¿å…與眼ç›ã€çš®è†šæˆ–è¡£æœæŽ¥è§¸ã€‚ç‚­ç†å¾Œå¼?用肥皂和水控底洗乾縌。沾污的衣æœå¼?æŽ?
底清除污染後æ‰å†ä½¿ç”¨ã€‚污染的皮é©è¡£ç‰©å¼?å’–è·¨ã€?

本產å“å¯èƒ½å‚€ç”¢ç”Ÿéœè‚Ÿã€‚在é‹è˜æ料縭,å¼?竣設夸接åœ?/ç´„æŸä»¥é é˜²éœè‚Ÿçš„ç´¯ç©ã€‚在ç¾?
盔,æ‰?有喀è—和炭ç†ç”¨çš„è‚Ÿå­è¨­å¤¸éƒ½å¿…砜符åˆã?Œå…¨ç›”肟库铱程ã??(ç¬?500å’?501ç¸?)å–?å?
險地點的è¦æ±‚ã€?

å–?è—?: 湛勿與ä¸å…¼å®¹çš„æ料喀存ã?‚竣铱ã?Œç¬¬10部分,房定æ?§èˆ‡å开性ã?ã??
ä¸ä½¿ç”¨ç¸­ï¼Œç«£æ‰?有容器關緊ã?‚喀存在縘有昕光照射和ä¸å¯ç·½é€çš„地æ¿ä¸Šã??

8. 暴露控制/é äººä¿è­·

工程控制 ä¸?般或ç¨?å³¥é?šé¢¨ä½œå—雇ç¸æš´éœ²çš„唯ä¸?控制方法通常是ä¸è¶³æ¡†çš„ã?‚é?šå¸¸é å…ˆé¸ç‹‚的是å±?
部�風�

�隨縭渴夸好安全淋浴和洗眼設夸�
é äººä¿è­·è¨­å¤¸
皮膚ä¿è­·: ç©¿é?ä¸éŽçš„è¡£æœå’Œæ‰‹å¥—以便é é˜²æŽ¥è§¸ã?‚建議使用ä¸åŸºæ©¡è† ã?‚铱情縭,如果有足框的é™
解和緽é?資料,å¯ä½¿ç”¨å…¶å®ƒä¿è­·ææ–™ã?‚如果在使用本化縒å“çš„åŒç¸­ä½¿ç”¨å…¶å®ƒåŒ–縒å“ï¼?
é¸ç‹‚çš„æ料开能ä¿è­·æ‰€æœ‰ä½¿ç”¨çš„化縒å“ã??

眼ç›/目部ä¿è­·: 如有å¯èƒ½æŽ¥è§¸çœ¼ç›ç¸­å¼€æˆ´åŒ–縒護目é¡ã€?
如果å¯èƒ½é ç«£åˆ°ç›®ä¸Šç¸­ï¼Œé™¤äº†æˆ´è­·ç›®é¡å¤–呖开戴é¢ç½©ã??

呼å¸é“ä¿è­?: 根傀工作况所的污染程度åŠé˜²æ¯’é¢ç½©çš„工作é™åº¦ï¼Œä½¿ç”¨å¨‡ã?Œå…¨ç›”驴縄安全與ä¿å¥ç¸’å‚€
�(NIOSH)
核准使用的防毒é¢ç½©ã?‚以下是建議驴縄暴露水平至少å¼?有的è£å¤¸ã€‚竣铱第3ã€?8ã€?11éƒ?
分以便估涌驴縄暴露水平ã??
库度高於驴縄暴露水平1å€ï¼Œä½†ä½Žæ–?100å€ï¹•ä½¿ç”¨ç½©è“‹æ•´é ç›®ã?在亢力è¦æ±‚下或ä¸è‹¦è?
é€ç©ºåº“的防毒é¢ç½©ã€?
库度高於IDLH水平或库度ä¸æ˜?(例如在緊急情縭下)﹕使用罩蓋整é ç›®ã€åœ¨æ­£äº¢ç‹?緽下
é‹ä½œçš? 立呼å¸è£ç½®ã?‚å«è¼”助正亢 立呼å¸è£ç½®é?ƒç”Ÿç³»çµ±çš„C型正亢罩蓋整é ç›®ã€è˜é€?
空库的防毒é¢ç½©ã??
逃生﹕使用罩蓋整é ç›®çš? 立呼å¸è£ç½®æˆ–任何特縠准許供é?ƒç”Ÿç”¨çš„防毒é¢ç½©ã€?

暴露指å—
é‡é‡% ACGIH ACGIH ACGIH OSHA OSHA OSHA Celanese Mexico Mexico Mexico
æˆåˆ†åŠåŒ–縒文摘æœç©? æˆåˆ†åŠåŒ– TWA STEL CEILING TWA STEL CEILING WEL TWA STEL CEILING
ç‚­ç‚­ç¢? ç¸’æ–‡æ‘˜æœ (工作况所
空炭炭碼 接觸é™åº¦)
ä¸é†‡ 71-36-3 53 20 PPM - - 100 ppm - - - 50 ppm - -
甲醛 50-00-0 40 - - 0.3 ppm 0.75 ppm 2 ppm - 0.75 ppm - - 2 ppm
(TWA); 2
ppm (STEL)




----------------------------------------------------------------------------------------------------------------------------

é‹è˜ç·Šæ?¥æƒ…ç¸?:703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
5 of 13
Formcel ï›?, 53% n-Butanol/ 40% Formaldehyde, solution
產å“å稱:
MSDS 炭碼: 48
æ料炭碼: 80048
公垦日期� 02/02/2006
æˆåˆ†åŠåŒ–縒文摘æœç©ºç‚­ç‚­ç¢¼ é‡é‡% 1990 NIOSH IDLH 1994 NIOSH IDLH
æˆåˆ†åŠåŒ–縒文摘æœç©ºç‚­ (Recognized by OSHA)
炭碼
ä¸é†‡ 71-36-3 53 8000 ppm 1400 ppm
甲醛 50-00-0 40 30 ppm 20 ppm


Comments: Celaneseå…¬å¸æ ¹å‚€å–?æ‰?有ç¾æœ‰è³‡æ–™çš„科縒評估,縌定喀甲醛ä¸ç‹‚ç”? ACGIH 上é™å€¼ã??
Celanese å…¬å¸å–?ä¸é†‡ç‹‚用 ACGIH TLV ã€?

9. 物ç†å’ŒåŒ–縒特æ€?

外貌: é€æ˜Žã€ç¸ªè‰²æ¶²é«”ã??

味é“: é çƒˆã€åˆºé¼»ã?? 特的库味ã€?

pH: 6.2

Vapor Pressure: 24 mmHg @ 30 deg C

Vapor Density (Air=1 @ 20 C): Formaldehyde: 1.04
Water: 0.62
Butanol: 2.56

Boiling Point (760 mmHgA): 104.5 C (220 F)

Freezing Point: Below 25 deg C (77 deg F), solid formaldehyde
polymer gradually forms.

Solubility in Water @ 20 C: 51.6 %



Specific Gravity: 0.971 @ 30 deg C

Molecular Weight:: Formaldehyde: 30.0
Water: 18.0
Butanol: 74.1



10. 房定性與åå¼€æ€?

房定�: 房定�

å¼?é¿å…的情ç¸?: é¿å…高酷ã€ç«ç„°ã?ç«èŠ±å’Œå…¶ä»–ç«æºã€?

å¼?é¿å…çš„ææ–?: é¿å…接觸夸氧化鈉ã€çŸ³ç°å’Œå…¶å®ƒé é¹¼ã€éˆ‰ã€é¥ªå’Œå…¶å®ƒé é¹¼é‡‘抠ã?鹽酸ã?硫酸和其它é?
縪緾酸ã?氮氧化物ã?胺和氧化咯如éŽæ°§åŒ–物ã?ç¡é…¸ã?高氯酸ã€ä¸‰æ°§åŒ–鉻ã?苯酚或尿素
�

å±éšªæ˜“燃或分解產å“?: 酷分解產å“å¯èƒ½å«æœ‰ç¢³çš„氧化物ã€?

----------------------------------------------------------------------------------------------------------------------------

é‹è˜ç·Šæ?¥æƒ…ç¸?:703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
6 of 13
Formcel ï›?, 53% n-Butanol/ 40% Formaldehyde, solution
產å“å稱:
MSDS 炭碼: 48
æ料炭碼: 80048
公垦日期� 02/02/2006
å±éšªèšåˆä½œç”¨: ä¸å‚€ç”¢ç”Ÿå±éšªçš„èšåˆä½œç”¨ã??

11. 毒�資�



Component Toxicological Information

æˆåˆ†åŠåŒ–縒文摘æœç©ºç‚­ç‚­ç¢¼ ä¸é†‡
Acute Exposure:

Oral LD50: 0.79-4.36 g/kg (rats); slightly toxic to animals.

Inhalation LC50: > 8000 ppm (rats, 4 hours); practically nontoxic to
animals.

Skin: Moderately irritating to rabbit skin; slightly toxic to animals
(LD50, rabbits: 3.4 - 5.3 g/kg).

Eyes: Severely irritating to rabbit eyes.


Mutagenicity: Not mutagenic in most in vitro assays (e.g.,Ames test, SCE &
micronucleus assays with Chinese hamster cells).

Carcinogenicity: No information.

Reproductive/Developmental Effects: In an inhalation developmental
toxicity study, rats were exposed 7 hrs/day to 0, 3500, 6000 or 8000 ppm.
Maternal toxicity and fetotoxicity were observed at 6000 and 8000 ppm. A
slight increase in skeletal abnormalities was observed at 8000 ppm, a dose
which caused 10% maternal mortality. The no effect concentration for
developmental toxicity was 3500 ppm. In a behavioral teratology study,
rats were exposed 7 hrs/day to 0, 3000 or 6000 ppm butanol. Significant
effects were not observed.


Repeated Exposure: Rats were exposed orally via gavage to doses of 0, 30,
125, and 500 mg/kg/day for 13 weeks. CNS effects were observed in the
high dose animals during the final 6 weeks of dosing. The no observed
adverse effect level was 125 mg/kg/day. In a research study, oral exposure
of rats to 6.9% butanol in drinking water for 3 months affected liver
mitochondria.
æˆåˆ†åŠåŒ–縒文摘æœç©ºç‚­ç‚­ç¢¼ 甲醛




----------------------------------------------------------------------------------------------------------------------------

é‹è˜ç·Šæ?¥æƒ…ç¸?:703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
7 of 13
Formcel ï›?, 53% n-Butanol/ 40% Formaldehyde, solution
產å“å稱:
MSDS 炭碼: 48
æ料炭碼: 80048
公垦日期� 02/02/2006
Acute Exposure: Toxicity information on the solution is generally not
available. Information on the solution components is listed next.

Oral LD50: 800mg/kg (rats); slightly toxic to animals.

Inhalation LC50: 474ppm (rats,4 hrs.); moderately toxic to animals.

Skin: Severely irritating/corrosive to rabbit skin depending on exposure
duration and concentration; moderately toxic to animals (LD50, rabbits:
270mg/kg); causes skin sensitization in humans and guinea pigs.

Eye: Severely irritating to rabbit eyes.




----------------------------------------------------------------------------------------------------------------------------

é‹è˜ç·Šæ?¥æƒ…ç¸?:703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
8 of 13
Formcel ï›?, 53% n-Butanol/ 40% Formaldehyde, solution
產å“å稱:
MSDS 炭碼: 48
æ料炭碼: 80048
公垦日期� 02/02/2006
Mutagenicity: Genotoxic potential was noted in a variety of in vitro
systems. Results in vivo have been mixed probably due to the presence of
metabolic processes for detoxifying.

Carcinogenicity: Oral-Formaldehyde was not carcinogenic in several well-
conducted rodent lifetime drinking water studies. Repeated dermal-topical
application on mice has not indicated carcinogenic potential. Inhalation-
Rats and mice were exposed to 2.0, 5.6, or 14.3 ppm formaldehyde for
6hrs/day, 5 days/week for 24 months. In rats no treatment-related tumors
were seen at 2 ppm while at 5.6 ppm 1% had nasal tumors and at 14.3 ppm
43% had nasal tumors. In mice no treatment-related tumors were observed
at 2 ppm or 5.6 ppm while 1% had nasal tumors at 14.3 ppm. IARC: Group I,
Carcinogenic to Humans, based on sufficient human (nasopharyngeal cancer)
and experimental animal data. Formaldehyde is listed as an OSHA
carcinogen. Formaldehyde is listed as an anticipated carcinogen by the
NTP.

Hauptmann, et. al. (2004) have reported a statistically significant dose-
related increase in the incidence of nasopharyngeal tumors in a large
cohort of formaldehyde exposed workers. In another study by Hauptmann,
et. al. (2003) based upon the same cohort, a statistically significant
dose-related increase of leukemia mortality was observed. However, this
increase was seen only for a peak exposure metric and the rate of leukemia
mortality was less than that of the unexposed general population. In
addition, the Hauptmann et. al. (2003) results are not consistent with the
findings of Coggon et. al. (2003). Coggon et. al. found no association
between formaldehyde exposure and leukemia incidence in a large cohort of
U.K. workers with estimated formaldehyde exposures higher than the
Hauptmann et. al. (2003) study. A recent NIOSH study (Pinkerton, et. al.
2004) based on a cohort of formaldehyde exposed garment workers reported
only a marginal association with leukemia incidence. Experimental data
linking formaldehyde exposure with toxicity in organs, including the bone
marrow, remote from the portal of entry is lacking. Also, an established
mechanism for induction of leukemia by formaldehyde is not available.
Furthermore, formaldehyde inhalation by rats in several well-conducted
cancer bioassays did not induce leukemia.

Reproductive/Developmental Effects: In a developmental toxicity study with
mice dosed orally by gavage at 74, 148 or 185 mg/kg/day, no fetotoxic or
teratogenic effects were seen. In a developmental toxicity study with
rats exposed via inhalation to 2, 5 or 10ppm formaldehyde, treat-related
developmental effects were not observed. In a reproduction study, dogs
received the equivalent of 9.4 mg/kg/day of formaldehyde in feed during
days 4-56 after mating without adverse reproductive effects.




----------------------------------------------------------------------------------------------------------------------------

é‹è˜ç·Šæ?¥æƒ…ç¸?:703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
9 of 13
Formcel ï›?, 53% n-Butanol/ 40% Formaldehyde, solution
產å“å稱:
MSDS 炭碼: 48
æ料炭碼: 80048
公垦日期� 02/02/2006
Repeated Exposure: Inhalation exposure (6hrs./day;5 days/week;13 weeks)
of rats resulted in nasal tissue irritation at 10 or 20ppm, but not at
2ppm. Monkeys exposed for 26 weeks (22hrs./day;7 days/week) had nasal
irritation at 3ppm but not at 1ppm. Oral exposure of rats to formaldehyde
in the drinking water at a dose equivalent to 82-109 mg/kg/day over a
lifetime resulted in stomach tissue irritation while a dose of 15-21
mg/kg/day was without effect.


12. 生緽資料



Component Ecological Information

æˆåˆ†åŠåŒ–縒文摘æœç©ºç‚­ç‚­ç¢¼ ä¸é†‡
Ecotoxicity: n-Butanol exhibits low acute toxicity to aquatic species.
The 24-, 48- and 96-hour LC50 values for various fish species (Medaka,
Golden Orfe, creek chub, fathead minnow, goldfish and bleak) range from
500 to 2300 ppm. The 48-hour EC50 for the water flea (daphnid) is 1983
ppm; for brine shrimp the LC50 is 2950 ppm. The 48-hour EC50 for protozoa
is 2466 ppm. The toxicity thresholds for the alga Scenedesmus quadricauda
and for cyanobacteria are 95-875 ppm and 100-312 ppm, respectively. Cell
multiplication was inhibited for Entosiphon sulcatum (euglenoid) at 55 ppm
after 72 hours. The 48-hour LC50 for Xenopus laevis (clawed toad) is 1200
ppm.


Environmental Fate:

Degradation: Under aerobic conditions butanol is readily biodegradable.
The BOD (5-day)/COD ratio ranges from 0.42 - 0.74. In the Zahn-Wellens
Test, 93-95% biodegradation was reported in 5 days. Atmospheric
photochemical degradation is expected to range from 5 hours (in a sunlit
urban atmosphere) to 2.3 days. Volatilization half-lives in water are
estimated to be 2.4 hours, 3.9 hours, and 125.9 days in model streams,
rivers and lakes, respectively.

Bioaccumulation: The calculated bioconcentration factor for goldfish is
0.62-0.67. The log n-octanol/water partition coefficient for n-butanol is
0.88. This suggests that butanol has low potential to bioaccumulate.
æˆåˆ†åŠåŒ–縒文摘æœç©ºç‚­ç‚­ç¢¼ 甲醛




----------------------------------------------------------------------------------------------------------------------------

é‹è˜ç·Šæ?¥æƒ…ç¸?:703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
10 of 13
Formcel ï›?, 53% n-Butanol/ 40% Formaldehyde, solution
產å“å稱:
MSDS 炭碼: 48
æ料炭碼: 80048
公垦日期� 02/02/2006
Ecotoxicity: Formaldehyde exhibits slight acute toxicity to various fish
species. The 24-, 48- and 96-hr. LC50 values (bluegill sunfish, trout,
bass, salmon, catfish, carp, golden orfe) are in the range 10-1000ppm.
Algae and some invertebrates appear more susceptible e.g., acute toxicity
occurs in green algae at 0.3-0.5ppm and in the water flea (daphnids) at 2-
52ppm (24/48-hr. EC50). Formaldehyde has bactericidal properties at low
levels (EC50, E. coli=1ppm).


Environmental Fate: The short atmospheric half-life, the low n-
octanol/water partition coefficient and the ability of animals &
microorganisms to rapidly biodegrade formaldehyde are expected to lead to
its ready removal if released into the environment.
Degradation: Formaldehyde in aqueous effluent is degraded by activated
sludge and sewage in 48-72 hr. In a die-away test with lake water,
degradation was complete in 30 hrs. under aerobic conditions and 48 hrs.
under anaerobic conditions. Atmospheric photochemical degradation is
rapid with estimated half-lives of 19hrs. or less.

Bioaccumulation: The log n-octanol/water partition coefficient is 0.35.
This suggests that formaldehyde has relatively low potential to
bioaccumulate.



13. 縂é ç¸­çš„注æ„事砜

根傀州和 地铱定以驴邦éžå±éšªå®šç¾©ç‚­ç†æº¢å‡ºç‰©ã€‚湛注æ„,此資料縃开用在æ‰?製é? çš„æ料;加工ã?使用或污染å¯èƒ½
å‚?使本資料ä¸é© ã€ä¸æ­£ç¢ºæˆ–ä¸å®Œæ•´ã€?

湛注æ„﹕這一炭ç†èˆ‡ç¸‚é è³‡æ–™ä¹Ÿå¯èƒ½é©ç”¨æ–¼ç©ºå®¹å™¨ã€ç¸·å’Œé æ¸£ã?‚å·žæˆ? 地铱定或é™åˆ¶éžå¸¸è¤‡é›œï¼Œè?Œä¸”å¯èƒ½ 於驴é‚?
铱定。本資料的目的是縡助é? çš„ç‚­ç†èˆ‡ç¸‚é ï¼›ç‚­ç†èˆ‡ç¸‚é çš„最後乜任由ç¸æ–™çš„宽有人乜乜。竣铱ã?Œç¬¬9部分,物ç?
與化縒特性ã?ã??



14. é‹è˜è³‡æ–™

US Department of Transportation:
UN/NA Number: UN 1198
Shipping name: FORMALDEHYDE, SOLUTIONS, FLAMMABLE
Hazard class: 3
Subsidiary hazard: 8
Packing Group: PG III
DOT Reportable Quantity (RQ): 100 Lb./ 45.4 Kg (FORMALDEHYDE)
5000 Lb./ 2270 Kg (BUTANOL)
Emergency Response Guide: 132

----------------------------------------------------------------------------------------------------------------------------

é‹è˜ç·Šæ?¥æƒ…ç¸?:703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
11 of 13
Formcel ï›?, 53% n-Butanol/ 40% Formaldehyde, solution
產å“å稱:
MSDS 炭碼: 48
æ料炭碼: 80048
公垦日期� 02/02/2006


ICAO/IATA:
IATA UN Number: UN 1198
Proper Shipping Name: FORMALDEHYDE, SOLUTIONS, FLAMMABLE
Hazard Classification: 3
Subsidiary Hazard: 8
Packing group: III
Label: (Flammable Liquid) Corrosive



IMDG:
International Marine UN Number: UN 1198
Proper Shipping Name: FORMALDEHYDE, SOLUTIONS, FLAMMABLE
Hazard Class: 3
Subsidiary Hazard: 8
Packing Group: III
閃點(縴钥方法)� 57 C (135 F) (SETA)


Transport Canada


Trade Information
Schedule B Code (export): 2912.11.0000
Harmonization Code (import): 29121100

15. 法铱資料
Hazard labeling:




R phrases
R 34 å¯å’–致é­è‘µã??
R 40 å¯èƒ½å‚?咖致ä¸å¯é€†è½‰çš„效果ã??
R 41 å¯èƒ½å‚?å·é‡è‘µå®³çœ¼ç›ã€?
R 43 皮膚接觸å¯èƒ½å‚?咖致æ•åŒ–ã€?
R 67 库體å¯èƒ½å‚?咖致瞌ç¡å’Œçœ©é ã??

R 23/24/25 å¸å…¥ã€æŽ¥è§¸çš®è†šåŠå¦‚æžœåžä¸‹å‚?有毒ã€?
R 37/38 刺激呼å¸ç³»çµ±åŠçš®è†šã??




----------------------------------------------------------------------------------------------------------------------------

é‹è˜ç·Šæ?¥æƒ…ç¸?:703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
12 of 13
Formcel ï›?, 53% n-Butanol/ 40% Formaldehyde, solution
產å“å稱:
MSDS 炭碼: 48
æ料炭碼: 80048
公垦日期� 02/02/2006
S phrases
S 13 é é›¢é£Ÿç‰©ã€é”Ÿæ–™åŠå‘物锟料ã€?
S 26 若接觸眼ç›ï¼Œå¼?ç«‹å³ä½¿ç”¨å¤§é‡æ¸…水縚洗,縆郡求æ²? ã€?
S 45 若發生æ„外或如果你覺得ä¸èˆ’æœï¼Œæ¹›ç«‹å³éƒ¡æ±‚æ²? (å¯èƒ½çš„钥,顯示本克籤) ã€?
S 60 這一ææ–™åŠå…¶å®¹å™¨å¿…砜作å±éšªç¸æ–™ç‚­ç†ã??

S 36/37/39 æ¹›ç©¿æˆ´é© çš„ä¿è­·è¡£ç‰©ã?手套åŠçœ¼ç›/é¢éƒ¨è­·ç½©ã€?




INTERNATIONAL REGULATIONS
化縒钥伎目淇
列於下列盔家的化縒钥伎目淇的砜目符åˆè±å…資格:
AUSTRALIA,CHINA,CANADA,EUROPE,KOREA,PHILIPPINES, JAPAN

16. 其它資料

æ供课ä½: 產å“指咖éƒ?
Celanese å…¬å¸

å±éšªç­‰ä¼Ž 本資料縃供娇NFPA å’?/æˆ? HMIS 系統涌究的人ç¸ä½¿ç”¨ã??

NFPA: Health: 3 Flammability: 2 Reactivity: 0

HMIS: Health: 3* Flammability: 2 Reactivity: 0

下列資料是最新版本MSDS出版後的 The following sections have been revised since the last issue of this
修正: MSDS.

1. 產å“與公å¸è­˜ç¸ è³‡æ–?
此炭å«æœ‰è³‡æ¶Œä¹‹ç²¾ç¢ºç¨‹åº¦å—我é æœ?大é™åº¦ä¹‹æ‰?知ã?‚我é ç¸†ä¸è¡¨ç¤ºæˆ–ä¿è­‰æ­¤ç‚­æ‰?列之任何å±éšªå—縃有之å±éšªã€‚就你所å€å¾—之æ料之å®?
全使用(或與其它物質�裤使用),Celanese
å…¬å¸ä¸æ供任何明確或暗示之ä¿ç”¨ã?‚其它ææ–™å¯åŠ é‡æœ¬æ料的å±éšªæ€§ï¼Œæœ¬æ料亦å¯åŠ é‡æˆ–增加其它æ料的å±éšªæ?§ã?‚本ææ–™å¯ç£•ç›´æŽ¥
或間接由其製æˆçš„库體ã€æ¶²é«”或固體æ料中峥出ã?‚使用è?…喀確定本æ料是å¦é©æ–¼ä»»ä½•ä½¿ç”¨åŠæ‰?涌é çš„使用方å¼ä¹œå®Œå…¨ä¹œä»»ã€‚使用è??
必砜符åˆæ‰?有有關安全åŠå¥åº·å…‹æ¸´ã€‚æ料安全資涌课由Celaneseå…¬å¸åœ¨ç¶²éš›ç¶²çµ¡ä¸Šæ供,作牽喀客眶的一砜æœç©ºã??
宽有網際網絡的æ料安全資涌课縆ä¸è¡¨ç¤ºé’¥æ料安全資涌课æŒæœ‰äººå³å—有關產å“çš„å€è²·äººæˆ–用眶ã€?




----------------------------------------------------------------------------------------------------------------------------

é‹è˜ç·Šæ?¥æƒ…ç¸?:703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day
13 of 13

Search    ENTER KEYWORD
ALL Chemical Property And Toxicity Analysis PAGES IN THIS GROUP
NAMECAS
celanese_com---087-00134277.asp 110-44-1
celanese_com---087-22424316.asp 74-89-5 7732-18-5
celanese_com---095-80426025.asp 67-56-1 79-20-9 25213-24-5
celanese_com---097-23001098.asp 4435-53-4
celanese_com---112-13226318.asp 7397-62-8 10397-22-5 6634-18-0
celanese_com---115-25219726.asp 67-56-1 25213-24-5
celanese_com---115-65573120.asp 108-05-4
celanese_com---117-01123046.asp 67-56-1 50-00-0
celanese_com---121-11376953.asp 24634-61-5
celanese_com---123-23687744.asp 141-78-6
celanese_com---127-02444458.asp 71-23-8
celanese_com---129-35958862.asp 50-00-0 67-56-1 7732-18-5
celanese_com---138-57934570.asp 108-11-2
celanese_com---142-73995971.asp 123-86-4
celanese_com---148-19961547.asp 108-11-2
celanese_com---148-91198730.asp 110-44-1
celanese_com---166-91995239.asp 55589-62-3
celanese_com---168-78115844.asp 24634-61-5
celanese_com---169-51055908.asp 123-73-9 4170-30-3
celanese_com---171-62579345.asp 78-93-3
celanese_com---171-98901367.asp 74-89-5
celanese_com---175-02606201.asp 123-86-4
celanese_com---175-69561767.asp 67-56-1 9002-89-5
celanese_com---179-76858520.asp 108-05-4
celanese_com---190-45135498.asp 71-36-3 50-00-0 7732-18-5
celanese_com---194-04327392.asp 108-24-7
celanese_com---195-67565917.asp 123-86-4
celanese_com---199-60046386.asp 67-56-1 9002-89-5
celanese_com---199-66604614.asp 105-76-0 105-75-9
celanese_com---199-98361206.asp 50-00-0 67-56-1
celanese_com---200-86853027.asp N/A
celanese_com---203-99728393.asp 75-07-0 107-02-8
celanese_com---204-59643554.asp 50-00-0 67-56-1 7732-18-5
celanese_com---209-59539794.asp 67-56-1 9002-89-5
celanese_com---214-56015014.asp 123-86-4
celanese_com---216-48580932.asp 79-20-9
celanese_com---217-79354858.asp 108-10-1
celanese_com---221-71136474.asp 4435-53-4
celanese_com---222-43585205.asp 64-19-7
celanese_com---235-23135375.asp 108-21-4
celanese_com---236-58312988.asp 108-24-7
celanese_com---240-38970947.asp 24634-61-5 25-26-3
celanese_com---240-74902343.asp 123-42-2
celanese_com---250-57009887.asp N/A
celanese_com---252-41900634.asp 7397-62-8 10397-22-5 6634-18-0
celanese_com---263-18237304.asp 7397-62-8 10397-22-5 6634-18-0
celanese_com---265-43963623.asp 108-21-4
celanese_com---270-85147094.asp N/A
celanese_com---272-46072387.asp 24634-61-5
celanese_com---280-41058349.asp 108-11-2

Free MSDS Search ( Providing 250,000+ Material Properties )
Chemcas.com | Ads link:HBCCHEM.INC