MEGUIAR'S M34 - FINAL INSPECTION
Chemwatch Material Safety Data Sheet
Issue Date: 16-Nov-2006 CHEMWATCH 4912-6
NA317EC CD 2006/4 Page 1 of 10
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
MEGUIAR'S M34 - FINAL INSPECTION
SYNONYMS
"Manufacturer's Code: M34"
PRODUCT USE
Surface cleanser.
SUPPLIER
Company: Meguiar' s Australia Pty Ltd
Address:
35 Slough Business Park
Holker St, Silverwater
NSW, 2128
AUS
Telephone: +61 2 9737 9422
Telephone: 1800 804 182
Fax: +61 2 9737 9414
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to the Criteria of
NOHSC, and the ADG Code.
POISONS SCHEDULE
None
RISK SAFETY
None under normal operating conditions. Do not breathe gas/fumes/vapour/spray.
Avoid contact with skin.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
propylene glycol mono- n- propyl ether 1569-01-3 1-5
propylene glycol 57-55-6 1-5
conditioners proprietary 0.5-2
water 7732-18-5 75-95
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MEGUIAR'S M34 - FINAL INSPECTION
Chemwatch Material Safety Data Sheet
Issue Date: 16-Nov-2006 CHEMWATCH 4912-6
NA317EC CD 2006/4 Page 2 of 10
Section 4 - FIRST AID MEASURES
SWALLOWED
- If swallowed do NOT induce vomiting.
- If vomiting occurs, lean patient forward or place on left side (head-down position, if
possible) to maintain open airway and prevent aspiration.
- Observe the patient carefully.
- Never give liquid to a person showing signs of being sleepy or with reduced awareness;
i.e. becoming unconscious.
- Give water to rinse out mouth, then provide liquid slowly and as much as casualty can
comfortably drink.
- Seek medical advice.
EYE
If this product comes in contact with the eyes:
- Wash out immediately with fresh running water.
- Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and
moving the eyelids by occasionally lifting the upper and lower lids.
- If pain persists or recurs seek medical attention.
- Removal of contact lenses after an eye injury should only be undertaken by skilled
personnel.
SKIN
If skin contact occurs:
- Immediately remove all contaminated clothing, including footwear
- Flush skin and hair with running water (and soap if available).
- Seek medical attention in event of irritation.
INHALED
- If fumes or combustion products are inhaled remove from contaminated area.
- Lay patient down. Keep warm and rested.
- Prostheses such as false teeth, which may block airway, should be removed, where
possible, prior to initiating first aid procedures.
- Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.
- Transport to hospital, or doctor.
NOTES TO PHYSICIAN
Treat symptomatically.
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
- Water spray or fog.
- Foam.
- Dry chemical powder.
- BCF (where regulations permit).
- Carbon dioxide.
FIRE FIGHTING
- Alert Fire Brigade and tell them location and nature of hazard.
- Wear breathing apparatus plus protective gloves for fire only.
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MEGUIAR'S M34 - FINAL INSPECTION
Chemwatch Material Safety Data Sheet
Issue Date: 16-Nov-2006 CHEMWATCH 4912-6
NA317EC CD 2006/4 Page 3 of 10
Section 5 - FIRE FIGHTING MEASURES
- Prevent, by any means available, spillage from entering drains or water courses.
- Use fire fighting procedures suitable for surrounding area.
- DO NOT approach containers suspected to be hot.
- Cool fire exposed containers with water spray from a protected location.
- If safe to do so, remove containers from path of fire.
- Equipment should be thoroughly decontaminated after use.
FIRE/EXPLOSION HAZARD
- The material is not readily combustible under normal conditions.
- However, it will break down under fire conditions and the organic component may burn.
- Not considered to be a significant fire risk.
- Heat may cause expansion or decomposition with violent rupture of containers.
- Decomposes on heating and may produce toxic fumes of carbon monoxide (CO).
- May emit acrid smoke.
Other combustion products include: carbon dioxide (CO2) and silicon dioxide (SiO2).
FIRE INCOMPATIBILITY
Avoid contamination with strong oxidising agents as ignition may result.
HAZCHEM: None
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
- Clean up all spills immediately.
- Avoid breathing vapours and contact with skin and eyes.
- Control personal contact by using protective equipment.
- Contain and absorb spill with sand, earth, inert material or vermiculite.
- Wipe up.
- Place in a suitable labelled container for waste disposal.
MAJOR SPILLS
Minor hazard.
- Clear area of personnel.
- Alert Fire Brigade and tell them location and nature of hazard.
- Control personal contact by using protective equipment as required.
- Prevent spillage from entering drains or water ways.
- Contain spill with sand, earth or vermiculite.
- Collect recoverable product into labelled containers for recycling.
- Absorb remaining product with sand, earth or vermiculite and place in appropriate
containers for disposal.
- Wash area and prevent runoff into drains or waterways.
- If contamination of drains or waterways occurs, advise emergency services.
EMERGENCY RESPONSE PLANNING GUIDELINES (ERPG)
The maximum airborne concentration below which it is believed that nearly all individuals could be exposed
for up to one hour WITHOUT experiencing or developing
life-threatening health effects is:
water 500 mg/m鲁
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MEGUIAR'S M34 - FINAL INSPECTION
Chemwatch Material Safety Data Sheet
Issue Date: 16-Nov-2006 CHEMWATCH 4912-6
NA317EC CD 2006/4 Page 4 of 10
Section 6 - ACCIDENTAL RELEASE MEASURES
irreversible or other serious effects or symptoms which could impair an individual's ability to take
protective action is:
water 500 mg/m鲁
other than mild, transient adverse effects without perceiving a clearly defined odour is:
water 500 mg/m鲁
The threshold concentration below which most people will experience no appreciable risk of health effects:
water 500 mg/m鲁
American Industrial Hygiene Association (AIHA)
Ingredients considered according to the following cutoffs
Very Toxic (T+) >= 0.1% Toxic (T) >= 3.0%
R50 >= 0.25% Corrosive (C) >= 5.0%
R51 >= 2.5%
else >= 10%
where percentage is percentage of ingredient found in the mixture
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
- Limit all unnecessary personal contact.
- Wear protective clothing when risk of exposure occurs.
- Use in a well-ventilated area.
- When handling DO NOT eat, drink or smoke.
- Always wash hands with soap and water after handling.
- Avoid physical damage to containers.
- Use good occupational work practice.
- Observe manufacturer's storing and handling recommendations.
SUITABLE CONTAINER
- Lined metal can, Lined metal pail/ can
- Plastic pail
- Polyliner drum
- Packing as recommended by manufacturer.
- Check all containers are clearly labelled and free from leaks.
STORAGE INCOMPATIBILITY
Avoid storage with oxidisers and acids.
STORAGE REQUIREMENTS
- Store in original containers.
- Keep containers securely sealed.
- Store in a cool, dry, well-ventilated area.
- Store away from incompatible materials and foodstuff containers.
- Protect containers against physical damage and check regularly for leaks.
- Observe manufacturer's storing and handling recommendations.
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MEGUIAR'S M34 - FINAL INSPECTION
Chemwatch Material Safety Data Sheet
Issue Date: 16-Nov-2006 CHEMWATCH 4912-6
NA317EC CD 2006/4 Page 5 of 10
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source Material TWA TWA STEL STEL Peak Peak TWA
ppm mg/m鲁 ppm mg/m鲁 ppm mg/m鲁 F/CC
_________________ __________________ ______ ______ ______ ______ ______ ______ ______
Australia Exposure propylene glycol 10
Standards (Propane- 1, 2-
diol: particulates
only)
Australia Exposure propylene glycol 150 474
Standards (Propane- 1, 2-
diol total:
(vapour &
particulates))
The following materials had no OELs on our records
鈥? propylene glycol mono-n-propyl ether: CAS:1569-01-3 CAS:30136-13-1
鈥? water: CAS:7732-18-5
MATERIAL DATA
None assigned. Refer to individual constituents.
INGREDIENT DATA
PROPYLENE GLYCOL MONO-N-PROPYL ETHER:
WATER:
No exposure limits set by NOHSC or ACGIH.
PROPYLENE GLYCOL MONO-N-PROPYL ETHER:
PROPYLENE GLYCOL:
Saturated vapour concentration @ 20 deg C.= 65.8 ppm, 204.6 mg/m3; i.e
higher concentrations can only occur as aerosols or at higher temperatures.
Odour Threshold: Practically odourless.
A small number of individuals show skin irritation or sensitisation from
repeated or prolonged exposure to propylene glycol. A workplace
environmental exposure limit (WEEL) has been established by AIHA and is
thought to be protective against systemic effects.
WATER:
PERSONAL PROTECTION
EYE
- Safety glasses with side shields; or as required,
- Chemical goggles.
- Contact lenses may pose a special hazard; soft contact lenses may absorb and
concentrate irritants. A written policy document, describing the wearing of lens or
restrictions on use, should be created for each workplace or task. This should include a
review of lens absorption and adsorption for the class of chemicals in use and an account
of injury experience. Medical and first-aid personnel should be trained in their removal
and suitable equipment should be readily available. In the event of chemical exposure,
begin eye irrigation immediately and remove contact lens as soon as practicable. Lens
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MEGUIAR'S M34 - FINAL INSPECTION
Chemwatch Material Safety Data Sheet
Issue Date: 16-Nov-2006 CHEMWATCH 4912-6
NA317EC CD 2006/4 Page 6 of 10
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
should be removed at the first signs of eye redness or irritation - lens should be
removed in a clean environment only after workers have washed hands thoroughly. [CDC
NIOSH Current Intelligence Bulletin 59].
HANDS/FEET
Wear protective gloves, eg. PVC.
OTHER
- Overalls.
- Eyewash unit.
RESPIRATOR
Selection of the Class and Type of respirator will depend upon the level of breathing
zone contaminant and the chemical nature of the contaminant. Protection Factors (defined
as the ratio of contaminant outside and inside the mask) may also be important.
Breathing Zone Level Maximum Protection Half- face Respirator Full- Face Respirator
ppm (volume) Factor
1000 10 A- AUS P -
1000 50 - A- AUS P
5000 50 Airline * -
5000 100 - A- 2 P
10000 100 - A- 3 P
100+ Airline**
* - Continuous Flow ** - Continuous-flow or positive pressure demand.
The local concentration of material, quantity and conditions of use determine the type of
personal protective equipment required.
For further information consult site specific
CHEMWATCH data (if available), or your
Occupational Health and Safety Advisor.
ENGINEERING CONTROLS
Use in a well-ventilated area.
General exhaust is adequate under normal operating conditions. If risk of overexposure
exists, wear SAA approved respirator. Correct fit is essential to obtain adequate
protection. Provide adequate ventilation in warehouse or closed storage areas.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Orange liquid with a pleasant odour, mixes with water.
PHYSICAL PROPERTIES
Liquid.
Mixes with water.
Molecular Weight: Not Applicable Boiling Range (掳C): 100
Melting Range (掳C): Not Available Specific Gravity (water=1): 1.00
Solubility in water (g/L): Miscible pH (as supplied): 8.00
pH (1% solution): Not Available Vapour Pressure (kPa): Not Available
Volatile Component (%vol): <0.8 (VOC) Evaporation Rate: <1
Relative Vapour Density (air=1): >1 Flash Point (掳C): >93 (PMCC)
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MEGUIAR'S M34 - FINAL INSPECTION
Chemwatch Material Safety Data Sheet
Issue Date: 16-Nov-2006 CHEMWATCH 4912-6
NA317EC CD 2006/4 Page 7 of 10
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Lower Explosive Limit (%): Not Available Upper Explosive Limit (%): Not Available
Autoignition Temp (掳C): Not Available Decomposition Temp (掳C): Not Available
State: Liquid Viscosity: Not Available
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
- Presence of incompatible materials.
- Product is considered stable.
- Hazardous polymerisation will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
Considered an unlikely route of entry in commercial/industrial environments.
The liquid is discomforting to the gastro-intestinal tract and may be harmful if
swallowed in large quantity.
Ingestion may result in nausea, abdominal irritation, pain and vomiting.
EYE
The liquid is discomforting to the eyes and is capable of causing a mild, temporary
redness of the conjunctiva (similar to wind-burn), temporary impairment of vision and/ or
other transient eye damage/ ulceration.
SKIN
The liquid is discomforting to the skin if exposure is prolonged and is capable of
causing skin reactions which may lead to dermatitis from repeated exposures over long
periods.
The material may accentuate any pre-existing skin condition.
INHALED
The vapour is discomforting to the upper respiratory tract.
Inhalation hazard is increased at higher temperatures.
Inhalation of vapour may aggravate a pre-existing respiratory condition.
CHRONIC HEALTH EFFECTS
Principal routes of exposure are by accidental skin and eye contact and by inhalation of
vapours especially at higher temperatures.
Prolonged or continuous skin contact with the liquid may cause defatting with drying,
cracking, irritation and dermatitis following.
As with any chemical product, contact with unprotected bare skin; inhalation of vapour,
mist or dust in work place atmosphere; or ingestion in any form, should be avoided by
observing good occupational work practice.
TOXICITY AND IRRITATION
Not available. Refer to individual constituents.
PROPYLENE GLYCOL MONO-N-PROPYL ETHER:
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MEGUIAR'S M34 - FINAL INSPECTION
Chemwatch Material Safety Data Sheet
Issue Date: 16-Nov-2006 CHEMWATCH 4912-6
NA317EC CD 2006/4 Page 8 of 10
Section 11 - TOXICOLOGICAL INFORMATION
TOXICITY IRRITATION
Oral (rat) LD50: 2504 mg/kg Skin (rabbit): 500 mg
Dermal (rabbit) LD50: 3550 mg/kg Eye (rabbit): 100 Moderate
Oral (rat) LD50: 2504 mg/kg [CARBIDE]
Dermal (rabbit) LD50: 2832 mg/kg
mixed isomers
PROPYLENE GLYCOL:
TOXICITY IRRITATION
Oral (rat) LD50: 20000 mg/kg Skin(human):500 mg/7days Mild
Dermal (rabbit) LD50: 20800 mg/kg Skin(human):104 mg/3d Intermit Moderate
Dermal (rabbit) LD50: 11890 mg/kg Eye (rabbit): 100 mg - Mild
Eye (rabbit): 500 mg/24h - Mild
The material may cause skin irritation after prolonged or repeated exposure and may
produce a contact dermatitis (nonallergic). This form of dermatitis is often
characterised by skin redness (erythema) and swelling the epidermis. Histologically there
may be intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of
the epidermis.
WATER:
No significant acute toxicological data identified in literature search.
Section 12 - ECOLOGICAL INFORMATION
No data for Meguiar's M34 - Final Inspection.
Refer to data for ingredients, which follows:
PROPYLENE GLYCOL MONO-N-PROPYL ETHER:
DO NOT discharge into sewer or waterways.
PROPYLENE GLYCOL:
log Kow (Prager 1995): - 0.92
log Kow (Sangster 1997): - 0.92
log Pow (Verschueren 1983): 4.7
BOD5: 0.955 (2.2
BOD20: 1.225
ThOD: 1.685
DO NOT discharge into sewer or waterways.
log Kow: -1.41- -0.3
Half-life (hr) air: 32
Henry's atm m鲁 /mol: 1.20E-08
BOD 5 if unstated: 0.995,2.2%
ThOD: 1.685
BCF: <1
Bioacculmulation: not sig
processes Abiotic: photoxid
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MEGUIAR'S M34 - FINAL INSPECTION
Chemwatch Material Safety Data Sheet
Issue Date: 16-Nov-2006 CHEMWATCH 4912-6
NA317EC CD 2006/4 Page 9 of 10
Section 13 - DISPOSAL CONSIDERATIONS
- Consult manufacturer for recycling options and recycle where possible .
- Consult State Land Waste Management Authority for disposal.
- Incinerate residue at an approved site.
- Recycle containers if possible, or dispose of in an authorised landfill.
Section 14 - TRANSPORTATION INFORMATION
HAZCHEM: None
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS:UN, IATA,
IMDG
Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE: None
REGULATIONS
propylene glycol mono-n-propyl ether (CAS: 1569-01-3) is found on the following
regulatory lists;
Australia Inventory of Chemical Substances (AICS)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule
6
OECD Representative List of High Production Volume (HPV) Chemicals
propylene glycol mono-n-propyl ether (CAS: 30136-13-1) is found on the following
regulatory lists;
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule
6
propylene glycol (CAS: 57-55-6) is found on the following regulatory lists;
Australia - Australia New Zealand Food Standards Code - Food Additives - Schedule 1
Permitted uses of food additives by food type
Australia - Australia New Zealand Food Standards Code - Food Additives - Schedule 2
Miscellaneous additives permitted in accordance with GMP in processed foods specified in
Schedule 1
Australia Exposure Standards
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
water (CAS: 7732-18-5) is found on the following regulatory lists;
Australia Inventory of Chemical Substances (AICS)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule
6
OECD Representative List of High Production Volume (HPV) Chemicals
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MEGUIAR'S M34 - FINAL INSPECTION
Chemwatch Material Safety Data Sheet
Issue Date: 16-Nov-2006 CHEMWATCH 4912-6
NA317EC CD 2006/4 Page 10 of 10
Section 16 - OTHER INFORMATION
INGREDIENTS WITH MULTIPLE CAS NUMBERS
Ingredient Name CAS
propylene glycol 1569- 01- 3, 30136- 13- 1
mono- n- propyl
ether
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written permission
from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 16-Nov-2006
Print Date: 11-Dec-2006
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