MATERIAL SAFETY DATA SHEET
In Case of Emergency, Call
Syngenta Crop Protection, Inc.
1-800-888-8372
Post Office Box 18300
Greensboro, NC 27419
1. PRODUCT IDENTIFICATION
BANNER GL
Product Name: Product No.: A8969C
EPA Signal Word: Warning
Active Ingredient(%): Propiconazole (41.8%) CAS No.: 60207-90-1
Chemical Name: 1-[[2-(2,4-dichlorophenyl)-4-propyl-1,3-dioxolan-2-yl]methyl]-1H-1,2,4-triazole
Chemical Class: Triazole Derivative Fungicide
EPA Registration Number(s): 100-736 Section(s) Revised: All sections
2. COMPOSITION/INFORMATION ON INGREDIENTS
ACGIH
OSHA NTP/IARC/OSHA
Other
TLV
PEL Carcinogen
Material
n-Butanol (not to exceed 41%) 100 ppm (300 mg/m鲁) 50 ppm (ceiling; skin) 50 ppm (150 mg/m鲁) No
TWA STEL TWA (skin)**
Propiconazole (41.8%) Not Established Not Established Not Established No
** recommended by NIOSH
Ingredients not precisely identified are proprietary or non-hazardous. Values are not product specifications.
3. HAZARDS IDENTIFICATION
Symptoms of Acute Exposure
Causes eye, skin and respiratory passage irritation. Exposure to high vapor levels may cause headache, dizziness,
numbness, nausea, incoordination, or other central nervous system effects.
Hazardous Decomposition Products
Can decompose at high temperatures forming toxic gases.
Physical Properties
Appearance: Dark blue to dark blue-green liquid (gel)
Odor: Strong solvent
Unusual Fire, Explosion and Reactivity Hazards
During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion.
4. FIRST AID MEASURES
Have the product container, label or Material Safety Data Sheet with you when calling Syngenta (800-888-8372), a poison
contol center or doctor, or going for treatment.
If swallowed: Call Syngenta (800-888-8372), a poison control center or doctor immediately for treatment
Ingestion:
advice. Have the person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so
after calling 800-888-8372 or by a poison control center or doctor. Do not give anything by mouth to an
unconscious person.
If in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses,
Eye Contact:
if present, after 5 minutes, then continue rinsing eye. Call Syngenta (800-888-8372), a poison control center
Product Name: Page: 1
BANNER GL
or doctor for treatment advice.
Skin Contact: If on skin or clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-
20 minutes. Call Syngenta (800-888-8372), a poison control center or doctor for treatment advice.
If inhaled: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial
Inhalation:
respiration, preferably mouth-to-mouth if possible. Call Syngenta (800-888-8372), a poison control center or
doctor for further treatment advice.
Notes to Physician
There is no specific antidote if this product is ingested.
Treat symptomatically.
Medical Condition Likely to be Aggravated by Exposure
None known.
5. FIRE FIGHTING MEASURES
Fire and Explosion
Flash Point (Test Method): 106掳F (Setaflash CC)
Flammable Limits (% in Air): Lower: % Not Applicable Upper: % Not Applicable
Autoignition Temperature: Not Available
Flammability: Combustible liquid
Unusual Fire, Explosion and Reactivity Hazards
During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion.
In Case of Fire
Use dry chemical, foam or CO2 extinguishing media. Wear full protective clothing and self-contained breathing
apparatus. Evacuate nonessential personnel from the area to prevent human exposure to fire, smoke, fumes or products of
combustion. Prevent use of contaminated buildings, area, and equipment until decontaminated. Water runoff can cause
environmental damage. If water is used to fight fire, dike and collect runoff.
6. ACCIDENTAL RELEASE MEASURES
In Case of Spill or Leak
Warning - flammable vapors may be present. Eliminate sources of ignition and ventilate spill area. Use non-sparking
clean-up equipment to prevent vapor ignition.
Control the spill at its source. Contain the spill to prevent it from spreading, contaminating soil, or entering sewage and
drainage systems or any body of water. Clean up spills immediately, observing precautions outlined in Section 8. If a
solid, sweep up material and place in a compatible disposal container. If a liquid, cover entire spill with absorbing
material and place into compatible disposal container. Scrub area with hard water detergent (e.g. commercial products
such as Tide, Joy, Spic and Span). Pick up wash liquid with additional absorbent and place into compatible disposal
container. Once all material is cleaned up and placed in a disposal container, seal container and arrange for disposition.
7. HANDLING AND STORAGE
Store the material in a well-ventilated, secure area out of reach of children and domestic animals. Do not store food, beverages
or tobacco products in the storage area. Prevent eating, drinking, tobacco use, and cosmetic application in areas where there is
a potential for exposure to the material. Wash thoroughly with soap and water after handling.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
THE FOLLOWING RECOMMENDATIONS FOR EXPOSURE CONTROLS/PERSONAL PROTECTION ARE INTENDED FOR
THE MANUFACTURE, FORMULATION, PACKAGING AND USE OF THIS PRODUCT.
FOR COMMERCIAL APPLICATIONS AND/OR ON-FARM APPLICATIONS CONSULT THE PRODUCT LABEL.
Prevent eating, drinking, tobacco usage and cosmetic application in areas where there is a potential for
Ingestion:
exposure to the material. Wash thoroughly with soap and water after handling.
Product Name: Page: 2
BANNER GL
Eye Contact: Where eye contact is likely, use chemical splash goggles. Facilities storing or utilizing this material should
be equipped with an eyewash facility and a safety shower.
Skin Contact: Where contact is likely, wear chemical-resistant (such as nitrile or butyl) gloves, coveralls, socks and
chemical-resistant footwear. For overhead exposure, wear chemical-resistant headgear.
Inhalation: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels
below exposure limits. A NIOSH-certified combination air-purifying respirator with an N, P or R 95 or HE
class filter and an organic vapor cartridge may be permissible under certain circumstances where airborne
concentrations are expected to exceed exposure limits. Protection provided by air-purifying respirators is
limited. Use a pressure demand atmosphere-supplying respirator if there is any potential for uncontrolled
release, exposure levels are not known, or under any other circumstances where air-purifying respirators
may not provide adequate protection.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Dark blue to dark blue-green liquid (gel)
Odor: Strong solvent
Melting Point: Not Applicable
Boiling Point: Not Available
Specific Gravity/Density: 1.03 g/ml @ 68掳F (20掳C)
4-7(1% solution in H2O)
pH:
Solubility in H2O
Propiconazole: 0.1g/l @ 68掳F (20掳C)
Vapor Pressure
Propiconazole: 9.8 x 10(-7) mmHg @ 68掳F (20掳C)
10. STABILITY AND REACTIVITY
Stability: Stable under normal use and storage conditions.
Hazardous Polymerization: Will not occur.
Conditions to Avoid: None known.
Materials to Avoid: None known.
Hazardous Decomposition Products: Can decompose at high temperatures forming toxic gases.
11. TOXICOLOGICAL INFORMATION
Acute Toxicity/Irritation Studies (Finished Product)
Ingestion: Slightly Toxic
Oral (LD50 Rat) : 2,750 mg/kg body weight
Dermal: Slightly Toxic
Dermal (LD50 Rabbit) : > 2,020 mg/kg body weight
Inhalation: Slightly Toxic
Inhalation (LC50 Rat) : > 2.5 mg/l air - 4 hours
Eye Contact: Moderately Irritating (Rabbit)
Skin Contact: Moderately Irritating (Rabbit)
Skin Sensitization: Not a Sensitizer (Guinea Pig)
Reproductive/Developmental Effects
Propiconazole: None observed.
Chronic/Subchronic Toxicity Studies
None observed.
Propiconazole:
Carcinogenicity
Propiconazole: Increased incidence of liver tumors at extremely high doses (male mice).
Product Name: Page: 3
BANNER GL
Other Toxicity Information
None.
Toxicity of Other Components
n-Butanol (not to exceed 41%)
Prolonged exposure to n-Butanol may result in drying and cracking of the skin from a defatting action. There is
evidence that long-term repeated exposure to vapor concentrations greater than 50 ppm may result in some loss of
hearing. N-Butanol vapor can cause specific injury to the cornea. Irritation of the skin and respiratory tract may
occur with brief exposures. Causes severe irritation to the eyes with lacrimation. Inhalation of n-Butanol may
result in loss of consciousness, headache, dizziness, nausea, drowsiness and vomiting.
Target Organs
Active Ingredients
Propiconazole: Liver
Inert Ingredients
n-Butanol : Respiratory tract, inner ear, eye, skin
12. ECOLOGICAL INFORMATION
Summary of Effects
Propiconazole:
Low toxicity to wildlife. Highly toxic to fish.
Eco-Acute Toxicity
Propiconazole: Rainbow Trout 96-hour LC50 5.2 mg/L
Bluegill Sunfish 96-hour LC50 >100 ppm
Daphnia magna 48-hour LC50 3.2 mg/L
Bobwhite Oral LD50 2,825 mg/kg
Mallard Oral LD50 >2,510 mg/kg
Bobwhite 8-day Dietary LC50 >5,620 ppm
Mallard 8-day Dietary LC50 >5,620 ppm
Eco-Chronic Toxicity
Propiconazole: Fish (Fathead minnow) Early Life Stage MATC >0.43 and <0.97 mg/L
Invertebrate (Daphnia Magna) Life Cycle MATC >0.31 and <0.69 mg/L
Mallard Reproduction NOEC 300 ppm
Bobwhite Reproduction NOEC 1,000 ppm
Environmental Fate
Propiconazole:
No data available for the formulation. The information presented here is for the active ingredient, propiconazole. A
thorough review of environmental information is not possible in this document.
Stable in sterile water, in the dark at pH 5, 7 and 9. Degradation in the light varies from slow in water (t1/2 = 249 d
@ pH 7) to variable in soil (t1/2 ~ 53 d to stable). Degradation in soil, in the dark is moderate under aerobic (t1/2 ~
43 to 70 d) and aquatic (t1/2 ~ 15-113 d) conditions. Stable under anaerobic aquatic conditions (t1/2 ~ >1 yr).
Medium to low mobility in various soils (Koc 382 to 1134). Some bioaccumulation (BCF = 203X, whole fish).
13. DISPOSAL CONSIDERATIONS
Disposal
Do not reuse product containers. Dispose of product containers, waste containers, and residues according to local, state,
and federal health and environmental regulations.
Characteristic Waste: Ignitable D001
Listed Waste: Not Applicable
14. TRANSPORT INFORMATION
Product Name: Page: 4
BANNER GL
DOT Classification
Flammable Liquid, n.o.s. (contains n-butanol), 3, UN1993, PGIII, LTD QTY
B/L Freight Classification
Fungicides, NOI, O/T poison
Comments
None
15. REGULATORY INFORMATION
EPCRA SARA Title III Classification
Acute Health Hazard
Section 311/312 Hazard Classes:
Chronic Health Hazard
Fire Hazard
Section 313 Toxic Chemicals: Propiconazole (41.8%) (CAS No. 60207-90-1)
n-Butanol (not to exceed 41%) (CAS No. 71-36-3)
California Proposition 65
Not Applicable
CERCLA/SARA 302 Reportable Quantity (RQ)
Report product spills > 1,400 gal. (based on n-butanol [RQ = 5,000 lbs.] content in the formulation)
RCRA Hazardous Waste Classification (40 CFR 261)
Ignitable D001
TSCA Status
Exempt from TSCA, subject to FIFRA
16. OTHER INFORMATION
HMIS Hazard Ratings 0 Minimal
NFPA Hazard Ratings
1 Slight
Health: 2 Health: 2
2 Moderate
Flammability: 2 Flammability: 2
3 Serious
Instability: 0 Reactivity: 0
4 Extreme
For non-emergency questions about this product call:
1-800-334-9481
Original Issued Date: 04/07/1992
Revision Date: 10/02/2002 Replaces: 10/26/2001
The information and recommendations contained herein are based upon data believed to be correct.
However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the
information contained herein.
RSVP# : SCP-955-736A-00104K
End of MSDS
Product Name: Page: 5
BANNER GL
|