MATERIAL SAFETY DATA SHEET MSDS 002
Page 1
ITEM NUMBER: C-002
VERSION 4 EFFECTIVE DATE: 03/08/04 SUPERCEDES: 11/03/00 PREPARED BY: Regulatory Compliance
Section(s) Revised: All
IDENTITY (As Used On Label and List): Claire Multi-Use Insecticide Fogger
Emergency Medical Telephone Number 1-800/228-5635 (24 HRS) Outside the U.S.A. Call 651/632-9275
PRODUCT HAZARD RATINGS (HMIS): - Health = 1, Fire = 2, Reactivity = 1, Protective Equipment = B
(Rating Legend: - 4 = Extreme, 3 = Serious, 2 = Moderate, 1 = Slight, 0 = Minimal, * = Chronic Hazard)
SECTION I
CLAIRE MANUFACTURING TELEPHONE NUMBER FOR INFORMATION: 1-800-252-4731
500 VISTA AVE.
ADDISON, IL 60101 DATE PRINTED: 3/8/04
NAME OF PREPARER: Ron Cepa
SECTION II - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION
Chemical Names CAS # SARA ACGIH OSHA % By Wt.
SEC 313 TLV-TWA/STEL PEL-TWA/STEL
Deodorized kerosene 64742-47-8 No 100 ppm*/NE NE/NE 1-10
Liquefied petroleum gas mixture 68476-86-8 No See Below Ingredient 30-40
Data
Propane 74-98-6 No 2500 ppm/NE 1000 ppm/NE 48-55
n-Butan 106-97-8 No 800 ppm/NE NE/NE 45-49
Isobutane 75-28-5 No NE/NE NE/NE 0.5/2.0
Balance of ingredients are non-hazardous or below reportable levels.
* Supplier recommendation
SECTION III - PHYSICAL CHARACTERISTICS
Boiling Point: NA Can Pressure (psig): 152 @ 130F / 71 @ 70F Specific Gravity 鈥? calculated (H20=1):
0.7583
pH: 5.93 Solubility/Water: Slight Vapor Density (AIR=1): ND Evaporation Rate (Ether=1): ND
Appearance and Odor: Off-white aerosol spray with characteristic odor.
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
Aerosol Flammability: Product does not need to be labeled as flammable as described in 40 CFR 156.10. Product
label is required to state 鈥淗ighly Flammable Ingredient鈥? per PR Notice 98-6.
Flashpoint: <0F (Propellant); 152F (Concentrate)
Flammable Limits - % Volume In Air (Propellant): LEL: 1.9 UEL: 9.5
Extinguishing Media: Carbon dioxide, water spray, foam, or dry chemical.
Special Fire Fighting Procedures: Containers should be cooled with water to prevent vapor pressure build up.
Use equipment or shielding, as required, to protect personnel from bursting, rupturing or venting containers.
Unusual Fire and Explosion Hazards: Fire fighters and others who may be exposed to the products of combustion
should be equipped with NIOSH-approved positive pressure self-contained breathing apparatus (SCBA) and full
protection clothing. At elevated temperatures (over 54C-130F) containers exposed to direct flame or heat contact
should be cooled with water to prevent weakening of container structure.
SECTION V - REACTIVITY DATA
Stability: Stable Hazardous Polymerization: NA
Incompatibility (Materials to Avoid): Oxidizing agents.
Hazardous Decomposition Products: Carbon monoxide, hydrocarbon vapors.
Conditions to Avoid: Keep away from heat, sparks, and flames. Dropping of containers may cause bursting.
SECTION VI - HEALTH HAZARD DATA
Route(s) of Entry - Inhalation: Y Eyes: Y Skin: Y Ingestion: N
HAZARDS IDENTIFICATION: EYES: May cause mild irritation. SKIN: Prolonged or repeated contact may dry or defat
the skin and lead to irritation (i.e. dermatitis). INHALATION: High concentration or prolonged exposure can be
irritating to eyes, nose and respiratory tract. Under misuse or intentional misuse, product may cause
asphyxiation. INGESTION: Exposure by ingestion is unlikely since an aerosol, but if ingested, the following may
occur: Irritating to the mouth, throat and stomach. May cause nausea, vomiting, pain, and stomach upset (e.g.,
diarrhea). Possible aspiration hazard 鈥? may cause inflammation of the lungs.
AGGRAVATED MEDICAL CONDITIONS: None Known.
CHRONIC EFFECTS/TARGET ORGANS: None known.
MATERIAL SAFETY DATA SHEET MSDS 002
Page 2
EMERGENCY AND FIRST AID PROCEDURES: EYES: Immediately flush with plenty of water for at least 15 minutes. Get
prompt medical attention. SKIN: Immediately flush with plenty of water for at least 15 minutes. Get prompt
medical attention. INHALATION: Remove to fresh air. If symptoms develop, seek immediate medical attention. If
not breathing, give artificial respiration. INGESTION: In the unlikely event of swallowing: Get immediate
medical attention. Do NOT induce vomiting unless directed by medical personnel. Never give anything by mouth to
an unconscious person.
CARCINOGENICITY:
No regulated ingredients.
TOXICITY INFORMATION:
Product:
LD50 Oral (Rat): >5000 mg/kg
LD50 Dermal (Rabbit): >2000 mg/kg
LC50 Inhalation (Rat): >3.03 mg/L @4 hr.
SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE
Releases or Spills: Remove all sources of ignition and ventilate area. Soak up spill with an inert absorbent
and place into a designated disposal container. Consult local regulatory agency for proper disposition of
material. Waste Disposal Method: Do not puncture or incinerate containers. When contents are depleted continue
to depress button until all gas is expelled. Dispose of container in accordance with local, state, and federal
regulations. Disposal regulations may be different for each state and/or locality.
Handling And Storing: Avoid breathing vapor. Keep away from heat, sparks and flame. Use with adequate
ventilation. Do not puncture or incinerate containers. Do not expose to direct sunlight or store at
temperatures above 120F (48.9C). Store as Level 1 Aerosol (NFPA 30B).
Other Precautions: Please read and follow the directions on the product label; they are your best guide to
using this product in the most effective way, and give the necessary safety precautions to protect your health.
SECTION VIII - EMPLOYEE PROTECTION
Respiratory Protection (Type): None required if good ventilation is maintained. If exposure exceeds
occupational exposure limits (Sec. II), use a NIOSH approved respirator to prevent overexposure.
Ventilation: Mechanical ventilation should be used when handling this product in enclosed or tight spaces.
Local exhaust ventilation may be necessary.
Protective Gloves: Chemical resistant gloves are recommended 鈥? consult glove manufacturer to determine the
proper type for a specific operation.
Eye Protection: Safety glasses are recommended.
Other Protective Clothing or Equipment: Wearing of impervious clothing to prevent skin contact may be worn.
Wearing of impervious clothing to prevent skin contact is optional.
Work/Hygienic Practices: Ensure strict sanitary conditions are conformed to when working around chemicals.
Protective clothing and equipment should be in accordance with 29 CFR 1910.132 and CFR 1910.133.
SECTION IX-OTHER REGULATORY CONTROLS
FEDERAL:
Toxic Substance Control Act (TSCA): Exempt.
STATE RIGHT-TO-KNOW:
Pennsylvania/New Jersey Right-To-Know (Chemical and CAS No.):
Deionized Water 7732-18-5
Deodorized kerosene 64742-47-8
Sodium Benzoate 532-32-1
N-Octyl Bicycloheptene Dicarboximide 113-48-4
Liquefied petroleum gas mixture (68476-86-8)
Propane 74-98-6
n-Butane 106-97-8
Isobutane 75-28-5
CANADA:
Domestic Substances List: Ingredients of this product are not listed: Esfenvalerate
Non-Domestic Substances list: Ingredients of this product are not listed: Esfenvalerate
SECTION X-TRANSPORTATION (D.O.T. CLASSIFICATION)
Shipping Name: Consumer Commodity Hazard Class: ORM-D
NG - Negligible NA-- Not Applicable NE-- Not Established UN-- Unavailable ND-- Not Determined
While the information set forth herein is believed to be accurate as of the date hereof, the Company makes no warranty or guarantee,
express or implied, and disclaims all liability arising out of the use of this information.
EFFECTIVE DATE: 03/08/04 SUPERCEDES: 11/03/00 PREPARED BY: Regulatory Compliance
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