**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 10025-69-1 |Tin (II) Chloride Dihydrate | >98 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 22 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Causes burns.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns. Causes redness and pain. May be harmful if
absorbed through the skin.
Ingestion:
Harmful if swallowed. Causes gastrointestinal tract burns. Exposure
may cause anemia and other blood abnormalities. May cause headache,
nausea, fatigue, and dizziness. Inorganic tin salts may cause
systemic effects on the central nervous system, heart and liver.
Inhalation:
Irritation may lead to chemical pneumonitis and pulmonary edema.
Causes chemical burns to the respiratory tract. May cause effects
similar to those described for ingestion. May be harmful if inhaled.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. May cause
liver and kidney damage. Adverse reproductive effects have been
reported in animals. Chronic exposure may cause effects similar to
those of acute exposure.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid. Do
NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Minimize dust generation and accumulation. Keep
container tightly closed. Do not get on skin or in eyes. Do not
ingest or inhale. Use with adequate ventilation. Discard
contaminated shoes.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances. Corrosives
area. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 10025-69-1:
United Kingdom, WEL - TWA: (listed as tin inorganic compounds): 2
mg/m3 TWA (except SnH4, as Sn)
United Kingdom, WEL - STEL: (listed as tin inorganic compounds):
mg/m3 STEL (except SnH4, as Sn)
United States OSHA: 2 mg/m3 TWA (as Sn) (listed under Tin inorga
compounds).
Belgium - TWA: (listed as tin inorganic compounds): 2 mg/m3 VLE (
Sn)
Malaysia: (listed as tin inorganic compounds): 2 mg/m3 TWA (as Sn
except tin hydride)
Netherlands: (listed as tin inorganic compounds): 2 mg/m3 MAC (as
Spain: (listed as tin inorganic compounds): 2 mg/m3 VLA-ED (as Sn
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: colorless to white
Odor: odorless
pH: Not available.
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: decomposes
Freezing/Melting Point: 100 deg F
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: decomposes in water
Specific Gravity/Density: 2.7
Molecular Formula: SnCl2.2H2O
Molecular Weight: 225.6228
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. May decompose on
exposure to moist air or water. Moisture sensitive.
Conditions to Avoid:
Moisture, heating to decomposition.
Incompatibilities with Other Materials:
Metals, strong oxidizing agents, strong reducing agents, strong
acids, strong bases, bromine trifluoride, ethylene oxide, potassium,
hydrogen peroxide, sodium, moisture, calcium carbide, hydrazine
hydrate, organic nitrates.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, tin/tin oxides.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 10025-69-1: XP8850000
LD50/LC50:
CAS# 10025-69-1: Oral, rat: LD50 = 2274.6 mg/kg.
Oral, rat: LD50 = 700
Carcinogenicity:
Tin (II) Chloride Dihydrate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3260
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3260
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3260
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 22 Harmful if swallowed.
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 10025-69-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 10025-69-1 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 10025-69-1 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/25/1999 Revision #5 Date: 8/30/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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