**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 18282-10-5 |Tin Oxide | 99 | 242-159-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully
investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological
properties of this substance have not been fully investigated.
Ingested inorganic tin exhibits only moderate toxicity due to poor
absorption and rapid tissue turnover. Ingestion of large amounts may
cause gastrointestinal irritation, nausea, cramps, vomiting and
diarrhea. May interfere with various enzyme systems. Inorganic tin
salts may cause systemic effects on the central nervous system, heart
and liver.
Inhalation:
May cause respiratory tract irritation. Inhalation of fumes may
cause metal fume fever, which is characterized by flu-like symptoms
with metallic taste, fever, chills, cough, weakness, chest pain,
muscle pain and increased white blood cell count. The toxicological
properties of this substance have not been fully investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Get medical aid. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use
extinguishing media appropriate to the surrounding fire. Substance is
noncombustible.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire. Use water spray, dry chemical, carbon
dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid ingestion and
inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 18282-10-5:
United Kingdom, WEL - TWA: (listed as tin inorganic compounds): 2
mg/m3 TWA (except SnH4, as Sn)
United Kingdom, WEL - STEL: (listed as tin inorganic compounds):
mg/m3 STEL (except SnH4, as Sn)
United States OSHA: 2 mg/m3 TWA (as Sn) (listed under Tin inorga
compounds).
Belgium - TWA: (listed as tin inorganic compounds): 2 mg/m3 VLE (
Sn)
Malaysia: (listed as tin inorganic compounds): 2 mg/m3 TWA (as Sn
except tin hydride)
Netherlands: 2 mg/m3 MAC
Spain: (listed as tin inorganic compounds): 2 mg/m3 VLA-ED (as Sn
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white to gray
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 3272 deg F
Freezing/Melting Point: 2061 deg F
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Insoluble in water.
Specific Gravity/Density: 6.95 (water=1)
Molecular Formula: SnO2
Molecular Weight: 150.6888
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, incompatible materials, dust generation.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, tin/tin oxides.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 18282-10-5: XQ4000000
LD50/LC50:
CAS# 18282-10-5: Oral, mouse: LD50 = >20 gm/kg; Oral, rat: LD50 =
>20 gm/kg.
Carcinogenicity:
Tin Oxide -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 18282-10-5: No information available.
Canada
CAS# 18282-10-5 is listed on Canada's DSL List.
CAS# 18282-10-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 18282-10-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/21/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Tin(IV) Chloride Anhydrous
| 7646-78-8 |
|
Tin(IV) Chloride Pentahydrate
| 7646-78-8 |
|
2,5-Dimethyl-3-Pyrroline, 75% Remainder 2,5-Dimethyl-1-Pyrroline
| 59480-92-1 |
|
Ruthenium on 1/8-inch alumina pellets (0.5% ru)
| |
|
6-Fluorotryptamine hydrochloride, 99%
| 55206-24-1 |
|
3-Phenyl-1-propylamine, 98%
| 2038-57-5 |
|
Tin (IV) Oxide
| 18282-10-5 |
|
Isethionic Acid Potassium Salt, 98% (Titr.)
| 1561-99-5 |
|
Tin (II) Chloride Anhydrous
| 7772-99-8 |
|
Tubocurarine Chloride, 98.0 - 102.0%
| 6989-98-6 |
|
Tin (II) Chloride Dihydrate
| 10025-69-1 |
|
Rhodium on srtio3 , 0.5 wt% rh
| |
|
Cochineal, extract powder
| |
|
Dimethyl trans-1,2-cyclopropanedicarboxylate, 99+%
| 826-35-7 |
|
3-Aminocrotonamide, Tech. 85%
| 15846-25-0 |
|
Normal-butyl sulfoxide, tech., 93%
| 2168-93-6 |
|
Tin (II) Oxide
| 21651-19-4 |
|
Stearic acid
| 57-11-4 |
|
Starch, Soluble and Hydrolysed
| 9005-25-8 |
|
2-Chloro-3,5-Dinitropyridine, 99%
| 2578-45-2 |
|
Phosphorous acid, 98%
| 10294-56-1 |
|
Poly(Methyl Methacrylate) (Pract)
| 9011-14-7 |
|
Octadecyltrichlorosilane, 95%
| 112-04-9 |
|
Ethyl Propionate, 97+% (gc)
| 105-37-3 |
|
4,4'-Diaminooctafluorobiphenyl, 98%
| 1038-66-0 |
|
Poly(4-methyl-1-pentene), high molecular weight
| 25068-26-2 |
|
Exo-2-Bromo-5-Oxo-Bicyclo(2.2.1)Heptane-Syn-7-Carboxylic Acid, 99%
| 63377-25-3 |
|
3-Methylsulphonylaniline Hydrochloride , 95+%
| 80213-28-1 |
|
Aminoreductone precursor
| |
|
Propyl Red, 98% (UV-Vis)
| 2641-01-2 |
|
5-Chloro-2-Mercaptobenzothiazole, 98%
| 5331-91-9 |
|
Strontium Chloride Hexahydrate
| 10025-70-4 |
|
3-Hydroxypyridine, 98%
| 109-00-2 |
|
N-Methyl-1,3-propanediamine, 99%
| 6291-84-5 |
|
Perfluoro-compound FC-72
| 355-42-0 |
|
2,4,4-Trimethyl-1-pentene (pract), 95% (gc)
| 107-39-1 |
|
2,6-Dimethoxypyridine, 99%
| 6231-18-1 |
|
Strontium nitrate
| 10042-76-9 |
|
2-Fluoroanisole, 98%
| 321-28-8 |
|
Cholic acid, 99+% (titr.)
| 81-25-4 |
|
1-Amino-1-cyclopentanecarboxylic acid, 97%
| 52-52-8 |
|
Dipentylamine, 99%
| 2050-92-2 |
|
Trioctylpropylammonium bromide, 99% (titr.)
| 24298-17-7 |
|
Styrene monomer, inhibited
| 100-42-5 |
|
p-Nitrocinnamic acid, 97%,predominantly trans
| 619-89-6 |
|
3,4-Dimethoxyphenethyl Alcohol
| 7417-21-2 |
|
Succinic acid
| 110-15-6 |
|
D(+)-Sucrose
| 57-50-1 |
|
2-Chlorothiophene, 98+%
| 96-43-5 |
|
Terephthalic-D4 Acid, 98 Atom % D
| 60088-54-2 |
|
|