**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 96-43-5 |2-Chlorothiophene | >98 | 202-505-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 10 23/24/25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Toxic by inhalation, in contact with skin and if
swallowed.Stench.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Harmful if absorbed through the skin.
Allergic reactions have been reported.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
May cause headache. May cause nausea and vomiting.
Inhalation:
Harmful if inhaled. May cause respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Flammable
liquid and vapor.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use foam, dry
chemical, or carbon dioxide. Water may be ineffective.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Ground and bond containers when transferring
material. Use spark-proof tools and explosion proof equipment. Avoid
contact with eyes, skin, and clothing. Use only with adequate
ventilation. Keep away from heat, sparks and flame. Avoid breathing
vapor.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container.
Refrigerator/flammables.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low. Ventilation fans
and other electrical service must be non-sparking and have an
explosion-proof design.
Exposure Limits
CAS# 96-43-5:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless to light straw
Odor: Stench.
pH: Not available.
Vapor Pressure: 23.8 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 127-129 deg C @ 760 mm Hg
Freezing/Melting Point: -71.9 deg C
Autoignition Temperature: Not available.
Flash Point: 22 deg C ( 71.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density: 1.280 g/cm3
Molecular Formula: C4H3ClS
Molecular Weight: 118.58
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, confined spaces.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, oxides of sulfur,
carbon dioxide, hydrogen sulfide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 96-43-5 unlisted.
LD50/LC50:
Not available.
Oral, rat: LD50 = 129-516 mg/kg.
Carcinogenicity:
2-Chlorothiophene -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S.*
Hazard Class: 3 (6.1)
UN Number: 1992
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S.
Hazard Class: 3.2 (6.1)
UN Number: 1992
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S.
Hazard Class: 3 (6.1)
UN Number: 1992
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 10 Flammable.
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 28B After contact with skin, wash immediately with
plenty of water and soap.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 38 In case of insufficient ventilation, wear
suitable respiratory equipment.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 96-43-5: No information available.
Canada
CAS# 96-43-5 is listed on Canada's DSL List.
CAS# 96-43-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 96-43-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/22/1998 Revision #3 Date: 11/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Tin(IV) Chloride Anhydrous
| 7646-78-8 |
|
Tin(IV) Chloride Pentahydrate
| 7646-78-8 |
|
2,5-Dimethyl-3-Pyrroline, 75% Remainder 2,5-Dimethyl-1-Pyrroline
| 59480-92-1 |
|
Ruthenium on 1/8-inch alumina pellets (0.5% ru)
| |
|
6-Fluorotryptamine hydrochloride, 99%
| 55206-24-1 |
|
3-Phenyl-1-propylamine, 98%
| 2038-57-5 |
|
Tin (IV) Oxide
| 18282-10-5 |
|
Isethionic Acid Potassium Salt, 98% (Titr.)
| 1561-99-5 |
|
Tin (II) Chloride Anhydrous
| 7772-99-8 |
|
Tubocurarine Chloride, 98.0 - 102.0%
| 6989-98-6 |
|
Tin (II) Chloride Dihydrate
| 10025-69-1 |
|
Rhodium on srtio3 , 0.5 wt% rh
| |
|
Cochineal, extract powder
| |
|
Dimethyl trans-1,2-cyclopropanedicarboxylate, 99+%
| 826-35-7 |
|
3-Aminocrotonamide, Tech. 85%
| 15846-25-0 |
|
Normal-butyl sulfoxide, tech., 93%
| 2168-93-6 |
|
Tin (II) Oxide
| 21651-19-4 |
|
Stearic acid
| 57-11-4 |
|
Starch, Soluble and Hydrolysed
| 9005-25-8 |
|
2-Chloro-3,5-Dinitropyridine, 99%
| 2578-45-2 |
|
Phosphorous acid, 98%
| 10294-56-1 |
|
Poly(Methyl Methacrylate) (Pract)
| 9011-14-7 |
|
Octadecyltrichlorosilane, 95%
| 112-04-9 |
|
Ethyl Propionate, 97+% (gc)
| 105-37-3 |
|
4,4'-Diaminooctafluorobiphenyl, 98%
| 1038-66-0 |
|
Poly(4-methyl-1-pentene), high molecular weight
| 25068-26-2 |
|
Exo-2-Bromo-5-Oxo-Bicyclo(2.2.1)Heptane-Syn-7-Carboxylic Acid, 99%
| 63377-25-3 |
|
3-Methylsulphonylaniline Hydrochloride , 95+%
| 80213-28-1 |
|
Aminoreductone precursor
| |
|
Propyl Red, 98% (UV-Vis)
| 2641-01-2 |
|
5-Chloro-2-Mercaptobenzothiazole, 98%
| 5331-91-9 |
|
Strontium Chloride Hexahydrate
| 10025-70-4 |
|
3-Hydroxypyridine, 98%
| 109-00-2 |
|
N-Methyl-1,3-propanediamine, 99%
| 6291-84-5 |
|
Perfluoro-compound FC-72
| 355-42-0 |
|
2,4,4-Trimethyl-1-pentene (pract), 95% (gc)
| 107-39-1 |
|
2,6-Dimethoxypyridine, 99%
| 6231-18-1 |
|
Strontium nitrate
| 10042-76-9 |
|
2-Fluoroanisole, 98%
| 321-28-8 |
|
Cholic acid, 99+% (titr.)
| 81-25-4 |
|
1-Amino-1-cyclopentanecarboxylic acid, 97%
| 52-52-8 |
|
Dipentylamine, 99%
| 2050-92-2 |
|
Trioctylpropylammonium bromide, 99% (titr.)
| 24298-17-7 |
|
Styrene monomer, inhibited
| 100-42-5 |
|
p-Nitrocinnamic acid, 97%,predominantly trans
| 619-89-6 |
|
3,4-Dimethoxyphenethyl Alcohol
| 7417-21-2 |
|
Succinic acid
| 110-15-6 |
|
D(+)-Sucrose
| 57-50-1 |
|
2-Chlorothiophene, 98+%
| 96-43-5 |
|
Terephthalic-D4 Acid, 98 Atom % D
| 60088-54-2 |
|
|