**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7646-78-8 |Stannic chloride | 100 | 231-588-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34 52/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns. Harmful to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns.
Skin:
May cause severe skin irritation with possible burns, especially if
skin is wet or moist.
Ingestion:
May cause severe digestive tract irritation with abdominal pain,
nausea, vomiting and diarrhea. May cause corrosion and permanent
tissue destruction of the esophagus and digestive tract.
Inhalation:
Irritation may lead to chemical pneumonitis and pulmonary edema. May
cause severe irritation of the upper respiratory tract with pain,
burns, and inflammation.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Chronic
exposure to tin oxide dusts and fumes may result in stannosis (benign
pneumoconiosis).
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give
anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Use water spray to keep fire-exposed containers
cool. Not combustible, but if involved in a fire, decomposes to
produce hydrogen chloride.
Extinguishing Media:
Do NOT use water directly on fire. Use extinguishing media most
appropriate for the surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation. Use water spray to cool and disperse vapors and protect
personnel.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Do not get in eyes, on skin, or on clothing. Do
not ingest or inhale. Use only with adequate ventilation.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Keep away from metals. Corrosives area. Storage under a
nitrogen blanket has been recommended. Do not get water inside
containers.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 7646-78-8:
United Kingdom, WEL - TWA: (listed as tin inorganic compounds): 2
mg/m3 TWA (except SnH4, as Sn)
United Kingdom, WEL - STEL: (listed as tin inorganic compounds):
mg/m3 STEL (except SnH4, as Sn)
United States OSHA: 2 mg/m3 TWA (as Sn) (listed under Tin inorga
compounds).
Belgium - TWA: (listed as tin inorganic compounds): 2 mg/m3 VLE (
Sn)
Malaysia: (listed as tin inorganic compounds): 2 mg/m3 TWA (as Sn
except tin hydride)
Netherlands: (listed as tin inorganic compounds): 2 mg/m3 MAC (as
Spain: (listed as tin inorganic compounds): 2 mg/m3 VLA-ED (as Sn
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: slightly yellow
Odor: Strong acrid odor.
pH: Not available.
Vapor Pressure: 20 mm Hg @ 22 deg C
Viscosity: Not available.
Boiling Point: 114 deg C @ 760 mm Hg
Freezing/Melting Point: -33 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Soluble in water with much heat
Specific Gravity/Density: 2.23 (water=1)
Molecular Formula: Cl4Sn
Molecular Weight: 260.50
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. May decompose on
exposure to moist air or water. Liberates heat and hydrochloric acid
on contact with water. Fumes in moist air.
Conditions to Avoid:
High temperatures, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong bases, alcohols, amines, ethylene oxide, potassium, sodium,
alkyl nitrates, turpentine.
Hazardous Decomposition Products:
Hydrogen chloride, tin/tin oxides.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7646-78-8: XP8750000
LD50/LC50:
CAS# 7646-78-8: Inhalation, rat: LC50 = 2300 mg/m3/10M.
Carcinogenicity:
Stannic chloride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: STANNIC CHLORIDE, ANHYDROUS
Hazard Class: 8
UN Number: 1827
Packing Group: II
IMO
Shipping Name: STANNIC CHLORIDE, ANHYDROUS
Hazard Class: 8
UN Number: 1827
Packing Group: II
RID/ADR
Shipping Name: STANNIC CHLORIDE, ANHYDROUS
Hazard Class: 8
UN Number: 1827
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
R 52/53 Harmful to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 7/8 Keep container tightly closed and dry.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 7646-78-8: 1
Canada
CAS# 7646-78-8 is listed on Canada's DSL List.
CAS# 7646-78-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7646-78-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/02/1998 Revision #3 Date: 11/11/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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