**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 6291-84-5 |N-Methyl-1,3-propanediamine | 99 | 228-544-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN C
Risk Phrases: 10 20/21/22 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful by inhalation, in contact with skin and if
swallowed. Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. Contact with eyes may cause severe irritation,
and possible eye burns. May cause chemical conjunctivitis and
corneal damage.
Skin:
Causes skin burns. May cause severe irritation and possible burns.
May cause skin rash (in milder cases), and cold and clammy skin with
cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. May cause systemic effects.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema. Causes
chemical burns to the respiratory tract. Aspiration may lead to
pulmonary edema. May cause systemic effects.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Wash clothing before
reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately. Do NOT induce
vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls
of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Not available.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Keep container tightly closed. Do not get on skin or in eyes. Do not
ingest or inhale. Use with adequate ventilation. Discard contaminated
shoes.
Storage:
Keep container closed when not in use. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low. Use adequate
general or local exhaust ventilation to keep airborne concentrations
below the permissible exposure limits.
Exposure Limits
CAS# 6291-84-5:
Personal Protective Equipment
Eyes:
Wear safety glasses and chemical goggles if splashing
is possible. Wear appropriate protective eyeglasses or
chemical safety goggles as described by OSHA's eye and
face protection regulations in 29 CFR 1910.133 or
European Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure. Wear appropriate protective
gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use. Wear a NIOSH/MSHA
or European Standard EN 149 approved full-facepiece
airline respirator in the positive pressure mode with
emergency escape provisions.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: clear slightly yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 139.0 - 141.0 deg C @ 760.00m
Freezing/Melting Point: 0 deg C
Autoignition Temperature: Not available.
Flash Point: 35 deg C ( 95.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: .8440g/cm3
Molecular Formula: C4H12N2
Molecular Weight: 88.15
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Not available.
Incompatibilities with Other Materials:
Not available.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 6291-84-5: TX8242500
LD50/LC50:
CAS# 6291-84-5: Inhalation, rat: LC50 = >189 mg/m3/6H; Oral, mouse:
LD50 = 282 mg/kg; Oral, rat: LD50 = 951 mg/kg.
Not available.
Carcinogenicity:
N-Methyl-1,3-propanediamine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S.*
Hazard Class: 8 (3)
UN Number: 2734
Packing Group: II
IMO
Shipping Name: AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S.
Hazard Class: 8 (3)
UN Number: 2734
Packing Group: II
RID/ADR
Shipping Name: AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S.
Hazard Class: 8
UN Number: 2734
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN C
Risk Phrases:
R 10 Flammable.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 34 Causes burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 6291-84-5: 1
Canada
CAS# 6291-84-5 is listed on Canada's NDSL List.
CAS# 6291-84-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 6291-84-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Tin(IV) Chloride Anhydrous
| 7646-78-8 |
|
Tin(IV) Chloride Pentahydrate
| 7646-78-8 |
|
2,5-Dimethyl-3-Pyrroline, 75% Remainder 2,5-Dimethyl-1-Pyrroline
| 59480-92-1 |
|
Ruthenium on 1/8-inch alumina pellets (0.5% ru)
| |
|
6-Fluorotryptamine hydrochloride, 99%
| 55206-24-1 |
|
3-Phenyl-1-propylamine, 98%
| 2038-57-5 |
|
Tin (IV) Oxide
| 18282-10-5 |
|
Isethionic Acid Potassium Salt, 98% (Titr.)
| 1561-99-5 |
|
Tin (II) Chloride Anhydrous
| 7772-99-8 |
|
Tubocurarine Chloride, 98.0 - 102.0%
| 6989-98-6 |
|
Tin (II) Chloride Dihydrate
| 10025-69-1 |
|
Rhodium on srtio3 , 0.5 wt% rh
| |
|
Cochineal, extract powder
| |
|
Dimethyl trans-1,2-cyclopropanedicarboxylate, 99+%
| 826-35-7 |
|
3-Aminocrotonamide, Tech. 85%
| 15846-25-0 |
|
Normal-butyl sulfoxide, tech., 93%
| 2168-93-6 |
|
Tin (II) Oxide
| 21651-19-4 |
|
Stearic acid
| 57-11-4 |
|
Starch, Soluble and Hydrolysed
| 9005-25-8 |
|
2-Chloro-3,5-Dinitropyridine, 99%
| 2578-45-2 |
|
Phosphorous acid, 98%
| 10294-56-1 |
|
Poly(Methyl Methacrylate) (Pract)
| 9011-14-7 |
|
Octadecyltrichlorosilane, 95%
| 112-04-9 |
|
Ethyl Propionate, 97+% (gc)
| 105-37-3 |
|
4,4'-Diaminooctafluorobiphenyl, 98%
| 1038-66-0 |
|
Poly(4-methyl-1-pentene), high molecular weight
| 25068-26-2 |
|
Exo-2-Bromo-5-Oxo-Bicyclo(2.2.1)Heptane-Syn-7-Carboxylic Acid, 99%
| 63377-25-3 |
|
3-Methylsulphonylaniline Hydrochloride , 95+%
| 80213-28-1 |
|
Aminoreductone precursor
| |
|
Propyl Red, 98% (UV-Vis)
| 2641-01-2 |
|
5-Chloro-2-Mercaptobenzothiazole, 98%
| 5331-91-9 |
|
Strontium Chloride Hexahydrate
| 10025-70-4 |
|
3-Hydroxypyridine, 98%
| 109-00-2 |
|
N-Methyl-1,3-propanediamine, 99%
| 6291-84-5 |
|
Perfluoro-compound FC-72
| 355-42-0 |
|
2,4,4-Trimethyl-1-pentene (pract), 95% (gc)
| 107-39-1 |
|
2,6-Dimethoxypyridine, 99%
| 6231-18-1 |
|
Strontium nitrate
| 10042-76-9 |
|
2-Fluoroanisole, 98%
| 321-28-8 |
|
Cholic acid, 99+% (titr.)
| 81-25-4 |
|
1-Amino-1-cyclopentanecarboxylic acid, 97%
| 52-52-8 |
|
Dipentylamine, 99%
| 2050-92-2 |
|
Trioctylpropylammonium bromide, 99% (titr.)
| 24298-17-7 |
|
Styrene monomer, inhibited
| 100-42-5 |
|
p-Nitrocinnamic acid, 97%,predominantly trans
| 619-89-6 |
|
3,4-Dimethoxyphenethyl Alcohol
| 7417-21-2 |
|
Succinic acid
| 110-15-6 |
|
D(+)-Sucrose
| 57-50-1 |
|
2-Chlorothiophene, 98+%
| 96-43-5 |
|
Terephthalic-D4 Acid, 98 Atom % D
| 60088-54-2 |
|
|