**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 109-00-2 |3-Hydroxypyridine | 98 | 203-637-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.The toxicological
properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
The toxicological properties of this material have not been fully
investigated.
Ingestion:
May cause irritation of the digestive tract. The toxicological
properties of this substance have not been fully investigated. May be
harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of
this substance have not been fully investigated. May be harmful if
inhaled.
Chronic:
Chronic inhalation and ingestion may cause effects similar to those
of acute inhalation and ingestion. Exposures to doses of pyridine
that are too low to produce overt clinical symptoms can cause liver
damage and repeated low-level exposures can cause cirrhosis. Feeding
studies in rats produced blood effects like changes in clotting
factors. Hazards associated with pyridine may be seen in this
product.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove
contaminated clothing and shoes. Get medical aid if irritation
develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. This
material in sufficient quantity and reduced particle size is capable
of creating a dust explosion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid generating dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Avoid breathing dust.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 109-00-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: beige to brown
Odor: None reported.
pH: 6 - 6.5 (3% aq soln)
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 180 deg C @ 22 mm Hg
Freezing/Melting Point: 125 - 130 deg C
Autoignition Temperature: 500 deg C ( 932.00 deg F)
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: 33 g/L (20C)
Specific Gravity/Density: Not available.
Molecular Formula: C5H5NO
Molecular Weight: 95.10
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, strong bases, acid chlorides,
heavy metal salts.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, cyanide fumes.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 109-00-2: UU7701400
LD50/LC50:
Not available.
Carcinogenicity:
3-Hydroxypyridine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/39 Wear suitable protective clothing and
eye/face protection.
WGK (Water Danger/Protection)
CAS# 109-00-2: No information available.
Canada
CAS# 109-00-2 is listed on Canada's NDSL List.
CAS# 109-00-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 109-00-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Tin(IV) Chloride Anhydrous
| 7646-78-8 |
|
Tin(IV) Chloride Pentahydrate
| 7646-78-8 |
|
2,5-Dimethyl-3-Pyrroline, 75% Remainder 2,5-Dimethyl-1-Pyrroline
| 59480-92-1 |
|
Ruthenium on 1/8-inch alumina pellets (0.5% ru)
| |
|
6-Fluorotryptamine hydrochloride, 99%
| 55206-24-1 |
|
3-Phenyl-1-propylamine, 98%
| 2038-57-5 |
|
Tin (IV) Oxide
| 18282-10-5 |
|
Isethionic Acid Potassium Salt, 98% (Titr.)
| 1561-99-5 |
|
Tin (II) Chloride Anhydrous
| 7772-99-8 |
|
Tubocurarine Chloride, 98.0 - 102.0%
| 6989-98-6 |
|
Tin (II) Chloride Dihydrate
| 10025-69-1 |
|
Rhodium on srtio3 , 0.5 wt% rh
| |
|
Cochineal, extract powder
| |
|
Dimethyl trans-1,2-cyclopropanedicarboxylate, 99+%
| 826-35-7 |
|
3-Aminocrotonamide, Tech. 85%
| 15846-25-0 |
|
Normal-butyl sulfoxide, tech., 93%
| 2168-93-6 |
|
Tin (II) Oxide
| 21651-19-4 |
|
Stearic acid
| 57-11-4 |
|
Starch, Soluble and Hydrolysed
| 9005-25-8 |
|
2-Chloro-3,5-Dinitropyridine, 99%
| 2578-45-2 |
|
Phosphorous acid, 98%
| 10294-56-1 |
|
Poly(Methyl Methacrylate) (Pract)
| 9011-14-7 |
|
Octadecyltrichlorosilane, 95%
| 112-04-9 |
|
Ethyl Propionate, 97+% (gc)
| 105-37-3 |
|
4,4'-Diaminooctafluorobiphenyl, 98%
| 1038-66-0 |
|
Poly(4-methyl-1-pentene), high molecular weight
| 25068-26-2 |
|
Exo-2-Bromo-5-Oxo-Bicyclo(2.2.1)Heptane-Syn-7-Carboxylic Acid, 99%
| 63377-25-3 |
|
3-Methylsulphonylaniline Hydrochloride , 95+%
| 80213-28-1 |
|
Aminoreductone precursor
| |
|
Propyl Red, 98% (UV-Vis)
| 2641-01-2 |
|
5-Chloro-2-Mercaptobenzothiazole, 98%
| 5331-91-9 |
|
Strontium Chloride Hexahydrate
| 10025-70-4 |
|
3-Hydroxypyridine, 98%
| 109-00-2 |
|
N-Methyl-1,3-propanediamine, 99%
| 6291-84-5 |
|
Perfluoro-compound FC-72
| 355-42-0 |
|
2,4,4-Trimethyl-1-pentene (pract), 95% (gc)
| 107-39-1 |
|
2,6-Dimethoxypyridine, 99%
| 6231-18-1 |
|
Strontium nitrate
| 10042-76-9 |
|
2-Fluoroanisole, 98%
| 321-28-8 |
|
Cholic acid, 99+% (titr.)
| 81-25-4 |
|
1-Amino-1-cyclopentanecarboxylic acid, 97%
| 52-52-8 |
|
Dipentylamine, 99%
| 2050-92-2 |
|
Trioctylpropylammonium bromide, 99% (titr.)
| 24298-17-7 |
|
Styrene monomer, inhibited
| 100-42-5 |
|
p-Nitrocinnamic acid, 97%,predominantly trans
| 619-89-6 |
|
3,4-Dimethoxyphenethyl Alcohol
| 7417-21-2 |
|
Succinic acid
| 110-15-6 |
|
D(+)-Sucrose
| 57-50-1 |
|
2-Chlorothiophene, 98+%
| 96-43-5 |
|
Terephthalic-D4 Acid, 98 Atom % D
| 60088-54-2 |
|
|