STRESS COAT
Chemwatch Material Safety Data Sheet CHEMWATCH 4656-3
Issue Date: 14-Oct-2005 CD 2005/3 Page 1 of 10
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
STRESS COAT
STATEMENT OF HAZARDOUS NATURE
CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR
1910.1200.
SUPPLIER
Company: Aquarium Pharmaceuticals Incorporated Company: Aquarium Pharmaceuticals Incorporated
Address: Address:
50 East Hamilton Street PO Box 218
Chalfont Chalfont
PA, 18914 PA, 18914-0218
USA USA
Telephone: +1 215 822 8181 Telephone: +1 215 822 8181
Emergency Tel: +1800 222 1222 (US Only)
PRODUCT USE
For product 85.
SYNONYMS
"Solution ID# 3370"
Section 2 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
Aloes, extract 85507-69-3 1-10
sodium thiosulfate 7772-98-7 1-10
water 7732-18-5 >80
Section 3 - HAZARDS IDENTIFICATION
CANADIAN WHMIS SYMBOLS
EMERGENCY OVERVIEW
RISK
Cumulative effects may result following exposure*. *(limited evidence)
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STRESS COAT
Chemwatch Material Safety Data Sheet CHEMWATCH 4656-3
Issue Date: 14-Oct-2005 CD 2005/3 Page 2 of 10
Section 3 - HAZARDS IDENTIFICATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
The material has NOT been classified as "harmful by ingestion". This is because
of the lack of corroborating animal or human evidence. The material may still be
damaging to the health of the individual, following ingestion, especially where
pre-existing organ (e.g. liver, kidney) damage is evident. Present definitions
of harmful or toxic substances are generally based on doses producing mortality
(death) rather than those producing morbidity (disease, ill-health).
Gastrointestinal tract discomfort may produce nausea and vomiting. In an
occupational setting however, unintentional ingestion is not thought to be cause
for concern.
EYE
Although the liquid is not thought to be an irritant, direct contact with the
eye may produce transient discomfort characterized by tearing or conjunctival
redness (as with windburn).
SKIN
The material is not thought to produce adverse health effects or skin irritation
following contact (as classified using animal models). Nevertheless, good
hygiene practice requires that exposure be kept to a minimum and that suitable
gloves be used in an occupational setting.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions,
may produce systemic injury with harmful effects. Examine the skin prior to the
use of the material and ensure that any external damage is suitably protected.
INHALED
Not normally a hazard due to non-volatile nature of product.
The material is not thought to produce adverse health effects or irritation of
the respiratory tract (as classified using animal models). Nevertheless, good
hygiene practice requires that exposure be kept to a minimum and that suitable
control measures be used in an occupational setting.
CHRONIC HEALTH EFFECTS
Substance accumulation, in the human body, may occur and may cause some concern
following repeated or long-term occupational exposure. Long term low level
exposure to hydrogen sulfide may produce headache, fatigue, dizziness,
irritability and loss of sexual desire. These symptoms may also result when
exposed to hydrogen sulfide at high concentration for a short period of time.
Section 4 - FIRST AID MEASURES
SWALLOWED
- Immediately give a glass of water.
- First aid is not generally required. If in doubt, contact a Poisons
Information Center or a doctor.
EYE
If this product comes in contact with eyes:
- Wash out immediately with water.
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STRESS COAT
Chemwatch Material Safety Data Sheet CHEMWATCH 4656-3
Issue Date: 14-Oct-2005 CD 2005/3 Page 3 of 10
Section 4 - FIRST AID MEASURES
- If irritation continues, seek medical attention.
- Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.
SKIN
If skin or hair contact occurs:
- Flush skin and hair with running water (and soap if available).
- Seek medical attention in event of irritation.
INHALED
- If fumes or combustion products are inhaled remove from contaminated area.
- Other measures are usually unnecessary.
NOTES TO PHYSICIAN
Treat symptomatically.
For exposures involving sulfides and hydrogen sulfide (including gastric acid
decomposition products of alkaline sulfides).
- Hydrogen sulfide anion produces its major toxic effect through inhibition of
cytochrome oxidases.
- Symptoms include profuse salivation, nausea, vomiting and diarrhea. Central
nervous effects may include giddiness, headache, vertigo, amnesia, confusion and
unconsciousness. Tachypnea, palpitation, tachycardia, arrhythmia, sweating,
weakness and muscle cramps may also indicate over-exposures.
Treatment involves:
- If respirations are depressed, application of artificial respiration,
administration of oxygen (continue after spontaneous breathing is established).
- For severe poisonings administer amyl nitrite and sodium nitrite (as for
cyanide poisoning) but omit sodium thiosulfate injection.
- Atropine sulfate (0.6 mg intramuscularly) may contribute symptomatic relief.
- Conjunctivitis may be relieved by installation of 1 drop of olive-oil in each
eye and sometimes by 3 drops of epinephrine solution (1:1000) at frequent
intervals. Occasionally local anesthetics and hot and cold compresses are
necessary to control pain.
- Antibiotics at first hint of pulmonary infection.
[Gosselin et al, Clinical Toxicology of Commercial Products].
Section 5 - FIRE FIGHTING MEASURES
Flash Point (掳F): Not Applicable
Lower Explosive Limit (%): Not Applicable
Upper Explosive Limit (%): Not Applicable
Autoignition Temp (掳F): Not Applicable
EXTINGUISHING MEDIA
- There is no restriction on the type of extinguisher which may be used.
Use extinguishing media suitable for surrounding area.
FIRE FIGHTING
- Alert Emergency Responders and tell them location and nature of hazard.
- Wear breathing apparatus plus protective gloves for fire only.
- Prevent, by any means available, spillage from entering drains or water
course.
- Use fire fighting procedures suitable for surrounding area.
- Do not approach containers suspected to be hot.
- Cool fire exposed containers with water spray from a protected location.
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STRESS COAT
Chemwatch Material Safety Data Sheet CHEMWATCH 4656-3
Issue Date: 14-Oct-2005 CD 2005/3 Page 4 of 10
Section 5 - FIRE FIGHTING MEASURES
- If safe to do so, remove containers from path of fire.
- Equipment should be thoroughly decontaminated after use.
GENERAL FIRE HAZARDS/HAZARDOUS COMBUSTIBLE PRODUCTS
Decomposition may produce toxic fumes of, sulfur oxides (SOx).
May emit poisonous fumes.
FIRE INCOMPATIBILITY
None known.
PERSONAL PROTECTION
Glasses:
Chemical goggles.
Gloves:
PVC chemical resistant type.
Respirator:
Particulate
Section 6 - ACCIDENTAL RELEASE MEASURES
MINOR SPILLS
- Clean up all spills immediately.
- Avoid breathing vapors and contact with skin and eyes.
- Control personal contact by using protective equipment.
- Contain and absorb spill with sand, earth, inert material or vermiculite.
- Wipe up.
- Place in a suitable labeled container for waste disposal.
MAJOR SPILLS
Moderate hazard.
- Clear area of personnel and move upwind.
- Alert Emergency Responders and tell them location and nature of hazard.
- Wear breathing apparatus plus protective gloves.
- Prevent, by any means available, spillage from entering drains or water
course.
- Stop leak if safe to do so.
- Contain spill with sand, earth or vermiculite.
- Collect recoverable product into labeled containers for recycling.
- Neutralize/decontaminate residue.
- Collect solid residues and seal in labeled drums for disposal.
- Wash area and prevent runoff into drains.
- After clean up operations, decontaminate and launder all protective clothing
and equipment before storing and re-using.
- If contamination of drains or waterways occurs, advise emergency services.
ACUTE EXPOSURE GUIDELINE LEVELS (AEGL) (in ppm)
AEGL 1: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could
experience notable discomfort, irritation, or certain asymptomatic nonsensory
effects. However, the effects are not disabling and are transient and
reversible upon cessation of exposure.
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STRESS COAT
Chemwatch Material Safety Data Sheet CHEMWATCH 4656-3
Issue Date: 14-Oct-2005 CD 2005/3 Page 5 of 10
Section 6 - ACCIDENTAL RELEASE MEASURES
AEGL 2: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could
experience irreversible or other serious, long-lasting adverse health effects
or an impaired ability to escape.
AEGL 3: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could
experience life-threatening health effects or death.
EMERGENCY RESPONSE PLANNING GUIDELINES (ERPG)
The maximum airborne concentration below which it is believed that nearly all
individuals could be exposed for up to one hour WITHOUT experiencing or developing
life-threatening health effects is:
sodium thiosulfate 500 mg/m鲁
water 500 mg/m鲁
irreversible or other serious effects or symptoms which could
impair an individual's ability to take protective action is:
sodium thiosulfate 50 mg/m鲁
water 500 mg/m鲁
other than mild, transient adverse effects
without perceiving a clearly defined odour is:
sodium thiosulfate 30 mg/m鲁
water 500 mg/m鲁
The threshold concentration below which most people.
will experience no appreciable risk of health effects:
sodium thiosulfate 10 mg/m鲁
water 500 mg/m鲁
American Industrial Hygiene Association (AIHA)
Ingredients considered according exceed the following cutoffs
Very Toxic (T+) >= 0.1% Toxic (T) >= 3.0%
R50 >= 0.25% Corrosive (C) >= 5.0%
R51 >= 2.5%
else >= 10%
where percentage is percentage of ingredient found in the mixture
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
- Avoid all personal contact, including inhalation.
- Wear protective clothing when risk of exposure occurs.
- Use in a well-ventilated area.
- Prevent concentration in hollows and sumps.
- DO NOT enter confined spaces until atmosphere has been checked.
- DO NOT allow material to contact humans, exposed food or food utensils.
- Avoid contact with incompatible materials.
- When handling, DO NOT eat, drink or smoke.
- Keep containers securely sealed when not in use.
- Avoid physical damage to containers.
- Always wash hands with soap and water after handling.
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STRESS COAT
Chemwatch Material Safety Data Sheet CHEMWATCH 4656-3
Issue Date: 14-Oct-2005 CD 2005/3 Page 6 of 10
Section 7 - HANDLING AND STORAGE
- Work clothes should be laundered separately.
- Launder contaminated clothing before re-use.
- Use good occupational work practice.
- Observe manufacturer's storing and handling recommendations.
- Atmosphere should be regularly checked against established exposure standards
to ensure safe working conditions are maintained.
RECOMMENDED STORAGE METHODS
- Polyethylene or polypropylene container.
- Packing as recommended by manufacturer
- Check all containers are clearly labeled and free from leaks.
STORAGE REQUIREMENTS
- Store in original containers.
- Keep containers securely sealed.
- Store in a cool, dry, well-ventilated area.
- Store away from incompatible materials and foodstuff containers.
- Protect containers against physical damage and check regularly for leaks.
- Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
No data available: Stress Coat as (CAS: 85507-69-3) / (CAS: 7772-98-7) / (CAS: 7732-18-5)
No data available: Aloes, extract as (CAS: 85507-69-3) / (CAS: 94349-62-9)
No data available: sodium thiosulfate as (CAS: 7772-98-7)
No data available: water as (CAS: 7732-18-5)
Not available. Refer to individual constituents.
EXPOSURE STANDARDS FOR MIXTURE
"Worst Case" computer-aided prediction of spray/ mist or fume/ dust components
and concentration:
"Worst Case" computer-aided prediction of spray/ mist or fume/ dust components
and concentration:
Composite Exposure Standard for Mixture (TWA) :100 mg/m鲁.
INGREDIENT DATA
ALOES, EXTRACT:
Dusts not otherwise classified, as inspirable dust;
ES TWA: 10 mg/m鲁.
SODIUM THIOSULFATE:
Dusts not otherwise classified, as inspirable dust;
ES TWA: 10 mg/m鲁.
WATER:
No exposure limits set by NOHSC or ACGIH.
PERSONAL PROTECTION
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STRESS COAT
Chemwatch Material Safety Data Sheet CHEMWATCH 4656-3
Issue Date: 14-Oct-2005 CD 2005/3 Page 7 of 10
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EYE
- Safety glasses with side shields
- Chemical goggles.
- Contact lenses pose a special hazard; soft lenses may absorb irritants and all
lenses concentrate them.
HANDS/FEET
Wear chemical protective gloves, eg. PVC.
Wear safety footwear or safety gumboots, eg. Rubber.
OTHER
- Overalls.
- P.V.C. apron.
- Barrier cream.
- Skin cleansing cream.
- Eye wash unit.
RESPIRATOR
Selection of the Class and Type of respirator will depend upon the level of
breathing zone contaminant and the chemical nature of the contaminant.
Protection Factors (defined as the ratio of contaminant outside and inside the
mask) may also be important.
Breathing Zone Maximum Protection Half-face Full-Face
Level ppm (volume) Factor Respirator Respirator
1000 10 -1 P -
1000 50 - -1 P
5000 50 Airline* -
5000 100 - -2 P
10000 100 - -3 P
100+ Airline* *
* - Continuous Flow ** - Continuous-flow or positive pressure demand.
The local concentration of material, quantity and
conditions of use determine the type of personal
protective equipment required.
Use appropriate NIOSH-certified respirator based on informed professional
judgement. In conditions where no reasonable estimate of exposure can be
made, assume the exposure is in a concentration IDLH and use NIOSH-certified
full face pressure demand SCBA with a minimum service life of 30 minutes, or
a combination full facepiece pressure demand SAR with auxiliary self-contained
air supply. Respirators provided only for escape from IDLH atmospheres shall be
NIOSH-certified for escape from the atmosphere in which they will be used.
ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. If risk of
overexposure exists, wear an approved respirator. Correct fit is essential to
obtain adequate protection. Provide adequate ventilation in warehouse or closed
storage areas.
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STRESS COAT
Chemwatch Material Safety Data Sheet CHEMWATCH 4656-3
Issue Date: 14-Oct-2005 CD 2005/3 Page 8 of 10
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL PROPERTIES
Liquid.
Mixes with water.
Molecular Weight: Not Applicable Boiling Range (掳C): Not Available
Melting Range (掳C): Not Available Specific Gravity (water=1): 1.013
Solubility in water (g/L): Miscible pH (as supplied): 9.5-9.9
pH (1% solution): Not Available Vapor Pressure (kPa): Not Available
Volatile Component (%vol): Not Available Evaporation Rate: Not Available
Relative Vapor Density (air=1): Not Available Flash Point (掳C): Not Applicable
Lower Explosive Limit (%): Not Applicable Upper Explosive Limit (%): Not Applicable
Autoignition Temp (掳C): Not Applicable Decomposition Temp (掳C): Not Available
State: Liquid
APPEARANCE
Viscous green liquid with a faint characteristic odor; mixes with water.
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
- Presence of incompatible materials.
- Product is considered stable.
- Hazardous polymerization will not occur.
STORAGE INCOMPATIBILITY
Contact with acids produces toxic fumes.
Section 11 - TOXICOLOGICAL INFORMATION
Stress Coat
Not available. Refer to individual constituents.
unless otherwise specified data extracted from RTECS - Register of Toxic Effects
of Chemical Substances
ALOES, EXTRACT:
TOXICITY IRRITATION
Aloe barbadensis Mill., extract
Intraperitoneal (mouse) LD50: 250 mg/kg Nil reported
SODIUM THIOSULFATE:
TOXICITY IRRITATION
Oral (human) TDLo: 300 mg/kg/7d Nil Reported
Oral (rat) LD50: >8000mg/kg [Hach]
WATER:
TOXICITY IRRITATION
No significant acute toxicological data identified in literature search.
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STRESS COAT
Chemwatch Material Safety Data Sheet CHEMWATCH 4656-3
Issue Date: 14-Oct-2005 CD 2005/3 Page 9 of 10
Section 12 - ECOLOGICAL INFORMATION
DO NOT discharge into sewer or waterways.
Section 13 - DISPOSAL CONSIDERATIONS
Disposal Instructions
All waste must be handled in accordance with local, state and federal
regulations.
- Recycle wherever possible.
- Consult manufacturer for recycling options or consult Waste Management
Authority for disposal if no suitable treatment or disposal facility can be
identified.
- Dispose of by: Burial in a licensed land-fill or Incineration in a licensed
apparatus (after admixture with suitable combustible material)
- Decontaminate empty containers. Observe all label safeguards until containers
are cleaned and destroyed.
Section 14 - TRANSPORTATION INFORMATION
Shipping Name: None
Hazard Class: None
SubRisk: None
UN/NA Number: None
Packing Group: None
Additional Shipping Information:
International Transport Regulations:
IMO: None
Section 15 - REGULATORY INFORMATION
RISK
US Federal Regulations
A. General Product Information
In addition to Federal and State regulation, local regulations may
apply. Check with your local regulatory authorities.
B. Component Information
This material contains one or more of the following chemicals required
to be identified under SARA Section 302 (40 CFR 455 Appendix A)
SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4): None
-------------------------------------------------------------------
Component TSCA
Aloes, extract N
sodium thiosulfate Y
State Regulations
A. General Product Information
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STRESS COAT
Chemwatch Material Safety Data Sheet CHEMWATCH 4656-3
Issue Date: 14-Oct-2005 CD 2005/3 Page 10 of 10
Section 15 - REGULATORY INFORMATION
B. Component Information
The following components appear on one or more of the following state
hazardous substance lists.
Component CAS No CA FL MA MN NJ PA
Aloes, extract 85507-69-3 N N N N N N
sodium thiosulfate 7772-98-7 N N N N N N
Y=Yes this material appears on that state's hazardous substances list.
N=No this material does not appear on that state's hazardous substances list.
Other Regulations
A. Component Information
CANADA
The following component(s) are identified under the Canadian
Hazardous Products Act Ingredient Disclosure List:
All of this product's components are on the Canadian Domestic
.
REGULATIONS
Aloes, extract (CAS: 85507-69-3) is found on the following regulatory lists
US DOE Temporary Emergency Exposure Limits (TEELs)
sodium thiosulfate (CAS: 7772-98-7) is found on the following regulatory lists
Canadian Domestic Substances List (DSL)
US Toxic Substances Control Act (TSCA)
US DOE Temporary Emergency Exposure Limits (TEELs)
Canadian Ingredient Disclosure List (SOR/88-64)
water (CAS: 7732-18-5) is found on the following regulatory lists
Canadian Domestic Substances List (DSL)
US Toxic Substances Control Act (TSCA)
US DOE Temporary Emergency Exposure Limits (TEELs)
US Californian Proposition 65 - Priority List for the Development of MADLs for
Chemicals Causing Reproductive Toxicity
No data available for Aloes, extract as CAS: 94349-62-9.
Section 16 - OTHER INFORMATION
Reasonable care has been taken in the preparation of this information, but the
author makes no warranty of merchantability or any other warranty, expressed or
implied, with respect to this information. The author makes no representations
and assumes no liability for any direct, incidental or consequential damages
resulting from its use. For additional technical information please call our
toxicology department on +800 CHEMCALL.
Issue Date: 14-Oct-2005
Print Date: 20-Oct-2005
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
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