(in compliance with EG-regulation 91/155/EEG imitated by 2001/58/EG-Nederland)
Pages : 5
Material Safety Data Sheet Revision nr : 7
Date : 31/5/07
Urea solution 32,5% Replaces : 22/9/06
1. Identification of the substance/preparation and the company/undertaking
Commercial Product Name Adblue庐 - Urea Solution 32,5%
Use of the Substance/Preparation Urea Solution 32,5%
Important application Determined for NOx decrease in the exhaust gasses of vehicles with
diesel engines.
Company Dureal a division of Univar N.V.
Admiraal Lucashof 6
3115 HM Schiedam
The Netherlands
Emergency telephone number Tel: +31 (0)10 246 2222
+800 2436 2255 or +61 3 9573 3112
2. Compostion/Information on ingredients
Chemical disposition of the Liquid
preparation
Naam component Waarde(n) CAS-nr. EG-nr.
Urea 32,5% 57-13-6 200-315-5
Water 67,5% 7732-18-5 231-791-2
Indeling The material is not subordinated to EG-regulations 7/548/EEC of
99/45/EC as dangerous chemical preparation.
3. Hazards Identification
Most important hazards The product contains no substances classified as hazardous to
health in concentrations which should be taken into account
according to EC directive.May cause skin irritation in susceptible
persons.
Inhalation Inhalation of aerosol may cause irritation to the upper respiratory
tract.
Skin contact Prolonged skin contact may cause skin irritation.
Eye contact Repeated or prolonged exposure may cause irritation of eyes and
skin.
Ingestion Gastrointestinal discomfort
Environmental properties No information available.
1
(in compliance with EG-regulation 91/155/EEG imitated by 2001/58/EG-Nederland)
4. First aid measures
Inhalation Oxygen or artificial respiration if needed. Keep at rest. Move to
fresh air. Obtain medical attention.
Skin contact Take off contaminated clothing and shoes immediately. Wash off
with soap and water. If symptoms persist, call a physician.
Eye contact Rinse thoroughly with plenty of water for at least 15 minutes and
consult a physician.
Ingestion Clean mouth with water and drink afterwards plenty of water.
Do not induce vomiting.
Obtain medical attention.
Protection of first-aiders : No special precautions required
Protection of first-aiders No special precautions required
Notes to physician Treat symptomatically.
5. Fire-fighting measures
Suitable extinguishing media Use dry chemical, CO2, water spray or alcohol resistant foam.
Extinguishing media which must not be None
used for safety reason
Specific hazards The product is not flammable nor combustible. Contaminated
equipment (brushes, rags) must be cleaned immediately with
water. Burning produces obnoxious and toxic fumes. CO, CO2,
Nox Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations. Cool
containers / tanks with spray water.
Special protective equipment for Wear personal protective equipment. Wear self contained
firefighters breathing apparatus for fire fighting if necessary.
6. Accidental relaease measures
Personal precautions Sweep-up to prevent slipping hazard. Avoid inhalation of gases.
Evacuate personnel to safe areas. Avoid contact with skin and
eyes. Wear personal protective equipment.
Environmental precautions Prevent product from entering drains.
Methods for cleaning up Clean contaminated surface thoroughly. Dam up. adsorption in
inert material (e.g. sand, kieselguhr, acid binder, universal binder,
sawdust) Sweep up and shovel into suitable containers for
disposal. Dispose of in accordance with local regulations
7. Handling and storage
Storage Handle in accordance with good industrial hygiene and safety
practice for diagnostics. Incompatible with strong acids and
oxidising agents. Keep in properly labelled containers.
Keep tightly closed in a dry, cool and well-ventilated place.
polyethylene containers.
Handling Impervious gloves. Wear personal protective equipment.
When using, do not eat, drink or smoke. Handle in accordance
with good industrial hygiene and safety practice. Wash hands
2
(in compliance with EG-regulation 91/155/EEG imitated by 2001/58/EG-Nederland)
before breaks and immediately after handling the product.
Ensure adequate ventilation.
Specific use(s) No information available
8. Exposure controls/ personal protection
Elements with job supervision of The product contains no relevant amount of chemicals which are
limited value. related to jobs in relation to supervised limited values.
Personal protective equipment Use only in an area equipped with a safety shower.
Respiratory protection In case of insufficient ventilation wear suitable respiratory
equipment.
Hand protection Butylrubber
Skin and body protection Protective suit
Eye protection Face-shield Safety glasses (EN166)
Hygiene measures Handle in accordance with good industrial hygiene and safety
practice.
9. Physical and chemical properties
Appearance Liquid
Coulour Clear
Odour Lightly ammonia effective
pH (conc. 10 %) 9,8 - 10,0
Boiling point/range -11掳C, Dissolution temperature 103掳C
Evaporation rate, vapour density and No data available
solubility in other solvents.
Autoignition temperature Not applicable
Explosive properties Protect from contamination. Strong acids , nitrates Exothermic
reaction with strong acids - Vapours may form explosive mixture
with air. Oxidising properties.
Oxidising properties No data available
Vapour pressure ca. 48 mm Hg @ 40 掳C
Water solubility Soluble
Viscosity No data available
Partition coefficient (n-octanol/water) No data available
Density 1090 kg/m鲁 @ 20掳C
10. Stability and reactivity
Stability Stable at normal conditions
Hazardous decomposition products Ammonia gas may be liberated at high temperatures. Burning
produces obnoxious and toxic fumes. Possible decomposition
products are: Carbon oxides , Nitrogen oxides (NOx).
Materials to avoid Reacts strongly with nitrites
Conditions to avoid Keep at temperatures above 50 掳C.
3
(in compliance with EG-regulation 91/155/EEG imitated by 2001/58/EG-Nederland)
11. Toxicological information
Inhalation May cause irritation of respiratory tract
Chronic toxicity : No information Irritating to skin
available
LD50/oral/rat : >2000 mg/kg
Contact met de huid
Eye contact Irritating to eyes
Ingestion Ingestion may cause irritation to mucous membranes.
Acute toxication when swallow LD50 rad Dosis: 15000mg/kg in relation to urea
Chronic toxicit No information available
LD50/oral/rat : >2000 mg/kg >2000 mg/kg
12. Ecological information
Bioaccumulation Low potential, the material should not be spread fiercely in the
environment.
Ecotoxicity effects Acute fish toxicity = LC 50 : >10000 mg/l 48 h (gold fish)
Mobility Soluble
Persistence and degradability Readily biodegradable
Eco toxic effects (toxic for fish) Type: Leuciscus idus dosis: >6810gr/ltr
Exposing time 96 h, in relation to urea
EC50 type: Daphnia magna (big water flea)
Dose: >10000mg/ltr
Exposing time 24 h, in relation to urea
13. Disposal considerations
Contaminated packaging Empty containers should be transported/delivered using a
registered waste carrier
to local recyclers for disposal.
Waste from residues Can be landfilled, when in compliance with the Environmental
Protection (Duty of Care) Regulations 1991. Dispose of in
accordance with local regulations
14. Transport Information
ADR/RID Not classified as dangerous in the meaning of transport
regulations.
Transport temperatuur van de stof max. 30掳C
15. Regulatory information
Labelling : 76/116/EC
The product is non-dangerous in accordance with Directive 1999/45/EC.
Symbol(s):
R-phrase(s)
4
(in compliance with EG-regulation 91/155/EEG imitated by 2001/58/EG-Nederland)
S-phrase(s) : S24 - Avoid contact with the skin.
16. Remaining information
Text of the R-terms which ware being quoted in Section 2
The contents and format of this MSDS are in accordance with EEC Commission Directive 2001/58/EC,
1999/45/EC, 1967/548/EC.
DISCLAIMER OF LIABILITY The information in this MSDS was obtained from sources which we believe are
reliable. However, the information is provided without any warranty, express or implied, regarding its
correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our
control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and
expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the
handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this
product. If the product is used as a component in another product, this MSDS information may not be
applicable.
End of document
5
|