PERMATHANE SM7108 SDS
Revision Date: 13 April 2007
SAFETY DATA SHEET
SCHNEE MOREHEAD PERMATHANE SM7108
1 SUBSTANCE INDENTIFICATION AND COMPANY
PRODUCT NAME: SCHNEE-MOREHEAD PERMATHANE SM7108
PRODUCT NO. E492073
SUPPLIER ITW POLYMERS & FLUIDS ITW POLYMERS & FLUIDS (NZ)
100 HASSALL ST 18-26 AMELIA EARHART AVE
WETHERILL PARK MANGERE AIRPORT OAKS,
NEW SOUTH WALES AUCKLAND
AUSTRALIA NEW ZELAND
T: 02 9757 8800 T: 09 256 2122
F: 02 9757 3855 F: 09 256 2124
2 HAZARDS IDENTIFICATION
HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS
(According to the criteria of the NOHSC and the ADG-6 code)
SIGNAL WORD(S)
Xn; Harmful
RISK PHRASES
R62 Possible risk of impaired fertility.
R63 Possible risk of harm to the unborn child.
SAFETY PHRASES
S2 Keep out of reach of children.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
S36/37 Wear suitable protective clothing and gloves.
S45 On case of accident or if you feel unwell, seek medical advice immediately (show the
label where possible.)
S53 Avoid exposure 鈥? obtain special instructions before use..
3 COMPOSITION / INFORMATION ON INGREDIENTS
Name CAS-No. Content Classification
BUTYL BENZYL PHTHALATE 85-68-7 10 鈥? < 30 % Repr. Cat 3; R62 鈥? Repr. Cat. 3; R63 鈥? N;
R50-53
TOLUENE 108-88-3 0 鈥? < 10 % F; R10, Xn; R20
This product has been tested and no volatile isocyanates are present.
4 FIRST AID MEASURES
GENERAL INFORMATION
Avoid contact with skin and eyes. Do not breath vapour. Show this safety data sheet to doctor in attendance.
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INHALATION
Move the exposed person to fresh air at once. When breathing is difficult, properly trained personnel may assist affected person by
administering oxygen. Contact physician if discomfort continues.
INGESTION
Do not induce vomiting. If vomiting occurs, the head should be kept low so that stomach vomit does not enter the lungs.
SKIN CONTACT
Remove contaminated clothing. Wash skin thoroughly with soap and water for several minutes. Contact physician if irritation persists.
EYE CONTACT
Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention.
Contact physician if irritation persists.
5 FIRE FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA
Fire can be extinguished using: Alcohol resistant foam. Carbon Dioxide (CO2). Dry Chemicals.
SPECIFIC HAZARDS
Combustible. Avoid breathing fire vapours.
PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
SPECIAL FIRE FIGHTING PROCEDURES
Keep upwind to avoid fumes. Avoid water in straight hose stream; will scatter and spread fire. Cool containers exposed to flames with
water until fire is out. Keep run-off water out of sewers and watercourses. Dike for water control.
6 ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
Avoid and contact with skin and eyes. Wear protective clothing as described in Section 8 of this safety data sheet. Provide adequate
ventilation.
ENVIRONMENTAL PRECAUTIONS
Do not allow to enter drains, sewers or watercourses. Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY
alerted to the Environmental Agency or other appropriate regulatory body.
SPILL CLEAN UP METHODS
Absorb with sand or other inert absorbent. Transfer to a container for disposal. Containers with collected spillage must be properly
labeled with correct contents and hazard symbol.
7 HANDLING AND STORAGE
USAGE PRECAUTIONS
Provide adequate ventilation, including appropriate local extraction, to ensure that the defined occupational exposure limit is not
exceeded. Do not eat, drink or smoke when using the product. Observe good industrial hygiene practices.
STORAGE PRECAUTIONS
Store in tightly closed original container in a cool, dry well-ventilated place. Keep away from heat, sparks and open flame.
8 EXPOSURE CONTROL / PERSONAL PROTECTION
EXPOSURE STANDARDS
No exposure standards available for product.
Exposure standards for ingredients:
Name TWA (LT) TWA (LT) STEL (ST) STEL (ST) Source
mg/m3 ppm mg/m3 ppm
TOLUENE 191 50 574 150 NOHSC
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PROTECTIVE EQUIPMENT
PROCESS CONDITIONS
Provide eyewash, quick drench.
ENGINEERING MEASURES
General exhaust is adequate under normal operating conditions. Local exhaust ventillation may be required under special conditions..
RESPIRATORY EQUIPMENT
Select and use respirators in accordance with AS/NZS 1715/1716.
In poorly ventilated areas use Type A organic vapour/gas filter with half face piece.
Filter capacity and respirator type depends on exposure levels and type of contaminant. If entering spaces where the airborne
concentration of a contaminant is unknown then the use of a Self-contained breathing apparatus (SCBA) with positive pressure air
supply complying with AS/NZS 1715 / 1716, or any other acceptable International Standard is recommended.
HAND PROTECTION
Use protective gloves made of: Chemical resistant gloves: e.g. PVC, Nitrile.
EYE PROTECTION
Wear safety glasses or approved chemical safety goggles where eye exposure is reasonably probable.
SKIN PROTECTION
Barrier cream, Protection suit or overalls should be worn.
HYGIENE MEASURES
Keep away from food, drink and animal feeding stuffs. Good personal hygiene is necessary. Wash hands and contaminated areas with
water and soap before leaving the work site. Do not eat, drink or smoke when using the product. Change work clothing daily before
leaving work place.
9 PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE Paste
COLOUR Grey
ODOUR Solvent.
SOLUBILITY Not soluble in water
BOILING POINT (掳C) n/a RELATIVE DENSITY 1.61 @ 20潞 C
VAPOUR DENSITY (air=1) n/a VAPOUR PRESSURE n/a
EVAPORATION RATE (butyl acetate =1) n/a VOLATILE BY VOL. (%) <3
pH-VALUE, CONC. SOLUTION n/a FLASH POINT (掳C) 57.7
FLAMMABILITY LIMIT - LOWER(%) n/a AUTOIGNITION TEMP. (潞C) n/a
FLAMMABILITY LIMIT - UPPER(%) n/a
10 STABILITY & REACTIVITY
STABILITY
Stable under normal temperature conditions and recommended use.
CONDITIONS TO AVOID
Avoid heat, flames and other sources of ignition.
MATERIALS TO AVOID
Strong oxidising agents.
HAZARDOUS DECOMPOSITION PRODUCTS
Fire or high temperatures create: Nitrous gases (NOx). Oxides of: Carbon monoxide (CO). Carbon dioxide (CO2).
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11 TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS CHRONIC HEALTH EFFECTS
Vapours may cause dizziness or suffocation. May cause harm to the unborn child.
Possible risk of impaired fertility.
TOXICITY AND IRRITATION
Not available. Refer to individual constituents.
BUTYL BENZYL PHTHALATE:
TOXICITY IRRITATION
Oral (rat) LD50: 2330 mg/kg Nil Reported
Oral (rat) LD50: 20400 mg/kg* **
Dermal (rabbit) LD50: >10, 000 mg/kg* [MONSANTO]**
Dermal (mammal) LD50: 13, 100 mg/kg** [BASF]*
Reproductive effector in rats.
Exposure to the material for prolonged periods may cause physical defects in the developing embryo (teratogenesis). The substance
is classified by IARC as Group 3: NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
TOLUENE:
TOXICITY IRRITATION
Oral (human) LDLo: 50 mg/kg Skin (rabbit): 20 mg/24h-Moderate
Oral (rat) LD50: 636 mg/kg Skin (rabbit): 500 mg -Moderate
Inhalation (human) TCLo: 100 ppm Eye (rabbit): 0.87 mg -Mild
Inhalation (man) TCLo: 200 ppm Eye (rabbit): 2 mg/24h -SEVERE
Inhalation (rat) LC50: >26700 ppm/1h Eye (rabbit): 100 mg/30sec -Mild
Dermal (rabbit) LD50: 12124 mg/kg
The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic).
This form of dermatitis is often characterised by skin redness (erythema) and swelling the epidermis.
MATERIAL CARCINOGEN REPROTOXIN SENSITISER SKIN
________________________ ____________________ ________________ ________________ ________________
butyl benzyl phthalate IARC:3
toluene IARC:3 ILOEl
CARCINOGEN
IARC: International Agency for Research on Cancer (IARC) Carcinogens: butyl benzyl phthalate Category: 3
CARCINOGEN
IARC: International Agency for Research on Cancer (IARC) Carcinogens: toluene Category: 3
REPROTOXIN
ILOEl: ILO Chemicals in the electronics industry that have toxic effects on reproduction: toluene
12 ECOLOGICAL INFORMATION
ECOTOXICITY
No data available, however expected to be harmful to the aquatic environment
MOBILITY
Do not discharge into drains, water courses or onto the ground.
DEGRADABILITY
No data available.
13 DISPOSAL INFORMATION
DISPOSAL METHODS
Dispose of waste and residues in accordance with local authority requirements.
14 TRANSPORT INFORMATION
Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods by Road and Rail (6th
Edition)
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15 REGULATORY INFORMATION
SUSDP Not scheduled
16 OTHER INFORMATION
REVISION DATE: 13 April 2007
DISCLAIMER
This information relates only to the specific material designated and may not be valid for such material used in combination with any
other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the
date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's
responsibility to satisfy himself as to the suitability of such information for his own particular use.
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