SAFETY DATA SHEET
CYANOACRYLATE ADHESIVE
Eximcorp India Pvt. Ltd.
KHASARA NO. 87/1, 50TH KM, MILESTONE, ROHTAK ROAD,
NEAR SARASWATI DHARAM KANTA, NEW DELHI-110041, INDIA
This safety data sheet has been prepared in accordance with the requirements of EC Directives 1999/45/EC
and 2001/58/EC and provides information relating to the safe handling and use of the product:
1. Product and Company Information
Product Name Cyanoacrylate Adhesive
st
Trade Name 21 Century
Supplier Eximcorp India Pvt. Ltd.
Khasara no. 87/1, 50th km, Milestone, Rohtak Road, Near
Address
Saraswati Dharam Kanta, New Delhi-110041, India
Phone Number Tel: 91 98910 38202
Fax Number Fax:91 11 41063444
2. Composition / Information on Ingredients
Nature - Cyanoacrylate Adhesive
Hazardous Components in Product
Component Name %WT CAS R Phrases EC No
86-99 7085-85-0 Xi R36/37/38
Ethyl Cyanoacrylate 230-391-5
Polymethyl 1-14 9011-12-7 Xi R36/37/38 n/e (polymer)
Methacrylate
3. Hazard Identification
Danger Cyanoacrylate 鈥? Bonds skin and eyes in seconds.
Keep out of the reach of children.
IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
Avoid contact with skin and eyes.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Wear suitable gloves and protective mask,
4. First Aid Measures
Inhalation: Remove to fresh air and rest.
If recovery is not rapid call for prompt medical attention.
Eyes: Cyanoacrylates bond eyelids in seconds. Irrigate thoroughly with water for at
least 15 minutes. Take care not to wash chemical from one eye to another. If
the eyelid is bonded closed, do not force open. Cover with wet pad soaked in
warm water. Get prompt medical attention, in case solid particles of cured
cyanoacrylate trapped behind the eye cause any abrasive damage. Keep eye
covered with wet pad until debonding is complete, usually 1-3 days.
(Cyanoacrylate will Cyanoacrylate will bond to eye protein, causing a
lachrymatory effect that aids debonding).
Skin: Do not pull bonded skin apart. Remove contaminated clothing. Wash with
soap/cleanser and rinse with plenty of water. Any bonded skin should be
gently peeled apart with the aid of a blunt object, preferably after soaking in
warm, soapy water. If irritation persists, obtain medical attention. In the case of
large spills on skin, superficial burns may occur-treat accordingly.
Ingestion: Ensure that breathing passages are not obstructed. Give plenty of water to
drink. Do not induce vomiting. The product will polymerize immediately in the
mouth, making it almost impossible to swallow. Saliva will separate the
solidified product from the mouth over a period of hours. Seek medical
attention.
SAFETY DATA SHEET
CYANOACRYLATE ADHESIVE
Eximcorp India Pvt. Ltd.
KHASARA NO. 87/1, 50TH KM, MILESTONE, ROHTAK ROAD,
NEAR SARASWATI DHARAM KANTA, NEW DELHI-110041, INDIA
5. Fire-Fighting Measures
Suitable Alcohol resistant foam. Dry powder. Carbon dioxide. Water spray/fog.
Extinguishers:
Unsuitable Direct water jets.
Extinguishers:
Hazardous Toxic fumes are produced in fire (CO, CO2, nitrogen oxides).
Decomposition:
Special Procedures: Do not breathe decomposition products and fumes.
Use approved self-contained breathing apparatus.
Wear fire retardant clothing. Wear eye protection.
Use water spray to cool containers.
Prevent runoff from fire control from entering waterways.
Large fires should only be dealt with by trained personnel.
6. Accidental Release Measures
Exposure Controls: Refer to Section 8 鈥? Personal Protection. Ventilate area. Evacuate
personnel.
Use approved self-contained breathing apparatus.
Do not allow spill to enter drains and watercourses.
Personal Wear suitable respiratory protection in confirmed spaces.
Protection: Wear polythene gloves.
Use eye protection such as goggles to BS EN 166 Chemical Grade
Disposal Absorb in inert material such as sand or absorbent granules (do not use
Considerations: cloths) or polymerize slowly with water and scrape up. Dispose in
accordance with local regulations.
7. Handling and Storage
Handling: Avoid skin and eye contact. Avoid inhalation of vapour. Ensure
adequate ventilation 鈥? Local Exhaust Ventilation may be required.
Wear eye protection and gloves. Ambient Relative Humidity should
be >40% to minimize discomfort.
Storage: Store in tightly closed labeled containers.
Store in a cool, dry, well-ventilated area.
8. Exposure Controls / Personal Protection
OES for ethyl cyanoacrylate is 0.3 ppm = 1.5mg/m3 (STEL 15 min.
Occupational
Exposure Limit: TWA, as stated in EH40/2000) Wear polythene gloves.
Wear suitable overalls or apron if usage is large and change if
contaminated.
Wear suitable eye protection such as BS En 166
Use in well-ventilated areas 鈥? Use mechanical ventilation if
necessary to maintain vapour level below TLV. If excessive
inhalation in a poorly ventilated areas is likely then use a respirator
with filter type P
After contact with skin wash off immediately
SAFETY DATA SHEET
CYANOACRYLATE ADHESIVE
Eximcorp India Pvt. Ltd.
KHASARA NO. 87/1, 50TH KM, MILESTONE, ROHTAK ROAD,
NEAR SARASWATI DHARAM KANTA, NEW DELHI-110041, INDIA
9. Physical & Chemical Properties
Appearance: Clear and almost colourless liquid ( black RT grades, 2 white RT)
Odour: Sharp, Pungent
pH: n/e
Boiling point/range: >150掳 C
Melting point/range: n/e
Flash point: >85掳 C (C.O.C.)
Flammability: NON-FLAMMABLE
Auto flammability: n/e
Explosive properties: None
Oxidizing properties: None
Vapour pressure: ~ 0.2 mm
Relative density: 1.04 鈥? 1.10 depending on grade
Solubility: polymerizes in water ( Note 鈥? soluble in acetone)
Vapour Density: n/e
Viscosity: Various 鈥? from 3cP (water-thin) to gel
Evaporation rate (Bu Ac =1): n/e (n/e=not established)
10. Stability and Reactivity
Stable at normal temperatures. Will polymerizes rapidly on contact with water.
Material to avoid: strong oxidizing agents, water, alkalis, amines, alcohols.
Conditions to avoid: high temperature, moisture & direct sunlight.
No hazardous decomposition products when stored and handled correctly.
11. Toxicological Information
Oral: LD50 oral-rat>5000mg/kg. Considered to have relatively low toxicity. Products is
almost impossible to swallow, due to polymerization in mouth.
Skin: LD50 skin-rabbit >2000mg/kg.
Inhalation: see section 8 for OES
Acute effects: eye watering, irritation of nasal cavities and respiratory tract and irritation and
redness at the site of skin contact. Repeated skin contact may possibly cause dermatitis in
sensitive individuals. Prolonged and repeated over-exposure to high concentrations of vapours
may lead to sensitizing.
12. Ecological Information
Ecotoxicity: No specific data available, but expected to be very low.
Persistence: No specific data available
Bio-accumulative potential: No specific data available
Mobillity: No specific data available, but expected to be very low.
13. Disposal Considerations
Polymerize adhesive by adding slowly to water (~10:1, adhesive: water).
Add water to contaminated packaging and then dispose of.
Do not discharge into drains or watercourses
Dispose of in accordance with local regulations
SAFETY DATA SHEET
CYANOACRYLATE ADHESIVE
Eximcorp India Pvt. Ltd.
KHASARA NO. 87/1, 50TH KM, MILESTONE, ROHTAK ROAD,
NEAR SARASWATI DHARAM KANTA, NEW DELHI-110041, INDIA
14. Transport Information
Not classified as hazardous for transport
15. Regulatory Information
X IRRITANT
a) Risk & Safety Danger 鈥? cyanoacrylate. Bonds skin and eyes in seconds. Keep out of
the reach of children
R36/37/38 IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN
S24/25 Avoid contact with skin and eyes
S26 In case of contact with eyes, rinse immediately with plenty of water
and seek medical advice
S37 Wear suitable gloves.
b) Other Regulations
Health & Safety at Work etc. Act 1974
Control of Substances Hazardous to Health Regulations 1994
Environmental Protection Act 1990
Special Waste Regulations 1996
This Safety Data Sheet is compiled with reference to The Chemicals (Hazard Information and
Packaging for Supply) regulations 1994 (CHIP2), which implement the Council Directives
67/548/EEC (The Dangerous Substances Directive) and 88/379/EEC (The Dangerous
Preparations Directive), and subsequent amending regulations, up to and including The
Chemicals (hazard Information and Packaging for Supply) Regulations 2000 (CHIP2000), which
implements the 26th ATP of 67/548/EEC/
16. Other Information
The information in this safety data sheet was obtained from reputable sources and to the best of
our knowledge is accurate and current at the mentioned date.
Neither Eximcorp India Pvt Ltd nor its distributor companies accept any liability arising out of the
use of the information provided here or the use, application or processing of the product(s)
described herein.
Attention of users is drawn to the possible hazards from improper use of the product(s).
This safety data sheet was prepared in accordance with Commission Directive 2001/59/EC
adapting to technical progress for the 28th time Council Directive 67/548/EEC and Commission
Directive 1999/45/EC
|