Material Safety Data Sheet
DOT / TDG Pictograms WHMIS Classification PROTECTIVE CLOTHING
NFPA Classification
Flammability
0
Health Reactivity
1 0
Specific Hazard
Section I. Chemical Product and Company Identification
PRODUCT NAME/ Kapuskasing Pit Run Phosphate Ore
TRADE NAME
14235
MSDS NUMBER:
SYNONYM Phosphate rock
Kap Rock
REVISION NUMBER 4.1
CHEMICAL NAME Fluoroapatite
Mineral ore from the Kapuskasing area of Ontario, MSDS prepared by the Environment, Health
CHEMICAL FAMILY
containing oxides of phosphorous, iron, aluminum, and Safety Department on:
calcium, sodium, magnesium, silicon and small September 12, 2001
amounts of fluorides.
CHEMICAL FORMULA Ca10F2(PO4)6 24 HR EMERGENCY TELEPHONE
NUMBER:
MATERIAL USES Agricultural use: Raw material in the production of
fertilizer. Transportation Emergency: 1 (800) 792-8311
Medical Emergency: 1 (888) 670-8123
Redwater site only: 6060
Kapuskasing site only: 222
MANUFACTURER SUPPLIER
Agrium
Agrium
North American Wholesale
North American Wholesale
13131 Lake Fraser Drive, S.E.
13131 Lake Fraser Drive, S.E.
Calgary, Alberta, Canada, T2J 7E8
Calgary, Alberta, Canada
T2J 7E8
Agrium U.S. Inc.
Suite 1700, 4582 South Ulster St.
Denver, Colorado, U.S.A., 80237
Section II. Hazardous Ingredients
Exposure Limits (ACGIH)
TLV- TLV- STEL STEL CEIL CEIL % by
mg/m3 mg/m3
NAME CAS # TWA TWA ppm ppm Weight
mg/m3 ppm
Fluoroapatite 1306-05-4 10 > 95
Silica, crystalline (quartz) 14808-60-7 0.1 1-3
Silica, crystalline (cristobalite) 7631-86-9 0.05 1-3
TOXICOLOGICAL DATA ON Phosphate rock
INGREDIENTS LD50: > 3g/kg
Section III. Hazards Identification.
POTENTIAL ACUTE HEALTH A dusty material if allowed to dry out due to the fine size of the particles. This product may
EFFECTS irritate the eyes, nose, throat and skin upon prolonged or repeated contact due to mechanical
action. Non-hazardous on ingestion. The material will pass through the digestive tract
unchanged and with no effect.
POTENTIAL CHRONIC
HEALTH EFFECTS
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Kapuskasing Pit Run Phosphate Ore Page Number: 2
Contains minor quantities of quartz and cristobalite. Prolonged or repeated overexposures
may cause progressive and permanent lung disorders, including silicosis. Quartz is classified
as a suspected human carcinogen by the American Conference of Governmental Industrial
Hygienists. Prolonged or repeated exposure to acid gases or mists from the digestion of
phosphate rock may cause skeletal or dental disorder (fluorosis).
Section IV. First Aid Measures
EYE CONTACT May cause eye irritation due to mechanical action. Rinse eyes with water to remove dust or
grit.
MINOR SKIN CONTACT No known toxic effect according to our database. May cause drying of the skin. Wash with
soap and water. If dryness occurs, use a moisturing lotion.
EXTENSIVE SKIN CONTACT No additional information.
MINOR INHALATION Inhalation of dust may produce irritation to the respiratory tract, characterized by sneezing and
coughing. Allow the person to rest in a well ventilated area. If irritation persists, seek medical
attention.
SEVERE INHALATION No additional information.
SLIGHT INGESTION The material is non-toxic on ingestion. The product will pass through the digestive tract
unchanged and with no effect. No specific treatment is required.
EXTENSIVE INGESTION No additional information.
Section V. Fire and Explosion Data
THE PRODUCT IS Non-flammable.
AUTO-IGNITION Not applicable.
TEMPERATURE
FLASH POINT Not applicable.
FLAMMABILITY LIMITS Not applicable.
PRODUCTS OF Not applicable.
COMBUSTION
FIRE HAZARD IN THE Not applicable.
PRESENCE OF VARIOUS
SUBSTANCES
This product is non-explosive.
EXPLOSION HAZARD IN THE
PRESENCE OF VARIOUS
SUBSTANCES
FIRE FIGHTING MEDIA AND Non combustible.
INSTRUCTIONS
SPECIAL REMARKS ON No additional information.
FIRE HAZARDS
SPECIAL REMARKS ON No additional information.
EXPLOSION HAZARDS
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Kapuskasing Pit Run Phosphate Ore Page Number: 3
Section VI. Accidental Release Measures
SMALL SPILL Use appropriate tools or equipment to place the spilled solid in a suitable container for use or
disposal. Flush or wash the contaminated surface.
LARGE SPILL No additional information.
Section VII. Handling and Storage
PRECAUTIONS If user operations generate dust, use ventilation to keep exposure to airborne contaminants
below the exposure limit. Watch for accumulation in low lying or confined areas.
STORAGE A dusty material if allowed to dry out. Moisture content of material (8-13% is sufficient to
reduce possibility for excessive dust levels. Protect from wind or airborne dust generation.
Material displays complex handling characteristics with bridging, fluid flow, and hard set-up
depending upon conditions of storage. Stockpiles of material may be unstable resulting in
slumping, cliffing, and sand-like characteristics. Ensure stabliity of stockpiled materials.
Section VIII. Exposure Controls/Personal Protection
Use process enclosures, local exhaust ventilation, or other engineering controls to keep
ENGINEERING CONTROLS
airborne levels below recommended exposure limits. If user operations generate dust, use
adequate local exhaust or general ventilation to keep exposure to airborne contaminants
below the exposure limits.
PERSONAL PROTECTION The selection of personal protective equipment varies, depending upon conditions of use.
Wear appropriate respiratory protection for dust when ventilation is inadequate. A filtering
facepiece dust mask is recommended for most applications if respiratory protection is
needed. Where skin and eye contact may occur as a result of brief periodic exposures, wear
long sleeved clothing, coveralls, chemical resistant gloves, and safety glasses with side
shields. A respiratory protection program that meets OSHA 29 CFR 1910.134 requirements
must be followed whenever workplace conditions warrant a respirator's use.
PERSONAL PROTECTION IN No further information.
CASE OF LARGE RELEASE
EXPOSURE LIMITS Occupational Exposure Limits are based on the content of cristalline silica in the produced
rock.
The ACGIH recommends the following Occupational Exposure Limits based on a 5% silica
content:
8 hr TWA: 1.0 mg/m3 as respirable dust.
12 hr TWA: 0.5 mg/m3 as respirable dust.
Federal, State or Provincial exposure limits may vary by jurisdiction. Consult local authorities
for acceptable exposure limits in your area.
Section IX. Physical and Chemical Properties
PHYSICAL STATE AND Solid.
APPEARANCE
COLOR
MOLECULAR WEIGHT 502.32 g/mole as fluroapatite May range from white to tan, sandy
brown to grey, or grey to black.
Earthy
ODOR
pH (10% SOLN/WATER) Not applicable.
BOILING POINT ODOR Not available.
Decomposes. (1100掳C or
THRESHOLD
2012掳F)
MELTING POINT Decomposes. (1100掳C or Not available.
TASTE
2012掳F)
VOLATILITY 8-13% (w/w) as water.
CRITICAL TEMPERATURE Not applicable.
Insoluble in cold water, hot water.
Not available
SPECIFIC GRAVITY g/cc SOLUBILITY
DISPERSION
BULK DENSITY Is not dispersed in cold water, hot
Not available.
PROPERTIES
kg/m3 ; lbs/ft3 water.
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Kapuskasing Pit Run Phosphate Ore Page Number: 4
VAPOR PRESSURE 0 mm of Hg (@ 20掳C) WATER/OIL DIST. Not available.
COEFF.
VAPOR DENSITY Not applicable.
Section X. Stability and Reactivity Data
The product is stable.
STABILITY
Not available.
INSTABILITY
TEMPERATURE
No additional information.
CONDITIONS OF
INSTABILITY
The product is stable.
INCOMPATABILITY WITH
VARIOUS SUBSTANCES
CORROSIVITY Low hazard for usual industrial or commercial handling.
SPECIAL REMARKS ON No additional information.
REACTIVITY
SPECIAL REMARKS ON
Non-corrosive.
CORROSIVITY
Section XI. Toxicological Information
Inhalation.
SIGNIFICANT ROUTES OF
EXPOSURE
LD50: > 3 g/kg.
TOXICITY TO ANIMALS
SPECIAL REMARKS ON Low toxicity for humans or animals under normal conditions of use.
TOXICITY TO ANIMALS
OTHER EFFECTS ON No additional information.
HUMANS
SPECIAL REMARKS ON No additional information.
CHRONIC EFFECTS ON
HUMANS
SPECIAL REMARKS ON No additional information.
OTHER EFFECTS ON
HUMANS
Section XII. Ecological Information
Not considered to be toxic to animals.
ECOTOXICITY
BOD and COD Not available.
PRODUCTS OF Resistant to degredation in the natural environment.
DEGRADATION
TOXICITY OF THE No additional remarks.
PRODUCTS OF
DEGRADATION
SPECIAL REMARKS ON THE No additional information.
PRODUCTS OF
DEGRADATION
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Kapuskasing Pit Run Phosphate Ore Page Number: 5
Section XIII. Disposal Considerations
WASTE DISPOSAL OR Recover and place material in a suitable container for intended use or disposal. Consult your
RECYCLING environmental advisor for information on disposal alternatives.
Section XIV. Transport Information
DOT / TDG CLASSIFICATION Not controlled under DoT (U.S.) or TDG (Canada).
PIN Not applicable (PIN and PG).
SPECIAL PROVISIONS FOR Not regulated under TDG
TRANSPORT
DOT (U.S.A) (Pictograms)
Section XV. Other Regulatory Information and Pictograms
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA): This product is on the Domestic
OTHER REGULATIONS
Substances List (DSL), and is acceptable for use under the provisions of CEPA.
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
TSCA (Toxic Substance Control Act): This product is listed on the TSCA Inventory.
OTHER CLASSIFICATIONS HCS (U.S.A.) HCS CLASS: May be toxic for the lungs.
Not available.
DSCL (EEC)
National Fire Protection Fire Hazard
Hazards presented under acute emergency
Association (U.S.A.)
0
conditions only: Reactivity
1
Health
0
Specific Hazard
TDG (Pictograms -
Canada)
DSCL (Europe)
Not Available
(Pictograms)
No Disponible
Pas Disponible
ADR (Europe)
Not Available
(Pictograms)
No Disponible
Pas Disponible
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Kapuskasing Pit Run Phosphate Ore Page Number: 6
Section XVI. Other Information
REFERENCES -TOMES Plus庐, Vol 43, Jan 2000, Micromedex Inc.
-American Conference of Governmental Industrial Hygienists, TLVsTM an other Occupational
Exposure Values, 2000.
-Corrosion Data Survey, Sixth Edition, 1985, National Association of Corrosion Engineers.
-The Transportation of Dangerous Goods Act (1992) and Regulations, Transport Canada.
-Fire Protection Guide to Hazardous Materials, (NFPA49, 325M, 491M, and 704), National Fire
Protection Association, 10th Ed, 1991.
-29 CFR Part 1910
-40 CFR Parts 1-799
-49 CFR Parts 1-199
OTHER SPECIAL No additional information.
CONSIDERATIONS
FOR FURTHER SAFETY, HEALTH, OR AGRIUM
ENVIRONMENTAL INFORMATION ON Environment, Health and Safety Department
THIS PRODUCT, CONTACT Telephone (780) 998-6134 or Fax (780) 998-6143
NOTICE TO READER
The buyer assumes all risk in connection with the use of this material. The buyer assumes all responsibility for
ensuring this material is used in a safe manner in compliance with applicable environmental, health and safety laws,
policies and guidelines. Agrium Inc. assumes no responsibility or liability for the information supplied on this sheet,
including any damages or injury caused thereby. Agrium Inc. does not warrant the fitness of this material for any
particular use and assumes no responsibility for injury or damage caused directly or indirectly by or related to the use
of the material. The information contained in this sheet is developed from what Agrium Inc. believes to be accurate
and reliable sources, and is based on the opinions and facts available on the date of preparation.
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