MSDS# KO
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* MATERIAL SAFETY DATA SHEET *
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SECTION I--PRODUCT IDENTIFICATION
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PRODUCT NAME: UVIJET ACUITY KO SERIES
KO-004 KO-052 KO-215 KO-867)
PRODUCT USE : ULTRAVIOLET CURABLE INK JET PRINTING INKS
SUPPLIER NAME AND ADDRESS: MANUFACTURER NAME AND ADDRESS:
FUJIFILM SERICOL CANADA LTD. REFER TO SUPPLIER
39 RIVIERA DRIVE, UNIT #6
MARKHAM, ONTARIO CANADA L3R 8N4
EMERGENCY TELEPHONE #: (816)-587-8178
WHMIS CLASS: D2B
HMIS RATING: HEALTH: 2; FLAMMABILITY: 1; REACTIVITY: 1
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SECTION II--HAZARDOUS INGREDIENTS
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LC50 ppm LD50 mg/kg
INGREDIENTS CAS# WEIGHT % (INHALATION, RAT) (ORAL, RAT)
DIPROPYLENE GLYCOL 57472-68-1 50-100 n/av >5,000
DIACRYLATE
TRIMETHYLBENZOYL 75980-60-8 5-10 n/av >5,000
PHOSPHINE OXIDE
2-HYDROXY-4-HYDROXY 106797-53-9 1-5 n/av 3,108
ETHOXY-2-METHYLPROPIOPHENONE (Dermal, rats >5,000)
2-BENZYL-2-DIMETHYL 119313-12-1 1-5 n/av >5,000
AMINO-4-MORPHOLINOBUTYROPHENONE (Dermal, rats >2,000)
CARBON BLACK 1333-86-4 1-5 n/av >8,000
(used in KO-004)
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SECTION III -- PHYSICAL DATA
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PHYSICAL STATE, ODOUR AND APPEARANCE: LIQUID.
ODOUR THRESHOLD: N/AV.
SPECIFIC GRAVITY: 1.1.
COEFFICIENT OF WATER/OIL DISTRIBUTION: N/AV.
VAPOUR PRESSURE (mm/hg @ 20 C): <1
BOILING POINT: 100 C.
FREEZING POINT: N/AV.
pH: N/AV.
VAPOUR DENSITY: (AIR = 1): >1.
EVAPORATION RATE (DIETHYL ETHER = 1): <1.
VOLATILES, ORGANIC %: NONE.
SOLUBILITY IN WATER: N/AV.
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SECTION IV -- PHYSICAL HAZARD DATA
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CONDITIONS OF FLAMMABILITY: REFER TO FLASH POINT.
MEANS OF EXTINCTION: CLASS "B" FIRE EXTINGUISHER USED PER INSTRUCTIONS
(ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER FOG).
SENSITIVITY TO MECHANICAL IMPACT/STATIC DISCHARGE: N/AV.
FLASH POINT (METHOD): >200 F (>92 C) (CLOSED CUP).
LOWER FLAMMABLE LIMITS (% BY VOLUME): N/AV.
UPPER FLAMMABLE LIMITS (% BY VOLUME): N/AV.
AUTO-IGNITION TEMPERATURE: N/AV.
HAZARDOUS COMBUSTION PRODUCTS: SEE "HAZARDOUS DECOMPOSITION PRODUCTS".
UNUSUAL FIRE AND EXPLOSION HAZARDS:
HIGH TEMPERATURES/INHIBITOR DEPLETION/ACCIDENTAL IMPURITIES/EXPOSURE
TO RADIATION/OXIDIZERS MAY CAUSE SPONTANEOUS POLYMERIZING REACTION,
GENERATING HEAT/PRESSURE. CLOSED CONTAINERS MAY RUPTURE/EXPLODE
DURING RUNAWAY POLYMERIZATION.
SPECIAL FIREFIGHTING PROCEDURES:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTION. SEE SECTION ON
DECOMPOSITION PRODUCTS POSSIBLE. FIGHT FIRE FROM SAFE
DISTANCE/PROTECTED LOCATION. HEAT/IMPURITIES MAY INCREASE
TEMPERATURE/BUILD PRESSURE/RUPTURE CLOSED CONTAINERS, SPREADING
FIRE, INCREASING RISK OF BURNS/INJURIES. WATER MAY BE INEFFECTIVE
IN FIREFIGHTING DUE TO LOW SOLUBILITY. USE WATER SPRAY/FOG FOR
COOLING. PRESSURE RELIEF SYSTEM MAY PLUG WITH SOLIDS, INCREASING
RISK OF OVERPRESSURE. NOTIFY AUTHORITIES IF LIQUID ENTERS
SEWER/PUBLIC WATERS.
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SECTION V -- REACTIVITY DATA
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STABILITY: THIS MIXTURE IS POTENTIALLY UNSTABLE AND HAZARDOUS
POLYMERIZATION MAY OCCUR IF EXPOSED TO INCOMPATIBLE MATERIALS AND
CONDITIONS OF REACTIVITY.
INCOMPATIBLE MATERIALS: STRONG ACIDS, OXIDIZERS, ALKALI METAL HYDROXIDES,
POLYMERIZATION INITIATORS, PEROXIDES, INERT GASES.
CONDITIONS TO REACTIVITY: EXTREME TEMPERATURES, DIRECT SUNLIGHT, X-RAY
SOURCES, ELECTRON BEAM SOURCES, OR ULTRAVIOLET RADIATION SOURCES.
HAZARDOUS DECOMPOSITION PRODUCTS: CARBON MONOXIDE, CARBON DIOXIDE,
MIXED OXIDES OF NITROGEN, OXIDES OF PHOSPHORUS.
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SECTION VI -- TOXICOLOGICAL PROPERTIES
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***ROUTES OF EXPOSURE AND ACUTE/CHRONIC EFFECTS***
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EXPOSURE LIMIT: ACGIH-TLV-TWA: 3.5 mg/m FOR CARBON BLACK.
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OSHA-PEL-TWA : 3.5 mg/m FOR CARBON BLACK.
DERMAL IS THE PRIMARY ROUTE OF ENTRY.
IRRITANCY OF PRODUCT: SKIN, EYES AND RESPIRATORY TRACT.
INHALATION: EXPOSURE TO VAPOURS IS UNLIKELY DUE TO LOW VAPOR PRESSURE
OF INGREDIENTS, BUT INHALATION OF MIST, AEROSOLS, OR VAPOURS MAY RESULT
IN IRRITATION OF RESPIRATORY TRACT, COUGHING, SHORTNESS OF BREATH AND
DIZZINESS.
SKIN: MAY CAUSE MODERATE SKIN INJURY (REDDENING AND SWELLING)
AND/OR SENSITIZATION. PROLONGED CONTACT MAY CAUSE BLISTER FORMATION
(BURNS) AND DERMATITIS. SINCE IRRITATION MAY NOT OCCUR IMMEDIATELY,
CONTACT CAN GO UNNOTICED. CONTAINS MATERIALS THAT MAY BE SLIGHTLY TOXIC
IF ABSORBED THROUGH THE SKIN.
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EYES: MAY CAUSE EYE INJURY WHICH MAY PERSIST FOR SEVERAL DAYS.
WILL CAUSE PAINFUL BURNING OR STINGING OF EYES AND LIDS, WATERING OF EYES
AND INFLAMMATION OF CONJUNCTIVA.
INGESTION: MAY CAUSE IRRITATION OF MOUTH AND THROAT, NAUSEA AND VOMITING.
CONTAINS MATERIAL THAT MAY BE SLIGHTLY TOXIC.
MEDICAL CONDITIONS KNOWN TO BE AGGRAVATED BY OVEREXPOSURE: LUNG
CONDITIONS, SENSITIZATIONS, OR ALLERGIES, SKIN AND EYE CONDITIONS.
CHRONIC EFFECTS: BASED ON ANIMAL STUDIES, REPEATED OR PROLONGED EXPOSURE
TO THE PHOTOINITIATOR MAY CAUSE SKIN, BLOOD, LIVER, KIDNEY AND TESTICULAR
EFFECTS.
CARCINOGENICITY: NTP? NO IARC? CARBON BLACK - 2B OSHA? NO
TERATOGENICITY, MUTAGENICITY, OTHER REPRODUCTIVE EFFECTS: NONE KNOWN.
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SECTION VII -- FIRST-AID
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PRIMARY ROUTES OF ENTRY ARE DERMAL.
INHALATION: REMOVE VICTIM TO A WELL VENTILATED AREA. GIVE OXYGEN
OR ARTIFICIAL RESPIRATION AS REQUIRED. TREAT SYMPTOMATICALLY AND
CONSULT PHYSICIAN.
SKIN: REMOVE CONTAMINATED CLOTHING. WASH THOROUGHLY WITH MILD SOAP AND
WARMWATER. CONSULT A PHYSICIAN IF THERE IS ANY PERSISTING IRRITATION.
EYES: FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST FIFTEEN MINUTES.
CONSULT PHYSICIAN.
INGESTION: DRINK TWO GLASSES OF WATER TO DILUTE. DO NOT INDUCE
VOMITING. CONSULT PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. TREAT SYMPTOMATICALLY.
BE PREPARED TO PROVIDE THE ATTENDING PHYSICIAN WITH A COPY OF THIS
DOCUMENT.
SPECIAL NOTES TO ATTENDING PHYSICIAN: THERE IS NO SPECIFIC ANTIDOTE.
TREATMENT OF OVEREXPOSURE SHOULD BE DIRECTED AT CONTROL OF THE SYMPTOMS
AND THE CLINICAL CONDITION.
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SECTION VIII -- PREVENTIVE MEASURES
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PRECAUTIONS IF MATERIAL IS SPILLED OR RELEASED:
SPILLED/RELEASED MATERIAL MAY POLYMERIZE AND RELEASE HEAT/GASES.
EXTINGUISH ALL IGNITION SOURCES. BLANKET WITH FIREFIGHTING FOAM.
IMPOUND/RECOVER LARGE LAND SPILL; SOAK UP SMALL SPILL WITH INERT
SOLIDS. ON WATER, CONTAIN/MINIMIZE DISPERSION/COLLECT. REPORT PER
REGULATORY REQUIREMENTS.
WASTE DISPOSAL METHODS:
CONTAMINATED PRODUCT/SOIL/WATER MAY BE RCRA/OSHA HAZARDOUS WASTE DUE
TO POTENTIAL FOR INTERNAL HEAT GENERATION (SEE 40 CFR 261 AND 29
CFR 1910). LANDFILL SOLIDS AT PERMITTED SITES. USE REGISTERED
TRANSPORTERS. BURN CONCENTRATED LIQUIDS IN SYSTEMS THAT USE
COMPATIBLE FUEL. DILUTE WITH CLEAN, LOW VISCOSITY FUEL. AVOID
FLAMEOUTS. ASSURE EMISSIONS COMPLY WITH APPLICABLE REGULATIONS.
DILUTE AQUEOUS WASTE MAY BIODEGRADE. AVOID OVERLOADING/POISONING
PLANT BIOMASS. ASSURE EFFLUENT COMPLIES WITH APPLICABLE REGULATIONS.
***PROTECTIVE EQUIPMENT***
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RESPIRATORY PROTECTION: DUE TO LOW VAPOUR PRESSURE, INHALATION IS NOT
CONSIDERED AN OCCUPATIONALLY SIGNIFICANT ROUTE OF EXPOSURE, HOWEVER,
A NIOSH-APPROVED RESPIRATOR IS RECOMMENDED FOR OPERATIONS RESULTING IN
EXCESS ORGANIC VAPOURS IN THE BREATHING ZONE.
VENTILATION REQUIREMENTS: LOCAL EXHAUST RECOMMENDED WHEN APPROPRIATE
TO CONTROL EXPOSURE TO MIST OR AEROSOLS. GENERAL EXHAUST IS NORMALLY
ADEQUATE TO MINIMIZE EXPOSURE TO VAPOURS.
PROTECTIVE GLOVES: RUBBER OR NEOPRENE TO MINIMIZE SKIN CONTACT.
EYE PROTECTION: SAFETY GOGGLES OR FULL FACE SHIELD WHENEVER A SPLASH
HAZARD IS PRESENTED.
OTHER PROTECTIVE EQUIPMENT: IMPERMEABLE APRONS AND BOOTS. SAFETY SHOWER
AND EYE BATH SHOULD BE MADE AVAILABLE.
***STORAGE AND HANDLING***
HANDLING: AVOID SKIN OR EYE CONTACT. WASH HANDS BEFORE EATING, USING
TOBACCO PRODUCTS, OR USING THE WASHROOM. TOBACCO AND FOOD SHOULD BE
CONSUMED IN DESIGNATED AREAS ONLY.
STORAGE REQUIREMENTS: STORE IN A COOL, DRY, WELL-VENTILATED AREA, AWAY
FROM INCOMPATIBLE MATERIALS AND CONDITIONS. AVOID PROLONGED STORAGE AT
TEMPERATURES IN EXCESS OF 100 DEGREES F (37.8 C).
OTHER PRECAUTIONS: LEATHER GLOVES, APRONS, BELTS, OR BOOTS MAY BE
PERMEATED BY THESE MATERIALS, CAUSING DELAYED AND PERSISTENT IRRITATION OR
CHEMICAL BURNS. LEATHER ITEMS SHOULD BE DISPOSED OF, ONCE CONTAMINATED.
PROTECT AGAINST THE INHALATION OF DUST OR PARTICLES GENERATED BY SANDING,
BLASTING, OR ABRADING OF THE DRIED COATING.
SPECIAL SHIPPING INFORMATION: SHIP ACCORDING TO TDG REGULATIONS.
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SECTION IX -- PREPARATION INFORMATION
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PREPARED BY: FUJIFILM SERICOL USA, INC.
TELEPHONE#: (913) 342-4060
PREPARATION DATE: MAY 29, 2007.
REVISIONS: SECTION II.
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SECTION X -- DISCLAIMER
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FUJIFILM SERICOL USA, INC. MAKES NO WARRANTY, EXPRESSED OR IMPLIED, AS
TO THE ACCURACY OR RELIABILITY OF INFORMATION CONTAINED HEREIN, EXCEPT
THAT SUCH INFORMATION IS, TO THE BEST OF FUJIFILM SERICOL 'S KNOWLEDGE
AND BELIEF, ACCURATE AS OF THE DATE INDICATED ON THIS DOCUMENT. FINAL
DETERMINATION OF SUITABILITY OF ANY MATERIAL IS THE SOLE RESPONSIBILITY
OF THE USER. ALL MATERIALS MAY PRESENT UNKNOWN HEALTH HAZARDS AND SHOULD
BE USED WITH CAUTION. ALTHOUGH CERTAIN HAZARDS ARE DESCRIBED HEREIN, WE
CANNOT GUARANTEE THAT THESE ARE THE ONLY HAZARDS THAT EXIST.
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SECTION XI -- PURCHASERS' OBLIGATIONS
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FUJIFILM SERICOL USA, INC. URGES THE CUSTOMER RECEIVING THIS MATERIAL
SAFETY DATA SHEET TO STUDY IT CAREFULLY TO BECOME AWARE OF HAZARDS, IF
ANY, OF THE PRODUCTS INVOLVED. IN THE INTEREST OF SAFETY, YOU SHOULD (1)
NOTIFY YOUR EMPLOYEES, AGENTS, AND CONTRACTORS OF THE INFORMATION ON
THIS SHEET, (2)FURNISH A COPY TO EACH OF YOUR CUSTOMERS FOR THIS PRODUCT,
AND (3) REQUEST YOUR CUSTOMERS TO INFORM THEIR EMPLOYEES, CUSTOMERS, AND
AGENTS, AS WELL.
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MSDS# KO
***ADDITIONAL NOTES OR REFERENCES***
ABBREVIATIONS:
N/AV: NOT AVAILABLE
N/AP: NOT APPLICABLE
NIOSH: NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH
TDG: TRANSPORTATION OF DANGEROUS GOODS ACT AND REGULATIONS
REFERENCES:
1. ACGIH, GUIDE TO OCCUPATIONAL EXPOSURE VALUES - 2007.
2. MANUFACTURER OF COMPONENTS MATERIAL SAFETY DATA SHEETS.
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