SAFETY DATA SHEET according to EC directive 2001/58/EC
EXCALIBUR庐
Version 2.2
Revision Date 16.08.2004 Ref. 130000000485
This SDS adheres to the standards and regulatory requirements of Great Britain and may not meet the regulatory
requirements in other countries.
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING
Product information
庐
Product name : EXCALIBUR
Synonyms : B11620009
Use of the : herbicide
Substance/Preparation
Company : Du Pont (U.K.) Limited
Wedgwood Way
SG1 4QN Stevenage, Herts SG1 4QN
Telephone : +4401438734450
Telefax :
Emergency telephone : +44-(0)2871-861.313
number
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS-No. EC-No. Classification Concentration [%]
Flupyrsulfuron 144740-54-5 30
N; R50 -R53
Tribenuron methyl 101200-48-0 401-190-1 R43 30
For the full text of the R phrases mentioned in this Section, see Section 16.
3. HAZARDS IDENTIFICATION
May cause sensitization by skin contact.
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
4. FIRST AID MEASURES
General advice : Never give anything by mouth to an unconscious person. For specialist advice
physicians should contact the National Poisons Information Service, (24-hr), Tel:
0870-600-6266.
Inhalation : Move to fresh air. Oxygen or artificial respiration if needed. Consult a physician.
Skin contact : Wash off immediately with soap and plenty of water. If skin irritation persists, call
a physician.
Eye contact : Rinse thoroughly with plenty of water, also under the eyelids. Keep eye wide
open while rinsing. Consult a physician.
Ingestion : Drink 1 or 2 glasses of water. Do not induce vomiting without medical advice.
Consult a physician.
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SAFETY DATA SHEET according to EC directive 2001/58/EC
EXCALIBUR庐
Version 2.2
Revision Date 16.08.2004 Ref. 130000000485
5. FIRE-FIGHTING MEASURES
Suitable extinguishing : water spray, foam, dry chemical, carbon dioxide (CO2),
media
Extinguishing media which : high volume water jet, (contamination risk),
must not be used for safety
reasons
Special protective : In the event of fire, wear self-contained breathing apparatus.
equipment for fire-fighters
Further information : (on small fires) If area is heavily exposed to fire and if conditions permit, let fire
burn itself out since water may increase the area contaminated. Cool containers
/ tanks with spray water.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Wear personal protective equipment.
Environmental precautions : Do not flush into surface water or sanitary sewer system. Do not allow material
to contaminate ground water system.
Methods for cleaning up : Clean up promptly by scoop or vacuum. Use approved industrial vacuum
cleaner for removal. Shovel into suitable container for disposal. If spill area is on
ground near valuable plants or trees, remove 5 cm of top soil after initial clean-
up.
7. HANDLING AND STORAGE
Handling
Advice on safe handling : Provide appropriate exhaust ventilation at places where dust is formed. Wear
personal protective equipment.
Advice on protection : Keep away from heat and sources of ignition.
against fire and explosion
Storage
Requirements for storage : Keep containers tightly closed in a dry, cool and well-ventilated place. Store in a
areas and containers place accessible by authorized persons only. Keep away from food, drink and
animal feeding stuffs. Keep out of reach of children.
Advice on common storage : No materials to be specially mentioned.
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SAFETY DATA SHEET according to EC directive 2001/58/EC
EXCALIBUR庐
Version 2.2
Revision Date 16.08.2004 Ref. 130000000485
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Components with workplace control parameters
Components CAS-No. Type Control Update Basis
parameters
Kaolin 1332-58-7 TWA 2 mg/m3 2003 EH40 OES
Engineering measures
Ensure adequate ventilation, especially in confined areas.
Personal protective equipment
Respiratory protection : Half mask with a particle filter P2 (EN 143).
Hand protection : Material: nitrile rubber
Glove thickness: 0,4 - 0,7 mm
Wearing time: > 480 min
Do not wear cotton or leather gloves., Take note of the information given by the
producer concerning permeability and break through times, and of special
workplace conditions (mechanical strain, duration of contact).
Eye protection : safety glasses with side-shields conforming to EN166
Skin and body protection : lightweight protective clothing
Hygiene measures : Wash hands before breaks and immediately after handling the product. When
using, do not eat, drink or smoke. For environmental protection remove and
wash all contaminated protective equipment before re-use. Dispose of rinse
water in accordance with local and national regulations.
Protective measures : All chemical protective clothing should be visually inspected prior to use.
Clothing and gloves should be replaced in case of chemical or physical damage
or if contaminated.
9. PHYSICAL AND CHEMICAL PROPERTIES
Form : solid, dry flowable granules,
Colour : tan, beige,
Odour : none,
pH : 6,3 at 10 g/l ( 20 掳C)
Flash point : not applicable
Explosive properties : Not explosive
Bulk density : 693 kg/m3
Water solubility : , dispersible
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SAFETY DATA SHEET according to EC directive 2001/58/EC
EXCALIBUR庐
Version 2.2
Revision Date 16.08.2004 Ref. 130000000485
10. STABILITY AND REACTIVITY
Hazardous decomposition : hydrogen fluoride, Carbon oxides, nitrogen oxides (NOx)
products
Hazardous reactions : Dust may form explosive mixture in air. No decomposition if stored and applied
as directed.
11. TOXICOLOGICAL INFORMATION
Acute oral toxicity : no data available
(Data on the product itself)
Acute inhalation toxicity : no data available
Acute dermal toxicity : no data available
Skin irritation : no data available
Eye irritation : no data available
Sensitization : May cause sensitisation by skin contact.
12. ECOLOGICAL INFORMATION
Further information on ecology
Additional ecological : No data is available on the product itself.
information
13. DISPOSAL CONSIDERATIONS
Product : In accordance with local and national regulations. Must be incinerated in a
suitable incineration plant holding a permit delivered by the competent
authorities. Do not contaminate ponds, waterways or ditches with chemical or
used container.
Contaminated packaging : Do not re-use empty containers.
14. TRANSPORT INFORMATION
ADR
Class: 9
Packaging group: III
Classification Code: M7
HI No:: 90
UN-No: 3077
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SAFETY DATA SHEET according to EC directive 2001/58/EC
EXCALIBUR庐
Version 2.2
Revision Date 16.08.2004 Ref. 130000000485
Labelling No.: 9
Proper shipping name: Environmentally hazardous substance, solid, n.o.s. (Flupyrsulfuron methyl,
Tribenuron methyl)
IATA_C
Class: 9
Packaging group: III
UN-No: 3077
Labelling No.: 9MI
Proper shipping name: Environmentally hazardous substance, solid, n.o.s. (Flupyrsulfuron methyl,
Tribenuron methyl)
IMDG
Class: 9
Packaging group: III
UN-No: 3077
Labelling No.: 9
Proper shipping name: Environmentally hazardous substance, solid, n.o.s. (Flupyrsulfuron methyl,
Tribenuron methyl)
15. REGULATORY INFORMATION
Labelling according to EEC Directive
Symbol(s) : Xi Irritant
N Dangerous for the environment
Hazardous components: Flupyrsulfuron
Tribenuron methyl
R-phrase(s) : R43 May cause sensitization by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
S-phrase(s) : S2 Keep out of reach of children.
S13 Keep away from food, drink and animal feeding stuffs.
S20/21 When using, do not eat, drink or smoke.
S24 Avoid contact with the skin.
S37 Wear suitable gloves.
S35 This material and its container must be disposed of in a safe
way.
S57 Use appropriate containment to avoid environmental
contamination.
Exceptional labelling of : To avoid risks to man and the environment, comply with the instructions for use.
special preparations
16. OTHER INFORMATION
Text of R phrases mentioned in Section 2
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SAFETY DATA SHEET according to EC directive 2001/58/EC
EXCALIBUR庐
Version 2.2
Revision Date 16.08.2004 Ref. 130000000485
R43 May cause sensitization by skin contact.
R50 Very toxic to aquatic organisms.
R53 May cause long-term adverse effects in the aquatic environment.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at
the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in
combination with any other materials or in any process, unless specified in the text.
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