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MSDS Material Safety Data Sheet
CAS

128639-02-1
144740-54-5
126-86-3

File Name: fluorideaction_org---flupyrsulfuron.methyl.lexus.class.uk.asp
SAFETY DATA SHEET              according to EC directive 2001/58/EC



LEXUS庐 CLASS
Version 2.0
Revision Date 03.05.2004 Ref. 130000000607

This SDS adheres to the standards and regulatory requirements of Great Britain and may not meet the regulatory
requirements in other countries.

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING

Product information

Product name : LEXUS CLASS

Synonyms : B10355325

Use of the : herbicide
Substance/Preparation

Company : Du Pont (U.K.) Limited
Wedgwood Way
SG1 4QN Stevenage
Telephone : +441438734000
Telefax :

Emergency telephone : +44-(0)2871-861.313
number


2. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS-No. EC-No. Classification Concentration [%]
Carfentrazone ethyl 128639-02-1 33,3
N; R50 -R53

Flupyrsulfuron 144740-54-5 16,3
N; R50 -R53

Tetramethyl Decynediol 126-86-3 204-809-1 Xi; R36 -R52/53 3

For the full text of the R phrases mentioned in this Section, see Section 16.

3. HAZARDS IDENTIFICATION

May cause sensitization by skin contact.
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

4. FIRST AID MEASURES

General advice : Never give anything by mouth to an unconscious person. For specialist advice
physicians should contact the National Poisons Information Service, (24-hr), Tel:
0870-600-6266.

Inhalation : Move to fresh air.

Skin contact : Wash off immediately with soap and plenty of water.

Eye contact : Rinse thoroughly with plenty of water, also under the eyelids. Keep eye wide
open while rinsing. If eye irritation persists, consult a specialist.

Ingestion : Drink 1 or 2 glasses of water. Do not induce vomiting without medical advice.
Consult a physician.


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SAFETY DATA SHEET according to EC directive 2001/58/EC



LEXUS庐 CLASS
Version 2.0
Revision Date 03.05.2004 Ref. 130000000607



5. FIRE-FIGHTING MEASURES

Suitable extinguishing : water spray, foam, dry chemical, carbon dioxide (CO2),
media

Extinguishing media which : high volume water jet, (contamination risk),
must not be used for safety
reasons

Special protective : In the event of fire, wear self-contained breathing apparatus.
equipment for fire-fighters

Further information : (on small fires) Cool containers / tanks with spray water. If area is heavily
exposed to fire and if conditions permit, let fire burn itself out since water may
increase the area contaminated.


6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Wear personal protective equipment.

Environmental precautions : Do not flush into surface water or sanitary sewer system. Avoid subsoil
penetration.

Methods for cleaning up : Clean up promptly by scoop or vacuum. Use approved industrial vacuum
cleaner for removal. If spill area is on ground near valuable plants or trees,
remove 5 cm of top soil after initial clean-up. Shovel into suitable container for
disposal.


7. HANDLING AND STORAGE

Handling
Advice on safe handling : Provide appropriate exhaust ventilation at places where dust is formed.

Advice on protection : Keep away from heat and sources of ignition.
against fire and explosion


Storage
Requirements for storage : Keep containers tightly closed in a dry, cool and well-ventilated place. Store in a
areas and containers place accessible by authorized persons only. Keep out of the reach of children.

Advice on common storage : No materials to be specially mentioned.




2/6
SAFETY DATA SHEET according to EC directive 2001/58/EC



LEXUS庐 CLASS
Version 2.0
Revision Date 03.05.2004 Ref. 130000000607


8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Components with workplace control parameters
Components CAS-No. Type Control Update Basis
parameters
Siliciumdioxide, 7631-86-9 TWA 2,4 mg/m3 2003 EH40 OES
amorphopus TWA 6 mg/m3 2003 EH40 OES


Engineering measures
Ensure adequate ventilation, especially in confined areas.

Personal protective equipment
Respiratory protection : Half mask with a particle filter FFP2/FFP3 (EN149)

Hand protection : Material: butyl-rubber
Glove thickness: 0,4 - 0,7 mm
Wearing time: > 480 min
Please observe the instructions regarding permeability and breakthrough time
which are provided by the supplier of the gloves. Also take into consideration the
specific local conditions under which the product is used, such as the danger of
cuts, abrasion, and the contact time.

Eye protection : safety glasses

Skin and body protection : long sleeved clothing

Hygiene measures : Wash hands before breaks and immediately after handling the product. Keep
away from food, drink and animal feedingstuffs.

Protective measures : All chemical protective clothing should be visually inspected prior to use.
Clothing and gloves should be replaced in case of chemical or physical damage
or if contaminated.


9. PHYSICAL AND CHEMICAL PROPERTIES


Form : solid,

Colour : tan,

Odour : slight, characteristic,

pH : 8,4 at 10 g/l ( 20 掳C), Method: CIPAC MT 75

Flash point : not applicable

Explosive properties : Not explosive

Water solubility : , dispersible



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SAFETY DATA SHEET according to EC directive 2001/58/EC



LEXUS庐 CLASS
Version 2.0
Revision Date 03.05.2004 Ref. 130000000607


10. STABILITY AND REACTIVITY

Hazardous decomposition : hydrogen fluoride, Carbon oxides, nitrogen oxides (NOx), Hydrogen chloride
products gas,

Hazardous reactions : Risk of dust explosion. No decomposition if stored and applied as directed.


11. TOXICOLOGICAL INFORMATION

Acute oral toxicity : LD50/rat : > 5 000 mg/kg

Acute inhalation toxicity : no data available

Acute dermal toxicity : LD50/rat : > 2 000 mg/kg

Skin irritation : No skin irritation

Eye irritation : No eye irritation

Sensitization : Maximisation Test (GPMT) May cause sensitisation by skin contact.


Toxicity to reproduction
鈥? Tetramethyl Decynediol :

12. ECOLOGICAL INFORMATION


Ecotoxicity effects
Toxicity to fish : LC50/96 h/Rainbow trout: 5,1 mg/l


Toxicity to algae : EC50/120 h/selenastrum capricornutum: 0,036 mg/l


Aquatic toxicity : EC50/48 h/Daphnia: 48 mg/l




13. DISPOSAL CONSIDERATIONS

Product : In accordance with local and national regulations. Must be incinerated in a
suitable incineration plant holding a permit delivered by the competent
authorities. Do not contaminate ponds, waterways or ditches with chemical or
used container.

Contaminated packaging : Do not re-use empty containers.


14. TRANSPORT INFORMATION

ADR

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SAFETY DATA SHEET according to EC directive 2001/58/EC



LEXUS庐 CLASS
Version 2.0
Revision Date 03.05.2004 Ref. 130000000607

Class: 9
Packaging group: III
Classification Code: M7
HI No:: 90
UN-No: 3077
Labelling No.: 9
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains
Carfentrazone-ethyl, Flupyrsulfuron methyl)

IATA_C
Class: 9
Packaging group: III
UN-No: 3077
Labelling No.: 9MI
Proper shipping name: Environmentally hazardous substance, solid, n.o.s. (contains Carfentrazone-ethyl,
Flupyrsulfuron methyl)

IMDG
Class: 9
Packaging group: III
UN-No: 3077
Labelling No.: 9
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains
Carfentrazone-ethyl, Flupyrsulfuron methyl)



15. REGULATORY INFORMATION

Labelling according to EEC Directive
Symbol(s) : Xi Irritant
N Dangerous for the environment


Hazardous components: Carfentrazone ethyl
Flupyrsulfuron

R-phrase(s) : R43 May cause sensitization by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.


S-phrase(s) : S2 Keep out of reach of children.
S13 Keep away from food, drink and animal feedingstuffs.
S20/21 When using, do not eat, drink or smoke.
S46 If swallowed, seek medical advice immediately and show this
container or label.
S24 Avoid contact with the skin.
S35 This material and its container must be disposed of in a safe
way.
S37 Wear suitable gloves.
S57 Use appropriate containment to avoid environmental
contamination.




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SAFETY DATA SHEET according to EC directive 2001/58/EC



LEXUS庐 CLASS
Version 2.0
Revision Date 03.05.2004 Ref. 130000000607

Exceptional labelling of : To avoid risks to man and the environment, comply with the instructions for use.
special preparations


16. OTHER INFORMATION

Text of R phrases mentioned in Section 2
R36 Irritating to eyes.
R50 Very toxic to aquatic organisms.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R53 May cause long-term adverse effects in the aquatic environment.



The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at
the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in
combination with any other materials or in any process, unless specified in the text.




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