MATERIAL SAFETY DATA SHEET
ND
#1700, 407 2 STREET S.W., CALGARY, ALBERTA T2P 2Y3
TELEPHONE: (403) 269-2242 FAX: (403) 269-2251
1-613-996-6666 鈥? CANUTEC 鈥? Transportation Emergency
1-888-243-9771 鈥? ChExSS 鈥? Chemical Exposure
T 2001
SECTION I: IDENTIFICATION OF PRODUCT
Workplace Hazard: Corrosive, poison, toxic, irritant,
Product Name: T 2001
flammable.
Chemical Family: Mixture of aromatic hydrocarbons,
Product Use: Demulsifier
oxygenated aliphatic hydrocarbons, Organic acid and
TDG Classification: Class 3(8)
amine compounds.
Packaging Group: II
WHMIS Classification: B2, D1B, D2A, D2B, E
PIN: UN 2924
SECTION II: HAZARDOUS INGREDIENTS
Ingredients Percent CAS Number LD50 (Species/Route) LC50 (Species/Route)
Xylene 40-70 1330-20-7
Alkylaryl Sulphonic acid 10-30 Not Available
Petroleum Naphtha 5-10 68477-31-6
Ethyl Benzene 5-10 100-41-4
Methanol 5-10 67-56-1
Petroleum Naphtha 1-5 64742-94-5
Naphthalene 1-5 91-20-3
Sulphuric Acid 1-5 7664-93-9
Benzene Trace 71-43-2
SECTION III: TOXICOLOGICAL PROPERTIES
Route of entry: Skin Eye Contact Inhalation Ingestion
Potential Health Effects: Product may cause severe irritation to the nose, throat and respiratory tract. Brief contact causes
irritation (itching or possible swelling) to the skin. May cause more severe response if skin is abraded (scratched, scrapped or
cut). Burns (chemical) can occur if not promptly removed. May be absorbed through intact skin. Prolonged or wide spread skin
contact may result in the absorption of potentially harmful amounts of material.
Vapours from this product are irritating to the eyes. Splashes to the eye may cause severe irritation, redness and pain. Burns
(chemical) can occur if not promptly removed.
Ingestion is not a likely route of exposure. Corrosive! This product causes severe burning and pain in the mouth, throat and
abdomen. Vomiting, diarrhea and perforation of the esophagus and stomach lining may occur.
Other health effects: Corrosive effects on the skin and eyes may be delayed, and damage may occur without sensation or onset
pain. Strict adherence to first aid measure following any exposure is essential.
May cause intense thirst, circulatory collapse, cardiovascular effects, central nervous system (CNS) depression, liver damage,
kidney damage, asthenia, pulmonary edema, hearing loss and cardiac arrhythmia. CNS depression is characterized by headache,
dizziness, drowsiness, nausea, vomiting and incoordination, Severe overexposures may lead to coma and possible death due to
respiratory failure.
Aromatic hydrocarbons pose potential human health risks which may vary from person to person. Solvent abusers, exposed to
high doses of aromatic solvents show signs of hearing loss as well as damage to the brain, liver and kidney. Liver damage is
characterized by the loss of appetite, jaundice, and occasional pain in the upper-left hand side of the abdomen. Signs and
symptoms of kidney damage generally progress from oliguria, to blood in the urine, to total renal failure. The lack or loss of
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strength and energy is called asthenia. Pulmonary edema is the build up of fluid in the lungs that may be fatal. Symptoms of
pulmonary edema, such as shortness of breath, may not appear until several hours of exposure and are aggravated by physical
exertion.
Xylene may sensitize heat muscle causing cardiac arrhythmia, in rare cases.
Methanol may cause visual disturbances, blindness, photophobia, metabolic acidosis and endocrine effects. Mild blurring of
vision to complete blindness may occur, including changes in colour perception and photophobia. Symptoms usually develop 12-
18 hours after exposure. Abnormal sensitivity to light is termed photophobia. Metabolic acidosis is a condition that describes a
decreased pH and bicarbonate concentration in the body fluids.
Naphthalene may cause skin sensitization or other allergic responses.
Exposure limits:
Ingredients ACGIH TLV
Xylene 100ppm
Alkylaryl Sulphonic acid -
Petroleum Naphtha -
Ethyl Benzene 100 ppm
Methanol 200 ppm (skin)
Petroleum Naphtha -
Naphthalene 10 ppm (skin)
Sulphuric Acid 0.2 mg/m3
Benzene 0.5 ppm (skin)
Irritancy of product: Causes skin and eye burns. Mists or sprays are extremely irritant to eyes and respiratory tract.
Sensitization to product: May cause skin sensitization or other allergic responses.
******
Carcinogenicity: Classified as a suspected carcinogen by IARC. Although no direct link has been established between exposure
to Sulphuric Acid, itself, and cancer in man, exposure to strong inorganic acid mists containing Sulphuric Acid is carcinogenic to
man, causing cancer of the larynx and, to a lesser extent, the lung. Exposure to any mist or aerosol during the use of this product
should be avoided, keep exposure below the occupational exposure limit for Sulphuric Acid.
Reproductive toxicity: Not available
Teratogenicity: Excessive exposure to Xylene during pregnancy may be hazardous to the developing fetus. High exposure to
Xylene in some animal studies, often at levels toxic to the mother, affected embryo/fetal development. The significance of this
finding to humans is not known.
Mutagenicity: Not available
Name of toxicological synergistic products: Ethylbenzene
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SECTION IV: FIRST AID MEASURES
Skin contact: Prompt removal of the material from the skin is essential. Remove contaminated clothing and wash exposed areas
with water and soap for a minimum of 30 minutes. To prevent swelling and blistering immerse exposed area in ice water. Place
cold packs, ice or wet clothes on burned areas if immersion is not possible. Cover exposed area with clean, sterile, lint-free
dressing. Obtain medical attention immediately and monitor breathing and treat for shock for severe exposure.
Eye contact: Immediately flush eyes with running water for a minimum of 20 minutes. Hold eye lids open during flushing. If
irritation persists, repeat flushing. Obtain medical attention IMMEDIATELY. Do not transport victim until the recommended
flushing period is completed unless flushing can be continued during transport. Where possible, consult and ophthalmologist.
Inhalation: Move victim to fresh air. Give artificial respiration ONLY if breathing has stopped. Give cardiopulmonary
resuscitation (CPR) if there is no breathing AND no pulse. Oxygen administration may be beneficial in this situation but should
only be administered by personnel trained in its issue. Obtain medical attention IMMEDIATELY.
Ingestion: Do not attempt to give anything by mouth to an unconscious person. If victim is alert and not convulsing, rinse mouth
and give 陆 to 1 glass of water to dilute material. IMMEDIATELY contact local Poison Control Centre. Vomiting should only be
induced under the direction of a physician or a poison control centre. If spontaneous vomiting occurs, have victim lean forward
with head down to avoid breathing in vomitus, rinse mouth and administer more water. IMMEDIATELY transport victim to en
emergency facility.
SECTION V: PHYSICAL DATA
Physical state: Liquid
Appearance and odour: Dark red liquid, aromatic odour
Odour threshold: Not available
Specific gravity (潞C): 0.906 鈥? 0.927
Vapor pressure (mmHG): Not available
Vapor density (Air=1): Not available
Evaporation rate: Not available
Boiling point (潞C> 65
Freeze/Melting point (潞C): -35
pH (%): 8.0 (1% IPA/Water 50/50 v/v)
Co-efficient of water/oil distribution: Not available
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SECTION VI: FIRE AND EXPLOSION DATA
Conditions of flammability: Flammable liquid.
Means of extinguishing: Foam. Use carbon dioxide or dry chemical media for small fires. If only water is available, use it in the
form of a fog, This material may produce a floating hazard in extreme fire conditions.
Flash point: 11掳C (estimated)
Upper flammable limit: 36% in air (estimated)
Lower flammable limit: 1% in air (estimated)
Auto-ignition temperature: 312潞C (estimated)
Hazardous combustion products: Thermal decomposition products are toxic and may include ammonia, aldehydes, ketones,
formaldehyde, oxides of carbon, sulphur, nitrogen and irritating gases
Unusual fire or explosion hazards: Vapours from this product are heavier than air, and may 鈥渢ravel鈥? to a source of ignition (eg.
Pilot lights, heaters, electric motors) some distance away, and then 鈥渇lash back鈥? to the point of product discharge causing
explosion and fire. Avoid direct contact of this product with water as this can cause a violent exothermic reaction. Do not direct a
solid stream of foam into hot, burning pools. This may cause spattering and increase fire intensity. Closed containers exposed to
heat may explode. Spilled material may cause floors and contact surfaces to become slippery.
Explosion data-sensitivity to mechanical impact: Not expected to be sensitive to mechanical impact
Explosion data-sensitivity to static discharge: Expected to be sensitive to static discharge when vapours are present between the
lower and upper explosive limits/
SECTION VII: REACTIVITY DATA
Chemically unstable (conditions): Stable under normal conditions, flammable under fire conditions
Product incompatible with: Strong oxidizing and reducing agents. Lewis or mineral acids. Strong bases. Acid Chlorides. Acid
Anhydrides. Vinyl Chloride. Vinyl Acetate, Monomer. Acrylonitrile. Combustibles. Organic materials. Organic Anhydrides.
Organic Halides Aldehydes. Ketones Alkali metals and their hydroxides. Formates. Lactones. Halogens. Activated carbon.
Attacks some types of rubber, plastics and coatings. Aluminum and its alloys. Iron. Zinc and its alloys. Bronze. Brass. Copper
and its alloys. Cast iron. Mild steel. Magnesium. Carbon steel.
Conditions of reactivity: Mixtures or reactions with the following materials may cause explosions: barium, perchlorate, chlorine,
hypochlorus acid, ethylene oxide, hexamethylene diisocyanate and other isocyanates, nitrogen tetroxide, permonosulfuric acid
and tri-isobultyl aluminum.
Hazardous decomposition products: Thermal decomposition products are toxic and may include ammonia, aldehydes, Ketones,
formaldehyde, oxides of carbon, sulphur, nitrogen and irritating gases.
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SECTION VIII: PREVENTATIVE MEASURES
Personal protective equipment:
Eye protection: Safety glasses with side shields are recommended as minimal eye protection. Use full face shield or chemical
safety goggles where there is potential for contact. Contact lenses should not be worn when working with this material.
Skin Protection: Gloves and protective clothing made from butyl rubber should be impervious under conditions of use.
Product attacks some types of rubber, plastics and coatings. Do not use gloves or protective clothing made of natural rubber,
PVS, neoprene, Nitrile rubber or polyvinyl alcohol (PVA). Prior to use, user should confirm impermeability.
Respiratory Protection: No specific guidelines available for respiratory protection. A NIOSH/MHSA approved full face piece
air purifying respirator equipped with acid gas, dust, mist, fume cartridges for concentrations up to 20ppm. A
NIOSH/MSHA- approved full face piece air-supplied respirator if concentrations are higher or unknown.
Other Protective Equipment: Wear impermeable apron and boots. Locate safety shower and eyewash station close to
chemical handling area. Take all precautions to avoid personal contact. Clothing and footwear that is fire retardant and
dissipates static electrical changes should be worn when handling flammable materials, Natural fibers (cotton, wool, leather
and linen) should be selected in favour of synthetic material (rayon, nylon and polyester).
Specific engineering controls: Local exhaust ventilation required. Ventilation should be corrosion and explosion proof. Make
up air should be supplied to balance air that is removed by local or general exhaust ventilation. Ventilate low lying areas such as
sumps or pits where dense vapours may collect. For personnel entry into confines spaces a proper procedure must be followed. It
must include consideration of, among other things, ventilation, testing of tanks atmosphere, provision and maintenance of SCBA,
and emergency rescue. Use the 鈥榖uddy system鈥?. The second person should be in view and trained and equipped to execute a
rescue.
Procedures for leak/spills: Utilize a spill kit, if available. Wear respirator, protective gloves and clothing. Recover spilled
material on non-combustible absorbents, such as sand or vermiculite, and place in covered containers for disposal. Use spark
resistant tools,. Eliminate sources of ignition. Collect product for recovery or disposal. For release to land, or storm, water runoff,
contain discharge by constructing dikes or applying inert absorbent; for release to water, utilize damming and/or water diversion
to minimize the spread of contamination. Ventilate enclosed spaces. Notify applicable government authority if release is
reportable or could adversely affect the environment. Replace damaged containers immediately to avoid loss of material and
contamination of surrounding atmosphere.
Waste disposal: It is the responsibility of the user of this product to determine at the time of disposal whether product meets
criteria for hazardous waste. This is because product use, transformation, processed, mixtures, etc., may render a non-hazardous
material hazardous, or a hazardous material non-hazardous. Empty container retains product residue. Containers must be rinsed
before disposal or reuse. Observe all hazard precautions. Keep away from heat, sparks and flames. Do not weld or use a cutting
torch on or near container. Do not distribute, make available, furnish or reuse empty container except for storage and shipment of
original product. Remove all hazardous product residue and puncture or otherwise destroy empty container before disposal.
Handling procedures and equipment: Ground and bond equipment and containers to prevent a static charge buildup. Use spark
resistant tools and avoid 鈥渟plash-filling鈥? of containers. Use normal 鈥済ood鈥? industrial hygiene and housekeeping practices. Drums
which have been exposed to heat may be under internal pressure. These should be cooled and carefully vented before opening. A
face shield and apron should be worn. Vent container frequently, and more often in warm weather, to relieve pressure. Enforce
NO SMOKING rules in area of use.
Use only with adequate ventilation and avoid breathing vapours or mists. Avoid contact with eyes, skin or clothing. Wash
thoroughly before re-use. Absorption via contact with skin, eyes and mucous membranes can contribute to the overall exposure.
Consider measures to prevent absorption to these routes. Store wiping rags and similar material I metal cans with fitting leads.
Do not store or transport with food or feed.
Storage requirements: Store in a cool, well-ventilated area. Keep away from heat, sparks and flames. Keep containers closed.
Do not expose sealed containers to temperatures above 40oC. Storage tanks should be in a contained area to control any spills or
leaks. Storage area should be equipped with corrosion-resistant floors, sumps and should have controlled drainage to a recovery
tank.
Special shipping information: Flammable liquid, Corrosive. Methanol, Sulphonic Acid) Class 3 (8), UN12924, PGII.
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SECTION IX: PREPARATION
Date updated: September 25, 2006 Prepared by: Product Safety Committee
All the recommendations and suggestions herein concerning this product are based upon tests and data believed to be reliable,
however it is the user鈥檚 responsibility to determine the safety, toxicity and sustainability for their own use of the product described
herein. Since the actual use by others is beyond our control, no guarantee, expressed or implied, is made by Q鈥橫ax Solutions Inc.
as to the effects of such use, the results to be obtained, or the safety and toxicity of the product nor does Q鈥橫ax Solutions Inc.
assume any liability arising out of use by others. Nor is the information herein to be considered as absolutely complete since
additional information may be necessary or desirable when particular or exceptional conditions or circumstances exist or because
of applicable laws or government regulations.
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