Polyurethane Construction Adhesive
MATERIAL SAFETY DATA SHEET
(Complies with OSHA 29 CFR 1910.1200)
SECTION I: PRODUCT IDENTIFICATION
The QUIKRETE庐 Companies Emergency Telephone Number
One Securities Centre (770) 216-9580
3490 Piedmont Road, Suite 1300
Atlanta, GA 30329 Information Telephone Number
(770) 216-9580
MSDS X3
Revision: Feb-07
QUIKRETE庐 Product Name Code #
POLYURETHANE CONSTRUCTION ADHESIVE 9902-10
PRODUCT USE: ADHESIVE FOR USE IN GENERAL CONSTRUCTION
SECTION II 鈥? HAZARDS IDENTIFICATION
Please note that as a service to our customers, hazard warnings and information have been
included for ALL chemicals listed in this MSDS. However, not all of these chemicals are
defined as 鈥渉azardous鈥? by ISO or OSHA standards. Only those chemicals listed in Section 2 of
this MSDS are defined by ISO and/or OSHA as 鈥渉azardous鈥? based upon the properties and
concentrations of each chemical.
MOST IMPORTANT HAZARDS
EYE: Direct contact irritates moderately with redness and swelling. Calcium carbonate,
xylene, calcium oxide, and MDI may cause severe eye irritation, especially in dust
form. Butyl benzyl phthalate (BBP) may cause irritation with symptoms of redness
and itching.
SKIN: A single short exposure (less than 24 hours) may irritate. Repeated prolonged
contact (24 to 48 hours) may irritate moderately. Product contains calcium
carbonate, xylene, and calcium oxide, which are possible skin sensitizers.
Contact with BBP may cause irritation with symptoms of redness and itching. MDI
may cause irritation to the skin or mucous membranes. Ethyl benzene may be
absorbed through the skin.
INHALATION: Vapor overexposure, and/or inhalation of silica or calcium oxide dust may severely
irritate eyes, nose, throat, upper respiratory tract, and lungs. Vapor overexposure
may cause drowsiness. Excessive inhalation of calcium carbonate (dust form)
may result in shortness of breath or reduced pulmonary function. Inhalation of
high concentrations of BBP, xylene, or ethyl benzene may cause respiratory
irritation or difficulties and central nervous system effects characterized by
headache, nausea, dizziness, and/or drowsiness. MDI vapors or mist can cause
irritation of upper respiratory tract: signs/symptoms can include soreness of the
nose and throat, coughing, and sneezing. Persons previously sensitized to
isocyanates may experience an allergic respiratory reaction: signs/symptoms can
include difficulty breathing, wheezing, tightness of chest, and respiratory failure.
Overexposure to titanium dioxide (dust form) may cause pulmonary fibrosis
(scarring of the lungs).
ORAL: Small amounts transferred to the mouth by fingers during use, etc. should not
injure. Swallowing large amounts may cause digestive discomfort and gastrointestinal irritation.
Ingestion of BBP may cause central nervous system depression with symptoms seen in acute
inhalation. Ingestion of xylene may cause central nervous system effects. Aspiration of xylene or ethyl
benzene into lungs may cause chemical pneumonitis.
SECTION III - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION
This product consists of a mixture/preparation.
CAS INGREDIENT WT LETHAL DOSES EXPOSURE LIMITS
NO. %
TWA STEL Ceiling
3 3 3
ppm mg/m ppm mg/m ppm mg/m
85-68-7 Butyl Benzyl Phthalate 15-40 Inhalation TCLo 鈥? OSHA No exposure limit guidelines have been established
789 mg/m3/6hr (rat)
(BBP) for this material.
Oral LD50 鈥? NIOSH
2,330 mg/kg (rat)
Dermal LD50 鈥? ACGIH
6,700 mg/kg (rat) CANADA
1317-65- Calcium Carbonate a 15, 5 b
3-7 Oral LD50 鈥? -
OSHA - - - -
3 (Limestone) b
7,340 mg/kg (rat) NIOSH - 10, 5 - - - -
ACGIH - 10 - - - -
10, 5 b
CANADA - - - - -
1305-78- Calcium Oxide a 1-5 Not established OSHA - 5 - - - -
8 2c
NIOSH - - - - -
ACGIH - 2 - - - -
CANADA - 2 - 4 - -
Titanium dioxide a 15 d
13463- 1-5 Inhalation TCLo 鈥? OSHA - - - - -
250 mg/m3/6hr (rat)
67-7
Oral LD50 鈥? NIOSH e - - - - -
>24,000 mg/kg (rat)
Dermal LD50 鈥? ACGIH - 10 - - - -
>10,000 mg/m3 10, 5 b
CANADA - - - - -
(rabbit)
1330-20- Xylene 1-5 Inhalation LC50 鈥? OSHA 100 435 - - - -
7 5,000 ppm/4hr (rat)
CAS INGREDIENT WT LETHAL DOSES EXPOSURE LIMITS
NO. %
TWA STEL Ceiling
3 3 3
ppm mg/m ppm mg/m ppm mg/m
Oral LD50 鈥? NIOSH 100 435 150 655 - -
4,300 mg/kg (rat)
ACGIH f
Dermal LD50 鈥? 100 434 150 651 - -
>1,700 mg/kg CANADA 100 434 150 652 - -
(rabbit)
101-68-8 Diphenylmethane 0.5- Inhalation LC50 鈥? OSHA - - - - 0.02 0.2
1.5 178 mg/m3 (rat)
diisocyanate (MDI) g
0.2 g
NIOSH 0.005 0.050 - - 0.020
Oral LD50 鈥? ACGIH 0.005 0.051 - - - -
2,200 mg/kg CANAD
(mouse) A 0.005 0.051 - - 0.02 0.2
100-41-4 Ethyl benzene 0.1- Oral LD50 鈥?
1.0 3,500 mg/kg (rat) OSHA 100 435 - - - -
Dermal LD50 鈥?
17,800 碌L/kg (rabbit) NIOSH 100 435 125 545 - -
ACGIH f
Inhalation LCLo 鈥? 100 434 125 543 - -
4,000 ppm/4hr (rat) CANAD
A 100 434 125 542 - -
Silica, crystalline a 30, 10 b,
14808- < 0.1 Implant TDLo 鈥?
OSHA - - - - -
h
60-7 (Silica, quartz) 900 mg/kg (rat)
NIOSH - 0.5 - - - -
Inhalation TCLo 鈥?
0.5 i
ACGIH - - - - -
300 碌g/m3 (human)
Intravenous LDLo 鈥? CANAD 0.3, 0.1
- - - - -
b
A
40 mg/kg (mouse)
a
Under normal conditions of use, no respirable particles should be released from this product.
b
Total mass; respirable mass, respectively.
c
NIOSH permissible exposure limits for calcium oxide are as follows: TWA 2 mg/m3; IDLH 25 mg/m3
d
OSHA 鈥? Total dust.
e
NIOSH 鈥? No threshold has been determined; limit occupational exposure to lowest feasible
concentration.
f
ACGIH 鈥? Biological Exposure Index (BEI).
g
NIOSH 鈥? Value based on an exposure time of 10 minutes.
h
OSHA PEL: Silica, Crystalline (Silica, Quartz) 鈥? respirable dust: TWA 10 mg/m3 divided by
(%SiO2+2); total dust: TWA 30 mg/m3 divided by (%SiO2+2) (Source: NIOSH Pocket Guide to
Hazardous Chemicals).
i
Respirable mass.
SECTION IV 鈥? FIRST-AID PROCEDURES
INHALATION: Remove to fresh air. If ill effects persist get medical attention.
SKIN CONTACT: Remove from skin and wash thoroughly with soap and water or waterless
cleanser. Get medical attention if irritation or other ill effects develop or persist.
EYE CONTACT: Immediately flush with water for 15 minutes. Get medical attention.
INGESTION: Get medical attention.
COMMENTS: Treat according to person鈥檚 condition and specifics of exposure.
SECTION V 鈥? FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA: Carbon Dioxide (CO2), water fog dry chemical, foam.
UNSUITABLE EXTINGUISHING MEDIA: Water.
SPECIFIC FIRE HAZARDS: Precipitated calcium carbonate will ignite on contact with
fluorine.
FIRE FIGHTING PROCEDURES: Wear full protective clothing including helmet, self contained,
positive pressure or pressure demand breathing apparatus,
bunker coat and pants, bands around arms, waist, and legs,
face mask, and protective covering for exposed areas of the
head. Water may not effectively extinguish fire; however, it
should be used to keep fire-exposed containers and surfaces
cool and prevent explosive rupture. If large amount is
involved, evacuate area.
FLASH POINT (SETAFLASH): Greater than 65掳C (150掳F)
FLAMMABILITY LIMITS IN AIR (XYLENE): LEL: 1%
UEL: 8%
HAZARDOUS DECOMPOSITION
PRODUCTS: By high heat and fire: oxides of carbon, oxides of nitrogen,
and isocyanates.
SECTION VI 鈥? ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS: Observe all personal protective equipment recommendations
described in Sections 5 and 8.
ENVIRONMENTAL PRECAUTIONS: Disposal of collected product, residues, and cleanup materials
may be governmentally regulated. Observe all applicable local,
state and federal waste management regulations.
METHODS FOR CLEANING UP: Ventilate area. Extinguish all ignition sources. Contain spill.
Evacuate unprotected personnel from hazard area. Cover with
absorbent, place in approved drum; do not seal drum for 48 hours to
avoid possible pressure build-up. Local, state, and federal reporting
requirements may apply to spills or releases of this material into the
environment. See applicable regulatory compliance information in
Section 15.
SECTION VII 鈥? HANDLING AND STORAGE
HANDLING: Assure good ventilation
STORAGE: Eliminate sources of ignition. Store in original sealed containers
away from heat and moisture. Shelf-life 12 months at 73掳F and
50% relative humidity.
SECTION VIII 鈥? EXPOSURE CONTROL AND PERSONAL PROTECTION
ENGINEERING CONTROLS:
LOCAL EXHAUST: Recommended
GENERAL VENTILATION: Recommended
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION: Avoid eye contact. Use proper protection - safety glasses as a
minimum.
SKIN AND BODY PROTECTION: Avoid skin contact. Protect hands with impervious rubber gloves
and wear typical full cover clothing. Gloves must be checked before
each use for signs of degradation and penetration and for proper
functioning. Wear appropriate gloves when handling this product.
RESPIRATORY PROTECTION: Avoid breathing of vapors. Wear appropriate, properly fitted
NIOSH/MSHA approved respirator when the airborne contaminant
levels exceed the exposure limits indicated on the MSDS. Follow
respirator manufacturer鈥檚 directions for respirator use. Industrial
hygiene personnel can assist in judging the adequacy of existing
engineering controls.
HYGIENE MEASURES (INGESTION): Wash hands after handling and before eating.
PRECAUTIONARY MEASURES: Avoid eye contact. Avoid skin contact. Avoid breathing vapor.
Keep container closed. Do not take internally.
Note: These precautions are for room temperature handling. Use at elevated temperatures or aerosol
spray applications may require added precautions.
SECTION IX 鈥? PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: Solid (Paste)
COLOR: Various
ODOR: Slight odor of xylene
pH: Not Applicable
BOILING POINT (AT 760 MM HG): Not Applicable
FLASHPOINT: Greater than 65掳C (150掳F)
EXPLOSION PROPERTIES: Not Determined
VAPOR PRESSURE (AT 100掳F): Not Applicable
VAPOR DENSITY: 3.66 (Xylene)
DENSITY: 10.7 lb/gal
SOLUBILITY IN WATER (%): NIL
SPECIFIC GRAVITY (AT 77掳F/25掳C): 1.28
VISCOSITY (AT 77掳F/25掳C): Greater than 700,000 cps (@ 2 rpm)
FREEZING / MELTING POINT: Not Applicable
ODOR THRESHOLD: Not Determined
EVAPORATION RATE: Not Applicable
% VOLATILE BY VOLUME: Less than 6%
VOLATILE ORGANIC CONTENT (VOC): 3.53% by weight; 45 g/L (0.38 lbs/gal)
NOTE: The above information is not intended for use in preparing product specifications.
SECTION X 鈥? STABILITY AND REACTIVITY
CHEMICAL STABILITY: Stable
HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur.
CONDITIONS TO AVOID: Exposure to air or moisture until ready to use. Store
away from water or moisture as this will lead to
premature curing of the material.
MATERIALS TO AVOID: Amines, alcohol, and water will react with this
material. Water reacts with this material to form
carbon dioxide, which could result in the buildup of
pressure in a sealed container. But it is highly unlikely
that enough water will mix-in to form enough carbon
dioxide to present a hazardous situation. Avoid
oxidizers.
INCOMPATIBILITY: Note that precipitated calcium carbonate will ignite on
contact with fluorine. It is incompatible with acids,
alum, ammonia salts, and mercury + hydrogen
mixtures.
HAZARDOUS DECOMPOSITION
PRODUCTS: Oxides of carbon and oxides of nitrogen, isocyanates.
Also possible are oxides of sulfur, phenol, and
hydrogen cyanide.
SECTION XI 鈥? TOXICOLOGICAL INFORMATION
May cause respiratory sensitization, eye and skin irritation. May cause allergic respiratory and/or
allergic skin reaction. See Section 2 for exposure limits, Section 3 for exposure effects.
ACUTE TOXICITY:
Inhalation TCLo 鈥? 789 mg/m3/6hr (rat)
FOR BUTYL BENZYL PHTHALATE:
Oral LD50 鈥? 2,330 mg/kg (rat)
Dermal LD50 鈥? 6,700 mg/kg (rat)
FOR CALCIUM CARBONATE: Oral LD50 鈥? 7,340 mg/kg (rat)
FOR CALCIUM OXIDE: Not established.
Inhalation TCLo 鈥? 250 mg/m3/6hr (rat)
FOR TITANIUM DIOXIDE:
Oral LD50 鈥? >24,000 mg/kg (rat)
Dermal LD50 鈥? >10,000 mg/m3 (rabbit)
FOR XYLENE: Inhalation LC50 鈥? 5,000 ppm/4hr (rat)
Oral LD50 鈥? 4,300 mg/kg (rat)
Dermal LD50 鈥? >1,700 mg/kg (rabbit)
Inhalation LC50 鈥? 178 mg/m3 (rat)
FOR MDI:
Oral LD50 鈥? 2,200 mg/kg (mouse)
FOR ETHYL BENZENE: Oral LD50 鈥? 3,500 mg/kg (rat)
Dermal LD50 鈥? 17,800 碌L/kg (rabbit)
Inhalation LCLo 鈥? 4,000 ppm/4hr (rat)
FOR SILICA, QUARTZ: Implant TDLo 鈥? 900 mg/kg (rat)
Inhalation TCLo 鈥? 300 碌g/m3 (human)
Intravenous LDLo 鈥? 40 mg/kg (mouse)
CHRONIC TOXICITY:
SKIN: Repeat contact with skin may cause severe irritation, sensitization, or allergic
reaction. Prolonged skin contact with xylene or ethyl benzene may cause skin
irritation or dermatitis. Chronic exposure to calcium oxide may cause severe
corrosive damage.
INHALATION: Vapor overexposure may cause drowsiness, irritate eyes, nose, and throat, or
injure blood, liver, or central nervous system. Prolonged inhalation of dust
(including calcium carbonate, titanium dioxide, and silica in dust form) may cause
respiratory effects including shortness of breath, reduced pulmonary function, and
pulmonary fibrosis (scarring of the lungs). Chronic exposure to BBP by inhalation
may cause sleepiness, withdrawal and weight loss or decreased weight gain.
Chronic exposure to xylene may cause damage to the eyes, central nervous
system, bone marrow, liver, or kidneys. Chronic inhalation of calcium oxide may
cause inflammation and ulcers in the respiratory system. Chronic overexposure to
isocyanates (found in MDI) may cause lung damage and isocyanate sensitization
(chemical asthma), which may be temporary or permanent. Chronic inhalation of
ethyl benzene may have central nervous effects.
ORAL: Small amounts transferred to the mouth by fingers during use, etc. should not
injure. Swallowing larger quantities may have adverse effects depending on
quantity ingested. Repeated ingestion of BBP may cause sleepiness, withdrawal,
and weight loss or decreased weight gain. Ingestion of xylene may cause central
nervous system effects.
SPECIFIC EFFECTS:
This material contains the following components with the special hazards listed below.
Carcinogens: See below.
Teratogens: Xylene and ethyl benzene may cause teratogenic effects.
Titanium dioxide has caused teratogenic effects in laboratory
animals.
Mutagens: Positive and negative results have been observed 鈥渋n vitro鈥?
for MDI and ethyl benzene. For ethyl benzene, mutation in
mammalian somatic cells (Rodent, mouse) Lymphocyte =
80 mg/L.
Reproductive toxins: BBP, xylene, and ethyl benzene may cause reproductive
effects.
CARCINOGENICITY:
BUTYL BENZYL PHTHALATE: The IARC has evaluated this chemical and listed it as Group 3, not
classifiable as to its carcinogenicity to humans.
TITANIUM DIOXIDE: The IARC has evaluated this chemical and listed it as Group 3, not classifiable as
to its carcinogenicity to humans.
XYLENE: The IARC has evaluated this chemical and listed it as Group 3, not classifiable as to its
carcinogenicity to humans.
MDI: The IARC has evaluated this chemical and listed it as Group 3, not classifiable as to its
carcinogenicity to humans.
ETHYL BENZENE: The IARC has evaluated this chemical and listed it as Group 2B, possibly
carcinogenic to humans.
SILICA, QUARTZ: The IARC has evaluated this chemical and listed it as Group 1, carcinogenic.
SECTION XII 鈥? ECOLOGICAL INFORMATION
FOR BUTYL BENZYL PTHALATE:
Environmental Fate: Biodegradability is 50 鈥? 100% after 28 days.
Environmental Toxicity: LC50 (Pimephales promelas): 1.5-2.25 mg/L (96hr);
LC50 (Rainbow trout): 1.1 mg/L (96hr);
EC50 (Daphnia magna): 1.7 mg/L (48 hr);
EC50 (Green algae): 1.5 mg/L (72hr)
FOR CALCIUM CARBONATE:
Environmental Fate: This chemical is not expected to have a significant impact when
released into the environment.
Environmental Toxicity: TLm (Mosquito Fish): 240 ppm/24hr; 220 ppm/48hr; 160 ppm/96hr
at 70-73.5 degrees F (21-23 degrees C)
FOR CALCIUM OXIDE:
Environmental Fate: Not available.
Environmental Toxicity: This chemical is expected to be toxic to aquatic life.
TLm (Mosquito Fish): 240 ppm/24hr 鈥? toxic
TLm (Sunfish): 100 ppm/3hr 鈥? toxic
TLm (Vector snail): 300 ppm/24hr 鈥? lethal
FOR TITANIUM DIOXIDE:
Environmental Fate: Not available.
Environmental Toxicity: Not available.
FOR XYLENE:
Environmental Fate: When released into the soil, this material may evaporate to a
moderate extent. When released into the soil, this material is expected
to leach into groundwater. When released into the soil, this material may
biodegrade to a moderate extent. When released into water, this
material may evaporate to a moderate extent. When released into water,
this material may biodegrade to a moderate extent. When released into
the air, this material may be moderately degraded by reaction with
photochemically produced hydroxyl radicals. When released into the air,
this material is expected to have a half-life of less than 1 day. This
material is not expected to significantly bioaccumulate. [Mixed xylenes:
octanol / water partition coefficient 3.1 - 3.2; bioconcentration factor = 1.3
(eels).]
Environmental Toxicity: This material is expected to be slightly toxic to aquatic life.
LC50 鈥? Range 10-100 mg/L/96hr (fish)
FOR MDI:
Environmental Fate: Aquatic: Rapidly hydrolyzes to form an insoluble crust.
Terrestrial: Will bind with moist soil. No leaching will occur.
Atmospheric: Remains in the vapor phase and is degraded by
photochemically produced hydroxyl radicals (half-life is 32 hours).
Will not bioconcentrate or biodegrade.
Environmental Toxicity: This material may be toxic to some types of aquatic life.
LC50 鈥? >500 mg/L/24hr static (Daphnia magna, Limnea Stagnalis, and
Zebra fish).
FOR ETHYL BENZENE:
Environmental Fate: No information available.
Environmental Toxicity: This chemical is expected to be toxic to aquatic life.
Fish: Rainbow Trout: LC50 鈥? 14.0 mg/L/96hr
Static Bioassay Fish: Fathead Minnow: LC50 鈥? 12.1 mg/L/96hr
Flow-through Bioassay Fish: Bluegill/Sunfish: LC50 鈥? 150.0 mg/L/96hr
Static Bioassay, pH 6.5-7.9, 21-23 degrees C,
Water flea: EC50 鈥? 2.1 mg/L/48hr
Static Bioassay Water Flea: EC50 鈥? 75.0 mg/L/48hr
Static Bioassay Shrimp (mysidoposis bahia): LC50 鈥? 87.6 mg/L/96hr
Sheepshead Minnow: LC50 鈥? 275mg/L/96hr
Fathead Minnow: LC50 鈥? 42.3 mg/L/96hr in hard water, 48.5mg/L/96hr in
soft water.
FOR SILICA, QUARTZ:
Environmental Fate: Not available.
Environmental Toxicity: Not available.
SECTION XIII 鈥? DISPOSAL INFORMATION
PRODUCT DISPOSAL: RCRA Hazard Class (40 CFR 261)
When a decision is made to discard this material, as received, is it classified as a
hazardous waste? No
Federal Hazardous Waste Code: Not Applicable
Characteristic Waste: Ignitable: Not Applicable Corrosive: Not Applicable
Reactive: Not Applicable TCLP: Not Applicable
WASTE FROM RESIDUES
CONTAMINATED PACKAGING: Residues of hazardous waste in empty containers should be
managed according to 40 CFR 261.7
State or local laws may impose additional regulatory requirements regarding disposal.
SECTION XIV 鈥? TRANSPORT INFORMATION
DOT Information (49CFR 172.101)
PROPER SHIPPING NAME: Not Applicable
HAZARD CLASS: Not Applicable
UN / NA NUMBER: None
PACKING GROUP: Not Applicable
QUANTITY LIMITATIONS: Not Applicable
VESSEL STORAGE REQUIREMENTS: Not Applicable
SECTION XV 鈥? REGULATORY INFORMATION
US FEDERAL REGULATIONS:
Occupational Health and Safety Administration (OSHA)
Ingredients listed on National Toxicology Program (NTP) Annual Report on Carcinogens
The following ingredients are known to be human carcinogens.
鈾? Silica, quartz (Silica, crystalline) 14808-60-7
鈾? Vinyl chloride 75-01-4
The following ingredients are reasonably anticipated to be human carcinogens.
鈾? Furan 110-00-9
鈾? Propylene oxide 75-56-9
鈾? Acetaldehyde 75-07-0
Ingredients listed on International Agency for Research on Cancer (IARC) Monographs
The following ingredient is listed as Group 1.
Group 1 is defined as: The agent (mixture) is carcinogenic to humans.
鈾? Silica, quartz 14808-60-7
鈾? Vinyl chloride 75-01-4
The following ingredients are listed as Group 2B.
Group 2B is defined as: The agent is possibly carcinogenic to humans.
鈾? Ethyl benzene 100-41-4
鈾? Furan 110-00-9
鈾? Propylene oxide 75-56-9
鈾? Acetaldehyde 75-07-0
The following ingredients are listed as Group 3.
Group 3 is defined as: The agent (mixture or exposure circumstances) is not classifiable as to its
carcinogenicity to humans.
鈾? Butyl benzyl phthalate 85-68-7
鈾? Polyvinyl chloride (PVC) 9002-86-2
鈾? Titanium dioxide 13463-67-7
鈾? Xylene 1330-20-7
鈾? Diphenylmethane diisocyanate (MDI) 101-68-8
Toxic Substance Control Act (TSCA)
TSCA Status: All chemical substances found in this product comply with the Toxic Substances Control
Act inventory reporting requirements.
Superfund Amendments and Reauthorization Act (SARA) Title III
- Section 302/304
These sections require emergency planning based on Threshold Planning Quantities (TPQs) and
release reporting based on Reportable Quantities (RQs) of 鈥淓xtremely Hazardous Substances鈥?
(EHS) listed in Appendix A of 40 CFR 355.
Chemical CAS No. Wt% RQ (lbs) TPQ (lbs)
Furan 110-00-9 < 0.0006 100 500
Propylene oxide 75-56-9 < 0.0002 100 10,000
Section 311/312
-
These sections require Tier I/Tier II - Emergency and hazardous chemical inventory form.
Minimum thresholds have been established for Tier One/Tier Two reporting under Title III,
Section 312. These thresholds are as follows:
For Extremely Hazardous Substances (EHSs) designated under Section 302 of Title III, the
reporting threshold is 500 pounds (or 227 kg.) or the threshold planning quantity (TPQ),
whichever is lower. For all other hazardous chemicals for which facilities are required to have or
prepare an MSDS, the minimum reporting threshold is 10,000 pounds (or 4,540 kg.).
Section 312 Hazard Class:
Acute: Yes
Chronic: No
Fire: No
Pressure: No
Reactive: No
Section 313
-
This product contains the following toxic chemicals subject to the reporting requirements of Section
313 of the Emergency Planning and Community Right to Know Act:
Chemical CAS No. Wt% Threshold Reporting %
Xylene 1330-20-7 1-5 1.0
Comprehensive Environmental Response, Compensation and Liability Act (CERCLA)
Releases of CERCLA hazardous substances, in quantities equal to or greater than their reportable
quantity (RQ), are subject to reporting to the National Response Center under CERCLA. Such
releases are also subject to state and local regulations under Section 304 of SARA Title III (EPCRA).
This material contains the following components and RQs on the CERCLA hazardous substance list.
Chemical CAS No. Wt% Reportable Quantity (RQ) in pounds
Butyl benzyl phthalate 85-68-7 15-40 100
Xylene 1330-20-7 1-5 100
MDI 101-68-8 0.5-1.5 5,000
Ethyl benzene 100-41-4 0.1-1.0 1,000
Chlorobenzene 108-90-7 < 0.01 100
Vinyl chloride 75-01-4 < 0.002 1
Furan 110-00-9 < 0.0006 100
Propylene oxide 75-56-9 < 0.0002 100
Acetaldehyde 75-07-0 < 0.00005 1,000
US STATE REGULATIONS:
California
California Safe Drinking Water and Toxic Enforcement Act 鈥? Proposition 65
This product contains the following chemical currently listed under California Proposition 65.
Chemical CAS No. Source List Designations
Vinyl chloride 75-01-4 Cancer
Furan 110-00-9 Cancer
Propylene oxide 75-56-9 Cancer
Acetaldehyde 75-07-0 Cancer
Volatile Organic Content (VOC)
Wt% g/L lbs/gal
3.53 45 0.38
This product does comply with the California Air Resources Board maximum for VOCs in a sealant.
Per the California Air Resources Board TITLE 17 Division 3 Chapter 1 Subchapter 8.5 Article 2
搂94508, a VOC is a substance with a vapor pressure greater than or equal to 0.1 mmHg at 20掳C
(68掳F), or is a chemical compound with less than or equal to 12 carbon atoms if the vapor pressure
is not known, or is a chemical compound with a boiling point less than or equal to 216掳C (421掳F).
State Right-to-Know Regulations
States within the US that have promulgated State Right-to-Know regulations with chemical listing
requirements including the chemicals in this product are provided below.
Chemical CAS No. Wt% States
Butyl benzyl phthalate 85-68-7 15-40 Delaware, Massachusetts, Michigan,
New Jersey, New York, Pennsylvania
Polyvinyl chloride 9002-86-2 10-30 New Jersey
Precipitated calcium carbonate 471-34-1 5-10 Minnesota
Calcium carbonate 1317-65-3 3-7 Massachusetts, Minnesota,
Pennsylvania, Washington
Calcium oxide 1305-78-8 1-5 Florida, Massachusetts, Minnesota,
Pennsylvania, Washington
Titanium dioxide 13463-67-7 1-5 Massachusetts, Minnesota, New Jersey,
Pennsylvania, Washington
Xylene 1330-20-7 1-5 Delaware, Florida, Massachusetts, Michigan,
Minnesota, New Jersey, New York,
Pennsylvania, Washington
MDI 101-68-8 0.5-1.5 Delaware, Florida, Massachusetts,
Minnesota, New Jersey, New York,
Pennsylvania, Washington
Ethyl benzene 100-41-4 0.1-1.0 Delaware, Florida, Massachusetts,
Minnesota, New Jersey, New York,
Pennsylvania, Washington
Silica, quartz 14808-60-7 < 0.1 Florida, Massachusetts, Minnesota, New
Jersey, Pennsylvania, Washington
Toluenesulfonyl chloride 98-59-9 < 0.01 Minnesota
Chlorobenzene 108-90-7 < 0.01 Delaware, Florida, Massachusetts, Michigan,
Minnesota, New Jersey, New York,
Pennsylvania, Washington
Stannous 2-ethylhexanoate 301-10-0 < 0.003 Massachusetts
Vinyl chloride 75-01-4 < 0.002 Delaware, Florida, Massachusetts, Michigan,
Minnesota, New Jersey, New York,
Pennsylvania, Washington
Furan 110-00-9 < 0.0006 Delaware, Florida, Massachusetts, New
Jersey, New York, Pennsylvania
Propylene oxide 75-56-9 < 0.0002 Delaware, Florida, Massachusetts,
Minnesota, New Jersey, New York,
Pennsylvania, Washington
Acetaldehyde 75-07-0< 0.00005Delaware, Florida, Massachusetts,
Minnesota, New Jersey, New York,
Pennsylvania, Washington
INTERNATIONAL:
Canada
This product has been classified according to the hazard criteria of the CPR and the MSDS contains
all the information required by the CPR.
Canadian DSL
All ingredients in this product are currently listed on the Canadian Domestic Substances List (DSL)
except the non-hazardous polyurethane prepolymer and dimorpholine ethane, which are both on the
NDSL. (Based upon the concentration of the prepolymer in the formulation, it would require over
128,000 10.1 fl.oz. cartridges of Low VOC 25 to reach the 10,000 kg yearly limit for an NDSL
polymer approved under Schedule VI before reporting is required. This is equal to approximately 49
200-Gal batches of Low VOC 25. There is also a cumulative limit of 50,000 kg that can take many
years to reach, assuming no one year exceeds the 10,000 kg limit. The dimorpholine ethane is in
such small quantities that it would require millions of cartridges to reach the yearly limit.) The
substances that are on the DSL would not be considered new for the purposes of the Canadian
Environmental Protection Act (CEPA).
Note:
The recipient of this product should be aware of the possible existence of additional local
regulations, which may be applicable to this product.
SECTION XVI 鈥? OTHER INFORMATION
HMIS-III: Health 鈥? 0 = No significant health risk
1 = Irritation or minor reversible injury possible
2 = Temporary or minor injury possible
3 = Major injury possible unless prompt action is taken
4 = Life threatening, major or permanent damage possible
Flammability- 0 = Material will not burn
1 = Material must be preheated before ignition will occur
2 = Material must be exposed to high temperatures before ignition
3 = Material capable of ignition under normal temperatures
4 = Flammable gases or very volatile liquids; may ignite spontaneously
Physical Hazard- 0 = Material is normally stable, even under fire conditions
1 = Material normally stable but may become unstable at high temps
2 = Materials that are unstable and may undergo react at room temp
3 = Materials that may form explosive mixtures with water
4 = Materials that are readily capable of explosive water reaction
Abbreviations:
ACGIH American Conference of Government Industrial Hygienists
CAS Chemical Abstract Service
CERCLA Comprehensive Environmental Response, Compensation & Liability Act
CFR Code of Federal Regulations
CPR Controlled Products Regulations (Canada)
DOT Department of Transportation
IARC International Agency for Research
MSHA Mine Safety and Health Administration
NIOSH National Institute for Occupational Safety and Health
NTP National Toxicity Program
OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
RCRA Resource Conservation and Recovery Act
SARA Superfund Amendments and Reauthorization Act
TLV Threshold Limit Value
TWA Time-weighted Average
WHMIS Workplace Hazardous Material Information System
Revision #07-01, supersedes all previous revisions
Created: 11/30/2006
Last Updated: February 7, 2007
NOTE: The information and recommendations contained herein are based upon data believed to
be correct. However, no guarantee or warranty of any kind, express or implied, is made with
respect to the information contained herein. We accept no responsibility and disclaim all liability for
any harmful effects which may be caused by exposure to silica contained in our products.
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