MATERIAL SAFETY DATA SHEET
ND
#1700, 407 2 STREET S.W., CALGARY, ALBERTA T2P 2Y3
TELEPHONE: (403) 269-2242 FAX: (403) 269-2251
1-613-996-6666 鈥? CANUTEC 鈥? Transportation Emergency
1-888-243-9771 鈥? ChExSS 鈥? Chemical Exposure
TDL 13
SECTION I: IDENTIFICATION OF PRODUCT
Workplace Hazard: Flammable, Toxic, Corrosive
Product Name: TDL 13
Product Use: Corrosion Inhibitor
Chemical Family: Mixture of aromatic hydrocarbons,
TDG Classification: Class 3.0
oxygenated aliphatic hydrocarbons, Petroleum Naphtha
Packaging Group: II
and amine compounds
PIN: UN 1993
WHMIS Classification: B2, D1B, D-2A, E
SECTION II: HAZARDOUS INGREDIENTS
Ingredients Percent CAS Number LD50 (Rat/Oral) LC50 (Rat/Inh)
Heavy Naphtha 15-40 64741-68-2 4300-4800 mg/kg 6700 ppm
Isopropanol 10-30 67-63-0 4420-5840 mg/kg 12000 ppm
Xylene 10-30 1330-20-7 4300 mg/kg 5000-6700 ppm
N-Coco Alkyl-Trimethylene 1-5 61791-63-7 272 mg/kg >2000 ppm (Rat/Dermal)
Diamine
Benzene Trace 71-43-2 - -
SECTION III: TOXICOLOGICAL PROPERTIES
Route of entry: Skin Eye Contact Inhalation Ingestion
Effects of acute exposure: Respiratory and digestive tract irritant. Pre-exsiting eye, skin and respiratory disorders may be
aggravated by exposure to this product. May cause nausea, dizziness, headache. Aspiration of fluid into lungs may cause
chemical pneumonitis. Aspiration caused death in rats. Possible CNS disturbance, narcotic effect. Possible allergic reaction.
Prolonged or repeated skin contact can cause defatting and drying of the skin resulting in irritation and dermatitis.
Effects of chronic exposure: Central nervous system depression, hearing loss, cardiac arrhythmia, liver damage and kidney
damage.
Exposure limits: Isopropanol 200 ppm ACGIH (TVL), Xylene 100 ppm ACGIH (TVL)
Irritancy of product: May cause corneal injury, moderate skin irritant.
Sensitization to product: Corrosive effects on the skin and eyes may be delayed, and damage may occur without the sensation or
onset of pain.
Carcinogenicity: Contains Benzene, cofirmed human carcinogen.
Reproductive toxicity: Not applicable
Teratogenicity: Excessive exposure to Xylene during pregnancy may be hazardous to the developing fetus.
Mutagenicity: Not applicable
Name of toxicological synergistic products: Alcohols may interact with chlorinated solvents, dithiocarbamates,
dimethylnitosamine and thioacetamide.
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TDL 13
SECTION IV: FIRST AID MEASURES
Skin contact: Prompt removal of the material from the skin is essential . Remove all contaminated clothing and immediately
wash the exposed areas with copious amounts of water for a minium of 30 minutes or up to 60 minutes for critical body areas.
Obtain medical attention IMMEDIATELY.
Eye contact: Immediately flush eyes with running water for a minium of 30 minutes, preferrably up to 60 minutes. Hold eyelids
open during flushing. If irritation persists, repeat flushing. Do not transport victim until the recommended flushing period is
completed unless flushing can be continued during transport.
Inhalation: Move victim to fresh air. Give artificail respiration ONLY if breathing has stopped. Give cardiopulmonary
resuscitation (CPR) if there is no breathing AND no pulse. Oxygen administration may be benificial in this situation but should
only be administered by personnel trained in its use. Obtain medical attention IMMEDIATELY.
Ingestion: Do not attempt to give anything by mouth to an unconscious person. IMMEDIALTELY contact local Poison Control
Centre. If victim is alert and not convulsing rinse mouth out and give 1 to 2 glasses of milk. Water may be used if milk is not
available but it is not as effective. If spontaneous vomiting occurs, have victim lean forward with head down to avoid breathing
in of vomitus, rinse mouth and administer more milk or water. IMMEDIATELY transport victim to an emergancy facility.
Note to Physicians: This product contains materials that may cause severe pneumonitis if aspirated. If ingestion has occurred less
than 2 hours earlier, carry out careful gastric lavage; use endotracheal cuff if available, to prevent aspiration. Observe patient for
respiratory difficulty from aspiration pneumonitis. Give artificial resuscitation and appropriate chemotherapy if respiration is
depressed. Isopropanol: Metabolism of isopropanol forms acetone, which may be detected in the urine and expired air. In
contrast to diabetic acidosis, acidosos will occur in the absence of hyperglycemia. Haemodialysis should be considered in severe,
acute intoxications. Xylene: Vasopressor drugs (e.g. epinephrine, ephedrine etc.) should not be given on their own as there may
be danger of cardiac arrhythmia. Medical conditions that may be aggravated by exposure to this product include neurological and
cardiovascular disorders, diseases of the skin, eyes or respiratory tract, preexisting liver and kidney disorders.
SECTION V: PHYSICAL DATA
Physical state: Liquid
Appearance and odour: Aromatic odor, dark red liquid.
Odour threshold: Not available
Specific gravity: 0.860 to 0.880
Vapor pressure (mmHG): Not available
Vapor density (Air=1): Not available
Evaporation rate: Not available
Boiling point (潞C): Above 82
Freeze/Melting point (潞C): -35
pH: 6.4 (1% IPA/Water 50/50 v/v).
Co-efficient of water/oil distribution: Not available
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TDL 13
SECTION VI: FIRE AND EXPLOSION DATA
Conditions of flammability: Heat, sparks, open flame; may be susceptible to spontaneous healting.
Means of extinguishing: CO2, Dry Chemical, Foam, Water Fog
Flash point: 11-12掳C Estimated
Upper flammable limit: 12% Estimated
Lower flammable limit: 1% Estimated
Auto-ignition temperature: 399掳C Estimated
Hazardous combustion products: Ammonia, oxides of carbon, nitrogen, irritating gases
Explosion data-sensitivity to mechanical impact: Probable.
Explosion data-sensitivity to static discharge: Probable.
SECTION VII: REACTIVITY DATA
Chemically unstable (conditions): Stable.
Product incompatible with: Strong oxidizers. Lewis or mineral acids. Activated carbon. Caustics. Alkali metals and their
hydroxides. Halogens. Aldehydes. Aluminum and its alloys. Attacks some types of rubber, plastic and coatings.
Conditions of reactivity: High temperature, sparks, open flames and all other sources of ignition.
Hazardous decomposition products: Ammonia, oxides of carbon, nitrogen, irritating gases upon combustion.
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SECTION VIII: PREVENTATIVE MEASURES
Personal protective equipment: NIOSH approved Cartridge/Canister; Organic Vapours. Chemical goggles must be worn at all
times when handling product. If there is a possibility of splashing, wear protective face shield. If vapours irritate eyes, wear full
face respirator. Chemical resistant protective clothing made from neoprene nitrile rubber, polyvinyl alcohol (PVA) or viton must
be worn at all times when handling product. Wash thoroughly or dispose of any contaminated clothing.
Specific engineering controls: Local exhaust ventialtion required. Ventilation should be corrosion and explosion proof. Make
up air should be supplied to balance air that is removed by local or general exhaust ventilation. Ventilate low lying areas such as
sumps or pits where dense vapours may collect. For personnel entry into confined spaces (i.e. bulk storage tanks) a proper
procedure must be followed. It must include consideration of, among other things, ventialtion, testing of tank atmosphere,
provision and maintenance of SCBA , and emergency recue.
Procedures for leak/spills: Avoid all bodily contact. Absorb marterial on appropriate absorbent and shovel into compatible
salvage containers. Appropriate breathing apparatus must be worn if ventilation is inadequate. Do not allow product to enter
sewers or storm water inlets.
Waste disposal: It is the responsilbility of the user of this product to determine at the time of disposal whether product meets
criteria for hazardous waste. This is because product uses, transformations, processes mixtures, etc., may render a nonhazardous
marterial hazardous, or a hazardous material nonhazardous. Empty container retains product residue. Containers must be triple
rinsed before disposal or reuse. Observe all hazard precautions. Keep away from heat, sparks and flames. Do not weld or use a
cutting torch on or near container. Do not distribute, make available, furnish or reuse empty container except for storage and
shipment of original product. Remove all hazardous product residue and punture or otherwise destroy empty container before
disposal.
Handling procedures and equipment: Ground and bond equipment and containers to prevent a static charge buildup. Use
spark-resistant tools and avoid "splash-filling" of containers. Use normal "good" industrial hygiene and houskeeping practices.
Drums which have been exposed to heat may be under internal pressure. These should be cooled and carefully vented before
opening. A face shield and apron should be worn. Vent container frequently, and more often in warm weather, to relieve
pressure. Enforce NO SMOKING rules in area of use.
Storage requirements: Store in a cool, well ventilated area. Keep away from heat, sparks and flames. Keep containers closed.
Do not expose sealed containers to temperatures above 40掳 C. Protect from direct sunlight. Protect against physical damage.
Special shipping information: Use steel. At elevated temperatures aluminum and it alloys should not be used in equipment for
storage, handling or transportation. Attacks some types of rubber, plastics and coatings. Confim suitability of any material before
using.
SECTION IX: PREPARATION
Date updated: February 7, 2008 Prepared by: Product Safety Committee
All the recommendations and suggestions herein concerning this product are based upon tests and data believed to be reliable,
however it is the user鈥檚 responsibility to determine the safety, toxicity and sustainability for their own use of the product described
herein. Since the actual use by others is beyond our control, no guarantee, expressed or implied, is made by Q鈥橫ax Solutions Inc.
as to the effects of such use, the results to be obtained, or the safety and toxicity of the product nor does Q鈥橫ax Solutions Inc.
assume any liability arising out of use by others. Nor is the information herein to be considered as absolutely complete since
additional information may be necessary or desirable when particular or exceptional conditions or circumstances exist or because
of applicable laws or government regulations.
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