MATERIAL SAFETY DATA SHEET
#1700, 407 2ND STREET S.W., CALGARY, ALBERTA T2P 2Y3
TELEPHONE: (403) 269-2242 FAX: (403) 269-2251
1-613-996-6666 鈥? CANUTEC 鈥? Transportation Emergency
1-888-243-9771 鈥? ChExSS 鈥? Chemical Exposure
TDL 33
SECTION I: IDENTIFICATION OF PRODUCT
Product Use: Antifoam agent
Product Name: TDL 33
TDG Classification: Class 3
Chemical Family: Alcohol blend
Packaging Group: II
WHMIS Classification: B2; E
PIN: UN 1993
Workplace Hazard: flammable liquid, Corrosive
SECTION II: HAZARDOUS INGREDIENTS
Ingredients Percent CAS Number LD50 (Rat/Oral) LC50 (Rat/Inhalation)
14,000 mg/m3
Trialkyl Phosphates- 40-70 - 3000 mg/kg
22,600 mg/ m3
Isopropanol Alcohol 10-30 67-63-0 4420-5840 mg/kg
SECTION III: TOXICOLOGICAL PROPERTIES
Route of entry: Skin Eye Contact Inhalation Ingestion
Effects of acute exposure: Irritant to eyes, nose and throat. Will cause chemical burn when contacted with skin.
Effects of chronic exposure: Not applicable
Exposure limits: Isopropanol 鈥? ACGIH 500 ppm TLV
Irritancy of product: Skin and Eye Irritant
Sensitization to product: Not applicable
Carcinogenicity: Not carcinogenic
Reproductive toxicity: No adverse effects anticipated
Teratogenicity: No adverse teratogenic effects are anticipated
Mutagenicity: No adverse mutagenic effects are anticipated.
Name of toxicological synergistic products: None known
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TDL 33
SECTION IV: FIRST AID MEASURES
Skin contact: Wash affected area with soap and water for at least 60 minutes. Remove and clean contaminated clothing. Seek
medical attention if irritation develops or persists.
Eye contact: Flush with water immediately for at least 20 minutes by holding eye open while flushing. Seek immediate medical
attention.
Inhalation: Remove victim from area to fresh air. Apply artificial respiration if breathing has stopped. If difficulty breathing,
administer oxygen. Seek immediate medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Give water. If vomiting occurs spontaneously have victim
lean forward with head down to avoid aspiration of vomitus.
SECTION V: PHYSICAL DATA
Physical state: Liquid
Appearance and odour: Clear purple liquid, sweet odour.
Odour threshold: Not available
Specific gravity: 0.9521
Vapor pressure (mmHG): Not available
Vapor density (Air=1): Not available
Evaporation rate: Not available
Boiling point (潞C): 82
Freeze/Melting point (潞C): -35
pH:5.9 (1% Aqueous solution)
Co-efficient of water/oil distribution: Not available
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TDL 33
SECTION VI: FIRE AND EXPLOSION DATA
Conditions of flammability: Heat, sparks, open flame
Means of extinguishing: CO2 X Dry Chemical X Foam X Water Fog X Other
Flash point: 12掳C
Upper flammable limit: 12%
Lower flammable limit: 2.0%
Auto-ignition temperature: 399 掳C (Isopropanol)
Hazardous combustion products: Oxides of carbon, phosphorus and irritating gases
Explosion data-sensitivity to mechanical impact: Not Expected
Explosion data-sensitivity to static discharge: Expected when vapours are present between flammability limits
SECTION VII: REACTIVITY DATA
Chemically unstable (conditions): Stable.
Product incompatible with: Strong oxidizers. Lewis or mineral acids. Strong bases. Reducing agents. Mixtures or reactions of
alcohols with the following materials may cause explosions: barium perchlorate, chlorine, hypochlorous acid, ethylene oxide,
hexamethylene diisocyanate and ether isocyanates, nitrogen tetroxide, permonosulfuric acid and tri-isobutyl aluminium.
Conditions of reactivity: Heat, sparks, open flame.
Hazardous decomposition products: Thermal decomposition products are toxic and may include oxides of carbon and irritating
gases.
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SECTION VIII: PREVENTATIVE MEASURES
Personal protective equipment: Chemical goggles must be worn at all times when handling product. If there is a possibility of
splashing, wear protective face shield. If vapours irritate eyes, wear full face respirator. Gloves and protective clothing made
from neoprene should be impervious under conditions of use. User should confirm impermeability prior to use. Wash thoroughly
or dispose of any contaminated clothing. Use of a NIOSH approved respirator with organic vapour cartridge highly
recommended.
Specific engineering controls: Local exhaust ventilation is recommended for controlled products. The use of mechanical
ventilation is recommended whenever this product is used in a confined space or when air circulation is inadequate. If product is
flammable/combustible, all equipment should be explosion proof.
Procedures for leak/spills: Avoid all bodily contact. Absorb material on appropriate absorbent and shovel into compatible
salvage containers. Appropriate breathing apparatus must be worn if ventilation is inadequate. Do not allow product to enter
sewers or stormwater inlets.
Waste disposal: It is the responsibility of the user of this product to determine at the time of disposal whether product meets
criteria for hazardous waste. This is because product uses, transformations, processes, mixtures, etc., may render a nonhazardous
material hazardous, or a hazardous material nonhazardous.
Handling procedures and equipment: Avoid inhalation of vapours/mists. Do not get on skin, in eyes or on clothing. Keep
container closed when not in use. Wear suitable protection for eyes and skin when handling. Use with adequate ventilation.
Avoid contact with incompatible materials. such as aluminium. Ground all equipment when transfering.
Storage requirements: Store in cool, dry, well ventilated area away from sources of heat, ignition, and sparks. Use proper
grounding techniques if product is classed as flammable or combustible. Eye wash and safety showers should be easily accessible
and in proper operating order.
Special shipping information: Note - Storage and Handling Precautions. Refer to Fire and Explosion Hazard for data on
flammability / combustibility of product. Do not ship with foodstuffs, feed or clothing.
SECTION IX: PREPARATION
Date updated: July, 2005 Prepared by: Product Safety Committee
All the recommendations and suggestions herein concerning this product are based upon tests and data believed to be reliable,
however it is the user鈥檚 responsibility to determine the safety, toxicity and sustainability for their own use of the product described
herein. Since the actual use by others is beyond our control, no guarantee, expressed or implied, is made by Q鈥橫ax Solutions Inc.
as to the effects of such use, the results to be obtained, or the safety and toxicity of the product nor does Q鈥橫ax Solutions Inc.
assume any liability arising out of use by others. Nor is the information herein to be considered as absolutely complete since
additional information may be necessary or desirable when particular or exceptional conditions or circumstances exist or because
of applicable laws or government regulations.
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